MX2008006775A - Use of di- or oligosaccharide polyester in hair styling products - Google Patents

Abstract

The present invention relates to the use of fully esterified di- or oligosaccharide polyesters in hair styling products selected from hair styling waxes, hair styling creams, hair styling foam wax products and hair styling spray wax products. Preferred saccharide polyesters are octaesters of sucrose and C8 to C30 fatty acids such as behenic acid and fatty acids derived from cottonseed oil.

Description

USE OF DIARY OLIGOSACARIDOS POLYESTERS IN PRODUCTS FOR HAIR STYLIZATION FIELD OF THE INVENTION The present invention relates to the use of fully esterified di- or oligosaccharide polyesters in hair styling products selected from hair styling waxes, hair styling creams, foam wax products for hair styling and wax products with atomization for styling hair.

BACKGROUND OF THE INVENTION The products for styling hair are intended to help create stylized individuals and to keep them temporarily that way for a period. Wax products for styling hair and cream products for styling hair play an important role among styling products. They find practical application particularly to give the short or moderately long hair a stylized fashion and impart firmness, texture and shine, as well as to stabilize, condition and fix the styling. They give form and shine to the stylized, and often give it a wet appearance. The application of hair styling products containing wax is usually based on the following principles. The solid products are extracted with the fingers of suitable containers.

Wax products with spray or foam are atomized in the hand. The creamy products can be removed by squeezing a tube and placing them in the hand. The product is distributed over the surface of the hand and the waxy ingredients melt or, at least, are considerably softened by the heat of the hand in combination with the friction energy of the rub. It is possible to work the wax in the hair just because it softens or melts because, otherwise, it would be very hard. The wax is worked on the hair in a softened or approximately liquid state. Then it cools and reaches its original solid or semi-solid consistency again. It hardens, and the stylized achieved has stability and firmness and, frequently, has a wet appearance. Not all waxy materials are equally suitable for use in wax products for styling hair given the multiple requirements. The product should have a homogeneous consistency and should not crumble during application. The wax should not be so hard as not to allow it to be distributed in the hand and hair or so soft that it does not allow sufficient firmness and texture. It should give shine to hair, but without forming particles or leave white residue that are visible in the hair. Carnauba wax is one of the most appropriate waxes. It is hard enough to provide good firmness and texture, but can soften to distribute properly, especially when combined with softer oils or waxes. A disadvantage of carnauba wax is its unpleasant yellowish color. Waxes of a whiter color, for example, hydrocarbon waxes, are known, but usually these waxes do not have all the performance benefits of carnauba wax. It is a real challenge to formulate a wax product for styling hair with an improved whiteness or color gloss, which has at least the same or even greater performance benefits as wax products with carnauba wax, especially considering the homogeneity of the product, its distribution capacity in the hand and in the hair, the texture, the firmness and the good shine of the hair, or the wet appearance. It is an object of the present invention to provide hair wax products that improve the firmness, texture and gloss of the styling. Improving hair texture means imparting desirable surface characteristics to hair or hairstyle. At the same time, the mass of the product should have a pleasant and white appearance, and be easy and satisfactory to process and work on the scalp and hair, without disintegrating or forming visible residues, with an acceptable load and not too high. product in the hair, which leaves a feeling of greater softness of the product itself and the hair after its application.

BRIEF DESCRIPTION OF THE INVENTION It has been found that wax products for high performance hair styling can be formulated using fully esterified di- or oligosaccharide polyesters. The present invention is directed to the use of at least one polyester of di-or oligosaccharides fully esterified in styling products selected from hair styling waxes, hair styling creams, foam wax products for hair styling Stylized hair and wax products with spray for styling hair. The present invention is further directed to methods of treatment for the hair using the hair styling products according to the invention. These and other attributes, aspects and advantages of the present invention will be apparent to those with industry experience in reading the present disclosure.

