MX2011002241A - Water-base acrylic waterproofing composition with low thermal conductivity which uses recycled materials in the formulation thereof. - Google Patents

Water-base acrylic waterproofing composition with low thermal conductivity which uses recycled materials in the formulation thereof.

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Publication number
MX2011002241A
MX2011002241A MX2011002241A MX2011002241A MX2011002241A MX 2011002241 A MX2011002241 A MX 2011002241A MX 2011002241 A MX2011002241 A MX 2011002241A MX 2011002241 A MX2011002241 A MX 2011002241A MX 2011002241 A MX2011002241 A MX 2011002241A
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MX
Mexico
Prior art keywords
water
thermal conductivity
formulation
low thermal
recycled materials
Prior art date
Application number
MX2011002241A
Other languages
Spanish (es)
Inventor
Ricardo Andres Rodriguez Zablah
Original Assignee
Polimeros Adhesivos Y Derivados S A De C V
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Publication date
Application filed by Polimeros Adhesivos Y Derivados S A De C V filed Critical Polimeros Adhesivos Y Derivados S A De C V
Priority to MX2011002241A priority Critical patent/MX2011002241A/en
Publication of MX2011002241A publication Critical patent/MX2011002241A/en

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Abstract

The present invention refers to a water-base acrylic waterproofing composition with low thermal conductivity having values of = 0.24 watt/m°K and preferably with values = 0.06 watt/m°K, which uses recycled materials in the formulation thereof, which is characterised in that the composition comprises an acrylic or modified acrylic resin including butyl acrylate with 20% to 60% of total solids; microspheres of glass, ceramic or polymeric and/or mixtures thereof; particles of milled tire rubber having a size of from about 10 mesh to about 400 mesh, loads, additives and water, an optionally comprising fibre, a water hardness controller, a fire retardant and dyes.

