MX2013009067A - Insecticidal compounds. - Google Patents

Abstract

The present invention relates to novel triazole derivatives of formula (I) having insecticidal activity, to processes and intermediates for preparing them, to insecticidal, acaricidal, nematicidal or molluscicidal compositions comprising them and to methods of using them to combat and control insect, acarine, nematode or mollusc pests wherein A¹, A², A³, A⁴, R¹, R², G¹, Q¹ and Q² are as defined in claim 1; or salts or N- oxides thereof.

Description

INSECTICIDES COMPOUNDS Description of the invention The present invention relates to novel triazole derivatives having insecticidal activity, to processes and intermediates for their preparation, to insecticidal, acaricidal, nematicidal or molluscicidal compositions comprising them and to methods for their use to combat and control insect pests, mites, nematodes or molluscs.

Accordingly, the present invention provides a compound of formula (I) where A1, A2, A3 and A4 are each independently C-X nitrogen, where each X can be the same or different; R1 is hydrogen, Ci-C4 alkyl, H2NC (0) -alkylCi-C4 alkylcarbonylCi-C4; R2 is hydrogen, halogen, Ci-C4 alkyl, haloalkyl Ci or cyano; G1 is oxygen or sulfur; X is hydrogen, halogen, cyano, C1-4alkyloxy, Ci-C4alkyl or haloCi-C4alkyl; Ref. 242760 Q1 is aryl or heterocyclyl, each optionally substituted by one to five substituents R3, which may be the same or different; or Q1 is Ci-C8 alkyl or Ci-C8 alkyl substituted by one to five 4, C2-C8 alkenyl, C2-C8 alkenyl substituted by one to five R4, C2-C8 alkynyl, C2-C8 alkynyl substituted by one to five R4, C3-Cio cycloalkyl, C3 cycloalkyl -Ci0 substituted by one to five R4 or alkylCi-C8- (CO) -N-Ci-C8 alkyl or C 1 -C 8 - (CO) -N-Ci-C 8 alkyl substituted by one to five R 4; R3 is selected from cyano, amino, nitro, hydroxy, oxo, halogen, Ci-C4 alkyl, Ci-C ^ haloalkyl, C2-C4 alkenyl, C2-C4 haloalkenyl, C2-C4 alkynyl, C2-C4 haloalkynyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C6 alkoxy, -C3, haloalkoxyC1-C3, alkylthioC-C3, haloalkylthioCi-C3, alkylsulfinylCi-C3, haloalkylsulfinylCi-C3, alkylsulfonylCi-C3, haloalkylsulfonylCi-C3, alkylaminoCi-C, di- (C1-C4alkyl) -amino, alkylcarbonylCi-Cj, alkylcarbonyloxyCi-C4, alkoxycarbonylCi-C4, alkylcarbonylaminoC1-C4 and phenyl; each R4 is independently halogen, cyano, nitro, hydroxy, C3-C3 cycloalkyl, C3-Ci0 cycloalkyl substituted by one to five R3, di (C1-C8 alkyl) amino, alkanoylaminoC-Cs, Cs-Cs alkyl, C2-C8 alkynyl, Ci-C8 alkoxy , haloalkoxyCi-C? 8, alkylthioCx-Cs, haloalkylthioCx-Cs, alkylsulfinylCi-C8, haloalkylsulfinylCi-C8, alkylsulfonylCi-C8, haloalkylsulfonylCi-C8, alkylcarbonylC; i C8, alkoxycarbonylCi-C8, aryl or aryl substituted by one to five R3, aryloxy or aryloxy substituted by one to five R3 or heterocyclyl or heterocyclyl substituted by one to five R3, - Q2 is a radical of formula (II) where R7 and R6 are independently from each other hydrogen, cyano, halogen, Ci-C6alkyl, Ci-C6haloalkyl, C1-C4alkoxyC1-C4alkyl, Ccy-C6alkylthio, haloalkylthioCi-C6, alkylsulfinylCi-C6 / haloalkylsulfinylCi-C6, alkylsulfonylCi-C6 or haloalkylsulfonylCi-C6; R5 is independently hydrogen, hydroxyl, amino, N-alkylaminoCi-Cs, N, N-di- (Ci- C6 alkyl) amino, Ci-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, alkyl! C6 substituted by one to five R9 substituents, C3-C6 cycloalkyl substituted by one to five R9 substituents, C2 alkynylC6 substituted by one to five R9 substituents, C2C6 alkenyl substituted by one to five substituents R9, aryl or aryl substituted by one to five substituents R10 , heteroaryl heteroaryl substituted by one to five R10 substituents, each R9 is independently cyano, nitro, amino, hydroxy, halogen, N-alkylCi-C6amino, N, N-di- (alkylCx-Cg) - amino, alkoxyCi-C6, alkylthioCi-C6, alkylsulfinylCi-C6, aryl or aryl which is substituted by one to five substituents which are independently selected from cyano, nitro, hydroxyl, halogen, Ci-C3 alkyl, haloalkylCx-Cg, Ci-C6 alkoxy or haloalkoxyCi-Ce, or heteroaryl or heteroaryl which is substituted by one to five substituents that are independently selected from cyano, nitro, hydroxy, halogen, Ci-Cg alkyl, Ci-C6 haloalkyl, Ci-C6 alkoxy or haloalkoxy-C6; each R10 is independently cyano, nitro, amino, hydroxy, halogen, Ci-C6alkyl, Ci-C6haloalkyl, Ci-C4alkoxyCi-C4alkyl, C2-C6alkenyl, C2-C6haloalkenyl, C2-C6alkynyl, C2-C6haloalkynyl, C3-C6cycloalkyl, haloalkylC3- C6, Ci-C6 alkoxy, Ci-C6 haloalkoxy, Ci-C4 alkoxyCi-C4 alkoxy, Ci-C6 alkylthio, Ci-C6 haloalkylthio, Ci-C6 alkylsulfinyl, Ci-C6 haloalkylsulfinyl, Ci-C6 alkylsulfonyl, Ci-C6 haloalkylsulfonyl, N-N-alkylaminoCi-C6, N, N- di- (alkylCi-C6) amino, M, W-di- (alkylCx-Cg) aminocarbonyl, N, N-di- (alkylCi-C6) aminosulfonyl, alkylcarbonylC-Cg, alkylcarbonyloxyCi-Ce, alkoxycarbonylCi-G6, alkylcarbonylaminoCi-C6; or a salt or agro-chemically acceptable N-oxides thereof.; The compounds of formula (I) can exist in various forms of geometric or optical isomers (enantiomers and / or diastereomers) or of tautomers. This invention covers all these isomers and tautomers and their mixtures in all proportions, as well as isotopic forms such as deuterated compounds.

Unless otherwise indicated, alkyl, alone or as part of another group, such as alkoxy, alkylcarbonyl or alkoxycarbonyl, may be straight or branched chain and may preferably contain from 1 to 6 carbon atoms, more preferably 1 to 4, and more preferably 1 to 3. Examples of alkyl include methyl, ethyl, n-propyl, iso-propyl, n-butyl, sec-butyl, iso-butyl and tere-butyl.

Unless otherwise indicated, alkenyl and alkynyl, alone or as part of another substituent, may be straight or branched chain and may preferably contain from 2 to 6 carbon atoms, preferably 2 to 4, more preferably 2 to 3, and when appropriate, they may have the configuration (E) or (Z). Examples include vinyl, allyl and propargyl.

Halogen means fluoro, chloro, bromo or iodo. The haloalkyl groups may contain one or more identical or different atoms of halogen, and include, for example, trifluoromethyl, chlorodifluoromethyl, 2,2,2-rifluoroethyl or 2,2-difluoroethyl. Perfluoroalkyl groups are alkyl groups that are completely substituted with fluorine atoms and include, for example, trifluoromethylo, pentafluoroethyl and heptafluoroprop-2-yl.

The haloalkenyl and haloalkynyl groups may contain one or more identical or different atoms of halogen, and include, for example, 2, 2-difluorovinyl, 1,2-dichloro-2-fluorovinyl or l-chloroprop-2-yn-1-yl .

Unless otherwise indicated, cycloalkyl may be mono- or bi-cyclic, may be optionally substituted by one or more Ci-C3 alkyl groups, and preferably contain 3 to 8 carbon atoms, more preferably 3 to 6 carbon atoms. Examples of cycloalkyl include cyclopropyl, 1-methylcyclopropyl, 2-methylcyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl.

The halocycloalkyl groups may contain one or more identical or different halogen atoms and include, for example, 2,2-dichlorocyclopropyl, 2,2-dichloro-1-methylcyclopropyl and 2-chloro-4-fluoro-cyclohexyl.

Aryl includes phenyl, naphthyl, anthracenyl, indenylp, phenanthrenyl and biphenyl, with phenyl being preferred.

"Heteroaryl" means a mono, bi- or tricyclic aromatic hydrocarbon, containing 3 to 14, preferably 5 to 10, more preferably 6 to 8, ring atoms, including 6, preferably 1 to 4, heteroatoms that are independently selected from nitrogen , oxygen and sulfur. Examples include furyl, thienyl, pyrrolyl, imidazolyl, pyrazolyl, thiazolyl, isothiazolyl, oxazolyl, isoxazolyl, oxadiazolyl, thiadiazolyl, triazolyl, tetrazolyl, pyridyl, pyridazinyl, pyrimidinyl, pyrazinyl, triazinyl, tetrazinyl, indolyl, benzothiophenyl, benzofuranyl, benzimidazolyl, benzothiadiazolyl, indazolyl, benzotriazolyl, benzothiazolyl, benzoxazolyl, quinolyl, isoquinolyl, phthalazinyl, quinoxalinyl, quinazolinyl, cinolinyl and naphthyridinyl.

Heterocyclyl, as used herein, includes heteroaryl, and further it may be a saturated or partially saturated cyclic hydrocarbon containing from 3 to 10 ring atoms of which up to 4 are heteroatoms which are selected from nitrogen, oxygen and sulfur , and may be optionally substituted by one or more groups that are independently selected from halogen, nitro, cyano, alkyl, alkoxy. Examples of non-aromatic heterocyclyl groups are Tietane, Tietane 1-oxide, Tietane 1,1-dioxide, oxiranyl, azetidinyl, tetrahydrofuranyl, thiolanyl, pyrrolidinyl, pyrrolinyl, imidazolidinyl, imidazolinyl, sulfolanyl, dioxolanyl, dihydropyranyl, tetrahydropyranyl, piperidinyl, pyrazolinyl. , pyrazolidinyl, dioxanyl, morpholinyl, dithianyl, thiomorpholinyl, piperazinyl, azepinyl, oxazepinyl, thiazepinyl, thiazolinyl and diazapanyl. Heterocyclyl, as used herein, also includes fused ring systems, such as, for example, indolyl, indazolyl, purinyl, benzofuranyl or benzothiophenyl.

The preferred values of A1, A2, A3, A4, R1, R2, R3, G1, X, Q1, Q2, R5, R6, R7 are, in any combination, as set forth below.

Preferably A1 is C-X.

Preferably A2 is C-X.

Preferably A3 is C-X.

Preferably A4 is C-X.

Preferably, X is hydrogen, halogen, cyano, methyl, trifluoromethyl or methoxy. More preferably, X is hydrogen, fluoro, chloro, cyano, trifluoromethyl or methoxy. Even more preferably, X is hydrogen, fluoro, cyano or methoxy. More preferably, X is hydrogen, fluoro or cyano.

More preferably, A1, A2, A3 and A4 are C-X and each X is independently selected from hydrogen, halogen, cyano, methyl, trifluoromethyl and methoxy and preferably A2 and A3 are both CH; and Al and A4 are C-X and each X is independently selected from hydrogen, halogen, cyano, methyl, trifluoromethyl and methoxy and most preferably each X is independently selected from hydrogen, fluoro, cyano and methoxy. Even more preferably, A1, A2, A3 and A4 are C-X and each X is independently selected from hydrogen, fluoro, cyano and methoxy .. More preferably, A1 is CH, C-CN, C-Cl: or C-F; and A2, A3 and A4 are CH or A1, A2 and A3 are CH and A4 is CH, C-OCH3 or C-F. Even more preferably A1 is CH, C-CN, C-Cl or C-F; and A2, A3 and A4 are CH. Even more preferably A1, A2 and A3 are CH and A4 is CH, C-OCH3 or C-F.

Preferably, G1 is oxygen.

Preferably, R1 is hydrogen, methyl, ethyl or acetyl. More preferably, R1 is hydrogen, methyl or ethyl. More preferably, R1 is hydrogen.

Preferably, R2 is hydrogen, methyl, trifluoromethyl or halogen. More preferably, R2 is hydrogen, trifluoromethyl or halogen. Even more preferably, R2 is hydrogen or halogen. More preferably, R2 is hydrogen.

Preferably, Q1 is aryl or heterocyclyl or C3-Ciocycloalkyl or Ci-C8 alkyl or C2-C8 alkenyl or C2-C8 alkynyl; each optionally substituted by one to five substituents which are independently selected from cyano, nitro, hydroxy, bromo, chloro, fluoro, methyl, trifluoromethyl, methoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl and phenyl.

More preferably, Q1 is cyclopropyl, cyclobutyl, cyclopentyl, benzyl, pyridin-2-ylmethyl, thirthan-3-yl, ethyl, propyl, butyl, allyl, propargyl, phenyl, 2-pyridyl; each optionally substituted by one to four its ituents which are independently selected from cyano, nitro, hydroxy, bromo, chloro, fluoro, methyl, trifluoromethyl, methoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl and phenyl.

Even more preferably, Q1 is phenyl, cyclopropyl and ethyl; each optionally substituted by one to four substituents which are independently selected from cyano, nitro, hydroxy, bromo, chloro, fluoro, methyl, ethyl, trifluoromethyl, methoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl and phenyl.

Even more preferably, Q1 is cyclopropyl and ethyl; each optionally substituted by one to four substituents which are independently selected from cyano, nitro, hydroxy, bromo, chloro, fluoro, methyl, ethyl, trifluoromethyl, methoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl and phenyl.

Preferred examples of Q1 include pyridin-2-ylmethyl, thirthan-3-yl, ethyl, butyl, cyclopropyl, benzyl, phenyl.

In another preferred embodiment Q2 is a residue of formula (II) wherein the substituents R5, R6 and R7 have the following meanings: R7 and R6 are independently hydrogen, cyano, halogen, Ci-C6alkyl, perfluoroalkylCi-C6, perfluoroalkylthioCi-C6, perfluoroalkylsulfinylCi-Ce or per-fluoroalkylsulfonylCi-C6 preferably independently perfluoroalkylCi-C, perfluoroalkylthioCi-C4, perfluoroalkylsulfinylCi-C4 or perfluoroalkylsulfonylCi-C4 even more preferably independently perfluoroalkylCi-C4, perfluoroalkylthioCi-C4, or per-fluoroalkylsulfonylCi-C4 more preferably independently trifluoromethyl or perfluoroethyl or trifluoromethylthio or perfluoroethylthio or trifluoromethylsulfonyl or perfluoroethylsulfonyl.

More preferably R7 and R6 are independently cyano, halogen, C6-C6alkyl, perfluoroalkylCi-C6 preferably independently perfluoroalkylCi-C6 even more preferably independently trifluoromethyl or perfluoroethyl.

Even more preferably R7 and R6 are independently halogen, perfluoroalkylCi-C6.

More preferably R6 is trifluoromethyl.

More preferably R7 is perfluoroethyl.

Preferably R5 is hydrogen, haloCi-C6 alkyl, Ci-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, phenyl or phenyl substituted by one to five substituents R10, which may be the same or different, pyridyl or pyridyl substituted by one to five substituents R10 , which can be the same or different.

More preferably R 5 is hydrogen, C 1 -C 6 haloalkyl, C 6 -C 6 alkyl; even more preferably R5 is Ci-C6 alkyl is preferably Ci-C alkyl.

In another preferred embodiment Q2 is a residue of formula (II) wherein the substituents R5, R6 and R7 have the following meanings: R7 and R6 are independently cyano, halogen, Ci-C6alkyl, perfluoroalkylCi-C6, perfluoroalkylthioCi-C6, perfluoroalkylsulfinylCi-C6 or perfluoroalkylsulfonylCi-Cg; and R5 is haloalkyl Ci-Ce or Ci-C6 alkyl; even more preferably R5 is Ci-C6 alkyl is preferably Ci-C4 alkyl.

In a preferred embodiment Q2 is 2-Methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazol-3-yl.

In a preferred embodiment (El) the substituents on the compounds of Formula (I) have the following meanings: R1 is hydrogen, methyl, ethyl or acetyl; R 2 is hydrogen, methyl, trifluoromethyl or halogen; G1 is oxygen; Q1 is aryl or heterocyclyl or C3-Ci0 cycloalkyl or Ci-C8 alkyl; each optionally substituted by one to five substituents which are independently selected from cyano, nitro, hydroxy, bromo, chloro, fluoro, methyl, trif luoromethyl, methoxy, trifluoromethoxy, methylthio, methylsulfonyl, methylsulfonyl and phenyl.

Q2 is a residue of formula (II) where R5 is hydrogen, haloalkylCx-Cg, alkylCx-C6; , C2-C6 alkenyl, C2-C6 alkynyl, phenyl or phenyl substituted by one to five substituents R10, which may be the same or different, pyridyl or pyridyl substituted by one to five R10 substituents, which may be the same or different; R7 and R6 are independently hydrogen, cyano, halogen, Ci-C6alkyl, perfluoroalkylCi-C6, perfluoroalkylthioCi-C6, perfluoroalkylsulphinyl-C6 or perfluoroalkylsulfonylCi-C6 preferably independently perfluoroalkylCi-C4, perfluoroalkylthioCi-Cj, perfluoroalkylsulfinylCi-C4 or per-fluoroalkylsulfonylCi-C more preferably independently perfluoroalkylCi-C4, perfluoroalkylCi-C4thio, or perfluoroalkylsulfonylCi-C4.

In a preferred embodiment (E2) the substituents in the compounds of formula (I) have the following meanings: R1 is hydrogen, methyl or ethyl; R2 is hydrogen, trifluoromethyl or halogen; Q1 is cyclopropyl, cyclobutyl, cyclopentyl, benzyl, pyridin-2-ylmethyl, thirthan-3-yl, ethyl, propyl, butyl, phenyl, 2-pyridyl; each optionally substituted by one to four substituents which are independently selected from cyano, nitro, hydroxy, bromo, chloro, fluoro, methyl, trifluoromethyl, methoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl and phenyl.

Q2 is a residue of formula (II) where R5 is hydrogen, haloCi-C6 alkyl, Ci-C6 alkyl; R7 and R6 are independently cyano, halogen, Ci-C6 alkyl, perfluoroalkyl Ci-C6.

In a preferred embodiment (E3) the substituents in the compounds of formula (I) have the following meanings: R1 is hydrogen, methyl or ethyl; R2 is hydrogen or halogen; Q1 is phenyl, cyclopropyl and ethyl; each optionally substituted by one to four substituents which are independently selected from cyano, nitro, hydroxy, bromo, chloro, fluoro, methyl, ethyl, trifluoromethyl, methoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl and phenyl.

Q2 is a residue of formula (II) where R 5 is preferably C 1 -C 4 alkyl; R7 and R6 are independently C6-C6 perfluoroalkyl.

In a preferred embodiment (E4) the substituents on the compounds of formula (I) have the following meanings: R1 is hydrogen; R2 is hydrogen Q1 is cyclopropyl and ethyl; each optionally substituted by one to four substituents which are independently selected from cyano, nitro, hydroxy, bromo, chloro, fluoro, methyl, ethyl, trifluoromethyl, methoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl and phenyl; Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazol-3-yl.

A preferred embodiment are compounds of formula (I) wherein A1, A2, A3 and A4 are CX and each X is independently selected from hydrogen, halogen, cyano, methyl, trifluoromethyl and methoxy and the other substituents have the meaning of Modality ( ).

A preferred embodiment are compounds of formula (I) wherein A2 and A3 are both CH; and A1 and A4 are CX and each X is independently selected from hydrogen, halogen, cyano, methyl, trifluoromethyl and methoxy and most preferably cad.sub.A X is independently selected from hydrogen, fluoro, cyano and methoxy and the other substituents have the meaning; Modality (El).

A preferred embodiment are compounds of formula (I), wherein A1, A2, A3 and A4 are CX and each X is independently selected from hydrogen, fluoro, chloro, cyano and methoxy and the other substituents have the meaning as in Modality ( He) .

A preferred embodiment are compounds of formula (I) wherein A1 is CH, C-CN, C-Cl or C-F; and A2, A3 and A4 are CH or A1, A2 and A3 are CH and A4 is CH, C-OCH3 or C-F and the other substituents have the meaning of Modality (El).

A preferred embodiment are compounds of formula (I), wherein A1 is CH, C-CN, C-Cl or C-F; and A2, A3 and A4 are CH and the other substituents have the meaning as in Modality (El).

A preferred embodiment are compounds of formula (I) wherein A1, A2 and A3 are CH and A4 is CH, C-OCH3 or C-F and the other substituents have the meaning of Modality (El).

A preferred embodiment are compounds of formula (I) wherein A1, A2, A3 and A4 are CX and each X is independently selected from hydrogen, halogen, cyano, methyl, trifluoromethyl and methoxy and the other substituents have the meaning of Modality (E2 ).

A preferred embodiment are compounds of formula (I), wherein A2 and A3 are both CH; and A1 and A4 are CX and each X is independently selected from hydrogen, halogen, cyano, methyl, trifluoromethyl and methoxy and more preferably each X is independently selected from hydrogen, fluoro, chloro, cyano and methoxy and the other substituents have the meaning as in the Modality (E2).

A preferred embodiment are compounds of formula (I), wherein A1, A2, A3 and A4 are C-X and each X is independently selected from hydrogen, fluoro, chloro, cyano and methoxy and the other substituents have the meaning as in the Modality (E2).

A preferred embodiment are compounds of formula (I) wherein A1 is CH, C-CN, C-Cl or C-F; and A2, A3 and A4 are CH or A1, A2 and A3 are CH and A4 is CH, C-OCH3 or C-F and the other substituents have the meaning of Modality (E2).

A preferred embodiment are compounds of formula (I) wherein A1 is CH, C-CN, C-Cl or C-F; and A2, A3 and A4 are CH methoxy and the other substituents have the meaning of 1 Modality (E2).

A preferred embodiment are compounds of formula (I) wherein A1, A2 and A3 are CH and A4 is CH, C-0CH3 or C-F and the other substituents have the meaning of Modality (E2).

A preferred embodiment are compounds of formula (I) wherein A1, A2, A3 and A4 are CX and each X is independently selected from hydrogen, halogen, cyano, methyl, trifluoromethyl and methoxy and the other substituents have the meaning of Modality (E3 ).

A preferred embodiment are compounds of formula (I), wherein A2 and A3 are both CH; and A1 and A4 are C-X and each X is independently selected from hydrogen, halogen, cyano, methyl, trifluoromethyl and methoxy and most preferably each; X is independently selected from hydrogen, fluoro, chloro, cyano and methoxy and the other substituents have the meaning as in Modality (E3).

A preferred embodiment are compounds of formula where A1, A2, A3 and A4 are C-X. and each X is independently selected from hydrogen, fluoro, chloro, cyano and methoxy and the other substituents have the meaning as in Modality (E3).

A preferred embodiment are compounds of formula (I) wherein A1 is CH, C-CN, C-Cl or C-F; and A2, A3 and A4 are CH or A1 / A2 and A3 are CH and A4 is CH, C-OCH3 or C-F and the other substituents have the meaning of Modality (E3).

A preferred embodiment are compounds of formula (I) wherein A1 is CH, C-CN, C-Cl or C-F; and A2, A3 and A4 are CH methoxy and the other substituents have the meaning of Modality (E3).

A preferred embodiment are compounds of formula (I) wherein A1, A2 and A3 are CH and A4 is CH, C-0CH3 or C-F and the other substituents have the meaning of Modality (E3).

A preferred embodiment are compounds of formula (I) wherein A1, A2, A3 and A4 are CX and each X is independently selected from hydrogen, halogen, cyano, methyl, trifluoromethyl and methoxy and the other substituents have meaning of Modality (E4) ).

A preferred embodiment are compounds of formula (I), wherein A2 and A3 are both CH; and A1 and A4 are C-X and each X is independently selected from hydrogen, halogen, cyano, methyl, trifluoromethyl and methoxy and most preferably each X is independently selected from hydrogen, fluoro, chloro cyano and methoxy and the other substituents have the meaning as in Modality (E4).

A preferred embodiment are compounds of formula (I), wherein A1, A2, A3 and A4 are CX and each X is independently selected from hydrogen, fluoro, chloro, cyano and methoxy and the other substituents have the meaning as in Modality ( E4).

A preferred embodiment are compounds of formula (I) wherein A1 is CH, C-CN, C-Cl or C-F; and A2, A3 and A4 are CH or A1, A2 and A3 are CH and A4 is CH, C-OCH3 or C-F and the other substituents have the meaning of Modality (E4).

A preferred embodiment are compounds of formula (I) wherein A1 is CH, C-CN, C-Cl or C-F; and A2, A3 and A4 are CH methoxy and the other substituents have the meaning of Modality (E4).

A preferred embodiment are compounds of formula (I) wherein A1, A2 and A3 are CH and A4 is CH, C-0CH3 or C-F and the other substituents have the meaning of Modality (E4).

A preferred embodiment (Ea) are compounds of formula (I) wherein A1 is C-CN and A2, A3 and A4 are CH.

A preferred embodiment (Eb) are compounds of formula (I) wherein A4 is C-F and A1, A2 and A3 are CH.

A preferred embodiment (Ec) are compounds of formula (I) wherein A4 is C-OMe, A1, A2 and A3 are CH.

A preferred embodiment (Ed) are compounds of formula (I) where A1, A2, A3, A4 are CH.

A preferred embodiment (Ee) are compounds of formula, (I) wherein A1 is C-Cl, A2, A3 and A4 are CH.

A preferred embodiment (Ef) are compounds of formula (I) wherein A1 is C-F and A2, A3 and A4 are CH.

A preferred embodiment (Eg) are compounds of formula (I) wherein A1 is C-CF3 and A2, A3 and A4 are CH.

A preferred embodiment (Eh) are compounds of formula (I) wherein A4 is N, A1, A2 and A3 are CH.

A preferred embodiment (Ei) are compounds of formula (I) wherein A4 is N, A1 is CN, A2 and A3 are CH.

A preferred embodiment (Ex) are compounds of formula (I) wherein A4 is N, A1 is F, A2 and A3 are CH.

A preferred embodiment (Eal) are compounds of formula (I) wherein A1 is C-CN and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (El).

A preferred embodiment (Ebl) are compounds of formula (I) wherein A4 is C-F and A1, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (El).

A preferred embodiment (Ecl) are compounds of formula (I) wherein A4 is C-OMe, A1, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (El).

A preferred embodiment (Edl) are compounds of formula (I) wherein A1, A2, A3, A4 are CH and the other substituyeiites have the meaning indicated in the mode of (El).

A preferred embodiment (Eel) are compounds of formula (I) wherein A1 is C-Cl, A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (El).

A preferred embodiment (Efl) are compounds of formula (I) wherein A1 is C-F and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (El).

A preferred embodiment (Egl) are compounds of formula (I) wherein A1 is C-CF3 and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (El).

A preferred embodiment (Ehl) are compounds of formula (I) wherein A4 is N, A1, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (El). i A preferred embodiment (Eil) are compounds of formula (I) where A4 is N, A1 is CN, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (El).

A preferred embodiment (Ejl) are compounds of formula (I) wherein A4 is N, A1 is F, A2 and A3 are CH and the others substituents have the meaning indicated in the mode of (El).

A preferred embodiment (Ea2) are compounds of formula (I) wherein A1 is C-CN and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (E2).

A preferred embodiment (Eb2) are compounds of formula (I) wherein A4 is C-F and A1, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (E2).

A preferred embodiment (Ec2) are compounds of formula (I) wherein A4 is C-O, A1, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (E2).

A preferred embodiment (Ed2) are compounds of formula (I) where A1, A2, A3, A4 are CH and the other substituents have the meaning indicated in the modality of (E2).

A preferred embodiment (Ee2) are compounds of formula (I) wherein A1 is C-Cl, A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (E2).

A preferred embodiment (Ef2) are compounds of formula (If) where A1 is C-F and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (E2).

A preferred embodiment (Eg2) are compounds of formula (I) wherein A1 is C-CF3 and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (E2).

A preferred embodiment (Eh2) are compounds of formula (I) where A4 is N, A1, A2 and A3 are CH and the other substituents have the meaning indicated in the modality of (E2).

A preferred embodiment (Ei2) are compounds of formula (I) wherein A4 is N, A1 is CN, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (E2).

A preferred embodiment (Ej2) are compounds of formula (I) wherein A4 is N, A1 is F, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (E2).

A preferred embodiment (Ea3) are compounds of formula (I) wherein A1 is C-CN and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (E3).

A preferred embodiment (Eb3) are compounds of formula (I) wherein A4 is C-F and A1, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (E3). A preferred embodiment (Ec3) are compounds of formula (I) where A4 is C-OMe, A1, A2 and A3 are CH and the other substituents have the meaning indicated in the modality of (E3).

A preferred embodiment (Ed3) are compounds of formula (I) wherein A1, A2, A3, A4 are CH and the other substituents have the meaning indicated in the mode of (E3).

A preferred embodiment (Ee3) are compounds of formula (I) wherein A1 is C-Cl, A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (E3).

A preferred embodiment (Ef3) are compounds of formula (I) wherein A1 is C-F and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (E3).

A preferred embodiment (Eg3) are compounds of formula (I) where A1 is C-CF3 and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (E3).

A preferred embodiment (Eh3) are compounds of formula (I) wherein A4 is N, A1, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (E3).

A preferred embodiment (Ei3) are compounds of formula (I) wherein A4 is N, A1 is CN, A2 and A3 are CH and the other substituents have the meaning indicated in the embodiment of (E3).

A preferred embodiment (Ej3) are compounds of formula (I) wherein A4 is N, A1 is F, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (E3).

A preferred embodiment (Ea4) are compounds of formula (I) wherein A1 is C-CN and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the embodiment of (E4).

A preferred embodiment (Eb4) are compounds of formula (I) where A4 is C-F and A1, A2 and A3 are CH and the other substituents have the meaning indicated in the modality of (E4).

A preferred embodiment (Ec4) are compounds of formula (I) wherein A4 is C-OMe, A1, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (E4).; A preferred embodiment (Ed4) are compounds of formula (I) wherein A1, A2, A3, A4 are CH and the other substituents have the meaning indicated in the mode of (E4).

A preferred embodiment (Ee4) are compounds of formula (I) wherein A1 is C-Cl, A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (E4).

A preferred embodiment (Ef4) are compounds of formula (I) where A1 is C-F and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (E4).

A preferred embodiment (Eg4) are compounds of formula (I) wherein A1 is C-CF3 and A2, A3 and A4 are CH and the other substituents have the meaning indicated in the mode of (E4).

A preferred embodiment (Eh4) are compounds of formula (I) wherein A4 is N, A1, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (E4).

A preferred embodiment (Ei4) are compounds of formula (I) wherein A4 is N, A1 is CN, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (E4).

A preferred embodiment (Ex4) are compounds of formula (I) wherein A4 is N, A1 is F, A2 and A3 are CH and the other substituents have the meaning indicated in the mode of (E4). I Intermediate compounds of formula (III) form a further aspect of the invention where A1, A2, A3, A4, R2 and Q2 are as defined on relation to formula (I); or a salt of it. The preferences for A1, A2, A3, A4, R2 and Q2 are the same as the preferences established for the corresponding substituents of the compounds of formula (I).

Intermediate compounds of formula (Illb), wherein R is Ci-C6 alkyl forms a further aspect of the invention where A1, A2, A3, A4, 2 and Q2 are as defined in relation to formula (I); or a salt of it. The preferences for A1, A2, A3, A4, R2 and Q2 are the same as the preferences established for the corresponding substituents of the compounds of formula (I).

In a preferred embodiment, the invention provides a compound of formula (III) wherein A1, A2, A3 and A4 are CH; R2 'is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (III) wherein A1 is C-CN; A2, A3 and A4 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (III) wherein A1 is C-F; A2, A3 and A4 are GH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (III) wherein A1 is C-Cl; A2, A3 and A4 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (III) wherein A4 is C-F; A2, A3 and A1 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (III) wherein A4 is C-OMe; A2, A3 and A1 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (III) wherein A4 is N; A2, A3 and A1 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (III) wherein A4 is; A1 is CN, A2 and A3 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (III) wherein A4 is N; A1 is F, A2 and A3 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (Illb) wherein A1 is C-CF3; A2, A3 and A4 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In a preferred embodiment, the invention provides a compound of formula (Illb) wherein A1, A2, A3 and A4 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (Illb) wherein A1 is C-CN A2, A3 and A4 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (Illb) wherein A1 is C-F; A2, A3 and A4 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (Illb) wherein A1 is C-Cl; A2, A3 and A4 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (Illb) wherein A4 is C-F; A2, A3 and A1 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (Illb) wherein A4 is C-OMe; A2, A3 and A1 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (Illb) wherein A4 is N; A2, A3 and A1 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (Illb) wherein A4 is N; A1 is CN, A2 and A3 s, on CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (Illb) wherein A4 is N; A1 is F, A2 and A3 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

In another preferred embodiment, the invention provides a compound of formula (Illb) wherein A1 is C-CF3; A2, A3 and A4 are CH; R2 is hydrogen; Q2 is a residue of formula (II).