DETAILED DESCRIPTION OF THE INVENTION All percentages, parts and proportions are based on the total weight of the compositions of the present invention, unless indicated otherwise. In the case of aerosol products, the ingredient amounts of the base composition are based on the total weight of the base composition without propellant, unless otherwise indicated. The amount of propellant is based on the total weight of the composition, including the base composition and the propellant. All these weights as far as the listed ingredients are concerned, are based on the active level and, therefore, do not include the solvents or by-products that may be included in the materials available in the market, unless otherwise indicated. As used herein, all molecular weights are weighted average molecular weights expressed in grams / moles, unless otherwise indicated. In this document, "comprising" means that other steps and other ingredients may be added that do not affect the final result. This term includes expressions "consists of" and "consists essentially of". The compositions and methods of the present invention may comprise, consist and consist essentially of the basic elements and limitations of the invention described herein, as well as any other optional ingredient, component, step or limitation described herein. As used herein, the term "hydrophobic" means substances that are practically insoluble in water (eg, less than 1% by weight at 25 ° C), but are soluble in oil phase; This solubility in the oil phase is greater than that in the aqueous phase. As used herein, the term "room temperature" means 25 ° C. As used herein, the terms "wax" or "wax-like" correspond to the definition of "wax" in the "Encyclopedia for Industrial Chemistry" of Ullmanns, 4a. edition, volume 24, page 3. According to this definition, wax substances are plastic at 20 ° C, solid to brittle, crystalline to coarse to fine, transparent to opaque, but not vitreous, and melted above 40 ° C without decomposing. They have a comparatively low viscosity above their melting temperature, have a consistency and a solubility that depend comparatively on temperature and can be polished with a gentle pressure. All cited references are incorporated in their entirety as reference in the present invention. The mention of any reference is not an admission with respect to any determination as to its availability as a prior art for the claimed invention.

Di-oliqosaccharide polyesters The di- or oligosaccharide polyesters can be liquid / oily or preferably solid / waxy at room temperature. The amounts of di- or oligosaccharide polyesters used in styling compositions may vary, for example, from 0.01 to 60% by weight, or preferably from 0.1 to 30% by weight, or from 0.5 to 20% by weight, or 1 to 15% by weight, and can be adjusted to the requirements of the specific product type. The di- and oligosaccharides suitable for use herein include, for example, maltose, kojibiosa, nigerose, cellobiose, lactose, melibiose, gentiobiose, turanosa, rutinose, trehalose, sucrose and raffinose. The preferred saccharides are the di- and trisaccharides; disaccharides are most preferred, especially sucrose. The saccharide esters can be esters of the respective saccharide with a single type of acid or they can be esters mixed with different acids. Esters with fatty acids are preferred, especially with C8 to C30 fatty acids, more preferred with C10 to C26 or C12 to C22 fatty acids, or with mixtures of these acids. Non-limiting examples of fatty acids are capric, capric, lauric, palmitic, margaric, stearic, arachic, behenic, isomiristic, myristic, caprylic, linolic, linoleic, oleic and triacontanoic acids. Also preferred are fatty acid mixtures derived from vegetable oils, such as cottonseed oil or soybean oil. Cottonseed oil, for example, is a mixture of triglycerides, predominantly linolic acid (approximately 45-58%), palmitic acid (21-27%), oleic acid (14-21%) and stearic acid (2-3%) from which the fatty acid mixture can be obtained cotton) by hydrolysis. The fully esterified saccharide esters can be used in combination with saccharides that are not fully esterified. For example, a disaccharide octaester can be used together with the respective hepta or hexa esters etc. The preferred saccharides are the disaccharides. The preferred disaccharide is sucrose. In general, commercial products are a mixture. The amount of octaester is preferably at least 70% by weight, for example, from 70 to 80% of all disaccharide esters. The amount of hepta ester can be, for example, from 20 to 30%, and the amount of hexa and penta lower esters and esters, preferably each of them, of less than 1%. The sum of octa and hepta esters is preferably at least 95% of all esters, and the sum of octa, hepta and hexa esters is preferably at least 97% of all esters. Preferred are sucrose polyesters of behenic acid or cottonseed acids or soyate acids with the designations INCI polybabenate of sucrose, polyester of fatty acid of cotton seed of sucrose and polyisoyate of sucrose, respectively. These substances are available under the trademarks behenate SEFA, SEFA cotton fatty acid ester and SEFA soyato from Procter & Gamble Chemicals. The most preferred is sucrose polybehenate.