Description

COMPOSITION OF ACRYLIC WATERPROOF BASE WATER WITH LOW THERMAL CONDUCTIVITY, WHICH USES MATERIALS OF RECYCLING IN YOUR FORMULATION FIELD OF THE INVENTION The present invention falls in the field of the construction industry and the production industry of waterproof coatings in general and more especially with the industry of the formulation, development and production of waterproofing for roofs and different substrates of the construction. More especially, the invention relates to a water-based acrylic waterproofing composition with low thermal conductivity that uses recycled materials in its formulation.
BACKGROUND OF THE INVENTION The waterproofing coatings for diverse constructions, have like objective to prevent the passage of water, for the isolation of the humidity and the water of diverse origins, for the spaces and porosities formed by the construction materials that conform walls, slabs, canopies and other structures of coverage of open or closed spaces.
In the state of the art, some systems of waterproofing coatings are well known, such as the asphalt, acrylic, cement systems and the prefabricated system.
The system of acrylic coating consists of 'waterproofing based on water-based liquid acrylic compositions that applied form a waterproof film on the surface where it is applied, which are easy to apply, highly reflective, and its elasticity does not crack or fissure, is 100% waterproof, ideal for roofs, and horizontal and inclined roofs, is applied on surfaces of cete, mortar, asbestos or galvanized sheet.
One of the inconentients of some compositions used to waterproof civil works constructions with this type of waterproofing is that of being too viscous; a high viscosity makes the application difficult, leaving areas of less mechanical resistance that absorb the dilatations and contractions of film and substrate.
The products that are known to date in the market are acrylic waterproofing; elastomeric without fibers that are applied and before drying the first layer a roll of reinforcing fabric is spread and when drying the second coat is applied; other waterproofing materials have reinforced fiber materials in their content. This type of fiber-bearing waterproofing has the drawback of losing its elongation properties, although on the one hand, when incorporating fibers, it achieves greater resistance to tension; but the elongation is sacrificed.
; The current acrylic waterproofing, some have as application system, a reinforcement fabric prior to the application of the waterproofing, in other cases one coat of the waterproofing is applied, the reinforcing fabric is added and the second coat of the waterproofing is applied; but this requires more skilled labor.
The constant climatic changes that generate drastic fluctuations in temperature, relative humidity, frequent rains during the rainy season, etc. they cause the reinforcement fibers to fracture and damage in a short time. Likewise, acrylic waterproofing can be diluted by the person who applies it, reducing its physical-chemical properties and affecting the quality of the membrane that is generated when it dries, lowering the properties and its durability and the times of activation are greater.
It is also important to note that water-based acrylic waterproofing products generally carry a high percentage of water that will evaporate applied, which implies that almost 50% or more of the product purchased is water.
On the other hand, it is known that in hot areas where extreme temperatures reach above 40 ° C in the shade, it is necessary to use materials that, in addition to waterproofing, can contain the effect of solar rays and partially isolate the structures, in order to avoid heat transfer to the buildings enclosures. Faced with this situation, it is known to use white waterproofing to favor the reflection of the sun's rays and to mitigate a heat and partially avoid heat. However, just by choosing a white waterproofing does not prevent excessive heating that occurs in buildings in areas with high temperatures. .
On the other hand, it is well known the problem that exists of environmental contamination by the infinity of discarded products, such as rubber and plastic materials such as bottles, bags and tires or tires for various vehicles.
Generally, once the useful life of the tires has ended, they are thrown away or thrown away1 and, at best, when they are partially worn, they can be vulcanized again to be used; but once this is discarded and thrown into large deposits, which represent a major environmental problem.
The rims are made of vulcanized synthetic rubber that is reacted with certain chemical products to harden it and make it less reactive with diverse chemical products, besides making it resistant to wear under adverse weather conditions such as sun, rain, among other factors and for make it resistant to friction, etc., they also incorporate metal cords.
Some solutions have been found for the problem of discarded tires; for example, they are used as fuels by brickmakers or in the cement industry; however, this implies the emission of large amounts of pollutants into the atmosphere; This requires the incorporation of emissions controls into the atmosphere.
Tires are also used to delimit areas, to generate containment fences for example on race tracks; they have also been used as flowerpots, or as fences and games in children's areas; among other uses; but these do not really solve the underlying problem, only the reuse and once they cease to be useful they are discarded again.
It is also known that the tires, once the metal ropes are removed, can be ground to be used as a raw material together with other additives for making rugs or the like. However, the amount of recycled tires is minimal.
However, the tires are kept in good condition in a period of approximately 5 years, after which the rubber begins to deteriorate due to aging and cracks, cracks, etc. appear.
It is known on the other hand that the tires to which the metal cords have been removed, regardless of the condition of the tires; Although the rubber is aged and grinded and used for various fine as to make rugs, some have made paintings. The existing mills do not allow to grind the tires to small sizes, being the smallest size of 0.3 mm.