Table 1: Table 1 provides 73 compounds of formula (la) according to formula (I) wherein A1 is C-CN, A2, A3 and A4 are CH and Q2 is 2-Methyl-5-pentafluoroethyl-4-trifluoromethyl-2H- pyrazol-3-yl, R2 is H and Q1 has the values listed in Table 1.

Table 2: Table 2 provides 73 compounds of formula (Ib) according to formula (I) wherein A4 is CF, A1, A2 and A3 soniC-H and Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazole -3-ilo, R2 is H and Q1 has the values listed in Table 1.

Table 3: Table 3 provides 73 compounds of formula (Ic) < you according to the formula (I) where A4 is C-OMe, A1, A2 and A3 are CH and Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazol-3-yl, R2 is H and Q1 has the values that are listed in Table 1.

Table 4: Table 4 provides 73 compounds of formula (Id) according to formula (I) wherein A1, A2, A3 and A4 are CH and Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazole-3. ilo, R2 is H and Q1 has the values listed in the table below.

Table 5: Table 5 provides 73 compounds of formula (le) according to formula (I) wherein A1 is C-Cl, A2, A3 and A4 are CH and Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H- pyrazol-3-yl, R2 is H and Q1 has the values listed in Table 1.

Table 6: Table 6 provides 73 compounds of formula (If), according to formula (I) wherein A1 is CF, A2, A3 and A4 are; CH and Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H- pyrazol-3-yl, R2 is H and Q1 has the values listed in Table 1.; Table 7: Table 7 provides 73 compounds of formula (Ig) according to formula (I) wherein A1 is C-CF3, A2, A3 and A4 are C-H and Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazol-3-yl, R2 is H and Q1 has the values listed in Table 1.

Table 8: Table 8 provides 73 compounds of formula (Ih) according to formula (I) wherein A4 is N, A1, A2 and A3 are CH and Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazole- 3 -yl, R2 is H and Q1 has the values listed in Table 1.

Table 9: Table 9 provides 73 compounds of formula (Ii), according to formula (I) wherein A4 is N, A1 is CN, A2 and A3 are CH and Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H -pyrazol-3-yl, R2 is H and Q1 has the values listed in Table 1.

Table 10: Table 10 provides 73 compounds of formula (Ij), according to formula (I) wherein A4 is N, A1 is F, A2 and A3 are CH and Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl1-2H -pyrazol-3-yl, R2 is H and Q1 has the values listed in Table 1.

Table 11: Table 11 provides 20 compounds of formula (Illb), wherein Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazol-3-yl, R2 is H, R and A1, A2, A3, A4 have the values listed in the table below Table 12: Table 12 provides 10 compounds of formula (III) where Q2 is 2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazol-3-yl, R2 is H and A1, A2, A3, A4 have the values listed in the table below.

The compounds of the invention can be prepared by the following methods. (1) The compounds of formula (I), wherein G1 is oxygen, can be prepared by reaction of a compound of formula (V) with an azido derivative, Q2-N3 (VII), in the presence of copper or a copper, such as copper sulfate or copper (I) iodide, and optionally in the presence of a base, such as N-ethyldiisopropylamine, in the presence of a solvent or a mixture of solvents, such as t-butanol, water. In the case of a Cu (II) catalyst, A reducing agent, such as sodium ascorbate, can be used. In the case of a Cu (0) catalyst, such as an amine salt, an oxidizing agent may be used. (See, for example: Angewandte Chemie, International Edition (2009), 48 (27), 4900-4908 and cited references, Angew, Chem. Int. Ed. 2008, 47,. 2182-2184 and the references cited, and Eur. J. Org. Chem. 2006, 51-68 and the references cited). (2) The compounds of formula (V), wherein G 1 is oxygen, can be prepared by reaction of a compound of formula (VI), wherein R is OH with a compound of formula (IV), in the presence of a reactive ide coupling, such as DCC (N, '-dicyclohexylcarbodiimide), EDC (l-ethyl-3- [3-dimethyl-amino-propyl] carbodiimide hydrochloride) or BOP-C1 (bis (2 -oxo-3-oxazolidinyl) phosphonic chloride ), in the presence of a base, such as pyridine, triethylamine, 4- (dimethylamino) iridine diisopropylethylamine, and optionally in the presence of a nucleophilic catalyst, such as hydroxybenzotriazole. Optionally, when R is Cl, the reaction can be carried out under basic conditions (for example in the presence of pyridine, triethylamine, 4- (dimethylamino) pyridine or diisopropylethylamine), optionally in the presence of a nucleophilic catalyst. Alternatively, the reaction can be carried out in a two-phase system comprising an organic solvent, preferably ethyl acetate, and an aqueous solvent, preferably a solution of sodium bicarbonate. Optionally, when R is C6-C6 alkoxy, the amide can be prepared by heating the ester (VI) and the amine (IV) together. (3) The compounds of formula (VI), wherein R is OH, can be prepared by reaction of a compound of formula (VI), wherein R is C6-C6 alkoxy, by hydrolysis. For example, in the case where R is methoxy or ethoxy, the hydrolysis can be carried out with water and a base, such as potassium hydroxide or lithium hydroxide, in the absence or in the presence of a solvent, such as, for example , tetrahydrofuran or methanol. In the case where R is, for example, tert-butoxy, the hydrolysis is carried out, in the presence of acid, such as trifluoroacetic acid or hydrochloric acid. The reaction is carried out at a temperature of -120 ° C to + 130 ° C, preferably -100 ° C to 100 ° C. (4) The compounds of formula (V), wherein R 1 is Ci-Cg alkyl, can be prepared from a compound of formula (V), wherein R 1 is H, by alkylation that can be achieved by treating the amine with a agent alkylating agent such as an alkyl halide, optionally in the presence of a base. (5) The compounds of formula (I), wherein G1 is oxygen, can also be prepared by reaction of a compound of formula (III), wherein R is OH, Cl or C6-C6 alkoxy, with a compound of formula (IV ) as described in (2). (6) The compounds of formula (III) can be prepared from a compound of formula (VI) by using the same conditions described in (1). (7) The compounds of formula (III) can be prepared by hydrolysis of an ester compound of formula (IIIb) by the method described in (3).

The compounds of formula (I), wherein G 1 is sulfur, they can be prepared from a compound of formula (I), wherein G1 is oxygen, by treatment with a thio-transfer reagent, such as Lawesson's reagent or phosphorus pentasulfide. (9) The compounds of formula (VIII) can be prepared from a compound of formula (IX), wherein A1, A2, A3 and A4 are each independently C-LG or CH and LG is a leaving group, such as fluorine or chlorine, by reaction with a nucleophile, such as an aliphatic alcohol, sodium cyanide. (10) The compounds of formula (Illb), wherein A1 ,; A2, A3 and A4 are as described for the compound of formula (I), can be prepared from a compound of formula (lile), wherein A1, A2, A3 and A4 are each independently C-LG or CH, and LG is a leaving group, such as fluorine or chlorine, by reaction with a nucleophile, such as an aliphatic alcohol, sodium cyanide. (lllc) (lllb) 11) Compounds of formula (VII), wherein Q 2 is as described for the compound of formula (I), can also be prepared by the reaction of a compound of formula (II) with sodium nitrite followed by the addition of sodium azide. sodium. See, for example: Diazo Chemistry I: Aromatic and Heteroaromatic Compounds. Zollinger, H. Germany. (1994), 380 pp. Editorial: (VCH, Weinheim, Germany) and cited references.

Q- NH2 Q- N = N = N (II) (VII) 12) The compounds of formula (II) wherein R5 is methyl, R7 is perfluoroethyl and R6 is trifluoromethyl can be prepared from a compound of formula (ly) where LG is halogen, as fluorine or chlorine, by reaction with a salt of azide, as sodium azide. (lia) í) 13) Alternatively, the compounds of formula (NH2Q2) are known or can be prepared by known methods by the one skilled in the art. 14) The compounds of formula (VI), (VIII) or (IX) are known or can be prepared by methods known to the person skilled in the art.

The compounds of formula (I) can be used to combat and control infestations of insect pests such as Lepidoptera, Diptera, Hemiptera, Thysanoptera, Orthoptera, Dictyoptera, Coleoptera, Siphonaptera, Hymenoptera and Isoptera and also other invertebrate pests, for example, pests of mites, nematodes and molluscs. Insects, mites, nematodes and molluscs hereinafter are collectively referred to as pests. Pests that can be combated and controlled by using the compounds of the invention include pests associated with agriculture (the term includes growing crops for food and fiber products), horticulture and animal husbandry, pet animals, afforestation and storage of products of plant origin (such as fruits, wood grains), · pests associated with damage to structures made by man and the transmission of diseases of man and animals; and also annoying pests (such as flies).

Examples of pest species that can be controlled with the compounds of formula (I) include: Myzus persicae (aphid), Aphis gossypii (aphid), Aphis fabae (aphid), Lygus spp. (capsids), Dysdercus spp. (capsids), Nilaparvata lugens (insect leaf), Nephotettixc incticeps (chicharra), Nezara spp. (chinches), Euschistus spp. (chinches), Leptocorisa spp. (chinches), Frankliniella occidentalis (thrips), Thrips spp. (thrips), Leptinotarsa decemlineata (potato beetle), Anthonomus granáis (cotton boll weevil), Aonidiella spp. (woodlice), Trialeurodes spp. (white flies), Bemisia tabaci (white fly), Ostrinia nubilalis (European corn borer), Spodoptera littorális (cotton worm), Heliothis virescens (tobacco worm), Helicoverpa armígera (mazorquero), Helicovérpa zea (mazorquero), Sylepta derogata (leaf curler), Pieris brassicae (white butterfly), Plutella xylostella (crucifera moth), Agrotis spp. (cutworms), Chilo suppressalis (rice borer), Locusta migratoria (carob), Chortiocetes terminifera (carob), Diabrotica spp. (rootworms), Panonychus ulmi (European red spider), Panonychus citri (red fruit spider), Tetranychus urticae (red spider mite), Tetranychus cinnabarinus (red spider), Phyllocoptruta oleivora (pink citrus mite), Polyphagotarsonemus latus (white mite.), Brevipalpus spp. (mite of the vineyard), Boophilus microplus (cattle tick), Dermacentor variabilis (dog tick), Ctenocephalides felis (cat flea), Liriomyza spp (miner), Musca domestica (housefly), Aedes aegypti (mosquito), Anopheles spp. (mosquitoes), Culex spp. (mosquitoes), Lucillia spp. (moscardones), Germanic Blattella (cockroach), American Periplaneta (cockroach), Biatta orientalis (cockroach), termites of Mastotermitidae (for example Mastoter spp.), Kalotermitidae (for example Neotermes spp.), Rhinotermitidae (for example Coptotermes for osanus, Reticulitermes flavipes, R. speratu, R. virginicus, R. hesperus, and R. santonensis) and Termitidae (eg Globitermes sulfureus), Solenopsis geminata (red ant), Monomorium pharaonis (ant pharaoh), Damalinia spp. and Linognathus spp. (biting and sucking lice), Meloidogyne spp. . (gill-forming nematodes), Globodera spp. and Heterodera spp. (cystic nematodes), Pratylenchus spp. (nematodes of lesions), Rhodopholus spp. (banana borer nematodes), Tylenchulus spp. (Citrus nematodes), Haemonchus contortus (sheep wireworm), Caenorhabditis elegans (vinegar nematode), Trichostrongylus spp. (gastrointestinal nematodes) and Deroceras reticulatüm (slug).

Therefore, the invention provides a method for combating and controlling insects, mites, nematodes or molluscs which comprises applying an amount insecticidally, acaricidally, nematicidally or molluscically effective of a compound of formula (I) or a composition containing a compound of formula (I), a pest, the place of a pest, preferably a plant or a plant susceptible to an attack by a pest or a plant reproductive material. The compounds of formula (I) are preferably used against insects, mites or nematodes.

Examples of mites are Tetranychus cinnabarinus, Tetranychus urticae, Panonychus citri, Aculops pelekassi, Tarsonemus spp.

Examples of nematodados Meloidogyne incognita, Bursaphelenchus lignicolus Mamiya et Kiyohara, Aphelenchoides besseyi, Heterodera glycines, Pratylenchus spp.

Also, the compounds can be used to control pests of animals, in particular insects, arachnids, helminths, nematodates and molluscs, which are found in agriculture, horticulture, veterinary medicine, in jungles, in gardens and recreational centers, in the protection of products and stored materials and in the hygiene sector. Preferably, they can be used as plant protection agents. They can be active against normally sensitive species: and resistant and against all or some stages of development, i These pests include, among others:.

From the order of the Anoplura (Phthiráptera), for example, Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp. ! From the Arachnida class, for example, Acarus served, Sheldoni mill, Aculops spp., Aculus spp. , Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp., Eríophyes spp., Hemitarsonemus spp., Hyalo spp. , Ixodes spp., Latrodectus mactans, Metatetranychus spp., Oligonychus spp., Ornithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasates lycopersici.

From the Bivalve class, for example, Dreissena spp.

From the order of the Chilopoda, for example, Geophilus spp., Scutigera spp.

From the order of the Coleoptera, for example, Acanthoscehdes obtectus, Adoretus spp., Agelastica alni, Agriotes spp., Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apogonia spp., Atomaria spp., Attageius spp., Bruchidius obtectus, Bruchus spp., Ceuthorhynchus spp., Cleonus mendicus, Conoderus spp., Cos opolites spp., Costelytra zealandica, Curculio spp., Cryptorhynchus lapathi, Dermestes spp., Diabrotica spp., Epilachna spp., Faustinus cubae , Gibbium psylloides, Heteronychus arator, Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypothenemus spp. , Lachnosterna consanguineous, Leptinotarsa decemlineata, Lissorhoptrus oryzophilus, Lixus spp., Lyctus sp. , Meligethes aeneus, Melolontha melolontha, Migdolus spp. , Monochamus spp., Naupactus xanthographus, Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Otiorrhynchus sulcatus, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp. , Popillia japonica, Premnotrypes spp. , Psylliodes chrysocephala, Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Sitophilus spp. , Sphenophorus spp. , Sternechus spp., Symphyletes spp., Tenebrio molitor, Tribolium spp. , Trogoderma spp. , Tychius sp. , Xylotrechus spp. , Zabrus sp.

From the order of the Collembola, for example, Onychiurus armatus.

From the order of the Dermaptera, for example, Forfícula auricularia.

From the order of the Diplopoda, for example, Blaniulus guttulatus.

From the order of the Diptera, for example, Aedes ap. , Anopheles spp., Bibio hortulanus, Calliphora erythrocephala, Ceratitis capitata, Chrysomyia spp., Cochliomyia spp., Cordylobia anthropophaga, Culex spp., Cuterebra spp., Dac s oleae, Dermatobia hominis, Drosophila spp., Fannia spp., Gastrophilus spp. ., Hylemyia spp., Hyppobosca spp., Hypoderma spp., Liriomyza spp., Lucilia spp., Musca spp., Nezara spp., Oestrus spp., Oscinella frit, Pegomyia hyoscyami, Phorbia spp., Stomoxys spp., Tabanus spp., Tannia spp., Typula paludosa, Wohlfahrtia spp. .

From the class of Gastropoda, for example, Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Succinea spp.

From the helminth class, for example, Ancylostoma duodenale, Ancylostomaceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunosto um spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp., Dictyocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Loa Loa, Nematodirus sp. , Oesophagostomum spp., Opisthorchis spp., Onchocerca volvulus, Ostertagia spp., Paragonimus spp., Schistosomen spp., Strongyloides fuelleborni, Strongyloides stercoralis, Stronyloides spp., Taenia saginata, Taenia solium, Trichinella spiralis, Trichinella native, Trichinella britovi , Trichinella nelsoni, Trichinella pseudopsiralis, Trichostrongulus spp., Trichuris trichuria, Wuchereria bañerofti.

Additionally it may be possible to control protozoa, such as Eimeria.

From the order of the Heteroptera, for example, Anasa tristis, Antestiopsis spp. , Blissus spp., Calocoris sp. , Campylomma livida, Cavelerius spp., Cimex spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., Eurygaster spp., Heliopeltis spp., Hordas nobilellus, Leptocorisa spp., Leptoglossus phyllopus, Lygus spp., Macropes excavatus, Miridae, Nezara spp., Oebalus spp., Pentomidae, Piesma guadrata, Piezodorus spp., Psallus seriatus, Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp.

From the order of the Homoptera, for example, Acyrthosipon spp., Aeneolamia spp., Agonoscena spp., Aleurodes spp., Aleurolobus barodensis, Aleurothrixus spp., Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia spp., Brachycaudus helichrysii, brachycolus spp., Brevicoryne brassicae, Calligypona marginata, Carneocephala fulgide, lanigera Ceratovacúna, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspís tegalensis, Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Dalbulus spp., Dialeurodes spp., Diaphorina spp., Diaspis spp., Doralis spp., Drosicha spp. , Dysaphis spp., Dysmicoccus spp. , Epoasca spp. , Eriosoma spp. , Erythroneura spp. , Euscelis bilobatus, Geococcus coffeae, Homalodisca coagulata, Hyalopterus arundinis, Icerya sp. , Idiocerus spp. , Idioscopus spp. , Laodelphax striatellus, Lecanium sp. , Lepidosaphes spp. , Lipaphis erysimi, Macrosiphum spp. , Mahanarva fimbriolata, Melanaphis sacchari, Metcalfiella sp. , Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus sp. , Nasonovia ribisnigri, Nephotettix spp., Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Parabemisia myricae, Paratrioza spp. , Parlatoria spp. , Pemphigus spp., Peregrinus maidis, Phenacoccus spp. , Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp. , Pinnaspis aspidistrae, Planococcus sp. , Protopulvinaria pyriformis, Pseudaulacaspis pentagon, Pseudococcus spp. , Psylla spp. , Pteromalus sp. , Pyrilla sp. , Quadraspididtus spp., Quesada gigas, Rastrococcus spp. , Rhopalosiphum spp. , Saissetia spp. , Scaphoides titanus, Schizaphis graminu, Selenaspidus articulatus, Sogata sp. , Sogatella furcifera, Sogatodes spp. , Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis sp. , Toxoptera sp. , Trialeurodes vaporariorum, Trioza sp. , Typhlocyba spp. , Unaspis spp. , Viteus vitifolii. | From the order of the Hymenoptera, for example, Diprion spp., Hoplocampa spp. , Lasius spp. , Monomorium pharaonis, Vespa spp.

From the order of the Isopoda, for example, Armadillidium vulgare, Oniscus asellus, Porcellio scaber.

From the order of the Isoptera, for example, Reticuli ermes spp., Odontotermes spp.

From the order of the Lepidoptera, for example, Acronicta major, Aedy leuco elas, Agrotis spp., Alabama argillacea, Anticarsia spp., Barathra brassicae, Bucculatrix thurberiella, Bupalus piniarius, Cacoecia podana, Capua reticulána, Carpocapsa pomonella, Cheimatobia brumata, Chilo spp ., Choristoneura fumiferana, Clysia ambiguella, Cnaphalocerus spp., Earias insulana, Ephestia kuehniella, Euproctis chrysorrhoea, Euxoa spp., Feltia spp., Galleria mellonella, Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homona magnanimous, Hyponomeuta padella, Laphygma spp., Lithocolletis blancardella, Lithophane antennata, Loxagrotis albicosta, Lymantria spp., Malacoso a neustria, Mamestra brassicae, Mocis repanda, Mythimna separata, Oria spp., Oulema oryzae, Panolis flammea, Pecbinophora gossypiella, Phyllocnistis citrella, Pieris spp., Plutella xylostella, Prodenia spp., Pseudaletia spp., Pseudoplusia includens, Pyrausta nubilalis, Spodoptera spp., Thermesia gemmatalis, Tinea pellionel la, Tineola bisselliella, Tortrix viridana, Trichoplusia spp.

From the order of Orthoptera, for example, Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotalpa sp. , Leucophaea maderae, Locusta spp. , Melanoplus spp., Periplaneta americana, Schistocerca gregaria.

From the order of the Siphonaptera, for example, Ceratophyllus spp., Xenopsylla cheopis.

From the order of the Symphyla, for example, Scutigerella immaculata.

From the order of the Thysanoptera, for example, Baliothrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.

From the order of the Thysanura, for example, Lepisma saccharina.

Phytoparasitic nematodes include, for example, Anguina spp., Aphelenchoides spp., Belonoaimus spp., Bursap elencus spp., Ditylenc us dipsaci, Globodera spp., Heliocotylenchus spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus. spp., Radopholus similis, Rotylenchus spp., Trichodorus spp., Tylenchorhynchus spp., Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp.

Likewise, in the field of veterinary medicine, the new compounds of the present invention can be used efficiently against several parasitic pests of animals harmful (endoparasites and ectoparasites), for example, insects and helminths.

Examples of such parasitic pests on animals include the pests described below.

Examples of insects include Gasterophilus spp., Stomoxys spp., Trichodectes spp., Rhodnius spp., Ctenocephalides canis, Cimx lecturius, Ctenocephalides felis, Lucilia cuprina and the like.

Examples of mites include Ornithodoros spp., Ixodes spp., Boophilus spp. and similar.

In the areas of veterinary medicine, for example, in the area of veterinary medicine, the active compounds according to the present invention are active against parasites of animals, in particular ectoparasites or endoparasites.

The term endoparasites includes in particular helminths, such as cestodes, nematodes or trematodes and protozoa, such as coccidia. : Ectoparasites are typically and preferably arthropods, in particular insects such as flies (stinging and lamen), parasitic fly larvae, louse, hair louse, bird louse, fleas and the like; or acarids such as ticks, for example, hard ticks and soft ticks or mites such as scabies mites, crop mites, bird mites and the like.

These parasites include: From the order of the Anoplurida, for example Haematopinus spp., Linognathus spp. , Pediculus spp. , Phtirus spp. , Solenopotes spp .; specific examples are: Linognathus setosus, Linognathus vituli, Linognathus ovillus, Linognathus oviformis, Linognathus pedalis, Linognathus stenopsis, Haematopinus asini macrocephalus, Haematopinus eurysternus, Haematopinus suis, Pediculus humanus capitis, Pediculus hu anus corporis, Phylloera vastatrix, Phthirus pubis, Solenopotes capillatus; of the order of the Mallophagidae and the suborders Amblycerina and Ischnocerina, for example Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp .; Particular examples are: Bovicola bovis, Bovicola ovis, Bovicola limbata, Damalina bovis, Trichodectes canis, Felicola subrostratus, Bovicola caprae, Lepikentron ovis, Werneckiella equi; from the order of the Diptera and the suborders Nematocerina and Brachycerina, for example Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Odagmia spp., Wilhelmia spp., Hybo itra spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga sp. , Oestrus sp. , Hypoderma spp. , Gastrophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp., Rhinoestrus spp., Typula spp. / Particular examples are: Aeáes aegypti, Stegomyia albopicta (Aedes albopictus), Aedes taeniorhynchus, 'Anopheles gambiae, Anopheles maculipénnis, Calliphora Erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Fannia canicularis, Sarcophaga carnaria, Stomoxys calcitrans, Typula paludosa, Lucilia cuprina, Lucilia sericata, Simulium reptans, Phlebotomus papatasi, Phlebotomus longipalpis, Odagmia ornata, IVil elmia equina, Boophthora erythrocephala , Tabanus bromius, Tabanus spodopterus, Tahanus atratus, Tajbanus sudeticus, Hjomi tra ciurea, Chrysops caecutiens Chrysops relictus, Haematopota pluvialis, Haematopota itálica, Musca autumnalis, Musca domestica, Haematobia irritans irritans, Haematobia irritans exigua, Haematobia sti ulans, Hydrotaea irritans, Hydrotaea albipuncta, Chrysomya chloropyga, Chrysomya bezziana, Oestrus ovis, Hypoder ma bovis, Hypoderma lineatum, Przhevalskiana silenus, Dermatobia hominis, Melophagus ovinus, Lipoptena capreoli, Lipoptena cervi, Hippobosca variegata, Hippobosca equina, Gasterophilus intestinalis, Gasterophilus haemorrhoidalis, Gasterophilus inermis, Gasterophilus nasalis, Gasterophilus nigricornis, Gasterophilus pecorum, Braula coeca; of the order of Siphonapterida, for example Pulex spp., Ctenocephalides spp. , Tunga spp. , Xenopsylla sp. , Ceratophyllus spp .; Particular examples are: Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis; of the order of the Heteroptera, for example Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.

From the order of the Blattarida, for example Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp. (for example, Suppella longipalpa); From the subclass of Acari (Acariña) and the orders of Meta- and Mesostigmata, for example, Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Rhipicephalus (Boophilus) spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Dermanyssus spp. , Rhipicephalus spp. (the original genus of multi-host ticks) Ornithonyssus spp., Pneumonyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp., Acarapis spp .; Particular examples are: Argas persicus, Argas reflexus, Ornithodorus moubata, Otobius megnihi, Rhipicephalus (Boophilus) microplus, Rhipicephalus (Boophilus) decoloratus, Rhipicephalus (Boophilus) annulatus, Rhipicephalus (Boophilus) calceratus, Hyalomma anatolicu, Hyalomma aegypticum, Hyalomma arginatum, Hyalomma transieñs, Rhipicephalus evertsi, Ixodes ricinus, Ixodes hexagonus, Ixodes canisuga, Ixodes pilosus, Ixodes rubicundus, Ixodes scapularis, Ixodes holocyclus, Haemaphysalis concinna, Haemaphysalis punctata, Haemaphysalis cinnabairina, Haemaphysalis otophila, Haemaphysalis leachi, Haemaphysalis longicorni, Dermacentor marginatus, Dermacentor reticulatus, Dermacentor pictus, Dermacentor albipictus, Dermacentor andersoni, Dermacentor variabilis, Hyalomma mauritanicum, Rhipicephalus sanguineus, Rhipicephalus bursa, Rhipicephalus appendiculatus, capensis Rhipicephalus, Rhipicephalus turanicus, Rhipicephalus zambeziensis, Amblyomma americanum , Amblyomma variegatum, Amblyomma maculatum, Amblyomma hebraeum, Amblyomma cajennense, Dermanyssus gallinae, Ornithonyssus bursa, Ornithonyssus sylviarum, Varroa jacobsoni; of the order of the Actinedida (Prostigmata) and Acaridida (Astigmata), for example Acarapis spp. , Cheyletiella spp. , Ornithocheyl tia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp .; particular examples are: Cheyletiella yasguri, Cheyletiella blakei, Demodex canis, Demodex bovis, Demodex ovis, Demodex caprae, Demodex equi, Demodex caballi, Demodex suis, Neotrombicula autumnalis, Neotrombicula desaleri, Neoschongastia xerothermobia, Trombicula akamushi, Otodectes cynotis, Notoedres cati, Sarcoptis canis, Sarcoptes bovis, Sarcoptes ovis, Sarcoptes rupicaprae (S. caprae), Sarcoptes equi, Sarcoptes suis, Psoroptes ovis, Psoroptes cuniculi, Psoroptes equi, Chorioptes bovis, Psoergates ovis, Pneumonyssoidic mange, Pneumonyssoides caninum, Acarapis woodi.

The active compounds according to the invention are also suitable for controlling arthropods, helminths and protozoa, which attack animals.

The animals include agricultural livestock such as, for example, cattle, sheep, goats, horses, pigs, donkeys, camels, buffalos, rabbits, chickens, turkeys, ducks, geese, nursery fish, bees.

Additionally, the animals include domestic animals, also referred to as companion animals, such as, for example, dogs, cats, cage birds, aquarium fish and those which are known as experimental animals such as, for example, hamsters, guinea pigs, Indians, rats and mice.

By controlling these arthropods, helminths and / or protozoa, it is intended to reduce deaths and improve performance (in the case of meat, milk, wool, hides, eggs, honey and the like) and the health of the host animal, Such a way of enabling a more economical and simple animal breeding by the use of the active compounds according to the invention.

For example, it may be desirable to prevent or interrupt the blood intake of the hosts by the parasites.

In addition, control of parasites can help prevent the transmission of infectious agents.

The term "control" as used herein in relation to the area of veterinary medicine means that the active compounds are effective in reducing the incidence of the respective parasite in an animal infected with the parasites to harmless levels.

More specifically, "control", as used herein, means that the active compound is effective to kill the respective parasite, inhibiting its growth or inhibiting its proliferation. Generally, when used for the treatment of animals, the active compounds according to the invention can be applied dilineally.

Preferably they are applied as pharmaceutical compositions which may contain pharmaceutically acceptable excipients and / or auxiliaries that are known in the art.

In the area of veterinary and animal husbandry, the active compounds are applied (eg,: administered) in the known manner by enteral administration in the form of, for example, tablets, capsules, beverages, potions, granules, pasta, boluses, the method of continuous feeding, suppositories; by parenteral administration, such as, for example, by injections (intramuscular, subcutaneous, intravenous, intraperitoneal and the like), implants, by nasal application, by dermal application in the form of, for example, bathing or dipping, spraying, pouring or staining, washing, spreading and with the help of modeled articles containing the active compound such as collars, ear tags, tails labels, limb bands, halters, marking devices and the like.

The active compounds can be formulated as a shampoo or as suitable formulations usable as aerosols, non-pressurized sprays, for example, pump sprayers and sprays.

When used for livestock, poultry, pets and the like, the active compounds according to the invention can be applied as formulations (eg powders, wettable powders ["WP"], emulsions, emulsifiable concentrates ["EC"], fluids, homogeneous solutions and suspension concentrates ["SC"] which comprise the active compounds in an amount of 1 to 80 weight percent, either dilute or after dilution (eg, 100 to 10,000 fold dilution) or as chemical bath When used in the veterinary field, the active compounds according to the invention can be used in combination with products. suitable synergists or other active compounds, such as, for example, acaricidal, insecticidal, anthelminthic, antiprotozoal drugs.

In the present invention, a substance having an insecticidal action against pests, including all of these; It is called insecticide.

An active compound of the present invention can be prepared by conventional formulation forms, when used as an insecticide.

Examples of the formulation forms include solutions, emulsions, wettable powders, water dispersible granules, suspensions, powders, foams, pastes, tablets, granules, aerosols, natural materials! and synthetic infiltrates with active compound, microcapsules, seed coating agents, formulations used with a combustion apparatus (eg, cartridges, drums, fumigation and smoke coils or the like as the combustion apparatus), ULV (ultra low volume ) (cold nebulizer, hot nebulizer) and the like.; These formulations can be produced by methods known per se.

For example, a formulation can be produced by mixing the active compound with a developer, i.e., a liquid diluent or carrier; a diluent or carrier of liquefied gas; a solid diluent or carrier and optionally with a surfactant, i.e., an emulsifier and / or dispersant and / or foaming agent.

In case water is used as a developer, for example, an organic solvent can also be used as an auxiliary solvent! Examples of the liquid carrier or diluent include aromatic hydrocarbons (eg, xylene, toluene, alkylnaphthalene and the like), chlorinated aliphatic or chlorinated aromatic hydrocarbons (eg, chlorobenzenes, ethylene chlorides, methylene chlorides), aliphatic hydrocarbons (eg, cyclohexanes) ), paraffins (for example, fractions of mineral oil), alcohols (for example, butanol, glycols and their ethers, steres and the like), ketones (for example, acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone and the like), strongly polar solvents ( for example, dimethylformamide, dimethylsulfoxide and the like), water and the like. The diluent or carrier of liquefied gas may be those which are gaseous at normal temperature and normal pressure, for example, aerosol propellants such as butane, propane, nitrogen gas, carbon dioxide and halogenated hydrocarbons. Examples of the solid diluent include powdered natural minerals (e.g., kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite, diatomaceous earth and the like), synthetic powdered minerals (e.g., highly dispersed silicic acid, alumina, silicates, and the like) and the like. Examples of the solid carrier for granules include pulverized and screened rocks (eg, calcite, marble, pumice, sepiolite, dolomite, and the like), synthetic granules of inorganic and organic powder, fine particles of organic materials (eg, sawdust, hulls). coconut, corn cobs, tobacco stems and the like) and the like. Examples of the emulsifier and / or foaming agent include anionic and nonionic emulsifiers [e.g., polyoxyethylene fatty acid esters, polyoxyethylene fatty acid alcohol ethers (e.g., alkylaryl polyglycol ether), alkylsulfonates, alkylsulfos, arylsulfonates and the like], albumin hydrolyzate and the like. Examples of the dispersant include residual liquor of lignin sulfite and methylcellulose.

