MX2013012539A - Destilacion por extraccion de producto de alcohol crudo. - Google Patents

Destilacion por extraccion de producto de alcohol crudo.

Info

Publication number
MX2013012539A
MX2013012539A MX2013012539A MX2013012539A MX2013012539A MX 2013012539 A MX2013012539 A MX 2013012539A MX 2013012539 A MX2013012539 A MX 2013012539A MX 2013012539 A MX2013012539 A MX 2013012539A MX 2013012539 A MX2013012539 A MX 2013012539A
Authority
MX
Mexico
Prior art keywords
ethanol
extractive distillation
column
crude ethanol
distillate
Prior art date
Application number
MX2013012539A
Other languages
English (en)
Inventor
R Jay Warner
Victor J Johnston
David Lee
Adam Orosco
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/094,588 external-priority patent/US8686200B2/en
Priority claimed from US13/162,034 external-priority patent/US8748675B2/en
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of MX2013012539A publication Critical patent/MX2013012539A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C07C29/84—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by extractive distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

La recuperación de etanol de un producto de etanol crudo obtenido de la hidrogenación de ácido acético utilizando una columna de destilación por extracción; la columna produce un primer residuo que comprende etanol, acetato de etilo, ácido acético, agua y el(los) agente(s) de extracción; el primer residuo se separa en una segunda columna para producir un segundo destilado que comprende etanol y acetato de etilo, el segundo destilado entonces se separa en una tercera columna para producir un tercer destilado que comprende acetato de etilo y un tercer residuo que comprende etanol.
MX2013012539A 2011-04-26 2012-04-26 Destilacion por extraccion de producto de alcohol crudo. MX2013012539A (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13/094,588 US8686200B2 (en) 2011-04-26 2011-04-26 Process to recover alcohol from an acidic residue stream
US13/162,034 US8748675B2 (en) 2011-06-16 2011-06-16 Extractive distillation of crude alcohol product
US201161566442P 2011-12-02 2011-12-02
PCT/US2012/035196 WO2012149148A1 (en) 2011-04-26 2012-04-26 Extractive distillation of crude ethanol

Publications (1)

Publication Number Publication Date
MX2013012539A true MX2013012539A (es) 2013-12-02

Family

ID=46052884

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013012539A MX2013012539A (es) 2011-04-26 2012-04-26 Destilacion por extraccion de producto de alcohol crudo.

Country Status (7)

Country Link
EP (1) EP2702026A1 (es)
CN (1) CN103270010B (es)
AR (1) AR086129A1 (es)
BR (1) BR112013027348A2 (es)
MX (1) MX2013012539A (es)
TW (1) TW201247301A (es)
WO (1) WO2012149148A1 (es)

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4379028A (en) 1982-03-30 1983-04-05 Lloyd Berg Separation of ethyl acetate from ethanol and water by extractive distillation
US5001259A (en) 1984-05-03 1991-03-19 Hoechst Celanese Corporation Methanol carbonylation process
US5026908A (en) 1984-05-03 1991-06-25 Hoechst Celanese Corporation Methanol carbonylation process
US5144068A (en) 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
US4569726A (en) 1984-07-19 1986-02-11 Lloyd Berg Process for the separation of ethyl acetate from ethanol and water by extractive distillation
US4615806B1 (en) 1985-03-07 1994-05-03 Hoechst Co American Removal of iodide compounds from non-aqueous organic media
US4654123A (en) 1985-07-08 1987-03-31 Lloyd Berg Dehydration of ethanol by extractive distillation
CA1299195C (en) 1986-06-16 1992-04-21 G. Paull Torrence Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol
US5139981A (en) 1987-06-24 1992-08-18 Union Carbide Chemicals & Plastics Technology Corporation Process for preparing silver(I)-exchanged resins
US5821111A (en) 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
US5599976A (en) 1995-04-07 1997-02-04 Hoechst Celanese Corporation Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process
IN192600B (es) 1996-10-18 2004-05-08 Hoechst Celanese Corp
US5993610A (en) 1998-05-04 1999-11-30 Berg; Lloyd Separation of ethyl acetate from ethanol by azeotropic distillation
US6375807B1 (en) 1999-01-28 2002-04-23 Izak Nieuwoudt Separation of ethanol mixtures by extractive distillation
PL203207B1 (pl) 1999-03-11 2009-09-30 Zeachem Inc Sposób wytwarzania etanolu
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
US6627770B1 (en) 2000-08-24 2003-09-30 Celanese International Corporation Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process
US6657078B2 (en) 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
US7115772B2 (en) 2002-01-11 2006-10-03 Celanese International Corporation Integrated process for producing carbonylation acetic acid, acetic anhydride, or coproduction of each from a methyl acetate by-product stream
US7005541B2 (en) 2002-12-23 2006-02-28 Celanese International Corporation Low water methanol carbonylation process for high acetic acid production and for water balance control
US7208624B2 (en) 2004-03-02 2007-04-24 Celanese International Corporation Process for producing acetic acid
EP1741692A1 (en) 2005-07-06 2007-01-10 BP Chemicals Limited Process for the conversion of hydrocarbons to C2-oxygenates
EP2121946A4 (en) 2007-02-09 2012-08-29 Zeachem Inc ENERGY-EFFICIENT METHOD FOR MANUFACTURING PRODUCTS
US7923405B2 (en) 2007-09-07 2011-04-12 Range Fuels, Inc. Cobalt-molybdenum sulfide catalyst materials and methods for ethanol production from syngas
EP2060553A1 (en) 2007-11-14 2009-05-20 BP p.l.c. Process for the conversion of hydrocarbons into alcohol
BRPI0908303A2 (pt) 2008-05-07 2015-08-18 Zeachem Inc Recuperação de ácidos orgânicos
US8501652B2 (en) 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US7608744B1 (en) 2008-07-31 2009-10-27 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
US7863489B2 (en) 2008-07-31 2011-01-04 Celanese International Corporation Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst
US8309772B2 (en) 2008-07-31 2012-11-13 Celanese International Corporation Tunable catalyst gas phase hydrogenation of carboxylic acids
US8546622B2 (en) * 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
US8471075B2 (en) 2008-07-31 2013-06-25 Celanese International Corporation Processes for making ethanol from acetic acid
US7588690B1 (en) 2009-02-10 2009-09-15 The Purolite Company Method of iodide removal
WO2011097220A2 (en) * 2010-02-02 2011-08-11 Celanese International Corporation Process for producing ethanol using an extractive distillation column
US8858659B2 (en) * 2010-02-02 2014-10-14 Celanese International Corporation Processes for producing denatured ethanol

Also Published As

Publication number Publication date
AR086129A1 (es) 2013-11-20
CN103270010A (zh) 2013-08-28
TW201247301A (en) 2012-12-01
EP2702026A1 (en) 2014-03-05
CN103270010B (zh) 2016-01-20
WO2012149148A1 (en) 2012-11-01
BR112013027348A2 (pt) 2017-01-17

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Legal Events

Date Code Title Description
FA Abandonment or withdrawal