MX2011007066A - Composicion de catalizador con donador a base de fosforo. - Google Patents
Composicion de catalizador con donador a base de fosforo.Info
- Publication number
- MX2011007066A MX2011007066A MX2011007066A MX2011007066A MX2011007066A MX 2011007066 A MX2011007066 A MX 2011007066A MX 2011007066 A MX2011007066 A MX 2011007066A MX 2011007066 A MX2011007066 A MX 2011007066A MX 2011007066 A MX2011007066 A MX 2011007066A
- Authority
- MX
- Mexico
- Prior art keywords
- phosphorus
- catalyst composition
- based donor
- electron donor
- external electron
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- TYBOKIPGZHEQSB-UHFFFAOYSA-N diphospazane Chemical compound PNP TYBOKIPGZHEQSB-UHFFFAOYSA-N 0.000 abstract 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 abstract 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6497—Catalysts containing a specific non-metal or metal-free compound organic containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Cosmetics (AREA)
- Catalysts (AREA)
Abstract
Se describen composiciones de catalizador que tienen un donador de electrón externo que incluye una o más de las siguientes composiciones: un fosfito, una fosfonita, un pirofosfito, y/o un difosfazano. Las composiciones de catalizador Ziegler-Natta que contienen el donante de electrón externo de la presente invención, exhiben una fuerte actividad y producen olefinas a base de propileno con alta isotacticidad y alto rango del flujo de fundición.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14117008P | 2008-12-29 | 2008-12-29 | |
PCT/US2009/069693 WO2010078330A2 (en) | 2008-12-29 | 2009-12-29 | Catalyst composition with phosphorus-based donor and method |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2011007066A true MX2011007066A (es) | 2011-12-16 |
Family
ID=41809289
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2011007066A MX2011007066A (es) | 2008-12-29 | 2009-12-29 | Composicion de catalizador con donador a base de fosforo. |
Country Status (10)
Country | Link |
---|---|
US (2) | US20100227988A1 (es) |
EP (1) | EP2373696A2 (es) |
JP (1) | JP2012514118A (es) |
KR (1) | KR20110110260A (es) |
CN (1) | CN102325804A (es) |
BR (1) | BRPI0918344A2 (es) |
MX (1) | MX2011007066A (es) |
RU (1) | RU2011131780A (es) |
SG (1) | SG172416A1 (es) |
WO (1) | WO2010078330A2 (es) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9790291B2 (en) * | 2013-03-14 | 2017-10-17 | Formosa Plastics Corporation, Usa | Non-phthalate compounds as electron donors for polyolefin catalysts |
US9593184B2 (en) | 2014-10-28 | 2017-03-14 | Formosa Plastics Corporation, Usa | Oxalic acid diamides as modifiers for polyolefin catalysts |
WO2017079940A1 (zh) * | 2015-11-12 | 2017-05-18 | 营口市向阳催化剂有限责任公司 | 含有磷酸酯类外给电子体的聚丙烯聚合用催化体系及其应用 |
US9777084B2 (en) | 2016-02-19 | 2017-10-03 | Formosa Plastics Corporation, Usa | Catalyst system for olefin polymerization and method for producing olefin polymer |
US11427660B2 (en) | 2016-08-17 | 2022-08-30 | Formosa Plastics Corporation, Usa | Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same |
CN107880174B (zh) * | 2016-09-30 | 2020-06-09 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备与应用 |
US9815920B1 (en) | 2016-10-14 | 2017-11-14 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
US10822438B2 (en) | 2017-05-09 | 2020-11-03 | Formosa Plastics Corporation | Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer |
US10124324B1 (en) | 2017-05-09 | 2018-11-13 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
CN109293805B (zh) * | 2017-07-25 | 2021-03-09 | 中国石油天然气股份有限公司 | 烯烃聚合固体催化组分、组分制备方法及其催化剂体系 |
CN114426603B (zh) * | 2020-10-16 | 2023-11-14 | 中国石油化工股份有限公司 | 乙烯聚合的方法及聚乙烯 |
CN113105575B (zh) * | 2021-04-13 | 2022-11-18 | 南京金陵塑胶化工有限公司 | 一种超高乙烯含量高韧性聚丙烯专用料的制备方法 |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3127432A (en) * | 1960-10-03 | 1964-03-31 | Monsanto Chemicals | Organic phosphorus-aluminum compounds and method of preparation |
US3328375A (en) * | 1966-05-19 | 1967-06-27 | Avisun Corp | Polymerization of olefins in the presence of a catalyst consisting of titanium trichloride, an alkyl aluminum dihalide and an alkoxy silane |