Fixing agents can also be used in the formulations (powders, granules, emulsions) and examples of the fixing agent include carboxymethyl cellulose, synthetic and natural polymers (eg, gamma arabic, polyvinyl alcohol, polyvinyl acetate and the like); and similar. Dyes can also be used and examples of dyes include inorganic pigments (for example, iron oxide, titanium oxide, Prussian blue and the like), organic dyes such as alizarin dyes, azo dyes or metal phthalocyanine dyes and also trace elements such as iron, manganese, boron salts , copper, cobalt, molybdenum and zinc. The formulations in general may contain the active ingredient in an amount ranging from 0.1 to 95 weight percent and preferably 0.5 to 90 weight percent. The compound according to the present invention can also exist as a mixture with other active compounds, for example, insecticides, poisoned baits, bactericides, acaricides, nematicides, fungicides, growth regulators, herbicides, and the like, in the form of their forms of formulation commercially useful and in the forms of application prepared from the formulations.

The content of the compound according to the present invention in a commercially useful application form can vary within a wide range.

The concentration of the active compound according to! the present invention in actual use can be, for example, i in the range of 0.0000001 to 100 weight percent; and preferably 0.00001 to 1 weight percent.; The compounds according to the present invention can be used through conventional methods that are appropriate for the way of use.

The active compounds of the present invention have, when used against hygiene pests and pests associated with stored products, effective stability against alkalis on lime materials and also exhibit excellent residual effectiveness on wood and soil. The compounds of the invention can have favorable properties with respect to the amount applied, to the residue formulation, selectivity, toxicity, production methodology, high activity, broad spectrum of control, safety, control of resistant organisms, for example, pests that they are resistant to phosphorus agents and / or organic carbamate agents.

Further embodiments of the invention are described below.

The compounds of formula (I) can be used to combat and control infestations of insect pests such as Lepidoptera, Diptera, Hemiptera, Thysanoptera, Orthoptera, Dictyoptera, Coleoptera, Siphonaptera, Hymenoptera and Isoptera and also other invertebrate pests, for example, pests of mites, nematodes and molluscs. Insects, mites, nematodes and molluscs hereinafter are collectively referred to as pests. Pests that can be combated and controlled by using the compounds of the invention include pests associated with agriculture (the term includes the cultivation of crops for food and fiber products), horticulture and animal husbandry, pet animals, afforestation and storage of products of plant origin (such as fruits, grains and wood); the pests associated with the damage of structures made by man and the transmission of diseases of man and animals; and also annoying pests (such as flies).

The compounds of the invention can be used, for example, on grass, ornaments, such as flowers, shrubs, leafy or perennial trees, for example, conifers, as well as for injection of a tree, pest management and the like.

The compounds of the invention can be used to control animal pests of housings including: ants, bed bugs (adult), bees, beetles, maple beetles, bumblebees, antrey, centipedes, cicada, beetles, clover, cockroaches, American flour beetle , crickets, earwig, fire insects, fleas, flies, large grain borers, millipedes, mosquitoes, red flour beetles, rice weevils, serrated beetle of grains, silverfish, cochineal; of humidity, spiders, termites, ticks, wasps, cockroaches, crickets, flies, dung beetles (such as black, 'of the skins and scavenger), mosquitoes, scale insects, scorpions, spiders, red spider mites (common red, spruce) and ticks.

The compounds of the invention can be used to control ornamental pests including: ants (including imported fire ants), cutworms, azalea caterpillars, aphids, sack worms, black vine weevils (adults), neon maple bugs , budworms, California oak worm, caterpillars, cockroaches, crickets, cutworms, eastern tent caterpillars, elm leaf beetles, European flies, autumn weavers worm, flea beetles, northern tent caterpillar , gypsy moth larvae, Japanese beetles (adults), June beetles (adults), lace bugs, leaf-eating caterpillars, chicharrillas, leaf miners (adults), carnation caterpillars, leaf skeletonizers, small mosquitoes , mosquitoes, larvae of the moth; of oleander, scale insects, pine saw flies, pine bugs beetle, pine moths, plant bugs, root weevils, saw flies, scale insects, spiders, saliva bugs, beetles striped mites, striped oak worms, thrips, moths, moth moth larvae, wasps, broad mites, soft shells, California red lice (caterpillars), clover mites, mealy bugs, white pineapple scales (caterpillars), mites spiders, white flies.

The compounds of the invention can be used to control including lawn pests: ants (including imported fire ants, armyworms, centipedes, crickets, cutworms, earwigs, fleas (adults), grasshoppers, Japanese beetles (adults), millipedes, mites) , mosquitoes (adults), scale insects, grassworm worms, scale insects, ticks (including, the species that transmit Lyme disease), blue-green weevil beetles for forage (adults), black grass ataenius (adults) ), chiggers, fleas (adults), larvae (suppression), weevils of Hyperodes (adults), mole crickets (nymphs and young adults), mole crickets (mature adults), bed bugs.

Examples of pest species that can be controlled with the compounds of formula (I) include: Myzus persicae (aphid), Aphis gossypii (aphid), Aphis fabae (aphid), Lygus spp. (capsids), Dysdercus spp. (capsids), Nilaparvata lugens (insect leaf), Nep otettixc incticeps (chicharra), Nezara spp. (chinches), Euschistus spp. (chinches), Leptocorisa spp. (chinches), Frankliniella occideñtalis (thrips), Thrips spp- (thrips), Leptinotarsa decemlineáta (potato beetle), Ant onomus granáis (cotton boll weevil), Aonidiella spp. (woodlice), Trialeurodes spp. (white flies), Bemisia tabaci (white fly), Ostrinia nubilalis (European corn borer), Spodoptera littoralis (cotton worm), Heliothis virescens (tobacco worm), Helicoverpa armígera (mazorquero), Helicoverpa zea (mazorquero), Sylepta derogata (leaf curler), Pieris brassicae (white butterfly),, Plutella xylostella (moth of cruciferas), Agrotis spp. (cutworms), Chilo suppressalis (rice borer), Locusta migratoria (carob), C ortiocetes terminifera (carob), Diabrotica spp. (rootworms), Panonychus ulmi (European red spider), Panonychus citri (red spider of fruit trees), Tetranychus urticae (red spider mite), Tetranychus cinnabarinus (red spider), Phyllocoptruta oleivora (pink mite 'citrus), Polyphagotarsonemus latus (white mite), Brevipalpus spp. (mite of the vineyard), Boophilus microplus (cattle tick), Dermacentor variabilis (dog tick), Ctenocephalides felis (cat flea), Liriomyza, spp (miner), Musca domestica (housefly), Aedes aegypti (mosquito), Anopheles spp. (mosquitoes), Culex spp. (mosquitoes), Lucillia spp. (moscardones), Blattella germanica (cockroach), Periplaneta americana (cockroach), Bl &tta orientalis (cockroach), termites of Mastotermitidae (for example Mastotermes spp.), Kalotermitidae (for example Neotermes spp.), Rhinotermitidae (for example Coptotermes formosanus, Reticulitermes flavipes, R. speratu,: R. virginicus, R. hesperus, and R. santonensis) and Termitidae (eg Globitermes sulfureus), Solenopsis geminata (red ant), Monomorium pharaonis (ant pharaoh), Damalinia sp. and Linognathus sp. (biting and sucking lice), Meloidogyne spp. (gill-forming nematodes), Globodera spp. and Heterodera spp. (cystic nematodes), Pratylenc us spp. (nematodes of lesions), Rhodopholus spp. (banana borer nematodes), Tylenchulus sp. (Citrus nematodes), Haemonchus contort s (sheep wireworm), Caenorhabditis elegans (vinegar nematode), Trichostrongylus spp. (gastrointestinal nematodes) and Deroceras reticulatum (slug).

The compounds of the invention can be used to control pests in various plants, including soybeans (for example, in some cases 10-70 g / ha), corn (for example, 1 in some cases 10-70 g / ha), sugar cane (for example, in some cases 20-200g / ha), alfalfa (for example, in some cases 10-70g / ha), cabbage (for example, in some cases 10-50g / ha), rapeseed (for example, cañola) (for example, in some cases 20-70g / ha), potatoes (including sweet potatoes) (for example, 'in some cases 10-70g / ha), cotton (for example, in some cases 10-70g / ha) , rice (for example, in some cases 10-70g / ha), coffee (for example, in some cases 30-150g / ha), citrus (for example, in some cases 60-200g / ha), almonds (for example , in some cases 40-180g / ha), fruit vegetables (for example, tomatoes, pepper, chili, eggplant, cucumbers, zucchini, etc.) (for example, in some cases 10-80g / ha), tea (for example, in some cases 20-150g / ha) , bulbous vegetables (for example, onions, leeks, etc.) (for example, in some cases 30-90g / ha), grapes (for example, in some cases 30-180g / ha), pipe fruits (for example , apples, pears, etc.) (for example, in some cases 30-180g / ha) and stone fruits (for example, pears, plums, etc.) (for example, in some cases 30-180g / ha).

The compounds of the invention can be used in soybean to control, for example, Elasmopalpus lignosellus, Diloboderus abderus, Diabrotica speciosa, Sternechus subsignatus, Formicidae, Agrotis ypsilon, Julus ssp. , Anticarsia gemmatalis, Megascelis ssp., Procornitermes ssp., Gryllotalpidae, Nezara viridula, Piezodorus spp. , Acrosternum sp. , Neomegalotomus spp., Cerotoma trifurcata, Popillia japonica, Edessa spp., Liogenys fuscus, Euchistus netos, stem weevil, Scaptocoris castanea, phyllophaga spp., Pseudoplusia includens, Spodoptera spp., Bemisia tabáci, Agriotes spp. The compounds of the invention are preferably used in soybean to control Diloboderus abderus, Diabrotica speciosa, Nezara viridula, Piezodorus spp., Acrosternum spp., Cerotoma trifurcata, Popillia japonica, Euchistus ñeros, Phyllophaga spp., Agriotes spp.

The compounds of the invention can be used in corn for controlling, for example, Euchistus heros, Dichelops furcatus, Diloboderus abderus, Elasmopalpus lignosellus, Spodoptera frugiperda, Nezara viridula, Cerotoma trifurcata, Popillia japonica, Agrotis ypsilon, Diabrotica speciosa, Heteroptera, Procornitermes ssp., Scaptocoris castanea, Formicidae, Julus ssp. , Dalbulus maidis, Diabrotica virgifera, Mocis latipes, Bemisia tabaci, heliothis spp. , Tetran chus spp., Thrips spp., Phyllophaga spp., Scaptocoris spp., Liogenys fuscus, Spodoptera spp., Ostrinia spp., Sesa ia spp. , Agriotes spp. The compounds of the invention are preferably used in corn to control Euchistus heros, Dichelops furcatus, Diloboderus abderus, Nezara viridula, Cerotoma trifurcata, Popillia japonica, Diabrotica speciosa, Diabrotica virgifera, Tetranychus spp., Thrips spp., Phyllophaga spp., Scaptocoris spp., Agriotes spp.

The compounds of the invention can be used in sugarcane to control, for example, Sphenophorus spp., Termites, Mahanarva spp. The compounds of the invention are preferably used in sugarcane to control termites, Mahanarva. spp.

The compounds of the invention can be used in alfalfa to control, for example, Hypera brunneipennis, Hypera postica, Colias eurytheme, Collops spp., Empoasca solana, Epitrix, Geocoris spp., Lygus hesperus, Lygus lineolaris, Spissistilus spp, Spodoptera spp., Trichoplusia ni.;The The compounds of the invention are preferably used in alfalfa to control Hypera brunneipennis, Hypera postica, Empoasca solana, Epitrix, Lygus hesperus, Lygus lineolaris, Trichoplusia ni.

The compounds of the invention can be used in cabbages to control, for example, Plutella xylostella, Pieris spp., Mamestra spp., Plusia spp., Trichoplusia ni, Phyllotreta, spp. , Spodoptera spp., Empoasca solana, Thrips spp., Spodoptera spp., Delia spp. The compounds of the invention are preferably used in cabbages to control Plutella xylostella Pieris spp., Plusia spp., Trichoplusia ', ni, Phyllotreta spp., Thrips spp.

The compounds of the invention can be used in rapeseed, for example, canola, to control, for example, Meligethes spp., Ceutor ync us napi, Psylloides spp.

The compounds of the invention can be used in potatoes, including sweet potatoes, to control, for example, Empoasca spp., Leptinotarsa spp., Diabrotica speciosa, Phthorimaea spp., Paratrioza spp., Maladera matrida, Agriotes spp. The compounds of the invention are preferably used in potatoes, including sweet potatoes, to control Empoasca spp., Leptinotarsa spp., Diabrotica speciosa, Phthorimaea spp., Paratrioza spp., Agriotes spp.

The compounds of the invention can be used in cotton to control, for example, Ant onomus grandis, Pectinophora spp., Helióthis spp., Spodoptera spp., Tetranychus spp., Epoasca spp., Thrips spp., Bemisia tabaci, Lygus spp., Phyllophaga spp., Scaptocoris spp. The compounds of the invention are preferably used in cotton to control Anthonomus granáis, Tetranychus spp., Empoasca spp., Thrips spp., Lygus spp., Phyllophaga spp., Scaptocoris spp.

The compounds of the invention can be used in control to control, for example, Leptocorisa spp., Cnaphaloc osis spp., Chilo spp., Scirpophaga spp., Lissorhoptrus spp., Oebalus pugnax. The compounds of the invention are preferably used in rice to control Leptocorisa sp. , Lissorhoptrus spp., Oebalus pugnax.

The compounds of the invention can be used in coffee to control, for example, Hypothenemus Hampei, Perileucoptera Coffeella, Tetranychus spp. The compounds of the invention are preferably used in coffee to control Hypothenemus Hampei, Perileucoptera coff it. \ The compounds of the invention can be used in citrus to control, for example, Panonychus citr'i, Pyllocoptruta oleivora, Brevipalpus spp., Diaphorina citri, Scirtothrips spp., Thrips spp., Unaspis spp., Ceratitis capitata, Phyllocnistis spp. The compounds of the invention are preferably used in citrus fruits to control Panonychus citri, Phyllocoptruta oleivora, Brevipalpus spp., Diaphorina citri, Scirtothrips spp., Thrips spp., Phyllocnistis spp.

The compounds of the invention can be used in almonds to control, for example, Amyelois transítella, Tetranychus spp.

The compounds of the invention can be used in fruit vegetables, including tomatoes, pepper, chilli, eggplant, cucumber, squash, etc., for the control of Thrips spp., Tetranychus spp., Polyphagotarsone us spp., Acülops spp., Empoasca spp., Spodoptera spp., Heliothis spp., Absolute uta, Liriomyza spp., Bemisia tabaci, Trialeurodes spp., Paratrioza spp., Frankliniella occidentalis, Frankliniella spp., Ant onomus spp., Phyllotreta spp., Amrasca spp., Epilachna spp., Halyomorpha spp., Scirtothrips spp., Leucinodes spp., Neoleucinodes spp. The compounds of the invention are preferably used in fruit vegetables, including, tomatoes, pepper, chili, eggplant, cucumber, zucchini, etc., to control, for example, Thrips spp., Tetranychus spp., Polyphagotarsonemus spp., Aculops spp. ., Empoasca spp., Spodoptera spp., Heliothis spp., Tuta absoluta, Liriomyza spp., Paratrioza spp., Frankliniella occidentalis, Frankliniella spp., Amrasca spp., Scirtothrips spp., Leucinodes spp., Neoleucinodes spp.

The compounds of the invention can be used in tea to control, for example, Pseudaulacaspis spp., Empoasca spp., Scirtothrips spp., Caloptilia theivora. The compounds of the invention are preferably used in tea to control Empoasca spp., Scirtothrips spp.

The compounds of the invention can be used in bulb vegetables, including onion, leek, etc., to control, for example, Thrips spp., Spodoptera spp., Heliothis spp. The compounds of the invention are preferably used in bulb vegetables, including onion, peru, etc., to control, Thrips spp.

The compounds of the invention can be used in grapes to control, for example, Empoasca spp., Lobesia spp., Frankliniella spp., Thrips spp., Tetranychus spp., Rhipiphorothrips Cruentatus, Eotetranychus Willamettei, Erythroneura Elegantula, Scaphoides spp. The compounds of the invention are preferably used in grapes to control Frankliniella spp., Thrips spp., Tetranychus spp., Rhipiphorothrips Cruentatus, Scaphoides spp.

The compounds of the invention can be used in pipe chips, including apples, pears, etc., to control for example Cacopsylla spp., Psylla spp., Panonychus ulmi, Cydia pomonella. The compounds of the invention are preferably used in pipe fruits, including apples, pears, etc., to control for example Cacopsylla spp., Psylla spp., Panonychus ulmi.

The compounds of the invention can be used in stone fruits to control, for example, Grapholita molesta, Scirtothrips spp., Thrips spp., Frankliniella s p., Tetranychus spp. The compounds of the invention are preferably used in bedding fruits to control Scirtothrips spp., Thrips spp., Frankliniella spp., Tetranychus spp. Accordingly, the invention provides a method for combating and / or controlling an animal pest, for example, an invertebrate animal pest, which comprises applying the pest to a pest site or a plant susceptible to attack by the pest. plague a pesticidally effective amount of a compound of formula (I). In particular, the invention provides a method for combating and controlling insects, mites, nematodes or molluscs which comprises applying an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula (I) or a composition containing a compound of formula ( I), a pest, the locus of a pest, preferably a plant or a plant susceptible to attack by a pest. The compounds; of formula (I) are preferably used against insects, mites or nematodes.

The term "plant", as used herein, includes seedlings, shrubs and trees. It will be understood that crops also include those crops that became tolerant to herbicides or classes of herbicides (eg, inhibitors of ALS, GS, EPSPS, PPO and HPPD) by conventional breeding methods or by genetic engineering.

An example of a culture that became tolerant to imidazolinones, eg, imazamox, by conventional breeding methods is the summer canola (canola) Clearfield®. Examples of crops that have become herbicide tolerant by genetic engineering methods include, for example, glyphosate and glufosinate resistant maize varieties commercially available with the RoundupReady® and LibertyLink® brands.

It should also be understood that - "crops" are those that have become resistant to insects, eg, by genetic engineering methods, for example, Bt maize (resistant to European corn borer), Bt cotton (resistant to cotton weevil) and also Bt potatoes (resistant to the Colorado beetle). Examples of Bt corn are corn hybrids 176 Bt of NK® (Syngenta Seeds). Examples of transgenic plants; which comprise one or more genes encoding an insecticidal resistance and expressing one or more toxins are KnockOut® (corn), Yield Gard® (corn), NuCOTIN33B® (cotton), Bollgard® (cotton), NewLeaf® (potatoes), NatureGard ® and Protexcta®. Plant crops or seed materials are therefore resistant to herbicides and at the same time; insect feeding (transgenic events "stacked"). For example, the seed may have the ability to express an insecticidal Cry3 protein while at the same time it is tolerant to glyphosate.

Crops will also be understood as those that are obtained by conventional methods of breeding or genetic engineering and contain so-called traits of egress (eg, improved storage stability, higher nutritive value and improved flavor).

To apply a compound of formula (I) as an insecticide, acaricide, nematicide or molluscicide to a pest, to a locus of a pest or to a plant susceptible to attack by a pest, a compound of formula (I) is generally formulated in a composition which includes, in addition to the compound of formula (I), a suitable inert diluent or carrier and, optionally, a surfactant (SFA). SFAs are chemical compounds capable of modifying the properties of an interface (for example, a liquid / solid, liquid / air or liquid / liquid interface) by reducing the interfacial tension and, thus, causing changes in other properties (for example, dispersion, emulsification and wetting). It is preferred that all: the compositions (both solid and liquid formulations) comprise, by weight, 0.0001 to 95%, more preferably 1 to 85%, for example 5 to 60% of a compound of formula (I). The composition is generally used to control pests such that a compound of formula (I) is applied at a rate of 0. lg to 10kg per hectare, preferably from lg to 6kg. ? per hectare, more preferably from lg to lkg per hectare.

When used in a seed treatment, a compound of formula (I) is generally used at a rate of O.OOOlg to lOg (for example O.OOlg or 0.05g), preferably 0.005ga lOg, more preferably 0.005ga 4g, per kilogram of seed.

In another aspect, the present invention provides a composition comprising a pesticidally effective amount of a compound of formula (I), in particular an insecticidal, acaricidal, nematicidal or molluscicidal composition comprising an amount insecticidally, acaricidally, nematicidally or molluscicidally effective a compound of formula (I) and a diluent or carrier suitable therefor. The composition is preferably an insecticidal, acaricidal, nematicidal or molluscicidal composition.

The compositions can be selected from various types of formulations, including spreadable powders (DP), soluble powders (SP), water soluble granules (SG), water dispersible granules (WG), wettable powders (WP), granules (GR) ( slow-release or rapid release), soluble concentrates (SL), oil miscible liquids (OL), ultra low volume liquids (UL), emulsifiable concentrates (EC, for its acronym in English), dispersible concentrates (DC, for its acronym in English), emulsions (oil in water (EW) and water in oil (EO)), microemulsions (ME), suspension concentrates (SC), aerosols, fogging / smoke formulations, capsule suspensions (CS, for their acronyms in English) and formulations for seed treatment. The type of formulation chosen in any case will depend on the specific objective envisaged and on the physical, chemical and biological properties of the compound of formula (I).

The spreadable powders (DP) can be prepared by mixing a compound of formula (I) with one or more solid diluents (for example natural clays, kaolin, pyrophyllite, bentonite, alumina, montmorillonite, diatomite, chalk, diatomaceous earth, calcium phosphates, carbonates of calcium and magnesium, sulfur, lime, flours, talc and other solid organic and inorganic carriers) and mechanically grinding the mixture to a fine powder.; Soluble powders (SP) can be prepared by mixing a compound of formula (I) with one or more water-soluble inorganic salts (such as sodium bicarbonate, sodium carbonate or magnesium sulfate) or one or more water-soluble organic solids ( such as polysaccharides) and, optionally, one or more wetting agents, one or more dispersing agents or a mixture of the agents to improve: dispersibility / solubility in water. Next, the mixture is milled to obtain a fine powder. You can also granular similar compositions to form water soluble granules (SG).

Wettable powders (P) can be prepared by mixing a compound of formula (I) with one or more solid diluents or carriers, one or more wetting agents and, preferably, one or more dispersing agents and, optionally, one or more suspending agents to facilitate dispersion in liquids. The mixture is then milled to obtain a fine powder. Similar compositions can also be granulated to form water dispersible granules (WG).

The granules (GR) can be formed by granulating a mixture of a compound of formula (I) and one or more solid diluents or carriers powder or from preformed blank granules by absorption of a compound of formula (I) (or a solution of the same, in a suitable agent) in a porous granular material (such as pumice stone, attapulgite clays, fuller's earth, diatomite, diatomaceous earths or crushed corn cobs) or by adsorption of a compound of formula (I) (or a solution of the same, eri a suitable agent) in a resistant core material (such as sands, silicates, mineral carbonates, sulfates or phosphates) and drying if necessary. Agents that are commonly used to facilitate absorption or adsorption include solvents (such as petroleum solvents) aromatics and aliphatics, alcohols, ethers, ketones and esters) and binding agents (such as polyvinyl acetates, polyvinyl alcohols, dextrins, sugars and vegetable oils). One or more other additives may also be included in the granules (for example, an emulsifying agent, wetting agent or dispersing agent).

Dispersible concentrates (DC) can be prepared by dissolving a compound of formula (I) in water or an organic solvent, such as a ketone, alcohol or glycol ether. These solutions may contain a surfactant (for example, to improve dilution in water or i prevent crystallization in a spray tank); Emulsifiable concentrates (EC) or emulsions! of oil in water (EW) can be prepared by dissolving a compound of formula (I) in an organic solvent (optionally containing one or more wetting agents, one or more emulsifying agents or a mixture of the agents). Organic solvents suitable for use in EC include aromatic hydrocarbons (such as alkylbenzenes or alkylnaphthalenes, for example, SOLVESSO 100, SOLVESSO 150; and SOLVESSO 200; SOLVESSO is a registered trademark), ketones (such as cyclohexanone or methylcyclohexanone) and alcohols (such as benzyl alcohol, furfuryl alcohol or butanol), N-alkylpyrrolidones (such as N-methylpyrrolidone or N-octylpyrrolidone), dimethylamides of fatty acids (such as the dimethylamide of a Ce-Cio fatty acid) and chlorinated hydrocarbons. An EC product can be spontaneously emulsified by adding water to produce an emulsion with sufficient stability to be spray-applied with suitable equipment. The preparation of an EW involves obtaining a compound of formula (I) as a liquid (if it is not a liquid at room temperature it can melt at a reasonable temperature, typically below 70 ° C) or in a solution (dissolving it in a solvent suitable) and then emulsify the liquid or solution in water containing one or more SFA, under high shear to produce an emulsion. Suitable solvents for use in EW include vegetable oils, chlorinated hydrocarbons (such as chlorobenzenes), aromatic solvents (such as alkylbenzenes or alkylnaphthalenes) and other suitable organic solvents which have low water solubility.

Microemulsions (ME) can be prepared by mixing water with a mixture of one or more solvents with one or more SFA to spontaneously produce a thermodynamically stable isotropic liquid formulation. A compound; of formula (I) is initially present in the water or the solvent / SFA combination. Suitable solvents for use in EM include those previously described herein for use in EC or EW. An ME can be a oil-in-water or water-in-oil system (one can determine which system is present by conductivity measurements) and may be suitable for mixing water-soluble or oil-soluble pesticides in the same formulation. A ME can be diluted in water, either by being maintained as a microemulsion or by forming a conventional oil-in-water emulsion.

The suspension concentrates (SC) may comprise aqueous or non-aqueous suspensions of finely divided insoluble solid particles of a compound of formula (I). The SCs can be prepared by beating with balls or beads the solid compound of formula (I) in a suitable medium, optionally with one or more dispersing agents, to produce a suspension of fine particles of the compound. One or more wetting agents may be included in the composition and a suspending agent may be included to reduce the rate at which the particles settle: Alternatively, a compound of formula (I) may be dry milled and added to water containing the agents described hereinabove, to produce the desired final product.

Aerosol formulations comprise a compound of formula (I) and a suitable propellant (e.g., n-butane). A compound of formula (I) can also be dissolved or dispersed in a suitable medium (e.g., water or a water-miscible liquid, such as n-propanol) to provide compositions for use in non-pressurized manually operated spray pumps.

A compound of formula (I) can be mixed in the dry state with a pyrotechnic mixture to form a composition suitable for generating, in a closed space, a smoke containing the compound.

Capsule suspensions (CS) can be prepared in a similar manner to the preparation of the EW formulations but with an additional polymerization step such that an aqueous dispersion of oil droplets is obtained, in which each drop of oil is encapsulated by a polymeric shell and contains a compound of formula (I) and, optionally, a carrier or diluent therefor. The polymeric shell can be produced both by an interfacial polycondensation reaction and by: a coacervation process. The compositions can be provided for controlled release of the compound of formula (I) and can be used for seed treatment. A compound of formula (I) can also be formulated in a biodegradable polymer matrix to provide a slow controlled release of the compound.; A composition may include one or more additives to improve the biological performance of the composition (e.g., improving wetting, retention or distribution). on surfaces; resistance to rain on treated surfaces; or intake or mobility of a compound of formula (I)). Such additives include surfactants, oil-based spraying additives, for example certain mineral oils or natural vegetable oils (such as soybean and rapeseed oil) and combinations of these with other bioenhancing adjuvants (ingredients that can aid or modify the action of a compound of formula (I)).

A compound of formula (I) can also be formulated for use as seed treatment, for example, as; a powder composition, including a powder for dry seed treatment (DS), a water soluble powder (SS) or a water dispersible powder for suspension treatment (WS) or as a liquid composition, including a fluid concentrate ( FS), a solution (LS) or a capsule suspension (CS). The preparations of the compositions of type DS, SS, WS, FS and LS are very similar to those of the compositions, of type DP, SP, WP, SC and DC, respectively, previously described. Compositions for treating seeds may include an agent to promote adhesion of the composition to the seed (for example, a mineral oil or a film-forming barrier).

The wetting agents, dispersing agents and emulsifying agents can be surface SFAs of the cationic, anionic, amphoteric or nonionic type.

Suitable SFAs of the cationic type include quaternary ammonium compounds (eg, cetyltrimethylammonium bromide), imidazolines and amine salts.

Suitable anionic SFAs include alkali metal salts of fatty acids, salts of aliphatic monoesters of sulfuric acid (eg, sodium lauryl sulfate), salts of sulfonated aromatic compounds (eg, sodium dodecylbenzenesulfonate, calcium dodecylbenzenesulfonate, butylnaphthalene sulfonate and mixtures of sodium di-isopropyl and tri-isopropyl-naphthalenesulfonates), ether sulfates, alcohol ether sulphates (for example, sodium lauryl-3-sulfate), ether carboxylates (for example, sodium lauryl-3-carboxylate) , phosphate ethers (products of the reaction between one or more fatty alcohols and phosphoric acid (predominantly monoesters) or phosphorus pentoxide (predominantly diesters), for example the reaction between lauric alcohol and tetraphosphoric acid, additionally these products may be ethoxylated), sulfosuccinamates, paraffin or olefin sulphonates, taurates and lignosulfonates.

Suitable SFAs of the amphoteric type include betaines, propionates and glycinates.

Suitable non-ionic type SFAs include condensation products of alkylene oxides, such as ethylene oxide, propylene oxide, butylene oxide or mixtures thereof, with fatty alcohols (such as oleyl alcohol or cetyl alcohol) or with alkylphenols (such as octylphenol, nonylphenol or octylcresol); partial esters derived from long-chain fatty acids or hexitol anhydrides; condensation products of the partial esters with ethylene oxide; block polymers (comprising ethylene oxide and propylene oxide); alkanolamides; simple esters (for example, polyethylene glycol fatty acid esters); amine oxides (for example, lauryldimethylamine oxide); and lecithins.

Suitable suspending agents include hydrophilic colloids (such as polysaccharides, polyvinylpyrrolidone or sodium carboxymethylcellulose) and spongy clays (such as bentonite or attapulgite).

A compound of formula (I) can be applied by any of the known means of applying pesticide compounds. For example, it can be applied, formulated or unformulated, to pests or locus of pests (such as the habitat of pests or a developing plant exposed to infestation of pests) for any part of the plant, including the foliage, the stems, the branches or roots, the seed before planting or other means in which the plants are developing or in which they are going to be planted (such as the earth that surrounds the roots, the earth in general , water from rice fields or hydroponic farming systems), can be applied dilute or can be sprayed, sprinkled, applied by dipping, applied as a cream or paste formulation, applied as a vapor or applied by distributing or incorporating a composition (such as a granular composition or a composition packed in a water-soluble bag ) on the ground or a watery environment.

A compound of formula (I) can also be injected into plants or sprayed onto vegetation using electrodynamic spray techniques or other low volume methods or applied by terrestrial or aerial irrigation systems.

Compositions for use as aqueous preparations (aqueous solutions or dispersions) are generally supplied in the form of a concentrate containing a high proportion of the active ingredient and the concentrate is added to water before use. It is often required that these concentrates, which can include DC, SC, EC, EW, ME, SG, SP, WP, WG and CS, can withstand long periods; storage and that, after storage, can be added to water to form aqueous preparations that remain homogeneous for a sufficient time to be possible to apply them with conventional spray kits. Such aqueous preparations may contain varying amounts of a compound of formula (I) (for example 0.0001 to 10%, by weight) depending on the object for which they are to be used.

A compound of formula (I) can be used in mixtures with fertilizers (for example, fertilizers containing nitrogen, potassium or phosphorus). Suitable formulation types include fertilizer granules. The mixtures preferably contain up to 25% by weight of the compound of formula (I).

The invention therefore also provides a fertilizer composition comprising a fertilizer and a compound of formula (I).

The compositions of this invention may contain other compounds with biological activity, for example, micronutrients or compounds with fungicidal activity or that possess plant growth regulating activity, herbicidal, insecticidal, nematicidal or acaricidal activity. The compound of formula (I) may be the sole active ingredient of the composition or may be mixed with one or more additional active ingredients such as a pesticide, for example, an insecticide, fungicide or herbicide or a synergistic product or growth regulator of the plant when appropriate. An additional active ingredient can provide a composition that has a spectrum: of broader activity or increased persistence at a locus; promoting the synergy of the activity or complementing the activity (for example, increasing the speed of the effect or overcoming the repellency) of the compound of formula (I), or help overcome or avoid the development of resistance to individual components. The particular additional active ingredient will depend on the desired utility of the composition. The compounds of the invention are also useful in the field of animal health, for example, they can be used against invertebrate parasitic pests, more preferably against invertebrate parasitic pests on or on an animal. Examples of pests include nematodes, trematodes, cestodes, flies, mites, ticks, lice, fleas, bed bugs and worms. The animal may be a non-human animal, for example, an animal associated with agriculture, for example, a cow, a pig, a sheep, a goat, a horse or a donkey, or a companion animal, for example, an animal. dog or a cat.