Oils The preferred compositions further contain at least one hydrophobic oil which is liquid at room temperature and different from the oil saccharide polyesters. As used herein, the term "liquid at room temperature" means substances that have a melting temperature below 25 ° C and a boiling point above 25 ° C. Low volatility oils with a boiling point of, for example, at least 200 ° C or at least 250 or 300 ° C are most preferred. The preferred amount of oil is at least 3% by weight, more preferred, 5 to 60% or 10 to 50% by weight and comprises hydrophobic oil which is liquid at 25 ° C and, optionally, lipophilic dissolved materials. The hydrophobic oils and lipophilic materials of the oil phase can, for example, be selected from vegetable oils, animal oils, mineral oils, silicone oils, hydrocarbon oils, hydrogenated polyolefins, fatty alcohols with at least 8 carbon atoms, including branched alcohols, such as Guerbet alcohols, fatty acid oils and polyols (especially triglycerides), fatty acid oils and monohydric alcohols of C1 to C30 (C3 to C22 alcohols are preferred), and mixtures of such hydrophobic oils. The non-limiting hydrophobic oils are, for example, cyclic paraffins, paraffin oils, isoparaffin oils, polydecene, mineral oil, isohexadecane, dodecane, isoeicosane, liquid polydimethylsiloxane, cyclotetrasiloxane, cyclopentasiloxane, phenyltrimethicone, isocetyl palmitate, isopropyl myristate, palmitate. of isopropyl, isopropyl stearate, iso octyl stearate, octyl cocoate, octyl palmitate, octyl dodecyl myristate, caprylic / capric triglyceride, butyloctanol, hexyloctanol, butylcarbonate, hexyldecanol, octyldodecanol, hexyldecanol, stearyl heptanoate, isohexyl decanoate, octanoate of isodecyl, dibutyl adipate, dicaprylyl ether, C12-15 alkylbenzoate, hydrogenated polyisobutene, squalane, squalene, native oils, such as jojoba oil, olive oil, sunflower oil, soybean oil, peanut oil, seed oil rapeseed oil, sweet almond oil, palm oil, coconut oil, castor oil, oil hydrogenated castor tea, wheat germ oil, grape seed oil, safflower oil, evening primrose oil, macadamia nut oil, corn oil, avocado oil, lanolin oil and similar oils. Especially preferred oil compounds are hydrocarbon oils, such as mineral oil (eg, paraffinum liquidum or viscous paraffin) and branched alkyl alcohols of C8 to C30. The silicone oils include polydimethylsiloxanes, phenylated silicones, polyphenylmethylsiloxanes, phenyltrimethicones, poly alkyl siloxanes and C 1 to C 20 alkylmethylsiloxanes.

Waxes The hair styling product according to the invention comprises a composition which may also contain waxes or wax-like substances other than the aforementioned wax saccharide polyesters. The amount of additional waxes is preferably 1 to 60% by weight or 5 to 50% by weight. These waxes include waxes of animal, vegetable, mineral and synthetic origin, solid paraffins, petrolatum (Vaseline®), ozokerite, ceresin, mountain wax, Fischer-Topsch waxes, polyolefin waxes, such as polybutene, beeswax, wool wax and its derivatives, such as wool wax alcohols, candelilla wax, carnauba wax, Japanese wax, hardened fats, fatty acid esters and fatty acid glycerides with a solidification point above 40 ° C, polyethylene waxes and silicone waxes. Waxes or wax-like substances have a solidification point above 40 ° C, preferably above 55 ° C. The penetration value of the needle (0.1 mm, 100 g, 5 s, 25 ° C, in accordance with DIN 51 579) is preferably in a range from 2 to 70, especially from 3 to 40. In the composition of preferably at least one wax having a needle penetration point that is less than 40, especially, preferably less than 20, is present preferably. Ceresin wax with a lower needle penetration point is especially preferred. of 20 or the beeswax or mixtures of these.

