MX2012013217A - Catalizadores soportados para la produccion de combustibles de ultra-bajo azufre. - Google Patents
Catalizadores soportados para la produccion de combustibles de ultra-bajo azufre.Info
- Publication number
- MX2012013217A MX2012013217A MX2012013217A MX2012013217A MX2012013217A MX 2012013217 A MX2012013217 A MX 2012013217A MX 2012013217 A MX2012013217 A MX 2012013217A MX 2012013217 A MX2012013217 A MX 2012013217A MX 2012013217 A MX2012013217 A MX 2012013217A
- Authority
- MX
- Mexico
- Prior art keywords
- ultra
- diesel fuel
- production
- catalysts supported
- hydrodesulphurization
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 239000000446 fuel Substances 0.000 title abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title 1
- 229910052717 sulfur Inorganic materials 0.000 title 1
- 239000011593 sulfur Substances 0.000 title 1
- 239000002283 diesel fuel Substances 0.000 abstract 3
- 239000003502 gasoline Substances 0.000 abstract 2
- 229910003294 NiMo Inorganic materials 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002803 fossil fuel Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 235000005985 organic acids Nutrition 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/166—Y-type faujasite
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
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- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
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- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
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- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Nanotechnology (AREA)
- Dispersion Chemistry (AREA)
Abstract
La presente invención pertenece al campo de preparación de catalizadores utilizados para la hidrodesulfuración de combustibles fósiles y proporciona una método para preparar catalizadores térmicamente estables y de bajo costo para la hidrodesulfuración de gasolina y diesel, con base en CoMo y NiMo altamente activos. El catalizador para hidrotratamiento de gasóleo o gasolina de la presente invención comprende un precursor que consiste de compuestos químicos obtenidos a partir de ácidos orgánicos y sales metálicas, y un soporte que contiene una zeolita tipo-Y ultraestable, útil en el hidrotratamiento del gasóleo pesado y/o de gasóleo cíclico ligero con altas conversiones.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2012013217A MX349965B (es) | 2012-11-14 | 2012-11-14 | Catalizadores soportados para la produccion de combustibles de ultra-bajo azufre. |
US14/442,863 US9675968B2 (en) | 2012-11-14 | 2013-11-14 | Supported catalysts for producing ultra-low sulphur fuel oils |
BR112015011032A BR112015011032A2 (pt) | 2012-11-14 | 2013-11-14 | catalisadores suportados para a produção de óleos de combustível de ultra-baixa quantidade de enxofre |
CA2894537A CA2894537A1 (en) | 2012-11-14 | 2013-11-14 | Supported catalysts for producing ultra-low sulphur fuel oils |
JP2015542987A JP2016502464A (ja) | 2012-11-14 | 2013-11-14 | 超低硫黄燃料油製造用の担持触媒 |
PCT/MX2013/000140 WO2014088388A1 (es) | 2012-11-14 | 2013-11-14 | Catalizadores soportados para la producción de combustibles de ultra-bajo azufre |
Applications Claiming Priority (1)
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MX2012013217A MX349965B (es) | 2012-11-14 | 2012-11-14 | Catalizadores soportados para la produccion de combustibles de ultra-bajo azufre. |
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US (1) | US9675968B2 (es) |