In a further aspect, the invention provides a compound of the invention for use in a method of therapeutic treatment.

In a further aspect, the invention relates to a method for controlling invertebrate parasitic pests in or on an animal comprising administering a pesticidally effective amount of a compound of the invention; The administration can be, for example, oral, parenteral or external administration, for example, 4 to the surface of the body of the animal. In a further aspect, the invention relates to a compound of the invention for controlling pests parasitic invertebrates in or on an animal. In a further aspect, the invention relates to the use of a compound of the invention in the manufacture of a medicament for controlling invertebrate parasitic pests in or on an animal.

In a further aspect, the invention relates to a method for controlling invertebrate parasitic pests comprising administering a pesticidally effective amount of a compound of the invention to the environment in which the animal resides.

In a further aspect, the invention relates to a method for protecting an animal from an invertebrate parasitic pest comprising administering to the animal a pesticidally effective amount of a compound of the invention. In a further aspect, the invention relates to a compound of the invention for use in the protection of an animal from an invertebrate parasitic pest. In a further aspect, the invention relates to the use of a compound of the invention in the manufacture of a medicament for protecting an animal from an invertebrate parasitic pest.; In a further aspect, the invention provides a method for treating an animal suffering from an invertebrate parasitic pest comprising administering to the animal a pesticidally effective amount of a compound of the invention. In a further aspect, the invention relates to a compound of the invention for use in the treatment of an animal suffering from an invertebrate parasitic pest. In a further aspect, the invention relates to the use of a compound of the invention in the manufacture of a medicament for treating an animal suffering from an invertebrate parasitic pest.

In a further aspect, the invention provides a pharmaceutical composition comprising a compound of the invention and a pharmaceutically suitable excipient.

The compounds of the invention can be used alone or in combination with one or more additional biologically active ingredients.

In one aspect, the invention provides a combination product comprising a pesticidally effective amount of a component A and a pesticidally effective amount of a component B, wherein component A is a compound of the invention and component B is a compound such as desévribe then.

The compounds of the invention can be used in combination with anthelmintic agents. Such anthelmintic agents include compounds selected from the class of macrocyclic lactone compounds such as ivermectin, avermectin, abamectin, emamectin, eprinomectin, doramectin, selamectin, moxidectin, nemadectin; and derivatives of milbemycin as described in | the EP-357460, EP-444964 and EP-594291. Additional anthelminthic agents include avermectin / milbemycin semisynthetic and biosynthetic derivatives such as those described in US-5015630, WO-9415944 and W0-9522552. Additional anthelminthic agents include benzimidazoles such as albendazole, cambendazole, fenbendazole, flubendazole, mebendazole, oxfendazole, oxybendazole, parbendazole and other components of the class. Additional anthelminthic agents include imidazothiazoles and tetrahydropyrimidines such as tetramisol, levamisole, pyrantel pamoate, oxantel or morantel. Additional anthelminthic agents include fluicides, such as triclabendazole and clorsulon, and cestocides, such as praziquantel and epsiprantel.

The compounds of the invention can be used in combination with derivatives and analogs of the class paraherquamide / marcfortine of anthelmintic agents; as well as the antiparasitic oxazolines, such as those disclosed in patents US-5478855, US-4639771 and, DE-19520936.

The compounds of the invention can be used; in combination with derivatives and analogs of the general class of dioxomorpholine antiparasitic agents, as described in patent WO 9615121, and also with anthelmintic active cyclic depsipeptides, such as those described in patents WO-9611945, WO-9319053, WO- 9325543, EP-6263,75, EP-382173, WO-9419334, EP-382173 and EP-503538.

The compounds of the invention can be used in combination with other ectoparasiticides; for example, fipronil; pyrethroids; organophosphates; regulators! of the growth of insects such as lufenuron; ecdysone agonists such as tebufenozide and the like; neonicotinoids such as imidacloprid and the like.

The compounds of the invention can be used in combination with terpene alkaloids, for example those described in International Patent Application Publication Nos. W095 / 19363 or WO04 / 72086, particularly the compounds disclosed therein.

Other examples of the biologically active compounds that can be used in combination with the compounds of the invention include, but are not limited to, the following: Organophosphates: acephate, azametifos, azinphos-ethyl, azinphos-methyl, bromophos, bromophos-ethyl, cadusaphos, chloretoxyphos, chlorpyrifos, chlorfenvinphos, chlormephos, demeton, demeton-S-methyl, demeth-S-methyl sulfone, dialiphos, diazinon, dichlorvos , dicrotophos, dimethoate, disulfoton, ethion, ethoprofos, etrimphos, famfur, fenamiphos, fenitrothion, fensulfothion, fenthion, flupirazophos, fonofos, formothion, fosthiazate, heptenofos, isazofos, isothioate, isoxatión, malathion, methacryphos, methamidophos, methidathion, methyl parathion , mevinfos, monocrotofs, naled, ometoate, oxydemeton-methyl, paraoxon, parathion, parathion-methyl, fentoate, phosalone, phospholon, phosphocarb, fosmet, phosphamidon, phorate, foxima, pirimiphos, pirimiphos-methyl, profenofos, propaphos, proetamfos, protiofos, piraclofos, pyridapentium, quinalphos, sulprofos, temephos, terbufos, tepupyrimphos, tetrachlorvinphos, thyméth, triazophos, trichlorfon, vamidothion.

Carbamates: alanicarb, aldicarb, 2-sec-butylphenyl methylcarbamate, benfuracarb, carbaryl, carbofuran, carbosulfan, cloetocarb, etiofencarb, phenoxycarb, fentiqcarb, furathiocarb, HCN-801, isoprocarb, indoxacarb, methibcarb, methomyl, 5-methyl-m- cumenylbutyryl (methyl) -carbamate, oxamyl, pyrimicarb, propoxur, thiodicarb, thiofanox, triazamate, UC-51717.

Pyrethroids: acrinatin, allethrin, alphamethrin, 5-benzyl-3-furylmethyl (E) - (1 R) -cis-2, 2-dimethyl-3- (2-oxothiol-3-ylidenemethyl) -cyclopropanecarboxylate, bifenthrin, beta -cifluthrin, cyfluthrin, α-cypermethrin, beta-cypermethrin, bioallethrin, bioallethrin ((S) -cyclopentyl ester), bioresmethrin, bifenthrin, NCI-85193, cycloprotrin, cyhalothrin, citritrine, cyphenothrin, deltamethrin, empenthrin, esfenvalerate, etofenprox, fenfluthrin, fenpropathrin, fenvalerate, flucythrinate, flumethrin, fluvalinate (D isomer), imiprotrin, cyhalothrin, lambda-cyhalothrin, permethrin, phenothrin, praletrin, pyrethrins (natural products), Resmethrin, tetramethrin, transfluthrin, teta-cypermethrin, silafluofen, t-fluvalinate, tefluthrin, tralometrine, Zeta-cypermethrin.

Regulators of the growth of arthropods: a) inhibitors of the synthesis of citin: benzoylüreas: chlorfluazuron, diflubenzuron, fluazuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novayuron, teflubenzuron, triflumuron, buprofezin, diophenol, hexythiazox, ethoxazole, chlorfentazine; b) ecdysone antagonists: halofenozide, methoxyfenozide, tebufenozide; c) juvenoids: pyriproxyfen, methoprene (including S-methoprene), phenoxycarb; d) inhibitors of lipid biosynthesis: spirodiclofen.

Other antiparasitic agents: acequinocyl, amitraz, AKD-1022, ANS-118, azadirachtin, Bacillus thuringiensis, bensultap, bifenazate, binapacryl, bromopropylate, BTG-504, BTG-505, camfeclor, cartap, chlorobenzilate, chlordimefor, chlorfenapyr, chromafenozide, clothianidin, cyromazine, diacloden, diafenthiuron, DBI-3204, dinactin, dihydroxmethyldihydroxypyrrole dina, dinobutone, dincycap, endosulfan, etiprole, etofenprox, fenazaquin, flumita, MTI-800, fenpyroximate, fluacripirim, flubenzimine, flubrocitrinate, flufenzine, flufenprox, fluproxyEen, halofenprox, hydramethylnon , IKI-220, kanemite, NC-196, neem guard, nidinorterfurán, nitenpirám, SD-35651, WL-108477, piridaril, propargite, protrifenbuto, pymetrozine, pyridaben, pyrimidifen, NC-1111, R-195, RH-0345, RH-2485, RYI-210, S-1283, S-1833, SI-8601, silafluofen, silomadine, spihosad, tebufenpyrad, tetradiphon, tetranactin, thiacloprid, thiocyclam, thiamethoxam, tolfenpyrad, triazamate, triethoxyspinosin, trinactin, verbutin, vertalec, YI-5301.

Fungicides: acibenzolar, aldimorf, ampropylphos, andoprim, azaconazole, azoxystrobin, benalaxyl, benomyl, bialaphos, blasticidin-S, bordeaux broth, bromuconazole, bupirimate, carpropamide, captafol, captan, carbendazim, chlorphenazole, chloroneb, chloropicrin, chlorothalonil, clozolinate, copper oxychloride, copper salts, ciflufenamid, cymoxanil, ciproconazole, cyprodinil, ciprofurám, RH-7281, diclocimet, diclobutrazol, dicloraezina, diclorán, difenoconazol, RP-407213, dimetomorf, domoxistrobina, diniconazol, diniconazol-M, dodina, enfós, epoxiconazole, famoxadone, fenamidone, fenarimol, fenbuconazole, fencaramide, fenpiclonil, fenpropidin, phenpropimorf, fentin acetate, fluazinam, fludioxonil, flumetover, flumorf / flumorlin, fentin hydroxide, fluoxastrobin, fluquinconazole, flusilazole, flutolanil, flutriafol, folpet, fosetyl- aluminum, furalaxyl, furametapir, hexaconazole, ipconazole, iprobenfos, iprodione, isoprothiolane, kasugamycin, krsoxim-methyl, mancoze b, maneb, mefenoxam, mepronil, metalaxyl, metconazole, metominostrobin / fenominostrobin, metrafenone, myclobutanil, neo-asozin, nicobifen, orisastrobin, oxadixyl, penconazole, pencicuron, probenazole, prochloraz, propamocarb, propioconazole, prochihazid, protioconazole, pirifenox, pyraclostrobin, pyrimethanil, pyroquilone, quinoxifen, spiroxamine, sulfur, tebucohazole, tetrconazole, thiabendazole, tifluzamide, thiophanate-methyl,, thiram, thiadinyl, triadimefon, triadimenol, tricyclazole, trifloxystrobin, triticonazole, validamycin, vinclozin.

Biological agents: Bacillus thuringiensis ssp aizawai, kurstaki, Bacillus thuringiensis endotoxin delta, baculovirus, entomopathogenic bacteria, viruses and fungi.

Bactericides: chlortetracycline, oxytetracycline, streptomycin.

Other biological agents: enrofloxacin, febantel, penetamate, moloxicam, cephalexin, kanamycin, pimobehdán, clenbuterol, omeprazole, tiamulin, benazepril, pyriprole, cefquinome, florfenicol, buserelin, cefovecin, tulatromycin, ceftiour, carprofen, metaflumizone, praziquarantel, triclabendazole.; When used in combination with other active ingrnts, the compounds of the invention are preferably used in combination with the following (wherein "T x" means a compound of formula (I) and in particular a compound selected from Tables 1 to Table 120, which may result in a synergistic combination with the active ingredient provided): imidacloprid + TX, enrofloxacin + TX, praziquantel + TX, pyrantel + TX embonate, febantel + TX, penetamate + TX, moloxicam + TX, cephalexin + TX, kanamycin + TX, pimobendan + TX, clenbuterol + TX , fipronil + TX, ivermectin + TX, omeprazole + TX, tiamulin + TX, benazepril + TX, milbemycin + TX, cyromazine + TX, thiamethoxam + TX, pyriprole + TX, deltamethrin + TX, cefquinome + TX, florfenicol + TX, buserelin + TX, cefovecin + TX, tulathromycin + TX, ceftiour + 'TX, selamectin + TX, carprofen + TX, metaflumizona TX, moxidectin + TX, raetoprene (including S-methoprene) + TX, clorsulon + TX, pirantel + TX, amitraz + TX, triclabendazole + TX, avermectin + TX, abamectin + TX, emamectin 4 TX, eprinomectin + TX, doramectin + TX, selamectin + TX, nemadectin + TX, albendazole + TX, cambendazole + TX, fenbendazole + TX, flubendazole + TX , mebendazole + TX, oxfendazole + TX, oxybendazole + TX, parbendazole + TX, tetramisol + TX, levamisole + TX, pamoa to de pirantel + TX, oxantel + TX, morantel + TX, triclabendazole + TX, epsiprantel + TX, fipronil + TX, lufenuron + TX, ecdysone + Tx or tebufenozide + Tx; more preferably, enrofloxacin +: TX, praziquantel + TX, pirantel + TX embonate, febantel +: TX, penetamate + TX, moloxicam + TX, cephalexin + TX, kanamycin + TX, pimobendan + TX, clenbuterol + TX, omeprazole + TX , tiamulin + TX, benazepril + TX, pyriprole + TX, cefquinome + TX, florfenicol + ?, buserelin + ?, cefovecin ', + ?, tulatromycin + TX, ceftiour + TX, selamectin + TX, carprofen + TX, moxidectin + TX, clorsulon + TX, pirahtel + TX, eprinomectin + TX , doramectin + TX, selamectin + TX, nemadectin + TX, albendazole + TX, cambendazole + TX, fenbendazole + TX, flubendazole + TX, mebendazole + TX, oxfendazole + TX, oxybendazole + TX, parbendazole + TX, tetramisol + TX, levamisole + TX, pyrantel pamoate + TX, oxantel + TX, morantel + TX, triclabendazole + TX, epsiprantel + TX, lufenuron + Tx or ecdysone + Tx; even more preferably enrofloxacin + TX, praziquantel + TX, pyrantel + TX embonate, febantel + TX, penetamate + TX, moloxicam + i TX, cephalexin + TX, kanamycin + TX, pimobendan + · TX, clenbuterol + TX, omeprazole + TX , tiamulin + TX, benazépril + TX, pyriprole + TX, cefquinome + TX, florfenicol + TX, buserelin + TX, cefovecin + TX, tulathromycin +] TX, ceftiour + TX, selamectin + TX, carprofen + TX, moxidectin + TX, clorsulón + Tx or pirantel + Tx.

Examples of ratios include 100: 1 to 1: 6000, 50: 1 to 1:50, 20: 1 to 1:20, even more specifically from 10: 1 to 1:10, 5: 1 to 1: 5, 2: 1 to 1: 2, 4: 1 to 2: 1, 1: 1, or 5: 1, OR 5: 2, OR 5: 3, OR 5: 4, OR 4: 1, OR 4: 2, OR 4 : 3, OR 3: 1, OR 3: 2, OR 2: 1, OR 1: 5, or 2: 5, OR 3: 5, OR 4: 5, OR 1: 4, or 2: 4, OR 3 : 4, or 1: 3, OR 2: 3, OR 1: 2 1: 600, OR 1: 300, or 1: 150, or 1:35, or 2:35, or 4:35, or 1:75 2:75, Or 4:75, Or 1: 6000, Or 1: 3000, Or 1: 1500, Or 1: 350, Or 2: 350, or 4: 350, or 1: 750, or 2: 750, or 4: 750. It is understood that the mixing ratios include, on the one hand, weight ratios and, on the other hand, molar ratios.

In particular, a combination is highlighted in which the additional active ingredient has a different site of action with respect to the compound of formula I. In certain instances, a combination with at least one other active ingredient of parasitic invertebrate pest control having a similar control spectrum but a different site of action will be particularly advantageous for resistance management. Thus, a combination product of the invention may comprise a pesticidally effective amount of a compound of formula I and a pesticidally effective amount of at least one active ingredient of parasitic invertebrate pest control having a similar control spectrum but a site of different action One skilled in the art will recognize that, since in the environment and in physiological conditions the salts of the chemical compounds are in equilibrium with their corresponding non-saline forms, the salts share the biological utility of the non-saline forms.; In that way, a wide variety of salts of the compounds of the invention (and active ingredients used in combination with the active ingredients of the invention) for the control of pests can be useful. invertebrates and parasites of animals. The salts include acid addition salts with inorganic or organic acids such as hydrobromic, hydrochloric, nitric, phosphoric, sulfuric, acetic, butyric, fumaric, lactic, maleic, malonic, oxalic, propionic, salicylic, tartaric, 4-toluenesulfonic or valeric The compounds of the invention also include N-oxides. Therefore, the invention comprises combinations of compounds of the invention, including N-oxides and salts thereof, and an additional active ingredient, including N-oxides and salts thereof.

Compositions for use in the health care of animals may also contain adjuvants and formulation additives, known to those skilled in the art as formulation aids (some of which may be considered to also function as solid diluents, liquid diluents or surfactants). The auxiliaries and formulation additives can control: the pH (buffer solutions), the foaming during processing (defoamers such as polyorganosiloxanes), the sedimentation of the active ingredients (suspending agents), the viscosity (thixotropic thickeners), the microbial growth inside containers (antimicrobial agents), freezing of products (antifreeze), color (dispersions of dyes / pigments), washing (film formers or self-adhesive), evaporation (agents that delay evaporation) and other attributes of the formulation. Film formers include, for example, polyvinyl acetates, polyvinyl acetate copolymers, polyvinyl pyrrolidone-vinyl acetate copolymer, polyvinyl alcohols, polyvinyl alcohol copolymers and waxes. Examples of auxiliaries and formulation additives include those mentioned in McCutcheon's Volume 2: Functional Materials, international and North American editions published by McCutcheon's Division, The Manufacturing Confectioner Publishing Co.; and in PCT Publication WO 03/024222.

The compounds of the invention can be applied without other adjuvants, but more often the application will be of a formulation comprising one or more active ingredients with suitable carriers, diluents and surfactants and possibly in combination with a food depending on the end use contemplated. One method of application involves spraying a dispersion in water or refined oil solution of the combination products. Compositions with spray oils, spray oil concentrations, self-adhesive spreaders, adjuvants, other solvents and synergistic agents such as piperonyl butoxide often improve the effectiveness of the compound. Sprayers can be applied from containers of sprays such as a can, a bottle or another container, either by means of a pump or by the administration of a pressurized container, for example, a can of pressurized aerosol spray. Spray compositions can take various forms, for example sprays, vapors, foams, gases or mists. In that way, the spray compositions may also comprise propellants, foaming agents, etc., as appropriate. A spray composition comprising a pesticidally effective amount of a compound of the invention and a carrier is highlighted. One embodiment of the spray composition comprises a pesticidally effective amount of a compound of the invention and a propellant. Representative propellants include, but are not limited to, methane, ethane, propane, butane, isobutane, butene, pentane, isopentane, neopentane, pentene, hydrofluorocarbons, chlorofluorocarbons, dimethyl ether and mixtures thereof. A spray composition (and a method using the spray composition dispensed from a spray container) used to control at least one parasitic invertebrate pest selected from the group consisting of mosquitoes, black flies, barn flies, deer flies, is highlighted. , horse flies, wasps, yellow wasps, hornets, ticks, spiders, ants, gnats and the like, included individually or in combinations.

The control of animal parasites includes controlling external parasites that are parasitic on the host animal's body surface (eg, shoulders, armpits, abdomen, inner thighs) and internal parasites that are parasitic on the animal's interior. host (for example, stomach, intestine, lung, veins, under the skin, lymphatic tissue). External parasitic pests or transmitters of diseases include, for example, chiggers, ticks, lice, mosquitoes, flies, mites and fleas. Internal parasites include heartworms, hookworms and helminths. The compounds of the invention may be particularly suitable for combating external parasitic pests. The compounds of the invention may be suitable for systemic and / or non-systemic control of infestation or infection by parasites in animals.

The compounds of the invention may be suitable for combating invertebrate parasitic pests that infest animal subjects, including wild animals, animals, breeding animals and agricultural work animals. Are breeding animals the term used to refer (singularly or plurally) to a domesticated animal raised intentionally? in an agricultural environment to produce, for example, food or fiber or for work; Examples of breeding animals include cattle, sheep, goats, horses, pigs, donkeys, camels, buffaloes, rabbits, chickens, turkeys, ducks and geese (for example, raised to obtain their meat, milk, butter, eggs, skin, leather, feathers and / or wool). By combating the parasites, fatalities and a low yield (in terms of meat, milk, wool, skin, eggs, etc.) are reduced, so that the application of the compounds of the invention allows a cheaper and simpler animal breeding .

The compounds of the invention may be suitable for combating invertebrate parasitic pests that infest companion animals and pets (eg, dogs, cats, birds and aquarium fish), research animals and experiments (eg, hamsters, guinea pigs, rats). and mice),., as well as animals bred for / in zoos, wild habitats and / or circuses.

In one embodiment of this invention, the animal is preferably a vertebrate and, more preferably, a mammal, bird or fish. In a particular embodiment, the animal subject is a mammal (including, great apes, such as humans). Other mammalian subjects include primates: (e.g., monkeys), bovine (e.g., cattle or dairy cows), swine (e.g., pigs or pigs), sheep (e.g., goats or sheep), horses (e.g., horses) ), canines (eg dogs), felines (eg domestic cats), camels, deer, donkeys, buffaloes, antelopes, rabbits and rodents (eg, guinea pigs, squirrels, rats, mice, gerbils and hamsters). The birds include members of the families Anatidae (swans, ducks and geese), Columbidae (for example, pigeons and doves), Phasianidae (for example, partridges, roosters and turkeys), Thesienidae (for example, domestic chickens), Psittacines ( for example, parrots, macaws and parrots), game birds and ratites (for example, ostriches).

Birds treated or protected by the compounds of the invention may be associated with commercial or non-commercial poultry farming. These include birds of the Anatidae families, such as swans, geese and ducks, Columbidae, such as domestic pigeons and pigeons, Phasianidae, such as partridge, rooster and turkey, Thesienidae, such as domestic chickens, and Psittacines, such as parakeets, Macaws and parrots, for the pet or collectible market, among others.

For the purposes of the present invention, it is understood that the term "fish" includes, but is not limited to, the Teleosti grouping of fish, that is, teleosts. Both the order Salmoniformes (which includes the family Salmonidae) and the order Perciformes (which includes the family Centrarchidae) are contained within the Teleosti cluster. Examples of possible recipient fish include Salmonidae, Serranidae, Sparidae, Cichlidae and Centrarchidae, among others.

It is also contemplated that other animals benefit with the methods of the invention, including marsupials (such as kangaroos), reptiles (such as breeding turtles) and other economically important domestic animals for which the methods of the invention are safe and effective in the treatment or prevention of infection or infestation by parasites.

Examples of parasitic invertebrate pests controlled by the administration of a pesticidally effective amount of the compounds of the invention to an animal to be protected include ectoparasites (arthropods, mites, etc.) and endoparasites (helminths, eg, nematodes, trematodes, cestodes). , acanthocephalic, etc.).

The disease or the group of diseases described in general as helminthiasis are due to the infection of a host animal with known parasitic worms, such as helminths. The term 'helminths' includes nematodes, trematodes, cestodes and acanthocephalics. Helminthiasis is a prevalent and serious economic problem with domesticated animals such as pigs, sheep, horses, cows, goats, dogs, cats and poultry.

Among the helminths, the group of worms described-? as nematodes it causes the extension and at times the serious infection in several species of animals.

The nematodes that are considered to be treated by the The compounds of the invention include, but are not limited to, the following genera: Acanthocheilonema, Aelurostrohgylus, Ancylostoma, Angiostrongylus, Ascaridia, Ascaris, Brugia, Bunostomum, Capillaria, Chabertia, Cooperia, Crenosoma, Dictyocaulus, Dioctophyme, Dipetalonema, Diphylloboihrium, DirofHaría, Dracunculus , Enterobius, Filaroides, Haemonchus, Heterakis, La.gochila.sca.ris, Loa, Mansonella, Muellerius, Necator, Nematodirus, Oesophagostomum, Ostertagia, Oxyuris, Parafilaria, Parascaris, Physaloptera, Protostrongylus, Setaria, Spirocerca, StephanofHaría, Strongyloides, Strongylus , Thelazia, Toxascaris, Toxocara, Trichinella, Trichonema, Trichostrongylus, Trichuris, Uncinaria and Wuc ereria.

Of the above, the most common genera of nematodes that infect the animals referred to above are Haemonchus, Trichostrongylus, Ostertagia, Nematodirus, Cooperia, Ascaris, Bunostomum, Oesophagostomum, Chabertia, Trichuris, Strongylus, Trichonema, Dictyocaulus, Capillaria. , Heterakis, Toxocara, Ascaridia, Oxyuris, Ancylosto a, Uncinaria, Toxascaris and Parascaris. Certain of these, such as Nematodirus, Cooperia and Oesophagostomum mainly attack the intestinal tract while others, such as Haemonchus and Ostertagia, are more prevalent in the stomach while others such as Dictyocaulus are found in the lungs. Even other parasites can localized to other tissues such as heart tissue or blood vessels, subcutaneous and lymphatic and the like.

The trematodes that are contemplated to be treated by the invention and by the methods of the invention include, but are not limited to, the following genera: Alaria, Fasciola, Nanophyetus, Opisthorchis, Paragonimus and Schistosoma.

The tapeworms that are contemplated to be treated by the invention and by the methods of the invention include, but are not limited to, the following genera: Diphyllobothrium, Diplydium, Spirometra and Taenia.

The most common genera of parasites from the gastrointestinal tract of humans are Ancylostoma, Necator, Ascaris, Strongy hides, Trichinella, Capillaria, Trichuris and Enterobius. Other medically important genera of parasites found in blood or other tissues and organs outside the gastrointestinal tract are filarial worms such as uchereria, Brugia, Onchocerca and Loa, as well as Dracunculus and extra intestinal stages of worms. Intestines St Onygyloides and Trichinella.

Numerous other genera and species of helminths are known in the art, which are also contemplated to be treated by the compounds of the invention. These are listed in great detail in Textbook of Veterinary Clinical Parasitology, Volume 1, Helminths, E. J. L. Soulsby, F. A. Davis Co., Philadelphia, Pa .; Helminths, Arthropóds and Protozoa, (6th Edition of Monnig's Veterinary Helminthology and Entomology), E. J. L. Soulsby, Williams and Wilkins Co., Baltimore, Md.

The compounds of the invention can be effective against several animal ectoparasites (e.g., arthropod ectoparasites of mammals and birds).

Pests of insects and acariñas include, for example, stinging insects such as flies and mosquitoes, expensive ticks, lice, fleas, field bugs, parasitic crests and the like.

Adult flies include, for example, the fly of the horns or Haematobia irritans, the horse fly or Tabanus spp. , the stable fly or Stomoxys calcitrans, the black fly or Simulium spp., the deer fly or Chrysops spp., the louse fly or Melophagus ovinus and the tse-tse fly or Glossina spp. Parasitic fly crests include, for example, the buzzard (Oestrus ovis and Cuterebra spp.), The phaenicia spp., The borer worm or Cochliomyia hominivorax, cattle larvae or Hypoderma, spp., The wool worm and the Gastrophil of horses. Mosquitoes include, for example, Culex spp., Anopheles spp. and Aedes spp.

Mites include Mesostigmalphatalpha spp. > for example mesostigmatids such as mites of the hen, Dermalphanyssus galphallinalphae; Itchy mites such as Sarcoptidae sp. , for example, Salpharcoptes scalphabiei; scabies mites such as Psoroptidae spp., including Chorioptes bovis and Psoroptes ovis; chiggers, for example, Trombiculidae spp., for example the nigua of North America, Trombicula alfreddugesi.

Ticks include, for example, soft-bodied ticks including Argasidae spp., For example, Argalphas spp. and Ornithodorqs spp .; hard-bodied ticks, including Ixodidae spp., for example, Rhipicephalphalus sanguineus, Dermacentor variabilis, Dermacentor andersoni, Amblyomma americanum, Ixodes scapularis and other Rhipicephalus spp. (including the previous Boophilus genera).

Lice include, for example, sucking lice, for example, Menopon spp. and Bovicola spp .; biting louse, for example, Haematopinus spp., Linognathus spp. and Solenopotes spp. : Fleas include, for example, Ctenocephalides spp., Such as dog flea (Ctenocephalides canis) and cat flea [Ctenocephalides felis); Xenopsylla spp. such as flea from the eastern rat (Xenopsylla cheopis); and Pulex spp. , such as human flea (Pulex irritans).

Field bugs include, for example, Cimicidae or, for example, the common bugs (Cimex lectularius); Triatominae spp., Including triatomine bugs, also known as vinchucas; for example Rhodnius prolixus and Triatoma spp.

Generally, flies, fleas, lice, mosquitoes, gnats, mites, ticks and helminths cause great losses to the livestock sector and pets. Arthropod parasites are also a nuisance to humans and can be vectors of organisms that cause diseases in humans and animals.

Numerous other parasitic invertebrate pests are known in the art, which are also contemplated to be treated by the compounds of the invention. i invention. These are listed in great detail in Medical and Veterinary Entomology, D. S. Kettle, John iley and Sons, 1 New York and Toronto; Control of Arthropod Pests of Livestock: A Review of Technology, R. O. Drummand, J. E. George, and S. E. Kunz, CRC Press, Boca Raton, Fia. ! The present invention also provides a method for controlling pests (such as mosquitoes and other disease vectors, see also http://www.who.int/malaria/vector_control/irs/en/). In one embodiment, the method for controlling pests comprises applying the compositions of the invention to the target pests:, to their locus or to the surface or substrate by brush, roller, spray, diffusion or immersion. By way of example, the method of the invention contemplates an IRS application (of internal residual spray) to a surface such as a wall, ceiling or floor surface. In another embodiment, it is contemplated to apply the compositions to a substrate such as a non-woven or cloth material in the form of (or that can be used in the manufacture of) nets, clothing, bedding, curtains and tents.

In one embodiment, the method for controlling pests comprises applying a pesticidally effective amount of the compositions of the invention to the targeted pests, to their locus or to a surface or substrate so as to provide an effective residual pesticidal activity on the surface or substratum. The application can be carried out by brush, roller, spray, diffusion or immersion of the pesticidal composition of the invention. By way of example, the method of the invention contemplates an IRS application on a surface such as a wall, ceiling or floor surface to provide effective residual pesticidal activity on the surface. In another embodiment, it is contemplated to apply the compositions for residual pest control on a substrate such as a tea material in the form of (or that can be used in the manufacture of) nets, clothing, bedding, curtains and tents. .

Substrates including non-woven materials: fabrics or nets to be treated can be made of natural fibers such as cotton, raffia, jute, linen, sisal, burlap or wool, or synthetic fibers such as polyamide, polyester, polypropylene, polyacrylonitrile or the like. The polyesters are particularly suitable. Textile treatment methods are disclosed, for example, in Hándbuch Textilveredlung: Band 1: Ausrüstung, Band 2: Farbgebung, Band 3: Beschichtung, Band 4: Umwelttechnik; Verlag: Deutscher Fachverlag Auflage: 15., überarbeitete Ausgabe (April 17, 2006); ISBN-10: 3866410123; ISBN-13: 978-3866410121, see especially Band 1: Ausrüstung pages 27-198, more preferably on page 118; or WO2008151984 or WO2.003034823 or US5631072 or O200564072 or O2006128870 or EP1724392 or WO2005064072 or WO2005113886 or WO2007090739.

The compounds of the invention can also be effective against ectoparasites, including: flies such as Haematobia (Lyperosia) irritans (fly of the horns), Simulium spp. (black fly), Glossina spp. (ts-ts fly), Hydrotaea irritans (head fly), Musca autúmnalis (face fly), Musca domestica (house fly), Morellia simplex (sweat fly), Tabanus spp. (horsefly), Hypoderma bovis, Hypoderma lineatu, Lucilia sericata, Lucilia cuprina (greenbottle), Calliphora spp.; (blue fly), Protophormia spp., Oestrus ovis (nasal fly), Culicoides spp. (mosquitoes), Hippobosca equine, Gastrophilus intestinalis, Gastrophilus haemorrhoidalis and Gastrophilus nasalis; lice such as Bovicola (Damalinia) bovis, Bovicola equi, Haematopinus asini, Felicola subrostratus, Heterodoxus spiniger, Lignonathus setosus and Trichodectes canis;; louse flies such as Melophagus ovinus; and mites such as Psoroptes spp. , Sarcoptes scabei, Chorioptes bovis, Demodex equi, Cheyletiella spp., Notoedres cati, Trombicula spp. and Otodectes cyanotis (ear mites). : The treatments of the invention are carried out by conventional means, such as by enteral administration in the form of, for example, tablets, capsules, beverages, preparations of potions, granules, pastes, boluses, processes through feeding or suppositories; or by parenteral administration, such as, for example, by injection (including intramuscular, subcutaneous, intravenous, intraperitoneal) or implants; or by nasal administration.