Emulsifiers Preferred embodiments of the invention further include at least one emulsifier in order to improve the washability of the hair composition and to further improve the performance benefits. The emulsifiers are preferably in an amount of 0.5 to 20% by weight, especially preferably 3 to 15% by weight. Preferred emulsifiers are selected from the group of nonionic and anionic surfactants. In a particularly preferred embodiment, the emulsifiers have a consistency similar to wax and a liquefaction point above 25 ° C. Nonionic emulsifiers are, for example, alkoxylated fatty alcohols, such as C8 to C30 alcohols or preferably C8 to C22 alcohols, alkoxylated fatty acids or alkoxylated fatty acid glycerides, such as C12 to C22 fatty acids, alkoxylated alkylphenols (p. eg, alkyl groups with 8 to 15 carbon atoms); the usual degrees of ethoxylation are from 2 to 100 or from 4 to 30, and the usual degrees of propoxylation are from 1 to 5; mono or diester of C8 to C30 fatty acid of glycerol, preferably C12 to C22, ethoxylated with 1 to 30 moles of ethylene oxide; castor oil or hydrogenated castor oil ethoxylated with 5 to 60 moles of ethylene oxide; sucrose mono or diester of fatty acid, especially sucrose ester with one or two fatty acids of C8 to C30 or of C12 to C22, INCI designation: sucrose cocoate, sucrose dilaurate, sucrose distearate, sucrose laurate, myristate sucrose, sucrose oleate, sucrose palmitate, sucrose ricinoleate, sucrose stearate; ethoxylated sorbitan ester, such as sorbitan ester with one, two or three C8 to C22 fatty acids and an ethoxylation degree of 4 to 20; polyglyceryl fatty acid ester, especially one, two or more C8 to C22 fatty acids with polyglycerol, preferably 2 to 20 glycerol units; - alkyl glucoside, alkyl oligoglucoside or alkyl polyglucoside with C8 to C22 alkyl groups, for example, decyl glucoside or lauryl glucoside. Anionic surfactants are, for example, alkyl carboxylic acids, alkyl ether sulphates, alkyl sulfates, sulfosuccinates, fatty acid isethionates, phosphoric acid alkyl esters, ethoxylated phosphoric acid alkyl esters, such as mono-, di- or triesters of phosphoric acid with alcohols. C8 to C22 fatty acids ethoxylated with 2 a moles of ethylene oxide, amino acids with acyl; these acyl groups preferably have from 8 to 30 carbon atoms. Preferred emulsifiers are the triesters of phosphoric acid with ethoxylated fatty alcohols, such as, for example, the phosphoric acid triester with cetyl and stearyl alcohol ethoxylated with 4 moles of ethylene oxide (INCI: triceteareth-4 phosphate).

Solid Wax Products for Hair Styling In one embodiment of the invention, di- or oligosaccharide polyesters are used in solid wax products for styling hair. These hair wax products according to the invention for the treatment or preparation of human hair styling usually comprise a composition with a solid and wax-like consistency, comprising at least one wax or a similar substance to the wax. The compositions of the solid wax products for the hair according to the invention have a needle penetration value (measuring unit 0.1 mm, test weight 100 g, test duration 5 s, test temperature 25 ° C. , in accordance with DIN 51 579) preferably greater than or equal to 10 or 20, and preferably not greater than 70. The wax or wax-like substance may be the di- or oligosaccharide polyester itself. In case the saccharide ester is liquid or oily, it is combined with at least one of the aforementioned non-saccharide ester waxes, for example, paraffin waxes, beeswax and the like. The total amount of waxes and wax-like substances in solid wax products for styling is preferably 5 to 60% by weight or 10 or 20 to 50% by weight. The solid wax compositions for hair styling may further contain the liquid hydrophobic oils of the types and in the aforementioned amounts.

Soft creams or waxes for styling hair In another embodiment of the invention, di- or oligosaccharide polyesters are used in creamy, soft or semi-solid products for hair styling. These hair wax products according to the invention for the treatment or preparation of the styling of human hair usually comprise a composition with a creamy or semi-solid consistency, comprising at least one oily substance. The cream products are, in general, emulsions of at least one hydrophobic oil and water, in the presence of at least one emulsifier of the types and in the amounts mentioned above. The amount of water is preferably 10 to 70%, or 20 to 60%, or 30 to 50% by weight. The oily substance can be the di- or oligosaccharide polyester itself. In case the di- or oligosaccharide ester is liquid or oily, it is combined with at least one of the aforementioned non-saccharide hydrophobic ester oils, for example, hydrocarbon oils, such as paraffin oil or isoparaffin oil or silicon oil and the like. The total amount of oils in the cream or semi-solid products for styling is preferably 5 to 60%, or 10 to 55%, or 15 to 50% by weight. The compositions of the creamy, soft or semi-solid products for styling the hair may also contain wax compounds of the types and in the amounts mentioned above.