JP (1) | JP2016502464A (es) |
BR (1) | BR112015011032A2 (es) |
CA (1) | CA2894537A1 (es) |
MX (1) | MX349965B (es) |
WO (1) | WO2014088388A1 (es) |
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CN105618073B (zh) * | 2016-03-29 | 2018-07-03 | 中国石油大学(北京) | 基于氧化铝晶面调控的轻质烃类脱硫醇催化剂及其制法 |
WO2017166046A1 (zh) * | 2016-03-29 | 2017-10-05 | 中国石油大学(北京) | 基于氧化铝晶面调控的轻质烃类脱硫醇催化剂及其制法 |
US10603657B2 (en) * | 2016-04-11 | 2020-03-31 | Saudi Arabian Oil Company | Nano-sized zeolite supported catalysts and methods for their production |
CN106115784B (zh) * | 2016-06-27 | 2017-06-30 | 济南大学 | 一种具有三甲胺敏感效应的CoMoO4纳米颗粒/MoO3纳米带异质结材料 |
US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
US20190233741A1 (en) | 2017-02-12 | 2019-08-01 | Magēmā Technology, LLC | Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil |
CN106824198B (zh) * | 2017-03-10 | 2019-06-21 | 中国科学技术大学 | 钴基产氧催化剂及其制备方法以及一种碱性制氢电解槽 |
CN107638882A (zh) * | 2017-05-08 | 2018-01-30 | 中国科学院大连化学物理研究所 | 一种汽油选择性加氢脱硫催化剂及其制备和应用 |
RU2687734C1 (ru) * | 2018-12-17 | 2019-05-16 | Акционерное Общество "Газпромнефть - Московский Нпз" (Ао "Газпромнефть - Мнпз") | Способ приготовления катализатора гидроочистки бензина каталитического крекинга |
KR20200086983A (ko) * | 2019-01-10 | 2020-07-20 | 코아텍주식회사 | 대용량 과불화화합물 제거를 위한 금속산화물 촉매 및 그 제조 방법 |
CN111097501B (zh) * | 2019-12-26 | 2022-10-18 | 中海油天津化工研究设计院有限公司 | 一种用于劣质柴油加氢处理的体相催化剂及其制备方法 |
RU2763889C1 (ru) * | 2021-04-09 | 2022-01-11 | Акционерное общество «Газпромнефть - Омский НПЗ» (АО «Газпромнефть - ОНПЗ») | Катализатор гидроочистки дизельного топлива |
CN113244932B (zh) * | 2021-05-17 | 2022-06-14 | 大连理工大学 | 一种合成无定型结构MoS2蛋壳型加氢脱硫催化剂的方法及应用 |
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US5342507A (en) * | 1992-06-11 | 1994-08-30 | Texaco Inc. | Mild hydrocracking process employing catalysts containing dealuminated y-zeolites |
CN1108356C (zh) * | 2000-10-26 | 2003-05-14 | 中国石油化工股份有限公司 | 一种高活性高中油性加氢裂化催化剂及其制备方法 |
EP1577007B1 (en) * | 2002-12-18 | 2013-03-20 | Cosmo Oil Co., Ltd. | Hydrotreating catalyst for gas oil, process for producing the same, and method of hydrotreating gas oil |
RU2366505C2 (ru) * | 2004-03-03 | 2009-09-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Носитель катализатора и каталитическая композиция, способы их получения и применения |
US9187702B2 (en) * | 2009-07-01 | 2015-11-17 | Chevron U.S.A. Inc. | Hydroprocessing catalyst and method of making the same |
AU2012240093B2 (en) * | 2011-04-08 | 2015-06-11 | W. R. Grace & Co.-Conn. | Mesoporous framework-modified zeolites |
IN2014CN04670A (es) * | 2011-12-23 | 2015-09-18 | Shell Int Research |
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- 2012-11-14 MX MX2012013217A patent/MX349965B/es active IP Right Grant
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- 2013-11-14 JP JP2015542987A patent/JP2016502464A/ja active Pending
- 2013-11-14 WO PCT/MX2013/000140 patent/WO2014088388A1/es active Application Filing
- 2013-11-14 CA CA2894537A patent/CA2894537A1/en not_active Abandoned
- 2013-11-14 US US14/442,863 patent/US9675968B2/en active Active
- 2013-11-14 BR BR112015011032A patent/BR112015011032A2/pt not_active IP Right Cessation
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MX349965B (es) | 2017-08-04 |
CA2894537A1 (en) | 2014-06-12 |
US20150306585A1 (en) | 2015-10-29 |
JP2016502464A (ja) | 2016-01-28 |
BR112015011032A2 (pt) | 2017-07-11 |
WO2014088388A1 (es) | 2014-06-12 |
US9675968B2 (en) | 2017-06-13 |
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