When the compounds of the invention are applied in combination with an additional biologically active ingredient, they can be administered separately, eg, as separate compositions. In this case, the biologically active ingredients can be administered simultaneously or sequentially. Alternatively, biologically active ingredients can be components of a composition.

The compounds of the invention can be administered in a controlled release form, for example, in slow-release formulations administered subcutaneously or orally.

Generally, a parasiticidal composition according to the present invention comprises a compound of the invention, optionally in combination with an additional biologically active ingredient, or N-oxides or salts thereof, with one or more pharmaceutically or veterinarily acceptable carriers comprising excipients and auxiliaries selected with respect to the intended route of administration (e.g., oral or parenteral administration such as injection) and in accordance with standard practice. In addition, a suitable carrier is selected based on compatibility with one or more active ingredients in the composition, including considerations such as stability with respect to pH and moisture content. Therefore, compounds of the invention are highlighted to protect an animal from an invertebrate parasitic pest comprising a pesticidally effective amount of a compound of the invention, optionally in combination with an additional biologically active ingredient and at least one carrier.

For parenteral administration including intravenous, intramuscular or subcutaneous injection, the compounds of the invention may be formulated in suspension, solution or emulsion in oily or aqueous vehicles, and may contain adjuncts such as suspending, stabilizing and / or suspending agents. dispersion.

The compounds of the invention can also be formulated by bolus injection or continuous infusion. Pharmaceutical compositions for injection include aqueous solutions of water-soluble forms of active ingredients (eg, a salt of an active compound), preferably in physiologically compatible buffer solutions containing other excipients or auxiliaries as are known in the pharmaceutical formulating art. Additionally, suspensions of the active compounds can be prepared in a lipophilic vehicle. Suitable lipophilic carriers include fatty oils such as sesame oil, esters of synthetic fatty acids such as ethyl oleate and triglycerides or materials such as liposomes.

Aqueous injection suspensions may contain substances that increase the viscosity of the suspension; such as sodium carboxymethyl cellulose, sorbitol or dextran. Formulations for injection may be presented in unit dosage form, for example, in ampoules i or in multi-dose containers. Alternatively, the active ingredient may be in powder form for constitution with a suitable vehicle, eg, sterile, pyrogen-free water, before use.

In addition to the formulations described above, The compounds of the invention can also be formulated as a depot preparation. Long-acting formulations can be administered by implantation (eg, subcutaneously or intramuscularly) or by intramuscular or subcutaneous injection.

The compounds of the invention can be formulated for this route of administration with suitable polymeric or hydrophobic materials (eg, in an emulsion with a pharmacologically acceptable oil), with ion exchange resins, or as a moderately soluble derivative such as, in a manner no taxative, a moderately soluble salt.

For administration by inhalation, the compounds of the invention can be administered in the form of an aerosol spray using a pressurized pack or a nebulizer and a suitable propellant, for example, non-exhaustively, dichlorodifluoromethane, trichlorofluoromethane, dichlorotetrafluoroethane or carbon dioxide. In the case of a pressurized aerosol, the dosage unit can be controlled by providing a valve to deliver a metered amount.

Capsules and cartridges of, for example, gelatin for use in an inhaler or insufflation can be formulated containing a powder mixture of the compound and a suitable powder base such as lactose or starch.

The compounds of the invention may have favorable pharmacokinetic and pharmacodynamic properties that provide systemic availability of oral administration and ingestion. Therefore, after ingestion of an animal to be protected, effective concentrations such as parasiticides of a compound of the invention in the bloodstream can protect the treated animal from blood-sucking pests such as fleas, ticks and lice. Therefore, a composition for protecting an animal from an invertebrate parasitic pest in a form for oral administration (i.e., comprising, in addition to a parasiticidally effective amount of a compound of the invention, one or more carriers selected from binders and fillers suitable for oral administration and concentrated feed carriers).

For oral administration in the form of solutions (the form that is most readily available for absorption), emulsions, suspensions, pastes, gels, capsules, tablets, boluses, powders, granules, retention blocks in the rumen and feed / water / for lick, the compounds of the invention can be formulated with binders / fillers known in the art which are suitable for compositions for oral administration, such as sugars and sugar derivatives (eg, lactose, sucrose, mannitol, sorbitol), starch (eg. , corn starch, wheat starch, rice starch, potato starch), cellulose and derivatives (e.g., methylcellulose, carboxylmethylcellulose, ethylhydroxycellulose), protein derivatives (e.g., zein, gelatin) and synthetic polymers (e.g., polyvinyl alcohol, polyvinylpyrrolidone). If desired, lubricants (e.g., magnesium stearate), disintegrating agents (e.g., crosslinked polyvinylpyrrolidinone, agar, alginic acid) and dyes or pigments may be added. Pastes and gels often also contain adhesives (eg, acacia, alginic acid, bentonite, cellulose, xanthan gum, colloidal magnesium aluminum silicate) to help keep the composition in contact with the oral cavity and not be easily expelled. .

In one embodiment, a composition of the present invention is formulated into a chewable and / or edible product (e.g., a chewable candy or edible tablet). The product would ideally have a pleasant flavor, texture and / or aroma for the animal to be protected to facilitate oral administration of the compounds of the invention.

If the parasiticidal compositions are in the form of concentrates for feeding, the carrier is generally selected from high-yield foods, feed cereals or protein concentrates.

Compositions containing concentrates for feeding may, in addition to the parasiticidal active ingredients, comprise additives that promote the health or growth of the animal, improving the quality of the meat of the animals for slaughter or otherwise useful for animal husbandry. .

These additives may include, for example, vitamins, antibiotics, chemotherapeutics, bacteriostats, fungistats, coccidiostats and hormones. j The compound of the invention can also be formulated in linear compositions such as suppositories or retention lines, using, for example, conventional suppository bases such as cocoa butter or other glycerides.

I Formulations for the method of this invention may include an antioxidant, such as BHT (butylated hydroxy-butylene). The antioxidant is generally present in amounts of 0.1-5 percent (w / vol). Some of: the formulations require a solubilizer, such as oleic acid, to dissolve the active agent, particularly if spinosad is included. Common diffusion agents used in these sprayable formulations include isopropyl myristate, isopropyl palmitate, caprylic / capric acid ether of saturated Ci2-Ci8 fatty alcohols, oleic acid, oleyl ester, ethyl oleate, triglycerides, oils of silicone and dipropylene glycol methyl ether. ' The Poured application formulations for the method of this invention are prepared according to known techniques. When the application form by pouring is a solution, the parasiticide / insecticide is mixed with the carrier or vehicle using heat and stirring if necessary. They can be added I auxiliary or additional ingredients to the mixture of active agent and carrier or can be mixed with the active agent before the addition of the carrier. The formulations of I application by. poured in the form of emulsions or suspensions are prepared in a similar manner using known techniques. í Other administration systems for relatively hydrophobic pharmaceutical compounds may be employed. Liposomes and emulsions are well known examples of vehicles or carriers for administration of drugs. i I hydrophobic In addition, organic solvents such as dimethyl sulfoxide can be used, if necessary! The application rate required for an effective control of invertebrate parasitic pests (eg, "pesticidally effective amount") will depend on factors such as the species of parasitic invertebrate pests! which must be controlled, the life cycle of the pest, the stage of life, its size, location, time of year, crop or host animal, feeding behavior, mating behavior, humidity of the environment, temperature and the like.

A person skilled in the art can easily determine the pesticidally effective amount necessary for the desired level of control of parasitic invertebrate pests, j In general, for veterinary use, the compounds of the invention are administered in a pesticidally effective amount to an animal, particularly a homeothermic animal, which must be protected from parasitic invertebrate pests. ' A pesticidally effective amount is the amount of active ingredient necessary to achieve an observable effect by decreasing the appearance or activity of the pest. i invertebrate parasitic objective. One skilled in the art will appreciate that the pesticidally effective dose may vary for the various compounds and compositions useful for the method of the present invention, the desired effect and duration of pesticide, the target parasitic invertebrate pest species, the animal to be protected. , the mode of application and the like, and the amount needed to achieve a particular result can be determined through simple experiments. ! For oral or parenteral administration to animals, a dose of the compositions of the present invention administered at suitable intervals is generally in the range of 0.01 mg / kg to about 100 mg / kg and preferably about 0.01 mg / kg. approximately 30 mg / kg of body weight of the animal.

Adequate intervals for the administration of; the compositions of the present invention to animals are in the range of from approximately daily to approximately annually. The administration intervals that are in the range of about once a week to about once every 6 months are highlighted. Particularly noteworthy are the monthly administration intervals (ie, administer the compounds to the animal once a month).

Within the scope of the invention, the useful plants that must be protected typically comprise the í following plant species: cereal (wheat, barley, rye, oats, rice, corn, sorghum and related species); beet (sugar beet and fodder beet) '; fruit of pipe, drupe and berries (apples, pears, plums, peaches, almonds, berries, strawberries, raspberries and blackberries); leguminous plants (beans, lentils, peas, plants, soy); plants to make oil (rapeseed, mustard, poppies, olives, sunflowers, coconut, plants to make castor oil, cocoa beans, peanuts); cucumber plants (pumpkins, cucumber, melons); fiber plants (cotton, linen, hemp, jute); citrus fruits (oranges, lemons, grapefruit, tangerines); vegetables (spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, peppers); lauraceae (avocado, Cinnamomum, camphor) or plants such as tobacco, nuts, coffee, aubergines, sugar cane, tea, pepper, vine, and hops, bananas and natural rubber plants, as well as ornamentals.

It will be understood that the term "useful plants" also includes useful plants that have become tolerant to j i herbicides, such as bromoxmil, or to classes of herbicides i (such as, for example, inhibitors of HPPD, inhibitors of j ALS, for example, primisulfuron, prosulfuron j and i trifloxysulfuron, EPSPS inhibitors (5-enolpirvil-shikimate-3-phosphate synthase) synthetase) or inhibitors as a result of conventional methods of selective culture or genetic engineering. An example of a crop that has been I imidazolinone tolerant, for example, imazammox, by conventional methods of cultivation (mutagenesis) is Clearfield® summer rapeseed Examples of crops that have become tolerant to herbicides or classes of herbicides by genetic engineering methods include corn varieties resistant to ! glyphosate and glufosinate available on the market with the brands RoundupRead ®, Herculex I ® and LibertyLink ®. · 'I It should be understood that the term "useful plants" also includes useful plants that have been transformed i by using recombinant DNA techniques so that i are able to synthesize one or more toxins that act selectively such as, for example, those known to come from bacteria that produce toxins, especially those of the genus Bacillus.

Some examples of these plants are: YieldGard ® (variety of corn that expresses a CrylA (b) toxin; YieldGard Rootworm ® (variety of corn that expresses a CryIIIB toxin (bl)), - YieldGard Plus ® (corn variety that expresses a CrylA toxin (b) and a CryIIIB (bl) toxin) Starlink ® i (variety of corn expressing a Cry9 (c)) toxin; Herculex I® (variety of corn expressing a CryIF (a2) toxin and the enzyme phosphinothricin N-acetyltransferase (PAT) to achieve tolerance to the herbicide glufosinate-ammonium); NuCOTlvI 33B ® (variety cotton that expresses a CrylA toxin (c)); Bollgard I ® (cotton variety that expresses a CrylA (c)) toxin Bollgard II® (cotton variety that expresses a CrylA toxin (c) and a CrylIA toxin (b)); VipCot ® (variety of cotton that expresses a VIP toxin); NewLeaf® (variety of potato expressing a CryIIIA toxin); NatureGard®, Agrisure® GT Advantage (glyph-toothed trait GA21 to), Agrisure® CB Advantage (trait Btll of corn borer worm (CB)), Agrisure® RW (trait of rootworm: corn) and Protecta® . I It will be understood that the term "useful plants" also includes useful plants that have been transformed from: such way by the use of recombinant DNA techniques which are capable of synthesizing antipathogenic substances with a selective action such as, for example, the so-called "proteins related to pathogenesis" (PRP, see, for example, EP-A-0 392 225). Examples of antipathogenic substances and transgenic plants capable of synthesizing antipathogenic substances are known, for example, from EP-A-0 392 225, WO 95/33818 and EP-A-0 353 191. The methods for producing Transgenic plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above.

The term "locus" of a useful plant, as used herein, is intended to encompass the place where the useful plants are grown, where the plant propagation materials of the useful plants are planted or where they are grown.

I they will place plant propagation materials on useful plants in the soil. An example of this locus is a field in which grow plants grow. j It will be understood that the term "plant propagation material" refers to generative parts of the plant, such as seeds, which can be used for the multiplication of the latter and to plant material, such as cuttings or tubers, for example. , potatoes. There may be mentioned, for example, seeds (in the strict sense), roots, fruits, tubers, bulbs, rhizomes and parts of plants. You can also mention the germinated plants and the seedlings that are going to be transplanted after the I germination or after they emerge from the earth. These seedlings can be protected before transplantation by a total or partial immersion treatment. Preferably, it will be understood that the "plant propagation material" refers to the seeds.

The compounds of formula I can be used in an unmodified form or, preferably, together with cers and adjuvants conventionally employed in the art of the formulation.

The terms "plant" or "useful plants", as used herein, include seedlings, shrubs and trees. It will be understood that the term "crop" also includes crop plants that have been so transformed by the use of recombinant DNA techniques that are capable of synthesizing one or more toxins that act selectively, as known, for example, from from bacteria that produce toxins, especially those of the genus Bacillus. ' Toxins that can be expressed by transgenic plants include, for example, insecticidal proteins of Bacillus cereus or Bacillus popilliae; or Bacillus thuringiensis insecticidal proteins, such as d-endotoxins, for example, CrylAb, CrylAc, CrylF, CrylFa2, Cry2Ab, Cry3A, Cry3Bbl or Cry9C, or vegetative insecticidal proteins (Vip), for example, Vipl, Vip2, Vip3 or Vip3A; or insecticidal proteins from bacteria-colonizing nematodes! for example Photorhabdus spp. or Xenorhabdus spp. (as Photorhabdus luminescens, Xenorhabdus nematophilus; I produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins and other insect-specific neurotoxins; toxins produced by fungi, such as Streptomyces toxins, plant lectins, such as peas lectins, barley lectins or winter chime lectins; agglutinins; proteinase inhibitors, as trypsin inhibitors, serine protease inhibitors, I patatma, cystatin, papain inhibitors; ribosome inactivation proteins (PIR), such as ricin, maize-PIR, abrin, lufina, saporin or bryodin, - steroid metabolism enzymes, such as 3-hydroxysterodeoxydase, ecdysteroid-jUDP-glycosyltransferase, cholesterol oxidases, ecdysone inhibitors, HMG -COA reductase, ion channel blockers, as blockers of sodium or calcium channels, juvenile hormone esterase, diuretic hormone receptors, synthase. of stilbeno, syntena of bibencil, chitinasas and glucanases. · t In the context of the present invention, d-endotoxins, for example, CrylAb, CrylAc, CrylF, CrylFa2, Cry2Ab, Cry3A, Cry3Bbl or Cry9C, or proteins, should be understood as vegetative insecticides (Vip), for example Vipl, Vip2, Vip3 or Vip3A, specifically also hybrid toxins, truncated toxins and modified toxins. Hybrid toxins are produced by recombination by a novel combination of different protein domains (see, for example, WO 02/15701). Truncated toxins, for example, a truncated CrylAb toxin, are known. In the case of modified toxins, one or more amino acids of the toxin of natural origin is replaced. In these substitutions! of amino acids, preferably artificial antibody protease recognition sequences are inserted into the toxin, as, for example, in the case of Cry3A055, a cathepsin G recognition sequence is inserted into a Cry3A toxin (see WO 03/018810) .

Examples of these toxins or transgenic plants capable of synthesizing these toxins are described in, for example, EP-A-0 374 753, WO 93/07278,: WO 95/34656, EP-A-0 427 529, EP -A-451 878 and WO 03/052073. j The processes for preparing these transgenic plants are generally known to the person skilled in the art and are described, for example, in the previously mentioned publications. Cryl-type deoxyribonucleic acids and their preparation are described, for example, in WO 95/34656, EP-A-0 367 474, EP-A-0 401 979 and WO 90/13651.

The toxin contained in transgenic plants: It confers tolerance against harmful insects. These insects can belong to any taxonomic group of insects, but usually belong to the group of insects.

I the beetles (Coleoptera), insects with two wings (Diptera) ! and butterflies (Lepidoptera). ! Transgenic plants that contain one or more genes that code for an insecticidal resistance and express one or more toxins are known and some of them are found Commercially available. Some examples of these plants are: YieldGard® (corn var that expresses a CrylAb toxin); YieldGard Rootworm® (corn var that expresses a Cry3Bbl toxin); YieldGard Plus® (var of corn that expresses a CrylAb toxin and a Cry3Bbl toxin); Starljink® (var of corn that expresses a Cry9C toxin); Herculéx I® (var of corn that expresses a CrylFa2 toxin and the highest phosphinothricin N-acetyltransferase (PAT) to achieve tolerance to the glufosinate-ammonium herbicide); NuCOTN 33B® (var cotton that expresses a CrylAc toxin); Bolígard i I ® (var of cotton that expresses a CryIAc toxin); Bollgard II® (cotton var that expresses a CrylAc toxin and a Cry2Ab toxin); VipCot ® (cotton var that expresses a Vip3A toxin and a CrylAb toxin); NewLÍeaf® (var of potato expressing a Cry3A toxin), · NatureGard®, Agrisure® GT Advantage (glyphosate-tolerant GA21 trait), Agrisure® CB Advantage (Btll trait of the worm corn borer (CB, for its acronym in English)) and Protecta®.

Other examples of these transgenic crops are:! 1. Corn Btll from Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31 790 St. Sauveur, France, registration number C / FR / 96/05/10. Genetically modified Zea mays that has become resistant to European screwworm attack (Ostrinia nubilalis and Sesamia nonagrioides) by the transgenic expression of a truncated CrylAb toxin. Corn Btll also transgenically expresses the PAT enzyme to obtain tolerance to the herbicide glufosinate-ammonium. 2. Corn Btl76 from Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31 790 St. Sauveur, France, registration number C / FR / 96/05/10. Genetically modified Zea mays that has become resistant to European screwworm attack. { Ostrinia nubilalis and Sesamia nonagrioides) by the transgenic expression of a CrylAb toxin. Btl76 corn also transgenically expresses the PAT enzyme to obtain tolerance to the glufosinate-ammonium herbicide. ? 3. Corn MIR604 from Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31 790 St. Sauveur, France, registration number C / FR / 96/05/10. Corn that has become insect resistant by the transgenic expression of a modified Cry3A toxin.

This toxin is Cry3A055 modified by the i serization of a cathepsin G protease recognition sequence.

I The preparation of these transgenic maize plants is described in WO 03/018810. 4. MON 863 corn from Monsanto Europe S.A. 270-272 Ayenue de Tervuren, B-1150 Brussels, Belgium, registration number C / DE / 02/9. MON 863 expresses a Cry3Bbl toxin and has resistance to certain coleopteran insects. | 5. Cotton IPC 531 from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C / ES / 96/02. ! 6. Corn 1507 from Pioneer Overseas Corporation, Ayenue Tedesco, 7 B-1160 Brussels, Belgium, registration number C / NL / OO / 10. Corn modified genetically for the expression of the CrylF protein to achieve resistance to certain lepidopteran insects and the PAT protein to achieve tolerance to the glufosinate-ammonium herbicide. 7. Corn NK603 x MON 810 from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C / GB / 02 / M3 / 03. It consists of vares of hybrid corn conventionally developed through the crossing of the genetically modified vares NK603 and MON 810. The corn NK603 x MON 810 transgenically expresses the protein CP4 EPSPS, obtained from the CP4 strain of Agrobacterium spp.,; which transmits tolerance to the Roundup® herbicide (contains glyphosate), and also a CrylAb toxin obtained from Bacillus thuringiensis subsp. kurstaki that produces tolerance to certain lepidoptera, including the European screwworm.

It should also be understood that "crops" are those that have become resistant to harmful insects and by genetic engineering methods, for example, Bt maize (resistant to the European corn borer), Bt cotton (resistant to cotton weevil) and also Bt papajs (resistant to Colorado beetle). Examples of Bt corn are the corn hybrids 175 Bt of NK® (Syngenta Seeds). Examples of transgenic plants comprising one or! more genes that code for an insecticidal resistance and express one or more toxins are KnockOut® (corn), YieldGard® (corn), NuCOTIN33B® (cotton), Bollgard® (cotton), NewLeaf® (countries), NatureGard® and Protexcta®. ' Plant crops or seed materials are therefore resistant to herbicides and at the same time feeding insects ("stacked" transgenic events). For example, the seed may have the ability to express an insecticidal Cry3 protein while at the same time It is tolerant to glyphosate. | It will be understood that the crops also include those that are obtained by conventional methods of selective cultivation or genetic engineering and that they contain; the so-called external traits (eg, improved storage stability, higher nutritional value and better taste) To apply a compound of formula (I) as a insecticide, acaricide, nematicide or molluscicide to a pest, a locus of a pest or a plant susceptible to attack ! of a pest, a compound of formula (I) is generally formulated into a composition that includes, in addition to the compound of formula (I), a suitable inert diluent or carrier and, optionally, a surfactant (SFA). SFAs are chemical compounds capable of modifying the properties of an interface '(for example, a liquid / solid, liquid / air or liquid / liquid interface) by reducing the i interfacial tension and, in this way, cause changes in other properties (for example, dispersion, emulsification and wetting). It is preferred that all compositions (both solid and liquid formulations) comprise, by weight, 0.0001 to 95%, more preferably 1 to 85%, for example. 5 to 60% of a compound of formula (I). The composition is generally used to control pests in such a way that a compound of formula (I) is applied at a rate of 0. 1 to 10 kg per hectare, preferably 1 to 6 kg per hectare, more preferably 1 to 1 kg. per hectare.

When used in a seed preparation ,; a compound of formula (I) is used at a rate of O.OOOlg to 10g (for example O.OOlg or 0.05g), preferably 0.005g to 1gOg, more preferably 0.005g to 4g, per kilogram of seed :.

In another aspect, the present invention provides; an insecticide, acaricide, nematicide or molluscicide composition comprising an effective amount as an insecticide, acaricide, nematicide or molluscicide of a compound of formula (I) and a suitable carrier or diluent therefor. The composition is preferably an insecticidal, acaricidal, nematicidal or molluscicidal composition. | The compositions can be selected from various types of formulations, including spreadable powders (DP), soluble powders (SP), water soluble granules (SG), water dispersible granules (WG), wettable powders (P), granules (GR) ( slow release or rapid release), soluble concentrates (SL), oil miscible liquids (OL), ultra low volume liquids (UL), emulsifiable concentrates (EC), dispersible concentrates (DC), emulsions (oil in water (E ) and water in oil (EO)), microemulsions (ME), suspension concentrates (SC), aerosols, fogging / smoke formulations, capsule suspensions (CS) | and formulations for seed treatment. The kind of ! The formulation chosen in any case will depend on the specific objective envisaged and the physical, chemical and biological properties of the compound of formula (I). \ The spreadable powders (DP) can be prepared by mixing a compound of formula (I) with one or more solid diluents (for example natural clays, kaolin, pyrophyllite, bentonite, alumina, montmorillonite, diatomite, chalk, diatomaceous earth, calcium phosphates, calcium carbonates and magnesium, sulfur, lime, flours, talc and other solid organic and inorganic carriers) and mechanically grinding the mixture to a fine powder.

! Soluble powders (SP) can be prepared by mixing a compound of formula (I) with one or more water-soluble inorganic salts (such as sodium bicarbonate, sodium carbonate or magnesium sulfate) or one or more water-soluble organic solids ( such as polysaccharides) and, optionally, one or more wetting agents, one or more dispersing agents or a mixture of the agents to improve the dispersibility / solubility in water. Then,! the mixture is milled to obtain a fine powder. It is also possible to granulate similar compositions to form water soluble granules (SG). I Wettable powders (WP) can be prepared by mixing a compound of formula (I) with one or more solid diluents or carriers, one or more wetting agents and, preferably, one or more dispersing agents and, optionally, one or more wetting agents. suspension to facilitate dispersion in liquids. The mixture is then milled to obtain a fine powder. Similar compositions can also be granulated to form water dispersible granules (WG). j The granules (GR) can be formed by granulating a mixture of a compound of formula (I) and one or more diluyent.es or solid carriers in powder form or from preformed blank granules by absorption of a compound of formula (I) (or a solution thereof, in a suitable agent) in a Porous granular material (such as pumice stone, attapulgite clays, fuller's earth, diatomite, diatomaceous earth or crushed corn cobs) or by adsorption of a compound of formula (I) (or a solution thereof, in an agent) suitable) in a resistant core material (such as sands, silicates, mineral carbonates, sulphates or phosphates) and drying if necessary. Agents that are commonly used to facilitate absorption or adsorption include solvents (such as petroleum solvents) Aromatics and aliphatics, alcohols, ethers, ketones and esters) and binding agents (such as polyvinyl acetates, polyvinyl alcohols, dextrins, sugars and vegetable oils). One or more other additives may also be included in the granules (e.g., an emulsifying agent, wetting agent or dispersing agent).

Dispersible concentrates (DC) can be prepared by dissolving a compound of formula (I) in water or an organic solvent, such as a ketone, alcohol or glycol ether. These solutions may contain a surfactant (for example to improve dilution in water or prevent crystallization in a spray tank). ' Emulsifiable concentrates (EC) or emulsions of ? i Oil in water (E) can be prepared by dissolving a compound of formula (I) in an organic solvent (optionally containing one or more wetting agents or one or more emulsifying agents or a mixture of the agents).

Suitable organic solvents for use in EC include aromatic hydrocarbons (such as alkylbenzene or alkylnaphthalenes, exemplified by SOLVESSO 100, SOLVESSO 150 and SOLVESSO 200; SOLVESSO is a Registered Trademark), i ketones (such as cyclohexanone or methylcyclohexanone) and alcohols (such as benzyl alcohol, furfuryl alcohol or butanol), N-alkylpyrrolidones (such as N-methylpyrrolidone or N-octylpyrrolidone), dimethylamides or fatty acids (such as C8-Ci0 fatty acid dimethylamide) and chlorinated hydrocarbons.

An EC product can be spontaneously emulsified by adding water to produce an emulsion with sufficient stability to be applied by spraying with a suitable kit. The preparation of an EW involves obtaining a compound of formula (I) as a liquid (if it is not a liquid at room temperature it can melt at a reasonable temperature, typically below 70 ° C) or in a solution (dissolving it in an appropriate solvent) and then i emulsify the liquid or solution in water containing one or more SFA, under high shear to produce an emulsion. Suitable solvents for use in EW include; oils vegetable, chlorinated hydrocarbons (such as chlorobenzenes), aromatic solvents (such as alkylbenzenes or alkylnaphthalenes) and other suitable organic solvents which have a low solubility in water.

Microemulsions (ME) can be prepared by mixing water with a mixture of one or more solvents with one more SFA to spontaneously produce an isotropic, modulamically stable liquid formulation. A compound 1 of formula (I) is initially present in water or Solvent / SFA combination. Suitable solvents for use in EM include those previously described herein for use in EC or E. A ME can be an oil-in-water or water-in-oil system (it can be determined which system is present by conductivity measurements) and can be suitable for mixing water-soluble or oil-soluble pesticides in the same formulation. A ME can be diluted in water, either: by being maintained as a microemulsion or by forming a conventional oil-in-water emulsion. I Suspension concentrates (SC) may comprise aqueous or non-aqueous suspensions of finely divided insoluble solid particles of a compound of formula (I) SCs can be prepared by beating with balls or beads the solid compound of formula (I) in a suitable medium , optionally with one or more dispersing agents, 'for produce a suspension of fine particles of the compound. One or more wetting agents may be included in the composition and a suspending agent may be included to reduce the rate at which the particles settle. Alternatively, a compound of formula (I) can be dry milled and added to water containing the agents described hereinabove, to produce the desired final product. J i The aerosol formulations comprise a compound of and formula (I) and a suitable propellant (e.g., n-butane). A compound of formula (I) can also be dissolved or dispersed in a suitable medium (e.g., water or a water-miscible liquid, such as n-propanol) to provide compositions for use in non-pressurized manually operated spray pumps. 1 A compound of formula (I) can be mixed in the dry state with a pyrotechnic mixture to form a composition suitable for generating, in a closed space, a humq containing the compound. Capsule suspensions (CS) can be prepared in a similar manner to the preparation of the formulations EW j but with an additional polymerization step such that an aqueous dispersion of oil droplets is obtained, in which each drop of oil it is encapsulated by a polymeric shell and contains a compound of formula (I); Y, optionally, a carrier or diluent for the same. The polymeric cover can be produced both by a interfacial polycondensation reaction as by a coacervation process. The compositions can be provided for controlled release of the compound of formula (I) and can be used for seed treatment. A compound of formula (I) can also be formulated in a biodegradable polymer matrix to provide. a slow controlled release of the compound.

A composition can include one or more additives to improve the biological performance of the composition (eg, by improving wetting, retention or distribution on surfaces, resistance to rain on treated surfaces, or intake or mobility of a compound of formula I)). Such additives include surfactants, oil-based spraying additives, for example, mineral oils or natural vegetable oils (such as soybean and rapeseed oil) and combinations of these with other bioenhancing adjuvants (ingredients that can aid or modify the action of a compound of formula (D).

A compound of formula (I) can also be formulated for use as seed treatment, for example, as; a powder composition, including a powder for dry seed treatment (DS), a water soluble powder (SS) or a water dispersible powder for suspension treatment; (WS) or as a liquid composition, including a fluid concentrate (FS), a solution (LS) or a capsule suspension (CS). The preparations of the Dsj type compositions SS, WS, FS and LS are very similar to those of the DP, SP, WP, SC and DC type compositions, respectively, previously described. Compositions for treating seeds may include an agent to promote adhesion of the composition to the seed (eg, a mineral oil or a film-forming barrier).

The wetting agents, dispersing agents and emulsifying agents can be surface SFAs of cationic, anionic, amphoteric or nonionic type.

Suitable SFAs of the cationic type include quaternary ammonium compounds (eg, cetyltrimethylammonium bromide), imidazolines and amine salts. | Suitable anionic SFAs include alkali metal salts of fatty acids, salts of aliphatic monoesters of sulfuric acid (eg, sodium lauryl sulfate), salts of sulfonated aromatic compounds (for example, sodium dodecylbenzenesulfonate, calcium dodecylbenzenesulfonate, butylnaphthalene sulfonate and mixtures of sodium di-isopropyl and tri-isopropyl naphthalenesulfonates), ether sulfates, ether alcohol sulphates (for example, lauryl-3) sodium sulfate), ether carboxylates (for example, sodium lauryl-3-carboxylate), phosphate ethers (products of: reaction between one or more fatty alcohols and phosphoric acid (predominantly monoesters) or phosphorus pentoxide (predominantly diesters), for example the reaction between lauric alcohol and tetraphosphoric acid; additionally these products may be ethoxylated), sulfosuccinamates, paraffin sulfonates or olefin, taurates and lignosulfonates.

Suitable SFAs of the amphoteric type include betaines, propionates and glycinates. j Suitable SFAs of the nonionic type include condensation products of alkylene oxides, such as ethylene oxide, propylene oxide, butylene oxide or mixtures thereof, with fatty alcohols (such as ethyl alcohol or cetyl alcohol) or with alkylphenols. (such as octylphenol, nonylphenol or octylcresol); Derivative partial esters of long-chain fatty acids or hexitol anhydrides; condensation products of the partial esters with ethylene oxide; block polymers (comprising ethylene oxide and propylene oxide); alkanolamides; simple esters (for example, glycolic esters of fatty acid polyethylene); amine oxides (for example, lauryldimethylamine oxide); and lecithins. : Suitable suspending agents include hydrophilic colloids (such as polysaccharides, polyvinylpyrrolidoha or sodium carboxymethylcellulose) and spongy clays (such as bentonite or attapulgite).

A compound of formula (I) can be applied by any of the known means of applying pesticidal compounds. For example, it can be applied, formulated or deformed, to pests or to a locus of pests (such as the habitat of pests or a plan in growth prone to infestation by the pest) or to any part of the plant, including the foliage, stems, branches or roots, to the seed before planting it or to another medium in which the plants are being cultivated they will be planted (such as the soil that surrounds the soil, generally, paddy systems or hydroponic), dilineally or can pulverize zarse, I dusted, applied by dipping, applied as a cream or paste formulation, applied as vapor or applied through distribution or incorporation of a composition (such as a granular composition or a concentrated composition in a water soluble pouch) in the i '. soil or in a watery environment. j A compound of formula (I) can also be injected into plants or sprayed onto vegetation. ! electrodynamic spray techniques or other low volume methods or applied by terrestrial or aerial irrigation systems.; | The compositions for use as aqueous preparations i | (aqueous solutions or dispersions) are supplied generally in the form of a concentrate containing a high proportion of the active principle and the concentrate is Do not add to the water before use. It is often required that these concentrates, which can include DC, SC, EC, EWj ME, SG, SP, WP, WG and CS, can withstand extended storage periods and, after storage, can be added to water to form aqueous preparations that remain homogeneous for a sufficient time so that it is possible to apply them with conventional spray kits. Such aqueous preparations may contain varying amounts of a compound of formula (I) (for example 0.0001 to 10¾, by weight) depending on the object for which they are to be used.