Wax products with spray and foam wax products Other embodiments of the invention are wax products with an atomizer for styling hair and foam wax products for styling hair. These products comprise a spray device or a device for foam and a composition comprising at least one of the polyesters of fully esterified di- or oligosaccharides described above. Spray or foam products can be aerosol products containing propellants or non-aerosol products, without propellants. The compositions may be atomized or foamed and are preferably liquid at room temperature. The composition preferably comprises at least one wax or a substance similar to wax. The wax or wax-like substance can be the di- or oligosaccharide polyester itself. In case the saccharide ester is liquid or oily, preferably it is combined with at least one of the aforementioned non-saccharide ester waxes, for example, paraffin waxes, beeswax and the like. The total amount of waxes and wax-like substances in wax products with spray or wax in foam is preferably 5 to 60% by weight or 10 or 15 to 50% by weight. The compositions of the wax products with atomizer or wax in foam can also contain liquid hydrophobic oils of the types and in the amounts mentioned above. The compositions may contain hydrophobic substances that are easily volatilized and are liquid at room temperature and have a boiling point in the range of 30 to 100 ° C, preferably 35 to 70 ° C. Liquid hydrocarbons, cyclic or linear liquid silicones (dimethylpolysiloxanes), or mixtures of the foregoing materials are suitable. Linear or branched alkanes with 5 to 7 carbon atoms are especially suitable hydrocarbons. Pentane is particularly preferred. Hexamethyldisiloxane is especially preferred as liquid silicone which volatilizes easily. Non-aerosol non-aerosol spray or wax wax products comprise a container with a mechanical pumping device and a spray head or foam head. The non-aerosol spray can according to the invention can be made with any suitable material known for spray or non-aerosol spray products, insofar as the material is sufficiently resistant to pressure against slight increases in pressure if hydrophobic substances are used that are easily volatilized, and provide a sufficient barrier for the diffusion of the ingredients of the composition contained in the package. Metals, such as aluminum or tinplate, or plastic are suitable materials. Transparent or at least translucent materials are preferred in such a way that the consistency of the product or the amount of the product remaining in the package are visible from outside of the container. The product package is preferably made of glass or polyethylene terephthalate (PET). The pumps, spray heads and foam heads commercially available for the wax product container with spray-free atomizer or foam wax according to the invention can be used. If a volatile hydrocarbon, such as pentane, is present in the composition contained in the package, an atomization pump which is made of a material resistant to swelling in the presence of pentane is preferred. This class of material is, for example, polyoxymethylene (POM). A suitable atomization pump according to the invention is, for example, the Seaquist-Perfect PZ1 / 100 HVT fine atomization pump. The atomization pumps may have an aeration opening, but it is not necessarily required if a volatile hydrocarbon is present in the composition. The wax product with spray or foam wax according to the invention can also be an aerosol product. Waxes that have especially large surface areas (wax snow) can be made by the use of gaseous substances (propellant gases, such as propane, butane and the like). This wax snow is easily processed and gently worked into the hair. Wax products with aerosol foam or spray wax comprise a pressure resistant package with an atomization cap or a lid for foam and a composition that can be atomized or foamed according to the invention, comprising at least a propellant contained in the pressure resistant container. The amount of propellant is preferably 5 to 60% or 10 to 50% or 20 to 40% by weight, based on the total composition. The wax material of the composition is preferably dissolved or suspended in a hydrophobic liquefied propellant gas. The waxes used in hair wax products are soluble or at least can be suspended in organic solvents. These solvents include alkanes that volatilize easily, such as pentane and its isomers, which are liquids at normal pressures and at room temperature, liquefiable propellant gases that are used in aerosol products, such as propane, butane and its isomers. If a hair wax composition is dissolved or suspended together with one of these propellant gases and introduced into an aerosol container, it can be atomized as a fine atomization or as a foam atomization, such as wax snow. Dense wax snow (frozen wax) occurs when a foam head is used instead of a spray head. The dense wax snow is produced by the loss of heat due to the evaporation of the propellant gas. The foam-like or similar to flake-like consistency with a larger wax surface area allows very easy distribution in the hands and hair. Preferred propellants are liquefied propellant gases which are gaseous at room temperature under normal pressure conditions and have the ability to liquefy under pressure at room temperature. Suitable propellant gases include propane, n-butane, isobutane and fluorinated hydrocarbons, such as 1,1-difluoroethanes or 1, 1, 1, 2-tetrafluoroethane or dimethylether. These propellant gases can be used alone or in a mixture, for example, a mixture of propane or butane and dimethylether. A mixture of propane and butane is especially preferred. A volatilized hydrophobic substance may also be included in addition to the propellant gas. This includes a material that is liquid at room temperature and that has a boiling point of 30 to 100 ° C, preferably 35 to 70 ° C. Liquid hydrocarbons, cyclic or linear liquid silicones (dimethylpolysiloxanes), or mixtures of the foregoing materials, are especially suitable as volatile hydrophobic substances. Suitable hydrocarbons include linear or branched alkanes with 5 to 7 carbon atoms, especially pentane. For example, hexamethyldisiloxane is especially suitable as a liquid silicone that volatilizes easily. The pressure-resistant aerosol container for the wax product with aerosol spray according to the invention can be made with known materials for aerosol products. Suitable materials include metals, such as aluminum or tinplate. Commercially available spray heads and spray heads may be employed for the aerosol containers of the wax product with aerosol spray or wax in aerosol foam according to the invention. In accordance with one embodiment of the invention, hair styling products are colored products that contain at least one colorant or color additive. The preferred product colorants are the oil-soluble organic dyes. However, insoluble pigments, or water-soluble or alcohol-soluble dyes can also be used. The colored hair wax products preferably contain essentially nothing or only a minor amount (such as, for example, less than about 5%, preferably less than about 1% by weight) of non-white waxes, such as carnauba wax, which is colored in itself. The amount of colorants may vary, for example, from 0.0001 to 5% by weight. Colorants and color additives can be selected from, for example, those listed in the "International Cosmetic Ingredient Dictionary and Handbook "(Dictionary and International Handbook of Cosmetic Ingredients), 10th edition, 2004, volume 3, section 3 in the function of" dyes. "Optional ingredients The composition according to the invention may also contain cosmetic additives commonly used in hair treatment compositions in addition to the aforementioned ingredients, for example, solvents, such as water or univalent or multivalent alcohols of C1 to C5, especially ethanol, propanol, glycerol or glycols, in an amount up to, for example, % by weight, preferably from 0.1 to 8% by weight, in cream emulsions, the amount of water can be higher (see above), fragrances and essential oils in an amount of up to 2% by weight, preferably from 0.01 to 1. % by weight, preservatives, such as, for example, parabens, phenoxetol, iodopropynyl carbamate, parahydroxybenzoic acid ester, benzoic acid, acid or salicylic, sorbic acid, mandelic acid, polyhexamethylene biguanidine hydrochloride or isothiazoline based on compounds in an amount of, for example, 2% by weight, preferably 0.01 to 1% by weight; hair care substances, such as, for example, betaine, panthenol, plant extracts, plant extracts, protein hydrolysates and silk hydrolysates, lanolin derivatives, in an amount of, for example, 0.01 to 5%, preferably from 0.1 to 4% by weight, pearlescent pigments or pigments in an amount of, for example, 0.01 to 25% by weight, preferably 1 to 20% by weight, for example, such as those based on dioxide titanium / mica; film-forming polymers, such as copolymers of polyvinylpyrrolidone or vinylpyrrolidone / vinyl acetate in an amount of up to 5% by weight, preferably from 0.1 to 4% by weight; physiologically compatible silicone derivatives, such as volatile and non-volatile silicone oils or high molecular weight siloxane polymers in an amount of 0.05 to 20% by weight; light protection agents, antioxidants, radical capture agents, anti-dandruff agents; vitamins; substances that impart shine and substances that improve the combing ability in an amount of 0.01 to 2% by weight; Production Method The compositions of the present invention can be made according to a formulation and conventional mixing techniques. The cream products in the form of emulsions can be made by emulsifying the aqueous phase and oil phase, preferably at high temperatures of, for example, 80 to 100 ° C. Volatile ingredients, such as fragrances, are preferably added at lower temperatures, for example, from 50 to 70 ° C. The emulsified composition is introduced into the final package when it is still in the fluid state at temperatures above room temperature, for example, from 50 to 70 ° C. The compositions become non-fluid after being cooled to room temperature. The final package is preferably a transparent or translucent container. The solid or creamy product of hair wax according to the invention can be made by melting together wax-like ingredients and mixing them with the other ingredients, except the volatile ingredients. Subsequently, the mixture is cooled. Volatile compounds are added and mixed shortly before the mixture solidifies. The still fluid mass is introduced into the desired container (a cup or other container) before solidification. The wax product with spray or foam wax according to the invention can be made by melting the waxy ingredients and mixing or dissolving them with the other ingredients and liquid substances, without the propellant. Subsequently, the mixture is cooled to room temperature. This liquid solution or suspension is introduced into the container with atomizer. In the case of a non-aerosol product, a mechanically operated pump device is provided. In the case of an aerosol product, propellant gas is supplied to the container. The container is then supplied with a spray head to produce an atomized wax or foam head to produce a wax foam.