The paint to which they are; It incorporates ground rims that turn dark or opaque and when applied, as they define a thin film, it does not generate a uniform film, there are clumps and protrusions that leave a textured surface with heterogeneous reliefs, leaving a gray and very rustic finish that favors the accumulation of dust and water and other waste and increases the heating by absorption of solar radiation when applied outdoors. In case of fire it is highly flammable and can ignite the substrate where it is applied generating toxic fumes.
Returning to the topic of 'waterproofing, there is a certification organization called as a certification organization called the National Organization for Standardization and Certification of Construction and Building (ONNCCE), which is a decentralized body, which has the standard NOM-018-ENER-1997"Thermal Insulators, for buildings. Characteristics, limits, and test methods ", which measures thermal conductivity in building materials through laboratory tests carried out on product samples, with which they certify products that comply with that standard.
The Electric Energy Savings Trust (FIDE) under the Federal Electricity Commission (CFE) is in charge of promoting energy savings, issues certification for certain products that must comply with the established standards and, as a result, grants a FIDE stamp which guarantees that said product complies with the Standards, Laws, Regulations, manufacturer's instructions, etc. in force related to its installation and application. Within these products are the Products for Buildings: Concrete, Foams, Fibers and Waterproofing. For the case of waterproofing, there are acrylic waterproofing products, for which the norm establishes as maximum value of thermal conductivity 0.06W / m K or less to be able to grant the use of the FIDE seal.
For the above, acrylic waterproofing that has values of thermal conductivity > 0.06W / m ° K do not comply with the standard and therefore are not worthy of the mentioned seal.
Given this regulation, it is known that in the market there are some waterproofing products that are mistakenly assigned the quality of being thermally insulating waterproofing, since they do not comply with the standard, and therefore use misleading advertising. : Derived from the scenario described above and with the aim of, on the one hand, solving the problem of tire recycling, and on the other hand offering an acrylic waterproofing with thermal insulation properties that meets the established standards, was that the waterproofing composition was developed water-based acrylic with low thermal conductivity that uses recycled materials in its formulation. ' OBJECTIVES OF THE INVENTION The main purpose of the present invention is to make available a water-based acrylic waterproofing composition with low thermal conductivity that can be categorized as waterproofing and thermal insulation and used in its application. formulation of recycling materials in its formulation.
Another objective of the invention is to make available said water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials, which also allows to eliminate other loads that do not lower the insulation properties, as opposed to improving or maintaining them.
Another object of the invention is to make available said water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials, which also comprises excellent; Tension strength properties without affecting elongation.
Another object of the invention is to make available said water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials, which also allows the formulation with different colors without the rim particles coming to significantly affect the color of the waterproofing.
I Another object of the invention is to make available said water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials, which also avoids the generation of grooves or cracks through which water is filtered.
Another object of the invention is to make available said water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials, be it easy to apply without the need for specialized labor and, under conditions of high temperatures and low relative humidity, not reduce its elongation does not affect its physical-chemical properties. I Another objective of the invention is to make available said water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials, which also does not require an additional reinforcing fabric to provide good performance and efficiency.
Another objective of the invention is to make available said water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials, which can also be used in any type of climate, since it is resistant to extreme temperatures without losing its properties.
Another object of the invention is to make available said water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials, which also does not require any additional product to achieve an excellent waterproofing of various substrates.
Another objective of the invention is to make available said water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials, which can also be used as a waterproofing in ceilings and / or walls.
And all those qualities and objectives that will become apparent when making a general and detailed description of the present invention supported by the illustrated modalities.
DESCRIPTION OF THE INVENTION Generally, the water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials, in accordance with the present invention consists of an acrylic resin or acrylic modified with glass, ceramic or polymeric microspheres, and / or mixtures of this; also comprising rubber particles of ground tire, fillers, additives and water; optionally it may comprise fibers, a water hardness controller, a flame retardant and pigments.
I In its preferred embodiment said resin preferably consists of butyl acrylate, comprising from 20 to 60% total solids.
In its preferred embodiment, the particle size of the ground rubber tire ranges from 10 mesh to 400 mesh.