US3558586A (en) * | 1968-02-14 | 1971-01-26 | Phillips Petroleum Co | Polymerization process and catalyst system |
SE363977B (es) * | 1968-11-21 | 1974-02-11 | Montedison Spa | |
US3940345A (en) * | 1971-07-13 | 1976-02-24 | Imperial Chemical Industries Limited | Olefine polymerization catalyst |
US3969269A (en) * | 1971-07-13 | 1976-07-13 | Imperial Chemical Industries Limited | Olefine polymerization catalyst incorporating an organo-phosphorus compound |
DE2739382A1 (de) * | 1977-09-01 | 1979-03-15 | Basf Ag | Verfahren zum herstellen einer titan enthaltenden komponente fuer katalysatoren des ziegler-natta-typs |
US4130503A (en) * | 1977-12-23 | 1978-12-19 | Phillips Petroleum Company | Phosphite in MgX2 supported TiX3 /AlCl3 catalyst system |
JPS58138711A (ja) * | 1982-02-12 | 1983-08-17 | Mitsui Petrochem Ind Ltd | オレフインの重合方法 |
US4458027A (en) * | 1983-03-18 | 1984-07-03 | E. I. Du Pont De Nemours And Company | Olefin polymerization catalysts |
DE3682928D1 (de) * | 1985-03-08 | 1992-01-30 | Mitsubishi Petrochemical Co | Verfahren zum polymerisieren von aethylen. |
CN1006071B (zh) * | 1985-04-01 | 1989-12-13 | 中国石油化工总公司 | 用于烯烃聚合和共聚合的催化剂体系 |
US4814314A (en) * | 1986-09-26 | 1989-03-21 | Mitsubishi Petrochemical Company Limited | Catalyst for olefin polymerization |
JP2550641B2 (ja) * | 1988-02-29 | 1996-11-06 | 住友化学工業株式会社 | 低級α−オレフィンの二量化方法 |
GB9300318D0 (en) | 1993-01-08 | 1993-03-03 | Oxford Analytical Instr Ltd | Improvements relating to sample monitoring |
TW354792B (en) * | 1993-08-13 | 1999-03-21 | Mitsui Petrochemical Ind | Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer |
JP3688078B2 (ja) * | 1996-11-20 | 2005-08-24 | 三井化学株式会社 | オレフィン重合用触媒、予備重合触媒、オレフィンの重合方法 |
CN1218951C (zh) | 2002-07-17 | 2005-09-14 | 中国石油化工股份有限公司 | 一种硅醚化合物及其制备方法和应用 |
US20040106815A1 (en) * | 2002-12-02 | 2004-06-03 | Ritter Joachim C. | Selective synthesis of organophosphites |
WO2005030815A1 (en) * | 2003-09-23 | 2005-04-07 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
US7323431B2 (en) | 2004-12-23 | 2008-01-29 | China Petroleum & Chemical Corporation | Catalyst for olefin polymerization and use of the same |
US7662901B2 (en) * | 2007-11-30 | 2010-02-16 | Sunoco Chemicals, Inc. | High crystallinity, high melt flow rate polypropylene |
EP2350143B1 (en) * | 2008-11-25 | 2016-02-17 | W.R. Grace & CO. - CONN. | Procatalyst composition multiple internal donor having silyl ester and method |
WO2019084133A1 (en) | 2017-10-25 | 2019-05-02 | Sensormatic Electronics, LLC | FRICTION-FREE ACCESS CONTROL SYSTEM USING SATELLITE CAMERAS FOR FACIAL RECOGNITION |
DE102019120446A1 (de) | 2019-07-29 | 2021-02-04 | Endress+Hauser Conducta Gmbh+Co. Kg | Verfahren zur Korrektur von zwei Messwerten von jeweils verschiedener Analysenmessgeräte sowie Messstelle zum Ausführen des Verfahrens |
-
2009
- 2009-12-29 CN CN2009801570599A patent/CN102325804A/zh active Pending
- 2009-12-29 KR KR1020117017693A patent/KR20110110260A/ko not_active Application Discontinuation
- 2009-12-29 BR BRPI0918344A patent/BRPI0918344A2/pt not_active Application Discontinuation
- 2009-12-29 MX MX2011007066A patent/MX2011007066A/es not_active Application Discontinuation
- 2009-12-29 JP JP2011544586A patent/JP2012514118A/ja active Pending
- 2009-12-29 WO PCT/US2009/069693 patent/WO2010078330A2/en active Application Filing
- 2009-12-29 SG SG2011047347A patent/SG172416A1/en unknown
- 2009-12-29 RU RU2011131780/04A patent/RU2011131780A/ru unknown
- 2009-12-29 EP EP09797239A patent/EP2373696A2/en not_active Withdrawn
- 2009-12-29 US US12/648,715 patent/US20100227988A1/en not_active Abandoned
-
2012
- 2012-12-11 US US13/710,975 patent/US8614162B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20100227988A1 (en) | 2010-09-09 |
US20130102457A1 (en) | 2013-04-25 |
CN102325804A (zh) | 2012-01-18 |
WO2010078330A4 (en) | 2010-12-09 |
JP2012514118A (ja) | 2012-06-21 |
BRPI0918344A2 (pt) | 2015-12-15 |
EP2373696A2 (en) | 2011-10-12 |
RU2011131780A (ru) | 2013-02-10 |
KR20110110260A (ko) | 2011-10-06 |
SG172416A1 (en) | 2011-07-28 |
WO2010078330A3 (en) | 2010-09-16 |
US8614162B2 (en) | 2013-12-24 |
WO2010078330A2 (en) | 2010-07-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FA | Abandonment or withdrawal |