Method of use One embodiment of the invention consists of a treatment method for the hair; this method comprises the steps of: a) providing a product for hair styling selected from hair styling waxes, hair styling creams, foam wax products for hair styling and wax products with spray for the styling of the hair, as described in detail above; these products comprise a composition containing at least one of the aforementioned fully esterified di- or oligosaccharide polyesters; b) applying the composition to hair, preferably to dry hair; and c) arranging or arranging the hair according to a styling without rinsing it later. This method generally involves applying an effective amount of product to dry, slightly damp or wet hair before arranging the hair according to a desired style. The composition is then dried or allowed to dry. By "effective amount" is meant an amount sufficient to provide the desired benefits of hair texture, hair shine and style considering the length and texture of the hair. In general, from about 0.5 g to about 50 g of product will be applied to the hair, depending on the product formulation, the length of the hair and the type of styling in particular. A specific embodiment of the invention for the application of raising the hair root is a treatment method for the hair, this method comprises the steps of: a) providing a hair styling product selected from foam wax products for the hair stylized hair and wax products with spray for styling hair, as described in detail above; these products comprise a composition containing at least one of the aforementioned polyesters of fully esterified di- or oligosaccharides in combination with a device for foam or an atomization device; b) atomize the composition directly on the hair root in the scalp. Compositions of the type of the illustrative compositions described below will have benefits over conventional wax hair styling products, containing carnauba wax instead of sucrose polyester, in one or more of the whiteness characteristics of the product color. in the case of non-colored products or color gloss in the case of colored products; easy distribution in the hand; ease to work on the hair; hair definition; hair texture; excellent brightness; low relative hair overload; absence of residues or residues barely visible in the hair; reduced disintegration of the mass of the product; good ability to shape the stylized.