A compound of formula (I) can be used in mixtures with fertilizers (for example, fertilizers containing nitrogen, potassium or phosphorus). Suitable formulation types include fertilizer granules. The mixtures preferably contain up to 25% by weight of the compound of formula (I).

The invention therefore also provides; a fertilizer composition comprising a fertilizer, and a compound of formula (I). ! The compositions of this invention may contain other compounds with biological activity, for example, micronutrients or compounds with fungicidal activity or having plant growth regulating activity, herbicide, insecticide, nematicide or acaricide activity.

The compound of formula (I) (shortened further by the term "TX") means, therefore, a compound comprised by the compounds of formula (1) or preferably, the term "TX" refers to a compound selected from Tables 1 to 12 and A) may be the sole active ingredient of the composition or may be mixed with one or more additional active ingredients (component (B)) such as a pesticide (pesticide against insects, acarines, molluscs and nematodes), fungicide, synergist, herbicide, protector or regulator of plant growth, when appropriate. Thus, the activity of the compositions of According to the invention, it can be considerably expanded and it can have surprising advantages that can also be described, in a broader sense, as a synergistic activity. An additional active ingredient for: providing a composition having a broader spectrum of activity or greater persistence at a locus; provide a composition that demonstrates better tolerance of plants / crops by reducing phytotoxicity; provide a composition that controls insects in their different stages of development; synergize the activity or complement the activity (for example, increasing the speed of the effects or overcoming the repellency) of the TX; or help overcome or avoid the development of resistance to comporients individual The particular additional active ingredient will depend on the desired utility of the composition. Examples of suitable pesticides include the following: a) Pyrethroids, such as permethrin, cypermethrin, fenvalerate, esfenvalerate, deltamethrin, cyhalothrin (in particular lambda-cyhalothrin), bifenthrin, fenpropathrin, cyfluthrin, tefluthrin, pyrethroids safe for fish (eg, etofenprox), natural pyrethrin, tetramethrin, -bioallethrin, fenfluthrin, pralethrin or 5-benzyl-3-furylmethyl- (E) - (IR, 3S) -2, 2-dimethyl-3- (2-oxothiolan-3-ylidene-methyl) -cyclopropane carboxylate; B) Organophosphates, such as profenofos, sulphophos, acephate, methyl parathion, azinphos-methyl, demeth-s-methyl, heptenofos, thiometon, fenamifos, monocrotophos, profenofos, triazophos, methamidophos, dimethoate, phosphamidon, malathion, chlorpyrifos, fosalone, terbufos , fensulfothion, fonofós, phorate, phoxim, pirimifós-methyl, pirimifós-etil, fenitrotión, fostiazáto or diazinón; C) Carbamates (including arylcarbamates) such as pyrimicarb, triazamate, cloetocarb, carbofuran, furathiocarb, etiofencarb, aldicarb, thiofurox, carbosulfan, bendiocarb, phenobucarb, propoxur, methomyl or oxamyl;; d) Benzoylureas, such as diflubenzuron, triflumuron, hexaflumuron, flufenoxuron or chlorfluazuron; : e) Organic tin compounds, such as cyhexatin, i fenbutatin oxide or azocyclotin; f) Pyrazoles, such as tebufenpyrad and fenpyroximate; g) Macrolides, such as avermectins or milbemycins, for example, abamectin, emamectin benzoate, ivermectin, milbemycin or spinosad, spinetoram or azadirachtin; j h) Hormones or pheromones; i) Organochlorine compounds, such as endosufin, benzene hexachloride, DDT, chlordane or dieldrin; j) Amidines such as clordimeform or amitraz; k) Fumigant agents such as chloropicrin, I dichloropropane, methyl bromide or metam; i 1) Neonicotinoid compounds, such as imidacloprid, I thiacloprid, acetamiprid, clothianidin, nitenpyram, and dinotefuran or thiamethoxam; m) Diacylhydrazines such as tebufenocide, chromafenocide or methoxyfenozide; N) Diphenyl ethers such as phenytoin or pyriproxyfen; j o) Indoxacarb; · P) Chlorfenapyr; q) Pymetrozine or pirifluquinazon; j r) Spirotetramat, spirodiclofen or spiromesifén;; s) Flubendiamide, chlorantraliniprole or cyantraniliprole; t) Cienopyrafen or cyflumetofen; or u) Sulfoxaflor. i In addition to the main chemical classes of pesticides for the desired utility of the composition. For example, selective insecticides may be employed for particular crops, for example, specific insecticides and for stem borer worms (such as cartap) or specific insecticides for fulgoromorphs (such as buprofencin) for use in rice. Alternatively, specific acaricidal insecticides may also be included in the insecticidal compositions specific for certain insect species / stages (eg, acaricidal ovo-larvicides such as clofentazine, flubenzimine, hexitiazox or tetradiphon, acaricidal motilicides such as dicofol or propargite, acaricides such as bromopropylate or chlorobenzilate; or growth regulators such as hydramethylnon, cyromazine, methoprene, chlorfluazuron or diflubenzuron).