In its preferred embodiment, the fillers are selected from: calcium carbonate in an average particle size of 10 microns combined with an average particle size of 1 miera, magnesium carbonate, talcs, wollastonite, mica, feldelpaste, natural silica or artificial, barite (barium carbonate) and / or mixtures thereof, with an equal or varied granulometry of each of the charges; which favor the accommodation (packaging) of the coating film.
In its preferred embodiment the additives consist of: dispersants selected from acrylates or, sodium, potassium or ammonium polyacrylates, and / or mixtures thereof; humectants selected from nonionic and ionic surfactants; defoamers selected from silica or mineral oils and / or mixtures thereof; bactericides selected from; formaldehyde or other organic bactericides; antifreezes such as glycols (ethylene glycol, diethylene glycol and propylene glycol and / or mixtures thereof); coalescents consisting of any non-volatile organic solution such as gas naphtha, mineral spirit or pentanediol; thickeners of the acrylic, cellulose or polyurethane type and a pH regulator selected from ammonium hydroxide, sodium hydroxide, potassium hydroxide, or a synthetic amine.
: The flame retardant is selected from inorganic retardants such as aluminum hydroxide, magnesium hydroxide or organic such as halogenated, phosphorus-based, among others. i The fibers that are incorporated into the composition are selected from: i rigid, flexible or elastic fibers, such as cellulosic fibers, polyester, polyethylene, polypropylene, elastane and / or mixtures thereof, with the same or different size, the same or different length and the same or different diameter. , The water hardness controller is selected from potassium tripolyphosphate, sodium tripolyphosphate, polyphosphate and / or mixtures thereof.
The pigments are selected from white, green, terracotta or other organic or inorganic pigments.
The inorganic pigments are selected from titanium dioxide (white), zinc oxide (white), zinc sulphide (white); iron oxide (red, yellow, black, green, blue), magnesium and cobalt, and / or mixtures thereof. i The organic pigments are selected from light-stable pigments, phosphorescent pigments, fluorescent pigments, phthalocyanines (green or blue), toluidine derivatives or naphthalene derivatives, quinones, carbon black, among others and / or mixtures thereof.
Quantitatively, the water-based acrylic waterproofing composition with low thermal conductivity, which employs recycled materials in its formulation, in accordance with the present invention comprises: composition additionally comprises the following speakers, in the following amounts: The water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials, comprises the following properties (measured at a temperature of 25 ° C): Abbreviations: W = Watts m = meters ° K = temperature degrees Kelvin Kg = KilogramLt = Liter cp = centipoise The thermal conductivity of the waterproofing can have values < 0.24 W / m ° K and preferably has a value of 0.06 W / m ° K.; The water-based acrylic waterproofing composition with low thermal conductivity and content of recycled materials when applied forms a film with high thermal insulation value and comprises an initial film elongation of 30 to 500%.
The following table shows the thermal conductivity of various materials, including the acrylic waterproofing of the present invention, which allows to make a comparison between common waterproofing of the market and the waterproofing of the present invention.
Abbreviations: W = Watts m = meters ° K = temperature degrees Kelvin In another of the embodiments of the invention, the rubber of ground tires, a cryogenic treatment is applied to pass it through a crusher or mill and obtain a smaller particle size that is incorporated with greater ease in the waterproofing.
The waterproofing as described and formulated complies with NOM-018-EN ER-1997, "Thermal Insulators, for Buildings, Characteristics, Limits, and Test Methods" of the National Organization for Standardization and Certification of Construction and Building (ON CCE), and having a thermal conductivity less than or equal to 0.06 Watt / m ° K fulfills the requirements to have the energy saving seal of the Fideicomiso para Saver de Energía Eléctrica (FIDE) and therefore ensures that the product complies with the Rules, Laws, Regulations, manufacturer's instructions, etc. in force related to its installation and application.
The thermal conductivity is! achieved to a greater extent by glass, ceramic or polymeric microspheres, or mixtures thereof.
The rubber particles of the tire milling are not very conductive, it works as an insulator and not as an inert charge; participates in the insulation because its thermal conductivity is from medium to low; the above combined with the microspheres allows to achieve the low value of desired thermal conductivity.
The composition of water-based acrylic waterproofing with low thermal conductivity and content of recycled materials, can be used as waterproofing for roofs of different materials and walls; in walls of industrial warehouses of galvanized sheet; it can be combined with other coatings to improve its refractive characteristics as a final finishing layer.
It can therefore be applied to concrete ceilings, fiber cement ceilings, after treatment of joints; in galvanized sheet and painted sheets used as roofs or walls. In the sheets besides acting as thermal insulation, it acts as acoustic insulation.
The invention has been sufficiently described so that a person with average skill in the art can reproduce and obtain the results that we mentioned in the present invention. However, any person skilled in the art who is competent in the present invention may be able to make modifications not described in the present application, however, if for the application of these modifications in a particular structure or in the process of manufacture of the same, it is required of the matter 'claimed in the following claims, said structures should be understood within the scope of the invention.