EXAMPLES The compositions illustrated in the following examples show specific embodiments of the hair styling compositions of the present invention, but are not intended to limit them. Experienced technicians can carry out other modifications without departing from the spirit or scope of this invention. These exemplified embodiments of the hair styling composition of the present invention provide stylized and glossy benefits with especially low hair loading. The compositions illustrated in the following examples are prepared according to a conventional formulation and mixing methods. All exemplified quantities are listed as percentages by weight and exclude minor materials, such as diluents, preservatives, coloring solutions, imaging ingredients, plant-based substances and so on, unless otherwise indicated. If a trade name is mentioned as an ingredient and the respective product itself is a mixture (eg, a solution, emulsion, dispersion, etc.), then the quantity exemplified refers to this mixture, unless otherwise indicated. Another way.

Example 1 Curling wax Example 2 Solid wax In accordance with the invention, the composition A has been compared with the comparative composition B. Benefits have been proven according to the following criteria: consistency: A is better than B, which disintegrates and is less homogeneous and less smooth distribution on the hands: A is better than B ability to shape the hair: A is better than B hair definition A is better than B hair shine hair A is better than B hair feeling A is better than B, which is more sticky and less smooth visual appearance in the bottle A: white; B yellowish / coffee Example 3 Aerosol wax The ingredients of the composition are introduced into an aerosol can. The base composition is charged with propane / butane (0.3 MPa (2.7 bar)) in a weight ratio of 30% propellant to 70% base composition. The can is provided with a spray cap or a commercial foam cap.