Preferred are the following mixtures of the compounds of formula (I) with active ingredients, wherein, preferably, the term "TX" refers to a compound encompassed by the compounds of formula (I) or, preferably, the term "TX" refers to a compound selected from Tables 1 to 12 and A: an adjuvant selected from the group of substances constituted by petroleum oils (alternative name) (628) + TX, an acaricide which is selected from the group of substances consisting of 1,1-bis (4-chlorophenyl) -2-ethoxyethanol (IUPAC name) (910) + TX, 2,4-dichlorophenyl benzenesulfonate (IUPAC name / Chemical Abstracts) (1059) + TX, 2-fluo or-lV-methyl-Nl-naphthylacetamide (IUPAC name) (1295) + TX; 4-chlorophenyl phenyl sulfone (IUPAC name) (981) + TX, abamectin (1) + TX, acequinocyl (3) + TX, acetoprol [CCN] + TX, acrinatrin (9) + TX, aldicarb (16) + TX, aldoxicarb j (863) i + TX, alpha-cypermethrin (202) + TX, amidithion (870) + TX, i amidoflumet [CCN] + TX, amidothioate (872) + TX, amiton (875) + TX, amiton hydrogen oxalate (875) + TX, amitraz (24) + i TX, aramite (881) + TX, arsenous oxide (882) + TX, AVI 382 I (compound code) + TX, AZ 60541 (compound code) + TX, azinphos-ethyl (44) + TX, azinphos-methyl (45) +: TX, azobenzene (name IUPAC) (888) + TX, azocyclotin ( 46) + TX, azotoate (889) + TX, benomyl (62) + TX, benoxafós (alternate name) [CCN] + TX, benzoximate (71) + TX, benzyl benzoate (IUPAC name) [CCN] + TX, bifenazate (74) +; TX, bifenthrin (76) + TX, binapacryl (907) + TX, brofenvalerate (alternative name) '+ TX, bromocyclen (918) + TX, bromophos (920) + TX, bromophos-ethyl (921) + TX, bromopropylate ( $ 4) + TX, buprofezin (99) + TX, butocarboxim (103) +: TX, butoxicarboxim (104) + TX, butylpiridaben (alternative name) + TX, calcium polysulfide (IUPAC name) (111) + '| TX, camfeclor (941) + TX, carbanolato (943) + TX, carbaryl (115) + TX, carbofuran (118) + TX, carbophenotion (947) + TX, CGA i 50 '439 (development code) (125) + TX, quinometionat! (126) + TX, chlorbenside (959) + TX, clordimeform (964) + TX, clordimeform hydrochloride (964) + TX, chlorfenapyr (130) + TX, Chlorphenetol (968) + TX, Chlorphenon (970) + TX, Chlorphenesulfide (971) + TX, Chlorfenvinphos (131) + TX, Chlorobenzilate (975) + TX, Chloromebuform (977) + 1 TX, Chlorometiuron (978) + TX, chloropropylate (983) + i TX, chlorpyrifos (145) + TX, chlorpyrifos-methyl (146) +; TX, clortiophos (994) + TX, cinerin I (696) + TX, cinerin II (696) + TX, cinerins (696) + TX, clofentezine (158) +! TX, closantel (alternate name) [CCN] + TX, coumaphos (174) + TX, crotamiton (alternate name) [CCN] + TX, crotoxifos (1010) + TX, cufraneb (1013) + TX, cyanoate (1020) + TX, ciflumetofen (CAS Reg. No .: 400882-07-7) + TX, cyhalothrin (196) + TX, cyhexatin (199) + TX, cypermethrin (201) +; TX, DCPM (1032) + TX, DDT (219) + TX, demephion (1037) + TX, demephion-0 (1037) + TX, demephion-S (1037) + TX, demeton (1038) + TX, demeton- methyl (224) + TX, demetone-0 (1038) +; TX, demethyl-O-methyl (224) + TX, demeton-S (1038) + TX, demeton-! S-methyl (224) + TX, demethyl-S-methylsulfone (1039) + 'i TX, diafenthiuron (226) + TX, dialiphos (1042) + TX, diazinon (227) + TX, diclofluanid (230) + TX, diclorvós (236) + TX, diclifós (alternative name) + TX, dicofol (242) + TX, dicrotofós (243) + TX, dienoclor (1071) + ??, dimefox (1081) TX, dimethoate (262) + TX, dinactin (alternative name) (653) + TX, dinex (1089) + TX, dinex-diclexine (1089) + TX, dino uton (269) + TX, dinocap (270) + TX, dinocap-4 [CCN] + TX, i dinocap-6 [CCN] + TX, dinocton (1090) + TX, dinopentone (1092) ! + TX, dinosulfon (1097) + TX, dinoterbón (1098) +: TX, dioxatión (1102) + TX, diphenyl sulfone (IUPAC name) (Í03) + TX, disulfiram (alternative name) [CCN] + TX, disulfoton (278) + TX, DNOC (282) + TX, dofenapine (1113) + j TX, doramectin (alternative name) [CCN] + TX, endosulfan (294) + TX, endotion (1121) + TX, EPN (297) + TX, eprinomectin (alternative name) [CCN] + TX, ethion (309) + TX, ethoate-methyl (1134) + TX, ethoxazole (320) + TX, etrimphos (1142)! + TX, fenazaflor (1147) + TX, phenazaquin ( 328) + TX, fenbutátina oxide (330) + TX, fenotiocarb (337) + TX, fenpropatrina (342) + TX, fenpirad (alternative name) + TX, fenpyroximate (345) + TX, fensón (1157) + TX, fentrifanilo (1161) + i TX, fenvalerate (349) + TX, fipronil (354) + TX, fluacripirim (360) + TX, fluazuron (1166) + TX, flubencimine (1167) + TX, flucycloxuron (366) + TX, flucitrinate (367) + TX, fl enéthyl (1169) + TX, flufenoxuron (370) + TX, flumethrin (372) +: TX, fluorbenside (1174) + TX, fluvalinate (1184) + TX, FMC ill37 (development code) ) (1185) + TX, formetanate (405) +: TX, formetanate hydrochloride (405) + TX, formothion (1192) + > TX, formparanate (1193) + TX, gamma-HCH (430) + TX, gliodine (1205) + TX, halfenprox (424) + ??, heptenofós (432) +; TX, hexadecyl cyclopropanecarboxylate (name IUPAC / Chenjiical Abstracts) (1216) + TX, hexitiazox (441) + TX, iodomethane (IUPAC name) (542) + TX, isocarbophos (alternative name) (473) + TX, 0- ( methoxyamothiofosphoryl) isopropyl salicylate (IUPAC name) (473) + TX, ivermectin (alternative name) [CCN] + TX, Jasmolin I (696) + TX, Jasmolyria II (696) + TX, Jodfenphos (1248) + TX, lindane (430) +: TX, lufenurón (490) + TX, malathion (492) + TX, malonoben (1254) + TX, mecarbam (502) + TX, mefosfolán (1261) + TX, mesúlfén (alternative name) [CCN] + TX, metacrifos (1266) +; TX, methamidophos (527) + TX, methidathion (529) + TX, methiocarb | (530) + TX, methomyl (531) + TX, methyl bromide (537) +, TX, metolcarb (550) + TX, mevinphos (556) + TX, mexacarbate (1290) + TX, milbemectin (557) + TX , milbemycin oxime (alternative name) [CCN] + TX, mipafox (1293) + TX, monochorone ofos (561) + TX, morphothion (1300) + TX, moxidectin (alternative name) [CCN] + TX, naled (567) + TX, NC-184 (compound code) + TX, NC-512 (compound code) + TX, nifluridide (1309) + TX, nicomycin (alternative name) [CCN] + TX, nitrilacarb (1313) + TX , nitrilacarb 1: 1 zinc chloride complex (1313) + TX, NNI-0101 (compound code) + TX, NNI-0250 (compound code) + TX, ometoate (594) + TX, oxamyl (602) + TX, oxideprofos (1324) +; TX, oxidisulfoton (1325) + TX, pp'-DDT (219) + TX, parathion (615) + TX, permethrin (626) + ??, petroleum oils (alternative name) (628) + TX, fenkapton (1330) + TX, fentoate (631) + TX, phorate (636) + TX, phosalone (637) + TX, phospholon (1338) + TX, fosmet (638) + TX, phosphamidon (639) + TX, phoxim (642) + TX, pirimiphos-methyl (652) + TX, polychloroterpenes (traditional name) (1347) + TX, polinactins (alternative name) ( 653) + TX, proclonol (1350) + TX, profenofos (662) +: TX, promacyl (1354) + TX, propargite (671) + TX, propetamfós (673) + TX, propoxur (678) + TX, protidathion ( 1360) + j TX, protoate (1362) + TX, pyrethrin I (696) + TX, piretrirta II (696) + TX, pyrethrins (696) + TX, pyridaben (699) +: TX, pyridathione (701) + TX , pyrimidifen (706) + TX, pyrimitate? (1370) + TX, quinalfós (711) + TX, quintiophos (1381) + TX, R-1492 (development code) (1382) + TX, RA-17 (development code) (1383) + TX, rotenone ( 722) + TX, scradán (1389) + TX, sebufós (alternative name) + TX, selamectin (alternative name) [CCN] + TX, SI-0009 (compound code) TX, sofamide (1402) + TX, spirodiclofen ( 738) + i TX, espiromesifén (739) + TX, SSI-121 (development code) (1404) + TX, sulfiram (alternate name) [CCN] + \ TX,? sulfluramid (750) + TX, sulfotep (753) + TX, sulfur (754) + TX, SZI-121 (development code) (757) + TX, j tau-fluvalinate (398) + TX, tebufenpirad (763) + TX, TEPP (1417) + TX, terbam (alternative name) + TX, tetrachlorvinfos (¡777) + TX, tetradifón (786) + TX, tetranactina (alternative name) (653) + TX, tetrasul (1425) + ?, thiafenox (alternative name) + TX, thiocarboxim (1431) + TX, thiofanox (800) + TX, thiometone (801) + TX, thioquinox (1436) + TX, turingierisin (alternative name) [CCN] + TX, triamiphos (1441) + ^ TX, triaratene (1443) + TX, triazophos (820) + TX, triazuron (alternative name) + TX, trichlorfon (824) + TX, triferiofós (1455) + TX, trinactin (alternative name) (653) + j TX, vamidothion (847) + TX, vaniliprole [CCN] and YI-5302 (compound code) + TX,, i an algicide selected from the group substances constituted by betoxazine [CCN] + TX, copper dioctanoate i (IUPAC name) (170) + TX, copper sulfate (172) +; TX, cibutrin [CCN] + TX, diclone (1052) + TX, dichlorophen (232) + TX, endotal (295) ^ + TX, fentin (347) + TX, hydrated lime [CCN] + TX, nabam (566) + TX, quinoclamine (714) + TX, quinonamide (1379) + TX, simazine (730) + TX, triphenyltin acetate (IUPAC name) (347) and triphenyltin hydroxide ( IUPAC name) (347) + TX, i an anthelmintic selected from the group of substances constituted by abamectin (1) + TX, crufomato (1011) · +; TX, doramectin (alternative name) [CCN] + TX, emamectin (291) + TX, emamectin benzoate (291) + TX, eprinomectin (alternative name) [CCN] + TX, ivermectin (alternative name) [CCN] + TX, milbemycin oxime (alternative source) [CCN] + TX, moxidectin (alternative name) [CCN] + TX, piperazine [CCN] + TX, selamectin (alternative no.) [CCN] + TX, spinosad (737) and thiophanate (1435) + TX, I an avicide selected from the group of substances constituted by chloralose (127) + TX, endrin (1122) + | TX, fenthion (346) + TX, pyridin-4-amine (name IUPAC) (2ß) and strychnine (745) + TX, i a bactericide that is selected from the group of substances consisting of l-hydroxy-lH-pyridine-2-thione (IUPAC name) (1222) + TX, 4 - (quinoxalin-2-ylamino) benzenesulfonamide (IUPAC name) (748) + TX, 8-hydroxyquinoline sulfate j (446) + TX, bronopol (97) + TX, copper dioctanoate (IÜPAC name) (170) + TX, copper hydroxide (IUPAC name) (169) + | TX, cresol [CCN] + TX, dichlorophen (232) + TX, dipyrithione (1105) + TX, dodycin (1112) + TX, fenaminosulf (1144) + \ TX, formaldehyde (404) + TX, hydrargafen (alternative name) [CCN] + TX, kasugamycin (483) + TX, kasugamycin hydrochloride hydrate (483) + TX, nickel bis (dimethyldithiocarbamate) (IUPAC name) (1308) + TX, nitrapyrin (580) +: TX, octylinone (590) + TX, oxolinic acid (606) +; TX, oxytetracycline (611) + TX, potassium hydroxyquinoline sulfate (446) + TX, probenazole (658) + TX, streptomycin (744) + TX, streptomycin sesquisulfate (744) +: TX, tecloftalam (766) + TX, and thiomersal (alternative name); [CCN] + TX, a biological agent that is selected from the group of substances consisting of Adoxophyes orana GV (alternative name) (12) + TX, Agrobacterium radiobacter (alternative name) (13) + TX, Amblyseius spp. (name native noun) t (19) + TX, Anagrapha falcifera NPV (alternative name): (28) + TX, Anagrus atomus (alternative name) (29) + i TX, Aphelinus abdominalis (alternative name) (33) + ¡TX, Aphidius colemani (alternate name) (34) + TX, Aphidoietes i aphidimyza (alternative name) (35) + TX, Autographa californica NPV (alternative name) (38) + TX, Bacillus firmus (alternative name) (48) + TX, Bacillus sphaericus i Neide (scientific name) (49) + TX, Bacillus thuringiensis i Berliner (scientific name) (51) + TX, Bacillus thuringiensis subsp. aizawai (scientific name) (51) + iTX, Bacillus thuringiensis subsp. israelensis (scientific name) (51) + TX, Bacillus thuringiensis subsp. japonensis (scientific name) (51) + TX, Bacillus thuringiensis subsp. kurstaki (scientific name) (51) + TX, Bacillus thuringiensis subsp. i tenebrionis (scientific name) (51) + TX, Beauveria bassiana (alternative name) (53) + TX, Beauveria brongniartii (alternative name) (54) + TX, Chrysoperla carnea (alternate name) (151) + TX, Cryptolaemus montrouzieri (first name i alternative) (178) + TX, Cydia pomonella GV (alternative name) (191) + TX, Dacnusa sibirica (alternative name) (212) + TX, Diglyphus isaea (alternative name) (254) +: TX, Encarsia formosa (scientific name) (293) + TX, Eretmocerus eremicus (alternative name) (300) + TX, Helicoverpa zea NPV (alternative name) (431) + TX, Heterorhabditis bacteriophora and H. egidis (alternative name) (433) +! TX, Hippodamia convergens (alternative name) (442) + TX, Lep ornastix dactylopii (alternative name) (488) TX, Macrolophus caliginosus (alternative name) (491) + TX, Mamestra brassicae NPV (alternative name) (494) + TX, Metaphycus helvolus (alternative name) (522) + TX, Metarhizium anisopliae var. acridum (scientific name) (523) + TX, Metarhizium anisopliae var. anisopliae (scientific name) (523) + TX, Neodiprion sertifer NPV and N. lecontei NPV (alternative name) (575) + TX, Orius spp. (alternate name) (596) + TX, Paecilomices fumosoroseus (alternate name) (613) + TX, Phytoseiulus persimilis (alternate name) (644) + TX, Spodoptera exigua virus \ multiple capsid nuclear polyhedrosis (scientific name) (741) + TX, Steinernema bibionis (alternate name) (742) + TX, Steinernema carpocapsae (alternate name) (742) TX, Steinernema feltiae (alternative name) (742) + TX, Steinernema glaseri (alternative name) (742) +: TX, Steinernema riojbrave (alternative name) (742) + TX, Steinernema riobravis (alternative name) (742) + TX, Steinernema scapterisci (alternative name) (742) +: TX , Steinernema spp. (alternative name) (742) + | TX, Trichogramma spp. (alternative name) (826) + TX, Tyflodromus occidentalis (alternative name) (844) and Vertical2ium lecanii (alternative name) (848) + TX, a soil sterilizer selected from the group of substances consisting of iodomethane (IUPAC name) (542) and methyl bromide (537) + TX, a chemical sterilant selected from the group of substances consisting of afolate [CCN] + TX, bisazir (alternative name) [CCN] + TX, busulfan (alternative name) [CCN] + TX, diflubenzuron (250) + TX, dimatif (alternative name) ) [CCN] + TX, hemel [CCN] + TX, hempa [CCN] † TX, metepa [CCN] + TX, metiotepa [CCN] + TX, methyl afolate [CCN] + TX, morzid [CCN] + TX, penfluron (alternate name) [CCN] + TX, tepa [CCN] + TX, tiohempa (alternate name) [CCN] + TX, thiotepa (alternative name) [CCN] + 'TX, tretamine (alternative name) [CCN] and uredepa (alternative name) [CCN] + TX, i an insect pheromone that is selected from the group of ! substances consisting of (E) -dec-5-en-l-yl acetate with (E) -dec-5-en-l-ol (IUPAC name) (222) + TX, (E) -tridec acetate -4-en-l-ilo (name IUPAC) (829) + TX, (B) -6-métilK. pt- 2-en-4-ol (name IUPAC) (541) + TX, acetate (Z) - tetradeca-, 10-dien-l-yl (IUPAC name) (779) + TX, (Z) -dodec-7-en-l-yl acetate (IUPAC name) (285) + TX, j (Z) - hexadec-ll-enal (name IUPAC) (436) + TX, acetate of (Z) - hexadec-ll-en-l-ilo (IUPAC name) (437) + TX, (Z) -hexadec-13-en-ll-in-l-yl acetate (IUPAC name) (438) + TX, (Z ) -icos-13-en-10-one (name IUPAC) (448) + TX, (Z) -tetradec-7-en-l-al (name IUPAC) (782) + TX, (Z) -tetradec- 9-en -ol (IUPAC name) (783) + TX, (Z) -tetradec-9-en-j-yl acetate (name IUPAC) (784) + TX, acetate (7E, 9Z) -dodeca47, 9-dien-l-ilo (IUPAC name) (283) + TX, acetate (9Z, Í1E) -tetradeca-9, 11 -dien-l-ilo (IUPAC name) (780) + TX, (9Z, 122?) acetate - tetradeca- 9, 12-dien-l-yl (IUPAC name) (781) + TX, 14-methyloctadec- l-eno (IUPAC name) (545) + TX; 4-methylnonan-5-ol with 4-methylnonan-5-one (IUPAC name) (544) + TX, alpha-multistriatin (alternative name) [CCN] + TX, brevicomin (alternative name) [CCN] + TX, codlure (alternative name) [CCN] + TX, codlemone (alternative name) (167) + TX, cuelure ( alternative name) (179) + TX, disparlure (277) + TX, dodec-8-en-y-yl acetate (IUPAC name) (286) + TX, dodec-9-en-l-yl acetate (IUPAC name) (287) + TX , dodeca-8 + TX, 10-dien-1-yl acetate (IUPAC name) (284) + TX, dominicalure (alternative name) [CCN] + TX, ethyl-methyloctanoate (IUPAC name) (317) + TX, eugenol (alternate name) [CCN] + | TX, frontalina (alternate name) [CCN] + TX, gosiplure (alternative name) (420) + TX, grandlure (421) + TX, grandlure I (alternative name) (421) + TX, grandlure II (alternative name) ( 421) + TX, grandlure III (alternative name) (421) + TX, grandlure IV (alternative name) (421) + j TX, hexalure [CCN] + TX, ipsdienol (alternate name) [CCN] + TX, ipsenol (alternative name) [CCN] + TX, japonilure (alternative name) (481) + TX, lineatin (alternate name) [CCN] + TX, litlure (alternate name) [CCN] + TX, looplure I (alternate name) [CCN] + TX, medlure [CCN] + TX, megatomoic acid (alternative name) [CCN] + TX, methyl eugenol (alternative name) (540) + TX, muscalure (563) + TX, acetate octadeca-2, 13-dien-l-yl (IUPAC name) (588) ¡+ TX, octadeca-3, 13-dien-l-yl acetate (IUPAC name) (589) i + TX, orfralure (alternative name) ) [CCN] + TX, orictalure (alternative name) (317) + TX, ostramona (alternate name) [CCN] + TX, siglure [CCN] + TX, sordidín (alternative name) (736) i + TX, sulcatol (alternate name) [CCN] + TX, tetradec-ll-en-l-yl acetate (IUPAC name) (785) + TX, trimedlure (839) + TX, trimedlure A (alternative name) (839 ) + TX, trimedlure Bi (alternative name) (839) + TX, trimedlure B2 (alternative name) (839) + TX, trimedlure C (alternative name) (839) and trunc-call (alternate name) [CCN] + TX,: an insect repellent selected from the group of substances constituted by 2- (octylthio) ethanol (IUPAC name) (591) + TX, butopironoxil (933) + TX, butoxy (polypropylene glycol) (936) + TX, dibutyl adipate (IUPAC name) ) (1046) + TX, dibutyl phthalate (1047) + TX, dibutyl succinate (IUPAC name) (1048) +; TX, diethyltoluamide [CCN] + TX, dimethyl carbate [CCN] 4 TX, dimethyl phthalate [CCN] + TX, ethylhexanediol (1137) -j TX, hexamide [CCN] + TX, butyl methane (1276) + i TX , methylneodecanamide [CCN] + TX, oxamate [CCN] and picaridin [CCN] + TX, an insecticide that is selected from the group of substances consisting of 1-dichloro-1-nitroethane (name IUPAC / Chemical i Abstracts) (1058) + TX, 1, 1-dichloro-2, 2-bis (-ethylphenyl) -ethane (IUPAC name) (1056), + TX, 1,2-dichloropropane (IUPAC name / Chemical Abstracts) (1062) + TX, 1,2-dichloropropane with 1,3-dichloropropene (IUPAC name) (1063) + TX, l-bromo-2- I chloroethane (IUPAC name / Chemical Abstracts) (916) + | TX, 2, 2, 2-trichloro-l- (3, 4-dichlorophenyl) ethyl acetate (IUPAC name) (1451) + TX, 2, 2-phosphate dichlorovinyl 2-ethylsulfinyl methyl (IUPAC name) (1066) + TX, 2- (1, 3-dithiolan-2-yl) phenyl dimethylcarbamate (IUPAC / Chemical Abstracts name) (1109) + TX, 2- (2-butoxyethoxy) ethyl thiocyanate (IUPAC name / Chemical Abstracts) (935) + TX, 2- (4,5-dimethyl-l, 3-dioxolan-2-yl) phenyl methylcarbamate (IUPAC name / Chemical Abstracts) (1084) + TX, 2- (4-chloro-3,5-xylyloxy) ) ethanol (IUPAC name) (986). + TX, 2- chlorovinyl diéthyl phosphate (IUPAC name) (984) + TX, 2-imidazolidone (IUPAC name) (1225) + TX, 2-isovalerilindan-l, 3-dione (IUPAC name) (1246) + TX , 2-methyl (prop-2-ynyl) aminophenyl methylcarbamate (IUPAC name) (1284) + TX, 2-thiocyanatoethyl laurate (IUPAC name) (1433) + TX, 3-bromo-l-chloroprop-l-ene (IUPAC no.) (917) + TX, 3- dimethylcarbamate methyl-1-phenylpyrazol-5-yl (IUPAC name) (1283) + TX, 4-methyl (prop-2-ynyl) amino-3,5-xylyl methylcarbonate (IUPAC name) (1285) + TX, 5,5-dimethyl-3-oxocyclohex-l-eneyl dimethylcarbamate (IUPAC name) (1085) + TX, abamectin (1) + TX, acerate (2) + TX, acetamiprid (4) + TX, acetyl (alternate name) 1 [CCN] + TX, acetoprol [CCN] + TX, acrinatrin (9) + TX, acrylonitrile (IUPAC name) (861) + TX, alanicarb (15) + TX, aldicarb (16) + TX , aldoxicarb (863) + TX, aldrina (864) J + TX, I allethrin (17) + TX, alosamidine (alternative name) [CCN] + TX, alixicarb (866) + TX, alpha-cypermethrin (202) + TX, ecdysone (alternative name) [CCN] + TX, phosphide al (640) + TX, amidithion (870) + TX, amidothioate (872) aminocarb (873) + TX, amiton (875) + TX, hydrogen oxalate of amiton (875) + TX, amitraz (24) + TX, anabasine (877) +; TX, atidation (883) + TX, AVI 382 (compound code) + TX1, AZ 60541 (compound code) + TX, azadirachtin (alternative name) (41) + TX, azamethiphos (42) + TX, azinphos-ethyl (44) + TX, azinphos-methyl (45) + TX, azotoate (889) +; TX, delta endotoxins from Bacillus thuringiensis (alternative name) (52) + TX, barium hexafluorosilicate (alternative name) [CCN] + TX, barium polysulfide (name IUPAC / Chemical Abstracts) (892) + TX, bartrina [CCN] + TX, Bayer 22/190 (development code) (893) + TX, Bayer 22408 (development code) (894) + TX, bendiocarb (58) + TX, j benfuracarb (60) + TX, bensultap (66) + TX, beta-cifluthrin i (194) + TX, beta-cypermethrin (203) + TX, bifenthrin (76) + TX, bioallethrin (78) + TX, S-cyclopentenyl isomer of bioallethrin (alternative name) (79) + TX, bioetanometrine [CCN] + TX, biopermethrin (908) + TX, bioresmethrin (80) ¡+ TX, bis (2-chloroethyl) ether (name IUPAC) (909) + TX, bistrifuron (83) + TX, borax (86) + TX, brofenvalerate ( alternative name) + TX, bromfenvinphos (914) + TX, bromocyclen I (918) + TX, bromo-DDT (alternative name) [CCN] + TX, bromophos (920) + TX, bromophos-ethyl (921) + TX, bufencarb (924) -ti TX, buprofezin (99) + TX, butacarb (926) + TX, butathiophos (927) + TX, butocarboxim (103) + TX, butonato (932) + j TX, butoxicarboxim (104) + TX , butylpyridaben (alternative name) + TX, cadusaphos (109) + TX, calcium arsenate [CCN] + j TX, calcium cyanide (444) + TX, calcium polysulfide (IUPAC name) (111) + TX, camfeclor ( 941) + TX, carbanolate (943) + TX, carbaryl (115) + TX, carbofuran (118) + TX, carbon disulfide (IUPAC / Che name) mical Abstracts) (945) + I TX, carbon tetrachloride (IUPAC name) (946) +; TX, carbophenotion (947) + TX, carbosulfan (119) + TX, letter; (123) + TX, cartap hydrochloride (123) + TX, cevadine (alternative name) (725) + TX, chlorbiciclen (960) + TX , chlordane (128) + TX, chlordecone (963) + TX, clordimeform (964) TX, \ Clordimeform hydrochloride (964) + TX, cloretoxiphos (129) 4 TX, chlorfenapyr (130) + TX, chlorfenvinphos (131) + j TX, chlorfluazuron (132) + TX, chlorormephos (136) + TX, chloroform [CCN] + TX, chloropicrin (141) + TX, chlorphoxim (989) -ti TX, chlorprazofos (990) + TX, chlorpyrifos (145) + TX, chlorpyrifos-methyl (146) + TX, clortiphosphate (994) + TX, chromafenozide (150 ) + TX, cinerin I (696) + TX, cinerin II (696) + TX, cinerins (696) + TX, cis-resmethrin (alternative name) + j TX, cismethrin (80) + TX, clocitrin (alternative name) + i TX, cloetocarb (999) + TX, closantel (alternative name) i [CCN] + TX, clothianidin (165) + TX, copper acetoarsenite I [CCN] + TX, copper arsenate [CCN] + TX, copper oleate [CCN] + TX, coumaphos (174) + TX, coumitoate (1006) +! TX, crotamiton (alternate name) [CCN] + TX, crotoxifos (0010) + TX, crufomate (1011) + TX, cryolite (alternative name) (177) + TX, CS 708 (development code) (1012) +, TX, I cyanofenphos (1019) + TX, cyanofos (184) + TX, cyanoate l020) + TX, cyclinthrin [CCN] + TX, cycloprothromine (188) + \ TX, cyfluthrin (193) + TX, cyhalothrin (196) + TX, cypermethrin (201) + TX, Cypherothrin (206) + TX, Ciromazine (209) -TI TX, Citioate (alternative name) [CCN] + TX, D-Limonene (alternative name) [CCN] + TX, D-tetramethrin (name) alternative) (788) + TX, DAEP (1031) + TX, dazomet (216) + TX, DDT (219) + TX, decarbofuran (1034) + TX, deltamethrin (223) + TX, demephion (1037) + TX , demephion-0 (1037) + TX, demephion-S (1037) + TX, demeton (1038) + ?, demethyl-methyl (224) -tj TX, demeton-0 (1038) + X, demeton-O-methyl (224) + TX, demeón-S (1038) + TX, demethyl-S-methyl (224) + TX, demeth-S-methylsulfone (1039) + TX, diafenthiuron (226) + TX, dialiphos (1042) + TX, diamidaphos (1044) + TX, diazinon (227) +! TX, dicapton (1050) + TX, diclofenion (1051) + TX, diclórvós (236) + TX, diclifos (alternative name) + TX, dicrésil (alternative name) [CCN] + TX, dicrotofos (243) +; TX, dicyclanil (244) + TX, dieldrin (1070) + TX, j 5-methylpyrazol-3-yl diethyl phosphate (IUPAC name) (1076) + TX, diflubenzuron (250) + TX, dilor (alternative name) I [CCN] + TX, dimefluthrin [CCN] + TX, dimefox (1081) + TX, dimethan (1085) + TX, dimethoate (262) + TX, dimetrin (1083) + 'TX, dimethylvinfos (265) + TX, dimethylan (1086) + TX, dinex (1089) + TX, dinex-diclexin (1089) + TX, dinoprop (1093) +! TX, dinosam (1094) + TX, dinoseb (1095) + TX, dinotefuran (27) + TX, diofenolán (1099) + TX, dioxabenzofós (1100) + | TX, dioxacarb (1101) + TX, dioxathion (1102) + TX, disulfoton; (278) + TX, dithicrophos (1108) + TX, DNOC (282) + TX, doramectin (alternative name) [CCN] + TX, DSP (1115) + TX, ecdysterone (alternative name) [CCN] + TX, El 1642 (development! Code) (1118) + TX, emamectin (291) + TX, emamectin benzoatp (291) + TX, EMPC (1120) + TX, empentrin (292) + TX, endosulfan (294) + TX, endotion (1121) + TX, endrin (1122) + TX, EPBP (1123) + TX, EPN (297) + TX, epophenone (1124) + TX, eprinomectin (alternative name) [CCN] + TX, esfenvalerate (302) + TX, etaphos (alternative name) [CCN] + TX, etiofencarb (308) + TX, ethion (309) + TX, etiprole (310) + TX, ethoate-methyl (1134) + TX, ethoprofos (312) + TX, ethyl formate (IUPAC name) [CCN] + TX, ethyl-DDD (alternative no.) (1056) + TX, dibromide of ethylene (316) +! TX, ethylene dichloride (chemical name) (1136) + TX, ethylene oxide [CCN] + TX, etofenpróx (319) + TX, etrimphos (1142) + TX, EXD (1143) + TX, famfur (323) + TX, fenamifos (326) + TX, fenazaflor (1147) + TX, fenclorphos (1148) + TX, fenetacarb (1149) + TX, fenfluthrin (1150) + TX, fenitrothion (335) + TX, Fenobucarb (336) + TX, fenoxacrim (1153) + TX, phenoxycarb (340) + TX, fenpiritrin (1155) + TX, fenprorin (342) + TX, fenpirad (alternative name) + TX, fensulfothion (1158) + TX, fenthion (346) + TX, fenthion-ethyl [CCN] + TX , fenvalerate (349) + TX, fipronil (354) + TX, flonicamid (358) +; TX, flubendiamide (CAS Reg. No.:272451-65-7) + TX, flucofuron (1168) + TX, flucycloxuron (366) + TX, flucythrinate (367) + TX, fluenethyl (1169) + TX, flufenerim [ CCN] + i TX, flufenoxuron (370) + TX, flufenprox (1171) + TX, flumethrin (372) + TX, fluvalinate (1184) + TX, FMC 1137 (development code) (1185) + TX, fonofós (1191) ) + TX, formetanate (405) + TX, formetanate hydrochloride (405) + TX, formothion (1192) + TX, formparanate (1193) + TX, fosmethyl (1194) TX, phosphate (1195) + TX, fostiazate (408) + TX, fostietán (1196) ? + TX, furathiocarb (412) + ??, furethrin (1200) + ??, gámraa-cyhalothrin (197) + TX, gamma ^ HCH (430) + TX, guazatine (422) + TX, guazatin acetates (422) + TX, GY-81 (development code) (423) + TX, halfenprox (424) + TX, halofenózida (425) + TX, HCH (430) + TX, HEOD (1070) + TX, heptachlor (1211) + TX, heptenofós (432) + TX, heterofós [CCN] + | TX, hexaflumuron (439) + TX, HHDN (864) + TX, hydramethylnon (443) + TX, hydrogen cyanide (444) + TX, hydroprene (445) TX, hiquincarb (1223) + TX, imidacloprid (458) + TX, imiprotrin (460) + TX, indoxacarb (465) + TX, iodomethane (name IÜPAC) (542) + TX, IPSP (1229) + TX, isazofós ( 1231) + TX, isobenzene (1232) + TX, isocarbophos (alternative name) (473) + TX, isodrin (1235) + TX, isophenphos (1236) + TX, isolane (123 ^ 7) + TX, isoprocarb (472) ) + TX, O- (oxy-aminothiophosphoryl) isopropyl salicylate (IUPAC name) (473) + TX, isoprothiolane (474) + TX, isothioate (1244) +, 'TX, isoxatión (480) + TX, ivermectin ( alternative name) [CCN] i + TX, jasmolin I (696) + TX, jasmolin II (696) + TX, jodfenfos (1248) + TX, juvenile hormone I (alternative name) [CCN] + TX, juvenile hormone II (alternative name) [CCN] + t TX, juvenile hormone III (alternative name) [CCN] + | TX, kelevan (1249) + TX, quinoprene (484) + TX, larfibda-cyhalothrin (198) + TX, lead arsenate [CCN] + | TX, lepimectin (CCN) + TX, leptophos (1250) + TX, lindane (430) + TX, lyrimphos (1251) + TX,. lufenurón (490) + TX, lithidátión (1253) + TX, m-cumenyl methylcarbamate (IÜPAC name) (1014) + TX, magnesium phosphide, (IUPAC name) (640) 4 TX, malathion (492) + TX, malonoben (1254) + TX, mazidox (1255) + TX, mecarbam (502) + TX, mecarphone (1258) + TX, menazon (1260) + TX, mefosfolán (1261) + TX, mercury chloride (513) + TX, mesulfenphos (1263) + TX, metaflumizone (CCN) + TX, metamj (519) +. TX, metam-potassium (alternative name) (519) + TX, meta-sodium (519) + TX, methacryphos (1266) + TX, methamidophos (527) + TX, methanesulfonyl fluoride (name IUPAC / Chemical i Abstracts) (1268) + TX, methidathion (529) + TX, methiocarb! (530) + TX, methocrotophos (1273) + TX, methomyl methoprene (532) + TX, methoquin-butyl (1276) + (alternative name) (533) + TX, methoxychlor (534) + TX, methoxyfenozide (535) + TX, methyl bromide (537) +! TX, methyl isothiocyanate (543) + TX, methyl chloroform (name I alternative) [CCN] + TX, methylene chloride [CCN] + j. TX, metofluthrin [CCN] + TX, metolcarb (550) + TX, methoxadieizone (1288) + TX, mevinfos (556). + TX, mexacarbate (1290) + TX, milbemectin (557) + TX, milbemycin oxime. (alternate name) [CCN] + TX, mipafox (1293) + TX, mirex (1294) + TX, monocrotophos (561) + TX, morphothion (1300) +; TX, moxidectin (alternative name) [CCN] + TX, naphthaophos (alternative name) [CCN] + TX, naled (567) + TX, ñaphthalene (name IUPAC / Chemical Abstracts) (1303) + TX, NC-170 (code) of development) (1306) + TX, NC-184 (compound code) + TX, nicotine (578) + ?, nicotine sulfate (578) + j TX, nifluridide (1309) + TX, nitenpyram (579) + TX, nitiazine (1311) + TX, nitrilacarb (1313) + TX, nitrilacarb complex and zinc chloride 1: 1 (1313) + TX, I-0101 (compound code) + TX, NNI-0250 (compound code) + TX, nornicotine (traditional name) (1319) + TX, novaluron (585) + TX, noviflumuron (586) + TX, 0-5-dichloro-4-iodophenyl 0-ethyl ethylphosphonium ioate (IUPAC name) (1057) +! TX, 0,0-diethyl 0-4-methyl-2-oxo-2H-chromen-7-yl phosphorothioate (IUPAC name) (1074) + TX, O-O-diethyl 0-6-methylthioate fosothothioate -2-propylpyrimidin-4-yl (IUPAC name) (1075) +; TX, 0,0,0 ', 0'-tetrapropyl dithiopriophosphate (name IÜPAC) (1424) + TX, oleic acid (IUPAC name) (593) + TX, omeéoato ! (594) + TX, oxamyl (602) + TX, oxydemeton-methyl (609) + TX, oxideprofos (1324) + TX, oxydisulfonthon (1325) + TX, pp'-DDT (219) + TX, para-dichlorobenzene [CCN] + TX, parathion (615) + TX, parathion-methyl (616) + TX, penfluron (alternative name) [CCN] + TX, pentachlorophenol (623) + TX, pentachlorophenyl laurate (IUPAC name). (623) + TX, permethrin (626) + TX, petroleum oils (alternative name) (628) + TX, · PH 60-38 I (development code) (1328) + TX, fenkapton (1330) +; TX, phenothrin (630) + TX, fentoate (631) + TX, phorate (636) + TX, phosalone (637) + TX, phospholphan (1338) + TX, fosmet (638) 1 TX, . i fosnicloro (1339) + TX, phosphamidon (639) + TX, phosphine I (name IUPAC) (640) + TX, foxim (642) + TX, foxim-méthyl (1340) + TX, pyrimethaphos (1344) + ??, pirimicarb (651) ^ ??, pirimiphos-ethyl (1345) + TX, pirimiphos-methyl (652) + TX, isomers of polychlorodicyclopentadiene (name IUPAC) (1346) + TX, polychloroterpene (traditional name) (1347) +; TX, potassium arsenite [CCN] + TX, potassium thiocyanate [CCN] + TX, praletrin (655) + TX, precocene I (alternative name) [CCN] + TX, precocene II (alternative name) [CCN] + TX, precocene III (alternative name) [CCN] + TX, primidophos (1349) + TX, profenofos (662) + TX, profluthrin [CCN] + | TX, promacyl (1354) + TX, promecarb (1355) + TX, propaphos (1356) + TX, propetamfós (673) + TX, propoxur (678) + j TX, protidathion (1360) + TX, protophytes (686) + TX, protoate (1362) + TX, protrifenbute [CCN] + TX, pymetrozine (688) +! TX, pyraclofos (689) + TX, pyrazophos (693) + TX, piresmethrin (1367) + TX, pyrethrin I (696) + TX, pyrethrin II (696) + TX, pyrethrins (696) + TX, pyridaben (699) + TX, pyridalyl (700) + TX, pyridafentation (701) + TX, pyrimidifen (706) + TX, pyrimitate (1370) + TX, pyriproxyfen (708) + TX, quasia (alternative name) [CCN] + TX, quinalfós (711) + i TX, quinalfós-methyl (1376) + TX, quinotión (1380) + I TX, quintiophos (1381) + TX, R-1492 (development code) (1382) + TX, rafoxanida (alternative name) ) [CCN] + TX, resmethrin (719) + TX, rotenone (722) + TX, RU 15525 (development code) (723) + TX, RU 25475 (development code) (1386) + TX, riania (name) alternative) (1387) + TX, rianódina (traditional name) (1387) + TX, sabadilla (alternate name) (725) + TX, scradán (1389) + TX, sebufós (alternative name) + TX, selamectin (alternative name) [CGN] + TX, SI-0009 (compound code) + TX, SI-0205 (compound code) + TX, SI-0404 (compound code) + TX, Slj0405 I (compound code) + TX, silafluofen (728) + TX, SN 72129 (development code) (1397) + TX, sodium arsenite [CGN] + TX, sodium cyanide (444) + TX, sodium fluoride ( IUPAC / Chemical Abstracts) (1399) + TX, sodium hexafluorosilicate (1400) + TX, sodium pentachlorophenoxide (623) + TX, sodium selenate (IUPAC name) (1401) + TX, thiocyanate i sodium [CCN] + TX, sofamide (1402) + TX, spinosad (737) f TX, spiromesifen (739) + TX, spirotetrmat (CCN) + TX, sulcofuron (746) + TX, sulcofuron-sodium (746) + TX, sulfluramid (750) + TX, sulfotep (753) + TX, sulfuryl fluoride (756) + TX, sulphophos (1408) + TX, alkyltrán oils (alternative name) (758) + TX, tauvavalinate ( 398) +; TX, tazimcarb (1412) + TX, TDE (1414) + TX, tebufenozide (762) + ! TX, tebufenpyrad (763) + TX, tebupirimfos (764) + 1 TX, teflubenzuron (768) + TX, tefluthrin (769) + TX, temephos; (770) + TX, TEPP (1417) + TX, teralethrin (1418) + TX, term (alternative name) + TX, terbufos (773) + · TX, tetrachloroethane [CCN] + TX, tetrachlorvinfos (777) + j TX , tetramethrin (787) + TX, theta-cypermethrin (204) + j TX, thiacloprid (791) + TX, thiafenox (alternative name) +: TX, thiamethoxazole (792) + TX, ticrophos (1428) + TX, thiocarboxime (1431) + TX, thiocyclam (798) + TX, hydrogen oxalatp of thiocyclam (798) + TX, thiodicarb (799) + TX, thiofanox (800) + I TX, thiometon (801) + TX, thionazine (1434) + TX, thiosulphate (803) + TX, thiosultap-sodium (803) + TX, thuringiensine (alternative name) [CCN] + TX, tolfenpirad (809) + TX, tralometrine (812) + TX, transfluthrin (813) + TX, transpermethrin (1440) + TX, triamiphos (1441) + TX, triazamate (818) + TX, triazophos (820) + TX, triazuron (alternative name) + TX, tricloride (824) + TX, trichlormetaphos-3 (alternative name) [CCN] 4 TX, trichloronate (1452) + TX, triphenos (1455) + TX, triflumuron (835) + TX, trimetacarb (840) + TX, triprene (1459) + TX, i vamidothion (847) + TX, vaniliprol [CCN] + TX, veratridine (alternative name) (725) + TX, veratrine (alternate name) (725) + TX, XMC (853) + TX, xylilcarb (854) | · + TX, YI-5302 (compound code) + TX, zeta- Cypermethrin (205) + TX, zetamethrin (alternative name) + TX, zinc phosphide i (640) + TX, zolaprofos (1469) and ZXI 8901 (code: development) (858) + TX, cyantraniliprol [736994-63-19] +! TX, chlorantraniliprol [500008-45-7] + TX, cienopyrafen [56Ú121-52-0]. + TX, ciflumethophene [400882-07-7] + j TX, pyrifluquinazone [337458-27-2] + TX, spinetoram [187166J40-1 + 187166-15-0] + TX, spirotetramat [203313-25-1] + J. TX, sulfoxaflor [946578-00-3] + TX, flufiprol [704886-18-0] +; TX, meperfluthrin [915288-13-0] + TX, tetramethylflutrin [84: 937- 88-2] + TX,; i a molluscicide selected from the group of substances constituted by bis (tributyltin) oxide (IUPAC name) (913) + TX, broraoacetamide [CCN] + TX, calcium arsenate [CCN] + TX, cloetocarb (999) + TX, copper acetoarsenite [CCN] + TX, copper sulfate (172) + TX, fentin (347) +. { TX, ferric phosphate (IUPAC name) (352) + TX, metaldehyde (j518) + TX, methiocarb (530) + TX, niclosamide (576) + TX, niclosamide-olamine (576) + TX, pentachlorophenol (623) + TX, sodium pentachlorophenoxide (623) + TX, tazimcarb (1412) ¡+ TX ,? thiodicarb (799) + TX, tributyltin oxide (913) +! TX, I trifenmorf (1454) + TX, trimetacarb (840) + TX, triphenyltin acetate (IUPAC name) (347) and triphenyltin hydroxide (IUPAC name) (347) + TX, pyriprole [394730-71-3] + TX ,! a nematicide that is selected from the group of substances consisting of AKD-3088 (compound code) + TX, 1,2-dibromo-3-chloropropane (name IUPAC / Chemical Abstracts) (1045) + TX, 1,2-dichloropropane (name IUPAC / Chemical Abstracts) (1062) + TX, 1,2-dichloropropane with 1,3-dichloropropene (IUPAC name) (1063) + TX, 1,3-dichloropropene (233) + TX, 1,1-dioxide of 3, 4-dichlorotetrahydrothiophene (name IUPAC / Chemical Abstracts) (1065) + TX, 3 - (-chlorophenyl) -5-methylrodanine (IUPAC name) (980) + TX, 5-methyl-6-thioxo-1 acid, 3, 5-thiadiazin-3-ylacetic (IUPAC name) (1286) + TX, 6-isopentenylaminopurine (alternative name) (210) + TX, abamectin (1) + TX, acetoprol [CCN] + j TX, (141) + TX, chlorpyrifos (145) + TX, cloetocarb (999) + TX, cytokinins (alternative name) (210) + TX, dazomet (216) + TX, DBCP (1045) + TX, DCIP (218) + TX, diamidaphos (1044)) + TX, diclofentión (1051) + TX, diclifós (alternative name) -tj TX, i dimethoate (262) + TX, doramectin (alternative name) [CCN] t + TX, emamectin (291) + TX, emamectin benzoate (29.1) + TX, eprinomectin (alternative name) [CCN] + TX, etopiofos (312) + TX, ethylene dibromide (316) + TX, fenamifos (; 326) I I + TX, fenpirad (alternative name) + TX, fensulfothion (1158) í + TX, fostiazate (408) + TX, fostietán (1196) + TX, furfural í .. (alternative name) [CCN] + TX, GY-81 (development code) (423) + TX, heterophos [CCN] + TX, iodomethane (name IUPAC) (542) + TX, isamidophos (1230) + TX, isazofos (1231) + j; TX, ivermectin (alternative name) [CCN] + TX , quine'tina (alternative name) (210) + TX, mecarphone (1258) + TX, metam (519) + TX, metam-potassium (alternative name) (519) + |: TX, metam-sodium (519) + TX, methyl bromide (537) + · TX, methyl isothiocyanate (543) + TX, milbemycin oxime (ndmbre i) alternative) [CCN] + TX, moxidectin (alternative name) [CCN] + TX, Myrothecio verrucaria composition (alternative name) (565) + TX, NC-184 (compound code) TX, oxamyl (602) + TX, phorate (636) + TX, phosphamidon (639) TX, phosphocarb [CCN] + TX, sebufos (alternative name) +. { TX, selamectin (alternative name) [CCN] + TX, spinosad (737) + TX, terbam (alternative name) + TX, terbufos (773) + j TX, tetrachlorothiophene (name IUPAC / Chemical Abstracts) (1422) + TX, thiafenox (alternative name) + TX, thionazine (1434) j + TX, triazophos (820) + TX, triazuron (alternative name) + i TX, xylenols [CCN] + TX, YI-5302 (code composed) and zeatin (name alternative) (210) + TX, fluensulfone [318290-98-1] + TX, ¡ a nitrification inhibitor selected from the group of substances constituted by potassium ethylxanthate [CCN] and nitrapyrin (580) + TX,; a plant activator selected from the group of substances consisting of acibenzolar (6) + TX, acibenzolar-S-methyl (6) + TX, probenazole (658) and extract of Reynoutria sachalinensis (alternative name) (720) + TX , > a rodenticide selected from the group of substances consisting of 2-isovaleryl indan-1,3-dione (name IÜPAC) (1246) + TX, 4 - (quinoxalin-2-ylamino) benzenesulfonatnide (IUPAC name) (748) + TX, alpha- chlorohydrin [CCN] + j TX, aluminum phosphide (640) + TX, antu (880) + TX, oxide arsenious (882) + TX, barium carbonate (891) +: TX, bistiosemi (912) + TX, brodifacum (89) + TX, bromadiolone (91) + TX, bromethalin (92) + TX, calcium cyanide (444) + TX, chloralose (127) + TX, chlorophacinone (140) + TX,? cholecalciferol (alternative name) (850) + TX, coumaclor (1004) + TX, coumafuril (1005) + TX, coumatetralil (175); + TX, crimidine (1009) + TX, difenacoum (246) + TX, difetialone i (249) + TX, diphacinone (273) + TX, ergocalciferol (301) + TX, flocoumafen (357) + TX, fluoroacetamide (379) + j TX, flupropadine (1183) + TX, flupropadine hydrochloride (1,118) ) + TX, gamma-HCH (430) + TX, HCH (430) + TX, hydrogen cyanide (444) + TX, iodomethane (IUPAC name) (542) + TX, lindane (430) + TX, phosphide magnesium (IUPAC name) (640) I + TX, methyl bromide (537) + TX, norbormide (1318) +! TX, fosacetim (1336) + TX, phosphine (IUPAC name) (640) + TX, phosphorus [CCN] + TX, pindone (1341) + TX, potassium arsenite [CCN] + TX, pirinuron (1371) + TX , sciliroside (1390) + | t ?, sodium arsenite [CCN] + TX, sodium cyanide (444) + i TX, sodium fluoroacetate (735) + TX, strychnine (745) + I TX, thallium sulfate [ CCN] + TX, warfarin (851) and zinc phosphide (640) + TX, and a synergist selected from the group of substances constituted by piperonylate of 2- (2-butoxyethoxy) ei i lo (IUPAC name) (934) + TX 5- (1, 3-benzodioxol-5-yl.} - 3-hexylcyclohex-2-enone (IUPAC name) (903) + TX, farnesol 'with nerolidol (alternative name) (324) + TX, MB-599 (development code) (498) + TX, MGK 264 (development code) (296) + TX, piperonyl butoxide (649) + TX, piprotal (1343) ) + TX, propyl isomer (1358) + TX, S421 (development code) (724) + TX, sesamex (1393) + TX, sesasmoline (1394) and sulfoxide (1406) + TX, i an animal repellent selected from the group of substances constituted by anthraquinone (32) + TX, chloralose (127) + TX, copper naphthenate [CCN] + TX, copper oxychloride (171) + TX, diazinon (227) + TX, dicyclopentadiene (chemical name) (1069) + TX, guazatine (422) + TX, acetylates of guazatine (422) + TX, methiocarb (530) + TX, pyridin-4-amine (name IUPAC) (23) + TX, thiram (804) + TX, trimetacarb (840) + TX, zinc naphthenate [CCN] and ziram (856) + TX, a virucide selected from the group of sustaricias constituted by imanin (alternative name) [CCN] and ribavirin (alternative name) [CCN] + TX,; i a wound protector selected from the group of substances constituted by mercuric oxide (512) +; TX, octylenone (590) and methyl thiophanate (802) + TX, and biologically active compounds that are selected from the group consisting of azaconazole (60207-31-0] + 'TX, bitertanol [70585-36-3] + TX, bromuconazole [116255-48-2] | + TX, ciproconazole [94361] -06-5] + TX, difenoconazole [119446-68- | 3] + TX, diniconazole [83657-24-3] + TX, epoxiconazole [106325-08-0] + TX, fenbuconazole [114369-43-6] + ??, fluquincoriazole [136426-54-5] + TX, flusilazole [85509-19-9] + TX, flutrjafol [76674-21-0] + TX, hexaconazole [79983-71-4] + TX, [35554-44-0] + TX, imibenconazole [86598-92-7] + TX, [125225-28-7] + TX, metconazole [125116-23-6] + TX, myclobutanil [88671-89-0] + TX, pefurazoate [101903-30-4] + TX, penconazole [66246-88-6] ] + TX, protioconazole [178928-70-6] + TX, pirifenox [88283-41-4] + TX, prochloraz [67747-09-5] + i TX, propiconazole [60207-90-1] + TX, simeconazole [149508-90-7] + TX, tebuconazole [107534-96-3] + TX, tetraconazole [112281-77-3] + TX, triadimefon [43121-] 43-3] + TX, triadirtienol. [55219-65-3] + TX, triflumizole [99387-89-0] + TX, triticonazole [131983-72-7] + TX, ancymidol [12771-68-5] + TX, fenarimol [60168-88-9] ] + TX, nuarimol [63284-71-9] + TX, bupirimate [41483-43-6] + TX, dimetirimol [5221-53-4] + TX, etirimol [23947-60-6] + TX, dodemorf [1593-77-7] + TX, phenpropidine [67306-00-7] + TX, phenpropimorf [67564 -91-Í4] + TX, spiroxamine [118134-30-8] + TX, tridemorf [81412-43 3 ] + TX, cyprodinil [121552-61-2] + TX, mepanipyrim [110235-47-7] + TX, pyrimethanil [53112-28-0] + TX, phenpiclonil [74738-17-3] + TX, fludioxonil [ 131341-86-1] + TX, benalaxyl [71626-f 11-4] + TX, furalaxyl [57646-30-7] + TX, metalaxyl [57837-194-1] + TX ,. metalaxyl-R [70630-17-0] + TX, ofurace [58810-48-3] + TX, oxadixyl [77732-09-3] + TX, benomyl [17804 TX, carbendazim [10605-21-7] + TX , debacarb [62732-91-6] TX, fuberidazole [3878-19-1] + TX, thiabendazole [148-79-8] +. TX, clozolinate [84332-86-5] + TX, diclozoline [24201-58-9] H | TX, iprodione [36734-19-7] + TX, myclozolin [54864-61-8] + TX, procymidone [32809-16-8] + TX, vinclozolin [50471-44-8] + TX, boscalid [188425-] 85-6] + TX, carboxy [5234-68-4] + | TX, fenfuram [24691-80-3] + TX, flutolanil [66332-96-5] + TX, mepronil [55814-41-0] + TX, oxycarboxine [5259-88-1] TX, pentiopyrad [183675-82] -3] + TX, tifluzamide [130000-40-; 7] + TX, guazatine [108173-90-6] + TX, dodine [2439-10-3] [112-65-2] (free base) + TX , iminoctadine [13516-27-3] + TX, azoxystrobin [131860-33-8] + TX, dimoxystrobin [149961-52-4] + TX, enestroburin. { Proc. BCPC, Int. Congr., Glasgow, 2003, 1, 93.}. + TX, fluoxastrobin [361377-29-9] + TX, kresoxim-methyl [143390-89-0] + TX, metominostrobin [133408-50-1] '+ TX, trifloxystrobin [141517-21-7] + TX, orisastrobin [248593-116-0] + TX, picoxystrobin [117428-22-5] + TX, pyraclosthiobin [175013-18-0] + TX, ferbam [14484-64-1] + TX, mancozeb [8018-01- 7] + TX, maneb [12427-38-2] + TX, metiram [9006-42-2] ¡+ TX, propineb '[12071-83-9] + TX, tiram [137-26-8] + TX , zineb [12122-67-7] + TX, ziram [137-30-4] + TX, captafol [2425-06-1] i + TX, captan [133-06-2] + TX, diclofluanid [1085-98-9] +: TX, fluoroimide [41205-21-4] + TX, folpet [133-07-3] + TX, tolylfluanid [731-27-1] + TX, Bordeaux mixture [8011-63-0] + TX, copper hydroxide [20427-59-2] + TX, copper oxychloride [1332-40-7] + TX, sulfate copper [7758-98-7] + TX, oxide of copper [1317-39-1] + TX, mancobre [53988-93-5] + ??, copper [10380-28-6] + TX, dinocap [131-72-6] + TX, nitro-isopropyl [10552-74-6] + TX, edifenfós [17109-49-8] + j TX, iprobenfós [26087 -47-8] + TX, isoprothiolane [50512-35-1] | + TX, fosdifen [36519-00-3] + TX, pyrazophos [13457-18-6] +; TX, tolclofos-methyl [57018-04-9] + TX, acibenzolar-S-methyl [135158-54-2] + TX, anilazine [101-05-3] + TX, bentiavalícarb [413615-35-7] + TX, blasticidin-S [2079-00-7] + TX, quinometionat [2439-01-2] + TX, chloroneb [2675-77-6] +: TX, chlorothalonil [1897-45-6] + TX, ciflufenamide [180409-60-3] + TX, cymoxanil [57966-95-7] + TX, diclone [117-80-6] + TX, diclocimet [139920-32-4] + TX, diclomezine [62865-36-5] ] + j TX, dicloran [99-30-9] + TX, dietofencarb [87130-20-9] + I TX, i dimetomorf [110488-70-5] + TX, SYP-LI90 (Flumorf) [211867-47-9] + TX, dithianon [3347-22-6] + TX, etaboxam + TX, etridiazol [2593-15-9] + TX, famoxadone + TX, fenamidone [161326-34-7] + TX, phenoxanil + TX, fentin [668-34-8] + TX, ferimzone [89269-64-7] + \ TX, ! fluazinam [79622-59-6] + TX, fluopicolide [239110-15-7] + | TX, flusulfamide [106917-52-6] + TX, fenhexamid [126833-17-8] + TX, fosetyl-aluminum [39148-24-8] + TX, himexazole [10004 -: 44 -1] + TX, iprovalicarb [140923-17-7] + TX, IKF-916 (Ciazofamid) i [120116-88-3] + TX, kasugamycin [6980-18-3] + TX, metasulfocarb [66952-49-6] + TX, metrafenone [220899-03-6] + TX, penicuron [66063-05- 6] + TX, phthalide [27355-22-2] + TX, I polyoxins [11113-80-7] + TX, probenazole [27605-76-1] + X, propamocarb [25606-41-1] + TX, proquinazid [189278-12-4] + TX, pyroquilone [57369-32] -1] + TX, quinoxifen [124495-18-7] + TX, quintozene [82-68-8] + TX, sulfur [7704-34-9] + TX, thiadinyl [223580-51-6] + TX, triazoxide [72459-58-6] + TX, tricyclazole [41814-78-2] + TX, triforin [26644-46-2] + TX, validan [37248-47-8] + TX, zoxamide (RH7281) [156052-68-5] +; TX, mandipropamid [374726-62-2] + TX, isopyrazam [881685-58-1] + TX, sedaxane [874967-67-6] + TX, (9-dichloromethylene- 1,2 j 3, 4 -tetrahydro- 1,4-Difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid 1,4-methano-naphthalen-5-yl) -amide (described in WO 2007/048556) + TX, [2- (2 3-difluoromethyl-1-methyl-1H-pyrazol-4-carboxylic acid (4-dichlorophenyl) -2-methoxy-1-methyl-ethyl] -amide (described in WO 2008/148570) + TX, 1 - [4 - [4 - [(5S) 5 - (2,6-difluorophenyl) -4,4-dihydro-1,2-oxazol-3-yl] -l, 3-thiazol-2-yl] piperidin -l-yl] -2 - [5-methyl-3- (trifluoromethyl) -lH-pyrazol-l-yl] ethanone + TX |, 1- [4- [4- [5- (2,6-difluorophenyl)] -4,5-dihydro-1,2-oxazol-3-yl] i-1,3-thiazol-2-yl] iperidin-1-yl] -2- [5-methyl-3- (trifluoromethyl) -lH -pyrazol-l-yl] ethanone [1003318-67-9], both described in WO 2010/123791, WO i 2008/013925, WO 2008/013622 and WO 2011/051243 page 20) -TX and 3-difluoromethyl-1-methyl-1H- (31,4 ', 51-trifluoro-biphenyl-2-yl) -amide of 3-difluoromethyl-l-methyl-lH- pyrazole-4-carboxylic acid (described in WO 2006/087343) + TX, 3 - (difluoromethyl) -N- methoxy-l-methyl-N- [l-methyl-2- (2,4,6-trichlorophenyl) ethyl] -1H-Pyrazole-4-carboxamide + TX, 4- [(5S) -5- (3, 5 -dichloropheni) -5- (trifluoromethyl) -4H-isoxazol-3-yl] -2-methyl-N- (tietan-3-j-D-benzamide (WO2011 / 104089) + TX, 4- [(5R) -5- ( 3,5-f-dichlorophenyl) -5- (trifluoromethyl) -4H-isoxazol-3-yl] -2-methy1-N- (thietan-3-yl) benzamide (O2011 / 104089) + TX, 4- [(5S ) -5- (3,5-dichlorophenyl) -5- (trifluoromethyl) -4H-isoxazol-3-yl] -2-methyl-N- (cis-l-oxo-thietan-3-yl) benzamide (WO2011 / 104089) + TX, | 4- [(5R) -5- (3, 5-dichlorophenyl) -5- (trifluoromethyl) -4H-isoxazolj-3 -yl] -2-methyl-N- (cis-l-oxo -tietan-3-yl) benzamide (WO2011 / 1O4089) t + TX, 4- [(5S) -5- (3,5-dichlorophenyl) -5- (trifluoromethyl)! -4H-isoxazol-3-yl] -2-methyl-N- (trans-l-oxo-thietan-3-yl) benzamide (O2011 / 104089) + TX, 4 - [(5R) -5- (3, 5-dichlorophenyl) -5- (trifluoromethyl) -4H-isoxazol-3-yl] -2-methyl-N- (trans-l-oxoj-thietan-3-yl) benzamide (WO2011 / 104089) + TX, 4- [(5S) -5- (i3, 5-dichlorophenyl) -5- (trifluoromethyl) -4H-isoxazol-3-yl] -N- (1, dioxothientan-3-yl) -2-methyl-benzamide (O2011 / 104089) + TX-, 4- [. { 5R) -5- (3,5-dichlorophenyl) -5- (trifluoromethyl) -4H-isoxazol-3-yl] -N- (1, 1-dioxothientan-3-yl) -2-methyl-benzamide (WO2011 / 1Q4089) + TX, 4- [(5S) -5- (3, 5-dichlorophenyl) -5- (trifluoromethyl) | -4H-isoxazol-3-yl] -2-methyl-N- [2-oxo-2 - (2,2,2- I I trifluoroethylamino) ethyl] benzamide (WO2011 / 104089) + TX ,: 4- [. { 5R) -5- (3,5-dichlorophenyl) -5- (trifluoromethyl) -4H-isoxazole 3-yl] -2-methyl-N- [2-OXO-2- (2, 2, 2- 1 trifluoroethylamino) ethyl] benzamide (WO2011 / 104089) + TX. ! The components (B) are known. The references indicated in parentheses after each active ingredient, for example [3878-19-1], refer to the Registijo number of Chemical Abstracts. The components of the mixtures described above are known. When the active ingredients are included in the pesticide manual [The Pesticide Manual - A World Compendium; Thirteenth edition; Editor: C. D. S. TomLin; British Ministry of Protection I of the Crops], are described herein with the entry number indicated in parentheses hereinabove for the particular compound, for example: the compound "abamectin" is described with the number of enerada (1). When "[CCN]" is added to the particular compound hereinabove, the compound in question is indluded in the "Compendium of Common Names of Pesticides", to which I It can be accessed through the Internet at http://www.alanwood.net/pesticides/ [A. Wood; Compendium of Pesticide Common Yams, Copyright® 1995-2012];; or i "preferably one of the additional pesticides listed below.