Claims (26)

R E I V I N D I C A C I O N S Having sufficiently described the invention, the content of the following claim clauses is claimed as property.
1. - A water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, characterized by comprising an acrylic resin or modified acrylic with glass, ceramic or polymeric microspheres and / or mixtures thereof; rubber particles of ground tires, fillers, additives and water:
2. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in i its formulation, according to claim 1, characterized in that said butyl acrylate: comprises from 20 to 60% of total solids.
3. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 1, characterized in that the rubber particle size of the ground rim goes from 10 mesh to 400 mesh.
4. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 1, characterized in that the fillers are selected from calcium carbonate, magnesium carbonate, talcs, wollastonite, mica. , feldelpasto, natural or artificial silica, barite (barium carbonate) and / or mixtures thereof, with an equal or varied granulometry, which favor the accommodation (packaging) of the coating film.
5. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 1, characterized in that the additives are selected from dispersants, humectants, defoamers, bactericides, antifreeze, coalescers, thickeners, and p (H) regulators or mixtures thereof.
6. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 5, characterized in that said dispersants. they are selected from acrylates or polyacrylates of sodium, potassium or ammonium, and / or mixtures thereof.
7. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 5, characterized in that said humectants are selected from non-ionic and ionic surfactants.
8. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 5, characterized in that said antifoams are selected from silicone or mineral oils and / or mixtures thereof.
9. The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 5, characterized in that said bactericides are selected from formaldehyde or other organic bactericides.
10. The composition of water-based acrylic waterproofing with low thermal conductivity, which uses recycled materials in its formulation, according to claim 5, characterized in that said antifreeze is selected from glycols (ethylene glycol, diethylene glycol and propylene glycol and / or mixtures thereof) ).
11. The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 5, characterized in that said coalescents consist of any non-volatile organic solution, for example naphtha, mineral spirit or pentanediol gas.
12. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 5, characterized in that said thickeners of the acrylic, cellulose or polyurethane type.
13. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 5, characterized in that said pH regulator is selected from ammonium hydroxide, sodium hydroxide, potassium hydroxide , or a synthetic amine.
14. The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claims 1 to 13, characterized in that it also comprises fibers, a water hardness controller, a flame retardant and pigments .
15. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 14, characterized in that the fibers are selected from rigid fibers, flexible fibers or elastic fibers; such as cellulosic fibers, polyester, polyethylene, polypropylene, elastane and / or mixtures thereof; with equal or different size, equal or different length and equal or different diameter.
16. - The composition of water based acrylic waterproofing with low thermal conductivity, which uses materials of. recycled in its formulation, according to claim 14, characterized in that said water hardness controller is selected from potassium tripolyphosphate, sodium tripolyphosphate, polyphosphate and / or mixtures thereof.
17. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to Claim I, characterized in that said flame retardant is selected from inorganic retardants such as aluminum hydroxide, hydroxide magnesium or organic retardants such as halogenated, based on phosphorus, among others.
18. The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 14, characterized in that said pigments are selected from inorganic pigments such as titanium dioxide (white), zinc oxide (white), zinc sulphide (white), iron oxide (red, yellow, black, green, blue), magnesium and cobalt; and organic pigments such as light-stable pigments, phosphorescent pigments, fluorescent pigments, phthalocyanines (green or blue), toluidine derivatives or naphthalene derivatives, quinones, carbon black, among others; and / or mixtures thereof.
19. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claims 1 to 13, characterized in that the composition quantitatively comprises: from 20 to 70% by weight of resin; from 20 to 60% by weight of water, from 2 to 35% by weight of total fillers, from 0 to 1% by weight of dispersants, from 0.05 to 0.80% by weight of humectants, from 0.03 to 0.70% by weight of defoamers , from 0.05 to 0.60% by weight of bactericide, from 0.10 to 2.0% by weight of antifreeze, from 0.10 to 2.0% by weight of coalescents, from 0.10 to 2.0% by weight of thickeners, from 0.10 to 0.8% by weight of regulator of pH, from 0.5 to 12% by weight of glass, ceramic or polymeric microspheres, and from 0.10 to 20% of rubber particles of ground rim.
20. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claim 19, further comprising from 0 to 10% by weight of flame retardant, from 0.05 to 1.0% by weight of fibers, from 0 to 20% by weight of pigments and from 0 to 0.01 to 0.80% by weight of hardness controller of Water.
21. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claims 1 to 20, characterized in that it has a density of 0.4 to 1.40 Kg / l. ;
22. The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claims 1 to 20, characterized in that it has a viscosity of 12000 to 70000 cps.
23. - The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claims 1 to 20, characterized in that it has from 40 to 80% of total solids.
24. The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claims 1 to 20, characterized in that it has a thermal conductivity = 0.24 watt / m ° K and preferably comprises a thermal conductivity < 0.06 watt / m ° K.
25. - The acrylic water-based waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claims 1 to 20, characterized in that it has a pH value of 7 to 11.
26. The water-based acrylic waterproofing composition with low thermal conductivity, which uses recycled materials in its formulation, according to claims 1 to 25, characterized in that applied it generates a film comprising an initial elongation of the film from 30 to 500% . 1 ) R E S U E N The present invention relates to a water-based acrylic waterproofing composition with low thermal conductivity with values of = 0.24 watt / m ° K and preferably with values < 0.06 watt / m ° K and using recycled materials in its formulation, the composition characterized by comprising an acrylic or modified acrylic resin composed of butyl acrylate with 20 to 60% total solids; glass, ceramic or polymeric microspheres and / or mixtures thereof; rubber particles of ground tire of size ranging from 10 mesh to 400 mesh, fillers, additives and water, and optionally comprising fibers, a water hardness controller, a flame retardant and pigments.
MX2011002241A 2011-02-28 2011-02-28 Water-base acrylic waterproofing composition with low thermal conductivity which uses recycled materials in the formulation thereof. MX2011002241A (en)

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MX2011002241A MX2011002241A (en) 2011-02-28 2011-02-28 Water-base acrylic waterproofing composition with low thermal conductivity which uses recycled materials in the formulation thereof.

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MX2011002241A MX2011002241A (en) 2011-02-28 2011-02-28 Water-base acrylic waterproofing composition with low thermal conductivity which uses recycled materials in the formulation thereof.

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9675905B2 (en) 2014-03-28 2017-06-13 Buckman Laboratories International, Inc. Defoamer compositions and methods of using the same
WO2019034930A1 (en) 2017-08-18 2019-02-21 Pagaza Melero Victor High-resistance waterproofing composition and products made using same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9675905B2 (en) 2014-03-28 2017-06-13 Buckman Laboratories International, Inc. Defoamer compositions and methods of using the same
WO2019034930A1 (en) 2017-08-18 2019-02-21 Pagaza Melero Victor High-resistance waterproofing composition and products made using same

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MX2011002241A (en) Water-base acrylic waterproofing composition with low thermal conductivity which uses recycled materials in the formulation thereof.

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