MX2014013647A - Proceso y catalizador para mejorar gasolina. - Google Patents

Proceso y catalizador para mejorar gasolina.

Info

Publication number
MX2014013647A
MX2014013647A MX2014013647A MX2014013647A MX2014013647A MX 2014013647 A MX2014013647 A MX 2014013647A MX 2014013647 A MX2014013647 A MX 2014013647A MX 2014013647 A MX2014013647 A MX 2014013647A MX 2014013647 A MX2014013647 A MX 2014013647A
Authority
MX
Mexico
Prior art keywords
tetramethylbenzene
catalyst
durene
trimethylbenzene
gasoline
Prior art date
Application number
MX2014013647A
Other languages
English (en)
Other versions
MX359965B (es
Inventor
Vivas Angélica Hidalgo
Finn Joensen
Original Assignee
Haldor Topsoe As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe As filed Critical Haldor Topsoe As
Publication of MX2014013647A publication Critical patent/MX2014013647A/es
Publication of MX359965B publication Critical patent/MX359965B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/043—Sulfides with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732—Catalytic processes
    • C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/46—Iron group metals or copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un proceso y catalizador para mejorar la gasolina que comprende dureno (1,2,4,5-tetrametilbenceno) y pseudocumeno, el proceso comprende la hidroisomerización de dureno (1,2,4,5-tetrametilbence no) y pseudocumeno (1,2,4-trimetilbenceno) contenidos en la gasolina en presencia de un catalizador que comprende un metal base sulfurado que es soportado sobre un portador ácido, convirtiendo de ese modo el dureno (1,2,4,5-tetrametilbenceno) a isodureno (1,2,4,5-tetrametilbenceno) y prehniteno (1,2,3,4-tetrametilbenceno) y convirtiendo el pseudocumeno (1,2,4-trimetilbenceno) a mesitileno (1,3,5-trimetilbenceno).
MX2014013647A 2012-05-29 2013-03-20 Proceso y catalizador para mejorar gasolina. MX359965B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201270284 2012-05-29
PCT/EP2013/055758 WO2013178375A1 (en) 2012-05-29 2013-03-20 Process and catalyst for upgrading gasoline

Publications (2)

Publication Number Publication Date
MX2014013647A true MX2014013647A (es) 2015-02-05
MX359965B MX359965B (es) 2018-10-18

Family

ID=47901124

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014013647A MX359965B (es) 2012-05-29 2013-03-20 Proceso y catalizador para mejorar gasolina.

Country Status (10)

Country Link
US (1) US10150714B2 (es)
CN (1) CN104334693B (es)
AR (1) AR091162A1 (es)
AU (1) AU2013269955B2 (es)
BR (1) BR112014029831A2 (es)
CA (1) CA2873955C (es)
EA (1) EA030888B1 (es)
MX (1) MX359965B (es)
WO (1) WO2013178375A1 (es)
ZA (1) ZA201408987B (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103864814B (zh) * 2014-02-24 2016-06-22 中国海洋石油总公司 一种由甲醇制汽油合成油中制备均苯四甲酐的方法
CN104498112B (zh) * 2014-12-25 2016-07-06 山西华顿实业有限公司 M85甲醇汽油复合添加剂
WO2016174145A1 (en) * 2015-04-28 2016-11-03 Haldor Topsøe A/S Heavy gasoline separation
AU2021253443A1 (en) 2020-04-06 2022-10-13 Topsoe A/S Selective production of light synthetic gasoline
WO2022117644A1 (en) 2020-12-01 2022-06-09 Topsoe A/S Selective and flexible production of synthetic gasoline

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3269937A (en) * 1962-12-26 1966-08-30 Shell Oil Co Hydroisomerization process
US3776968A (en) 1968-08-05 1973-12-04 Sun Oil Co Catalytic conversion of polycyclic aromatic hydrocarbons in the pres-ence of hydrogen
US3562342A (en) * 1968-11-27 1971-02-09 Texaco Inc Isomerization of alkyl aromatics
US3619408A (en) * 1969-09-19 1971-11-09 Phillips Petroleum Co Hydroisomerization of motor fuel stocks
US3912659A (en) * 1972-05-15 1975-10-14 Texaco Inc Catalyst for conversion of alkylaromatics
DE2225655A1 (de) 1972-05-26 1973-12-06 Kali Chemie Ag Verfahren zur herstellung eines nickeltraegerkatalysators
US4127471A (en) * 1977-07-28 1978-11-28 Texaco Inc. Hydrocracking alkylaromatic-containing hydrocarbons at mild cracking conditions and then subjecting the alkylaromatic hydrocarbon to alkyl transfer
US4384471A (en) * 1980-12-10 1983-05-24 Engelhard Minerals & Chemicals Corporation Chromatographic analysis of hydrocarbon mixtures
US4304951A (en) * 1981-01-14 1981-12-08 Mobil Oil Corporation Hydrotreating of bottoms fractions resulting from conversion of methanol to gasoline in order to decrease durene and produce distillate
US4387261A (en) * 1982-04-09 1983-06-07 Mobil Oil Corporation Treatment of effluent resulting from conversion of methanol to gasoline in order to decrease durene and produce distillate
US4508836A (en) * 1982-07-27 1985-04-02 Mobil Oil Corporation Catalytic conversion process for aromatic feedstocks with hydrogen regeneration of coke-selectivated zeolite catalyst
US5004854A (en) 1986-12-04 1991-04-02 Mobil Oil Corp. Pseudocumene and mesitylene production and coproduction thereof with xylene
US5576256A (en) * 1994-05-23 1996-11-19 Intevep, S.A. Hydroprocessing scheme for production of premium isomerized light gasoline
CN102131579A (zh) * 2008-07-25 2011-07-20 科诺科飞利浦公司 将含氧物料转化成高辛烷值汽油的改进方法
AU2009291276B2 (en) * 2008-09-10 2014-01-30 Haldor Topsoe A/S Hydroconversion process and catalyst
US8686206B2 (en) * 2010-11-09 2014-04-01 Primus Green Energy Inc. Single loop multistage fuel production

Also Published As

Publication number Publication date
AR091162A1 (es) 2015-01-14
AU2013269955B2 (en) 2017-12-07
EA030888B1 (ru) 2018-10-31
CN104334693B (zh) 2016-06-29
MX359965B (es) 2018-10-18
CA2873955A1 (en) 2013-12-05
AU2013269955A1 (en) 2014-12-18
ZA201408987B (en) 2017-05-31
EA201492151A1 (ru) 2015-09-30
US10150714B2 (en) 2018-12-11
CN104334693A (zh) 2015-02-04
BR112014029831A2 (pt) 2017-06-27
CA2873955C (en) 2020-12-29
US20150094510A1 (en) 2015-04-02
WO2013178375A1 (en) 2013-12-05

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