In the various preceding lists of the active ingredients for mixing with an X, the compound of the formula I is preferably a compound of Tables 1 to 12 and A; and more preferably, a compound TX is selected from Table A, or a compound TX is selected from Table B, or a Compound X is selected from Table C, and still: more preferably a compound TX is selected from Al, A3, A4, A5, A8, A17, A18, A19, A25, A40, A78, A97, A102, A103, A105, A106, A107, A108, A110, There, A112, A115, A123, A131, A135, A136, A137, A139, A140, A141, A142, A143, A144, A145, A148, A150 or a compound TX is selected from Al, A2, A3, A4, A5, A8, All, A12, A14, A15, A16, A17, A19, A22, A25, A27, A40, A56, A102, A103, A105, A106, A107, A108, A110, There, A115, A114, A126, A131, A135, A136, A137, A139, A140, A141, A142, t A143, A144, A145, A146, A147, A148, A149, A150 or a compound TX is selected from Al, A2, A3, A4, A5, A8, All, A12, A13, A14, A15, A16, A17, A18, A19, A20, A21, A22, A23, A40, A52, A53, A55, A64, A67, A70, A78, A85, A91, A103, A105, A106, A107, A108, A110, There, A112, A115, A118, A119, A122, A123, A126, A131, A134, A135, A136, A137, A138, A139, A140, A141, A142, A143, A145, A146, A147, A148,? 1 · 50 or I a compound TX is selected from Al, A3, A4, A8, All, A12, A15, A16, A17, A22, A23, A25, A27, A28, A40, A45, A47,; A52, A53, A55, A64, A68, A78, A78, A97, A102, A103, A105, A106, A107, A108, A110, There, A115, A119, A126, A135, A137, A138, A 39, A140, A141, A142, A143 , A144, A145, A147, A148, A150 or a compound TX is selected from Al, A2, A3, A4, A5, A8, A9, All, A14, A15, A17, A18, A20, A21, A22, A23, A25, A26, A27, A28, A41, A52, A52, A53, A55, A62, A68, A70, A78, A85, A102, A103, A105, A106, A107, A108, A112, A114, A115, A117, A119, A132, A133, A134, A136, A137, A138, A139, A140, A141, A142, A144, A145, A148 or a compound TX is selected from Al, A2, A3, A,! A5, A6, A8, All, A14, A15, A16, A25, A26, A27, A40, A56, A102, A103, A106, A107, A110, A112, A114, A115, A122, A129, A136, A137, A138, A139, A140, A141, A143, A144, A148, A151 or a compound TX is selected from Al, A4, A102, A106, A148.

In the different preceding lists of ingredients Active to be mixed with a TX, the compound of formula I is preferably a compound selected from Al, A3, A4, A5, A8, A17, A18, A19, A25, A40, A78, A97, A102, A103, A105, A106, A107, A108, A110, There, A112, A115, A123, A135, A136, A137, A139, A140, A141, A142, A143, A144, A148, A150, A1, A2, All, A12, A14, A15, A16, A22, A27, A114, A126, A146, A147, A149, A13, A20, A21, A23, A52, A53, A55, A64, A67, A70, A85, A91, A118, A119, A122, A134, A138, A28, A45, A47 , A68, A9, A26, A41, A62, A117, A132, A133, A6, A129, A151. i In the mixtures of compounds of formula I mentioned above, in particular, a compound selected from Tables 1 to 12 and A, with other insecticides, fungicides, herbicides, protectants, adjuvants and the like; Mixing ratios can vary widely and will be, preferably from 100: 1 to 1: 6000, especially 50: 1 to 1:50, j more ! especially 20: 1 to 1:20, even more especially 10: 1 to 1:10. It is understood that these mixing ratios include, on the one hand, weight ratios and, on the other hand, molar ratios.

The mixtures can be conveniently used in | the formulations mentioned previously (in which cascj the "active ingredient" refers to the respective mixture of TX with its mixing partner). i Some mixtures may comprise active ingredients with significantly different physical, chemical or biological properties, so that they do not easily lend themselves to the same type of conventional formulation! Under these circumstances, other types of formulations can be prepared. For example, when an active substance is a i solid insoluble in water and the other a liquid insolublje in ! water, it may however be possible to disperse each active ingredient in the same continuous aqueous phase by dispersing the solid active substance as a suspension a preparation analogous to that of a SC) but the liquid active ingredient as an emulsion (using a preparation analogous to that of an E). The resulting composition is a formulation of the suspoemulsion (SE) type.

Mixtures comprising a TX selected from; Tables 1 to 12 and A and one or more active ingredients as described above can be applied, for example, in a simple "pre-mixed" form, in a combined aerosol mixture composed of separate formulations of; simple active ingredient components, such as' a 'tank mix', and in a combined use of the simple active ingredients when applied sequentially, i.e., one behind the other with a reasonably short interval, such as some hours or days. The order of application of the compounds of formula (I) selected from Tables 1 to 12 and A and the active ingredients as described above is not essential for the practice of the present invention. ! The compounds of formula (I) can be mixed! with soil, peat or other means of rooting to protect plants from diseases of seeds, soil and foliar fungal diseases.

Examples of suitable synergists to be employed in the compositions include piperonyl butoxide, sesamemex, safroxan and dodecyl imidazole.

The inclusion of suitable herbicides and plant growth regulators in the compositions will depend on the objective to be aved and the necessary effect. i An example of a selective herbicide for the arro? What can be included is propanil. An example of regulated growth of plants for use in cotton is the product Pix ™. : Some mixtures may comprise active ingredients with significantly different physical, chemical or biological properties, so that they do not readily lend themselves to the same type of formulation. Under these circumstances, they may be prepared from formulations. For example, when a prin water-insoluble solid and the other a liquid insoluble in water, it may still be possible to disperse each active ingredient in the same continuous aqueous phase by dispersing the solid active substance as a suspension (using a preparation analogous to that of a SC) but dispersing the liquid active ingredient as an emulsion (using a preparation analogous to that of an E). The resulting composition is a suspoemulsion (SE) type formulation.

Preparation of examples j Intermediate II: 5-azido-l-methyl-3-pentafluoroethyl-4-trifluoromethyl-1H-pyrazole! 5-Fluoro-l-methyl-3-pentafluoroet l-4-trifluoromethyl-1H-pyrazole (which was prepared according to the invention) was added.

Russian Chemistry Bulletin 1990, 39, No. 11, p2338; 2 jg; 7 mmol) was added to a mixture of DMSO (10 mL) and sodium azide (0.5 g, 7.7 mmol) was added to the mixture, which was added. maintained at room temperature. The mixture was stirred overnight at room temperature. Once the reaction was finished, a mixture of water (100 mL) and diethyl ether (100 mL) was added. The s they were separated and the aqueous phase was extracted twice with diethyl ether. This compound was used without further purification.

Intermediary 12: 2-Chloro-5-ethynyl-benzoic acid methyl ester A solution of 25 mL of 5-Bromo-2-chlorobenzoic acid methyl ester (commercially available, 0000 mmol), 22.94 mL of ethynyltrimethylsilane (162.3 mmol), 0.45 g of palladium (II) acetate (2.0 mmol), and 1.05 g 'of I Triphenylphosphine (4.0 mmol) in 300 mL of anhydrous triethylamine was rapidly heated to reflux under drone overnight. The mixture was cooled and isolated: by filtration the white crystalline solid of bromhydrated triethylamine. The dark brown filtrate was concentrated, j was mixed with 250 mL of aqueous sodium bicarbonate and extracted with dichloromethane (3 x 100 mL). The organic fractions were combined, dried over magnesium sulfate and concentrated to give an oil which was dissolved in ! 200mL of THF and treated with 300mL of methanol and 500 mg of potassium carbonate. The mixture was stirred for 1 hour and concentrated. The concentrated solution was mixed with 250 mL of aqueous sodium bicarbonate and extracted with ethyl acetate (3 x 100 mL). The organic fractions were combined; dried over magnesium sulfate and concentrated in vacuo and chromatographed with cyclohexane / ethyl acetate (3:17) to give 2-chloro-5-ethynyl-benzoic acid methyl ester (14. Og, 74% yield) . 1H NMR (40QMHz, CDC13): 7.96 (s, 1H), 7.5 (d, 1H), 7.42 (d, 1H), 3.93 (s, 3H), 3. 14 (s, 1H) ppm. j Intermediary 13: Bl: 2-Chloro-5- [1- (2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazolyl) methyl ester 3-yl) -lH- [1,2,3] triazol-4-yl] -benzoic acid 2-Chloro-5-ethynyl-benzoic acid methyl ester (Intermediate 12, 1.13g, 5.8 mmol) and 5-azido-l-methyl-3-pentafluoroethyl-4-trifluoromethyl-1H-pyrazole were suspended (Intermediate II, 1.80 g, 5.8 mmol) in a mixture of water and t-BuOH (30 mL) i. Sodium ascorbate (0.600 ml of sol, 1M in water, freshly prepared) was added to the mixture followed by pentahydrat copper sulphate (II) (0.015 g). The resulting heterogeneous mixture was stirred vigorously for 96 hours. The reaction mixture was diluted with water and the product was extracted with ethyl acetate. The organic phase was washed with brine, dried over magnesium sulfate and evaporated. The residue was subjected to ! i column chromatography on silica gel (c-HEX / EtOAc = 3: 1) to give the desired product 2-chloro-5- [1- (2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H) methyl ester - j pyrazol-3-yl) -1 H- [1, 2, 3] triazol-4-yl] -benzoic acid (Compound I Bl, 53% yield). ¾ NM (400MHz, CDC13): 8.47 (s, 1H), 8.12 (ls, 1H), 8.0 (d, 1H), 7.62 (d, 1H), 3.98 (s, 3H), 3.87 (sj 3H) ppm . LC-MS T 2.12, 504 (M + H +), 545 (M + CH3CN + H +) ¡i The same reaction was used for the synthesis of methyl 3-j [1- [2-methyl-5- (1,1,2,2,2-pentafluoroethyl) -4- (trifluoromethyl) pyrazole) 3-yl] triazol-4-yl] benzoate (Compound B2). j t Intermediate 14: Cl: 2-Chloro-5- [1- (2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazol-3-yl) -1H- [1,2,3] triazole-4 acid -yl] -benzoic acid 2-Chloro-5- [1- (2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazol-3-yl) -1H- methyl ester was suspended. [1, 2, 3] triazol-4-yl] -benzoic acid (Intermediate 13, 1.53g, 3.0 thmol)? in a mixture of water and tetrahydrofuran (1: 3, 50 mL) and lithium hydroxide (0.22 g, 9.1 mmol) was added. The resulting mixture was stirred vigorously for 5 hours at 60 ° C. The reaction mixture was diluted with water and acidified with hydrogen chloride (2N). The aqueous phase was extracted twice with AcOEt, dried over MgSO4 and concentrated in vacuo to give the dexated product 2-chloro-5- [1- (2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazole) -3-yl) -1 H- [1,2,3] triazol-4-yl] -benzoic acid. This compound It was used without further purification (Compound Cl). 1H NMR (400MHz, CDC13): 8.52 (s, 1H), 8.18 (ls, 1H), 8.09 (d, 1H),; 7.66 (d, 1H), 3.88 (s, 3H) ppm. LC-MS TR 2.08, 488 (M-H +).

The same reaction was used for the synthesis of 3- [1- [2-methyl-5- (1,1,2,2,2-pentafluoroethyl) -4- (trifluoromethyl) pyrazole; -3-yl] triazole- 4-yl] benzoic acid (Compound C2).

Example Pl: 2-Chloro-N-cyclopropyl-5- [1- (2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazol-3-yl) -1H- [1, 2, 3] triazole- 4 -yl] -benzamide (Compound Al) To a solution of 2-chloro-5- [1- (2-methyl-5- pentafluoroethyl-4-trifluoromethyl-2H-pyrazol-3-yl) -1H- j [1, 2, 3] triazol-4-yl] -benzoic acid (Example 14) (0.20 g, 0.4 mmol) and N, iV-dimethylformamide (2 drops) in dichloromethane (5 ml) under a nitrogen atmosphere was added chloride of oxalyl (0.086 ml, 1.0 mmol). The reaction mixture was stirred for one hour at room temperature and then at 60 ° C for: 1.5 hours. The reaction mixture was concentrated and the residue was dissolved in tetrahydrofuran (5 ml). The solution was added dropwise to a solution of cyclopropylamine (0.03 g, 0.6 mmol) and pyridine (O.lml, 1.2 mmol) in tetrahydrofuran (5 ml).

The reaction mixture was stirred at room temperature 16 hours. The reaction mixture was poured. { in aqueous sodium hydrogen carbonate (1M) and the mixture was extracted three times with ethyl acetate. The combined organic phases were dried over sodium sulfate and concentrated. The residue was purified by column chromatography on silica gel (eluent: ethyl acetate / cyclohexane) to provide Compound No. Al on the Table A (0.13 g, 60.2% yield). P.f. 150-152 ° C.

¾ NMR (400 MHz, CDCl 3): 8.14 (m, 2H), 8.01 (d, 1H), 7.03 (d, 1H), 6.42 (sb, 1H), 3.89 (s, 3H), 2.97 (m, 1H) ), 0.92 (m,, j2H), I 0. 68 (m, 2H) ppm. LC-MS: TR: 1.99, ES- [573, M + HCOO "] j The compounds A2 of Table A were prepared by the same method. P.f. 136-140 ° C. 1 H NMR (400 MHz, CDCl 3): 8.57 (db, 1H), 8.21 (s, 1H), 8.12 (s, 1H), 8.04 (d, 1H), and 7.72. (m, 2H), 7.58 (d, 1H), 7.38 (d, 1H), 7.24 (m, 1H), 4.82 (d, 2H), 3.87 (s, 3H) ppm. LC-MS: T: 1.92, ES- [624, M + HCOO ") Additionally, compounds A102 to A109, A135 aj A14 of Table A were prepared by the same or similar method.

Example P2: General method for acylation of an amino-benzamide in parallel To a solution of the appropriate carboxylic acid (30 ymol), for example 2-chloro-5- [1- (2-methyl-5-pentafluoroethyl-4-trifluoromethyl-2H-pyrazol-3-yl) -1H- [1] , 2,3] triazol - - il] - j benzoic acid (Example 14) in the case of Compound No. A20 of Table A, a solution of an amine of formula HNR1Q1 (36 μp) was added successively in dimethylacetamide (0.4 ml). ???),: for example 3-methyl-tietan-3-yl-amine (preparation described in, for example, document O2007 / 080131) in the case; of Compound No. A20 of Table A, in dimethylacetamide (0.145 ml), diisopropylethylamine (Hunig's base) (0.03 ml, 180 μp) and a solution of bis (2-oxo-3-oxazolidinyl) phosphonic chloride ("B0P-C1") (15.3 mg) in dimethylacetamide (0.2 ml). The reaction mixture i was stirred at 50 ° C for 16 hours. The reaction mixture was diluted with acetonitrile / dimethylformamide (4: 1) (0.8 ml) and purified by HPLC. This method or; a similar i was used to prepare a number of compounds i (Compound Nos. A3 to A101 and A110 to A134 of Table A) in parallel. j Method A: j LC-MS method (positive or negative) for Al compounds, A2, Bl, Cl, B2, C2, A108 and A109: j Waters ZQ mass spectrometer (single quadrupole mass spectrometer) Parameters of the instrument: Ionization method: Electrospray j ! Polarity: positive ions ! Capillarity (kV) 3.00, Cone (V) 30.00, Extractor! (V) 2.00, Source temperature (° C) 100, Desolvation temperature (° C) 250, Cone gas flow (L / Hr); 50, Desolvation gas flow (L / Hr) 400! Mass interval: 100 to 900 Da. j Agilent 1100 Series HPLC: solvent degasser i, quaternary pump (ZCQ) / binary pump (Z | DQ), Heated column compartment and i diode fix detector. ' Column: Phenomenex Gemini C18, 3 μ? T ?, 30 x 3 rare, Temp: 600C Wavelength range of DAD (nm): 200 to 500 Solvent gradient: A = water + 0.05% HCOOH B = acetonitrile / methanol (4: 1, v: v) + 0.04% HCOOH Method B LC-MS method (positive) for compounds A3 a, A101, A110 to A134 and A152 to A197: ACQUITY SQD mass spectrometer from Waters (single quadrupole mass spectrometer) Ionization method: Electrospray Polarity: positive ions Capillarity (kV) 3.00, Cone (V) 20.00, Extractor; (V) 3.00, Source temperature (° C) 150, Desolvation temperature (° C) 400, Cone gas flow (L / Hr): 60, Desolvation gas flow (L / Hr) 700 Dough interval: 100 to 800 Da Wavelength range of DAD (nm): 210 to 400 Waters ACQUITY UPLC method - with the following HPLC gradient conditions (Solvent A: Water / Methanol 9: 1.0.1% formic acid Solvent B: Acetonitrile, 0.1% formic acid) Type of column: Waters ACQUITY UPLC HSS T3; Length of column: 30 mm Internal diameter of column: 2.1 mm; Particle size: 1.8 microns; Temperature: 60 ° C.

I Table A: Compounds of formula (I '): R2 = H I I i i Table B: Compound of formula (Illb '): R2 = H (lllb ') Table C: Compound of formula (??? '): R2 = H (III ·) j Biological examples { Biological examples describe the pesticidal / insecticidal properties of compounds of formula (I) J The tests were carried out as described below: Spodoptera littoralis (black donut): j Disks of cotton sheets were placed on agar in a 24-well microtiter plate and; they were sprayed with test solutions at an application rate of 200 ppm. After drying, the discojs of I leaves were infested with 5 larvae Ll. The samples were evaluated to determine mortality, feeding behavior and growth regulation 3 days after Of treatment (DDT). | The following compounds provided a control of at least 80% of Spodoptera littoralis: Al, A3, A4, A5, A8, A17, A18, A19, A25, A40, A78, A97, A102, A103, A105, A106, A107, A108, A110, There, A112, A115, A123, A131, A135, 8, Heliothis virescens (tobacco budworm;): I Eggs (0 to 24 h of life) were placed in a plate of 1 microtitration of 24 wells with artificial diet and were treated with test solutions at an application rate of 200 ppm (concentration in well of 18 ppm) by pipetting. After an incubation period of 4 the Samples were evaluated to determine egg mortality, larval mortality and growth regulation.

The following compounds provided a At least 80% of Heliothis virescens: Al, A2, A3, All, A12, A14, A15, A16, A17, A19, A22, A25, A27 A102, A103, A105, A106, A107, A108, A110, There, A126, A131, A135, A136, A137, A139, A140, A141, A144, A145, A146, A147, A148, A149, A150.

Plutella xylostella (cabbage moth): A microtiter plate was treated ( Wells with artificial diet with one test solutions i Application rate of 200 ppm (concentration in well 18 | I: · ppm) by pipetting. After drying, the PMTs I infested with L2 larvae (7 to 12 per well). After an incubation period of 6 days, the samples were evaluated to determine larval mortality and growth regulation. |: The following compounds provided a control of at least 80% Plutella xylostella: Al, A2, A3-, A4; A5 j "A8, All, A12, A13, A14, A15, A16, A17, A18, A19, A20, A21,] A22, A23, A25, A27, A40, A52, A53, A55, A64, A67, A70, A78, VA85, A91, A97, A102, A103, A105, A106, A107, A108, A110, There, A112, A115, A118, A119, A122, A123, A126, A131, A134, A135, ! . A136, A137, A138, A139, A140, A141, A142, A143, A145, A146, A140, A141, A142, A143, A144, A145, A147, A148, A150 .:: Tetranychus urticae (common red spider mite): I Bean leaf discs were sprayed on the jagar i in 24-well microtiter plates with test solutions at an application rate of 200 ppm. After drying, leaf discs were infested with mite populations of different ages. Eight days later! The discs were evaluated to determine the mortality of eggs, larval mortality and mortality from adults. i The following compounds provided a control of at least 80% of Tetranychus urticae: Al, A2, A3, A4, A5j A8,? A9, All, A14, A15, A17, A18, A20, A21, A22, A23, A25, A26, I A27, A28, A41, A52, A53, A55, A55, A62, A68, A70, A78, A85, A102, A103, A105, A106, A107, A108, A112, A114, A115, A117, A119, A132, A133, A134, A136, A137, A138, A139, A140, A141, A142, A144, A145, A148.

Thrips tabaci (onion thrips): Sunflower leaf discs were placed on agar in a 24-well microtiter plate and sprayed with test solutions at an application rate of 20o | ppm. After drying, leaf discs were infested with a population of aphids of different ages. After an incubation period of 7 days, the samples were evaluated to determine mortality. ! i.

The following compounds provided a contrql of? At least 80% of Thrips tabaci: Al, A2, A3, A4, A5, A6,: A8, All, A14, A15, A16, A25, A26, A27, A40, A56, A102, A103, A106, A107, A110 , A112, A114, A115, A122, A129, A135, A136, A137, A138, A139, A140, A141, A143, A144, A148, A150, A151.

Myzus persicae (green peach aphid): j Sunflower leaf discs were placed on aga: in a 24-well microtiter plate and i were sprayed with test solutions at an application rate of 200 ppm. After drying, the discs of leaves were infested with a population of aphids of different ages. After an incubation period of 6 ddt, the samples were evaluated to determine mortality. i The following compounds provided a control of at least 80% Myzus persicae: Al, A4, A102, A103, A106, A148 ..

It is noted that in relation to this date, the best method known to the applicant to carry out the practice I said invention is that which is clear from the present description of the invention.

Claims (1)

1. CLAIMS Having described the invention as above) is claimed as property contained in the following claims: 1. A compound of formula (I) characterized by A1, A2, A3 and A4 or nitrogen, where each X can be the same or different; R1 is hydrogen, C1-C4alkyl, H2NC (O) -alkylCi-C4 or I alkylcarbonylCi-C4; j R is hydrogen, halogen, Ci- C alkyl, haloalkyl Ci-Q or cyano; : i. G1 is oxygen or sulfur; ] X is hydrogen, halogen, cyano, C1-C4alkyloxyCi-C4alkyl or C4-haloalkyl; i Q1 is aryl or 'heterocyclyl, each optionally substituted by one to five substituents R3, which may be the same or different; i , or Q is C 1 -C 8 alkyl or C 1 -C 8 alkyl substituted by a C2-C4 haloalkenyl, C2-C4 alkynyl, haloalkynylG2-C4, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, G-C3 alkoxy, di- (alkylCi-C4) -amino, alkylcarbonyl-1-C4, alkylcarbonyloxyCi-C4, alkoxycarbonylGji-C4, alkylcarbonylaminoCi-C4 and phenyl; each R 4 is independently halogen, cyano, nitro, hydroxy, C 3 -Cio cycloalkyl, C 3 -Cy cycloalkyl substituted by one to five R 3, di (C 1 -C 8 alkyl) amino, C 1 -C 8 alkanoylamino, C 1 -C 8 alkyl, C 2 -C 8 alkynyl, C 1 -C 8 alkoxy, haloalkoxyCi-C8, alkylCi-C8alkyl, haloalkylthioCi-C8, alkylsulfinylG'i'-C8, haloalkylsulfinylCi-C8, alkylsulfonyloyl-C8, haloalkylsulfonylCi-C8, alkylcarbonylCi-C8, alkoxycarbonylCi-C8, aryl or aryl substituted by one to five R3 , aryloxy or aryloxy substituted by one to five R3 or heterocyclyl or heterocyclyl substituted by one to five R3; Q2 is a residue of formula (II) where R7 and R6 are independent other hydrogen, cyano, halogen, Ci-C6alkyl, haloalkylGi-C6, alkoxyCi-C4alkylCi-C4, alkylthioCi-C6, haloalkylthioGi-C6, alkylsulfinylCi-C6, haloalkylsulphyl iniCji-C6, alkylsulfonylCi-C6 or haloalkylsulfonylCi-C3 j R5 is independently hydrogen, hydroxyl, amino, N-alkylaminoCx-Cg, N, N-di- (Ci- C6 alkyl) amino, C ^ -6 alkyl, C3-C6 cycloalkyl / C2-C6 alkenyl, C2-C6 alkynyl, C6-C6 alkyl substituted by one to five substituents R9, cycloalkylpC3-C6 j substituted by one to five substituents R9, alkynylqC2-Ce substituted by one to five substituents R9, C2-C6 alkenyl substituted by one to five substituents R9, aryl or. aryl substituted by one to five substituents R10, heteroaryl or heteroaryl substituted by one to five substituents R10,: each R9 is independently cyano, nitro, amino, hydroxy, halogen, N-alkylaminoCi-Cg, N, N-di- (alkylCi) C6) - amino, C6-C6-alkyloxyCi-C6alkylsulfonylCi-C6alkyl, aryl or aryl which is substituted by one to five substituents independently selected from cyano, nitro, hydroxyl, halogen, C-alkyl, haloalkylCi-Ce , C6-C6 alkoxy or haloalkoxyCi-C6, or heteroaryl or heteroaryl which; is substituted by one to five substituents which are independently selected from cyano, nitro, hydroxy, halogen, Ci-C6 alkyl, Ci-C6 haloalkyl, Ci-C6 alkoxy or haloalkoxy Ci-be; t each R10 is independently cyano, nitro, amino, hydroxy, halogen, Ci-Cg alkyl, CX-Cs haloalkyl, Ci-C4 alkoxyCi-C4 alkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 alkynyl, C2-C6 haloalkynyl, C3-C6 cycloalkyl, halocycloalkyl C3 -? C6, alkoxyCi-C6, haloalkoxyCi-C6, alkoxyCi-C4alkoxyGi-C4, alkylthioCi-C6, haloalkylthioC-C6, alkylsulfinylGi-C6, haloalkylsulfinylCi-C6, alkylsulfonylCx-Cg, haloalkylsulfonylCi-C6, N-alkylaminoCi-C6, N, N -di - (alkylCi-? C6) amino, N, N-di- (alkylCi-C6) aminocarbonyl, N, N-di- (C 1 -C 6 alkyl) aminosulfonyl, C 1 -C 6 alkylcarbonyl, C 1 -C 6 alkylcarbonyloxy, C 1 -C 6 alkoxycarbonyl, C 1 -C 6 alkylcarbonylamino;; i or a salt or agro-chemically acceptable N-oxides thereof.; 2. A compound according to claim 1, characterized in that; i A1, A2, A3 and A4 are C-X and each X is independently selected from hydrogen, halogen, cyano, metallo, trifluoromethyl and methoxy. : 3. A compound according to claim 2, characterized in that 1 R1 is hydrogen, methyl, ethyl or acetyl; R 2 is hydrogen, methyl, trifluoromethyl or halogen; G1 is oxygen; Q1 is aryl or heterocyclyl or cycloalkylC3-Gi0 or Ci-Ca alkyl; each optionally substituted by one to five substituents which are independently selected from cyano, nitro, hydroxy, bromo, chloro, fluoro, methyl, trifluoromethyl, methoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl and phenyl; R5 is hydrogen, haloCi-C6 alkyl, Ci-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, phenyl or phenyl substituted by one to five substituents R10, which may be the same or different, pyridyl or pyridyl substituted by one to five substituents R10, which may be the same or different; R7 and R6 are independently hydrogen, cyano, halogen, Ci-C6alkyl, perfluoroalkylCi-C6, perfluoroalkylthioCi-C6, perfluoroalkylsulfinylCi-C6 or perfluoroalkylsulfonylCi-C6 preferably independently perfluoroalkylCi-C, perfluoroalkylthioCi-C4, perfluoroalkylsulfihiloC; i-C4 or per-fluoroalkylsulfonylCi C even more preferably independently perfluoroalkylCi-C4, perfluoroalkylthioCi-C4, or perfluoroalkylsulfonylCx-C4. 4. A compound according to claim 3, characterized in that R1 is hydrogen, methyl or ethyl R2 is hydrogen, trifluoromethyl or halogen; Q1 is phenyl, cyclopropyl and ethyl; each: one optionally replaced by one to four substitutes that they are independently selected from cyano, nitro, hydiroxy, bromine, chlorine, fluoro, methyl, ethyl, trifluoromethyl, methoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl and phenyl, t R5 is hydrogen, haloalkylCx-Cg, Ci-C6alkyl; R and R are independently cyano, halogen, CX-Cg alkyl, perfluoroalkylCx-Cg. | 5. A compound according to claim 4, characterized in that R1 is hydrogen, methyl or ethyl R2 is hydrogen or halogen; Q is phenyl, cyclopropyl and ethyl; each Optionally substituted by one to four substituents which are independently selected from cyano, nitro, hydroxy, bromo, chloro, fluoro, methyl, ethyl, trifluoromethyl, methoxy, I trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl and phenyl;; R5 is preferably Ci- C alkyl; j R7 and R6 are independently perfluoroalkylCx-Ce. 6. A compound according to claim 5, characterized in that] R1 is hydrogen;; 8. A compound of formula (III) characterized in that A1, A2, A3, A4, R2 and Q2 are such j as I 'define in relation to formula (I); or a salt thereof 9. A compound of formula (Illb) characterized in that A1, A2, A3, A4, R2 and Q2 are such as defined in relation to formula (I); and R is CX-Cg alkyl or a salt of it. 10. A method for combating and controlling insects, mites, nematodes or molluscs characterized in that it comprises applying to a pest, a pest locus or a susceptible plant I an attack by a pest or plant propagation material an insectlerely, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula (I) in accordance with any of claims 1 to 7. j i 11. An insecticidal, acaricidal or nematid composition I characterized in that it comprises an insecticidally, acaricidally or nematicidally effective amount of a compound of formula (I) in accordance with any of | Claims 1 to 7.!