Example 4 Wax cream Example 5 Soft wax Example 6 Curling wax Example 7 Solid wax EXAMPLE 8 Aerosol Wax The ingredients of the composition are introduced into an aerosol can. The base composition is charged with propane / butane (0.3 MPa (2.7 bar)) in a weight ratio of 30% propellant to 70% base composition. The can is provided with a spray cap or a commercial foam cap.

Example 9 Wax cream Example 10 Soft wax The dimensions and values set forth herein are not to be construed as strictly limited to the exact numerical values mentioned. Instead, unless otherwise specified, each of these dimensions will mean both the aforementioned value and a functionally equivalent range that encompasses that value. For example, a dimension expressed as "40 mm" will be understood as "approximately 40 mm".

Claims (10)

1. The use of at least one polyester of di-or oligosaccharides fully esterified in hair styling products selected from waxes for hair styling, hair styling creams, wax products for styling hair, wax products in foam for the styling of the hair and wax products with atomization for styling the hair.

2. The use according to claim 1, further characterized in that the di- or oligosaccharide is selected from maltose, kojibiosa, nigerosa, cellobiose, lactose, melibiose, gentiobiose, turanosa, rutinose, trehalose, sucrose and raffinose.

3. The use according to claim 2, further characterized in that the disaccharide polyester is sucrose octaester.

4. The use according to any of the preceding claims, further characterized in that the di- or oligosaccharide polyester is the ester of a di- or oligosaccharide of one or more fatty acids of C8 to C30.

5. The use according to claim 4, further characterized in that fatty acids are selected from capric, capric, lauric, palmitic, margaric, stearic, arachic, behenic, isomiristic, myristic, caprylic, linolic, linoleic, oleic and triacontanoic acids .

6. The use according to claim 4, further characterized in that fatty acids are selected from behenic acid and fatty acids derived from cottonseed oil. The use according to any of the preceding claims, further characterized in that the product for hair styling comprises a composition containing from 5 to 60% by weight of at least one non-volatile, liquid and hydrophobic oil having a melting temperature below 25 ° C. The use according to claim 7, further characterized in that the hydrophobic oil is selected from vegetable oils, animal oils, mineral oils, silicone oils, hydrocarbon oils, hydrogenated polyolefins, fatty alcohols, branched alcohols with at least 8 carbon atoms, oils of fatty acids and polyols, oils of fatty acids and monohydric alcohols of C1 to C30, or mixtures of these. 9. The use according to any of the preceding claims, further characterized in that the hair styling product comprises a composition containing 0.5 to 20% by weight of an emulsifier. The use according to claim 9, further characterized in that the emulsifier is selected from the group consisting of alkoxylated fatty alcohols, alkoxylated fatty acids, alkoxylated fatty acid glycerides, alkoxylated alkylphenols, C8 to C30 fatty acid mono- or di-ester of glycerol ethoxylated, ethoxylated castor oil or ethoxylated hydrogenated castor oil, sucrose mono or diester of fatty acid, ethoxylated sorbitan esters, alkyl ethers of ethoxylated phosphoric acid or mixtures thereof. The use according to any of the preceding claims, further characterized in that the hair styling product comprises a composition similar to wax with a needle penetration value of no greater than 70 to 25 ° C. 12. The use according to any of the preceding claims, further characterized in that the hair styling product is a wax product for hair styling comprising a composition similar to wax, and because the composition similar to wax it comprises from 5 to 60% by weight of at least one wax or a substance similar to wax. The use according to claim 12, further characterized in that the wax-like composition comprises from 10 to 50% by weight of at least one wax or a substance similar to wax and has a needle penetration value of 10 to 70 at 25 ° C. 14. The use according to any of claims 1 to 10, further characterized in that the hair styling product is a hair styling cream in the form of a creamy or pasty emulsion comprising water, at least one emulsifier and at least one of said di-u polyesters. fully esterified oligosaccharides. 15. The use according to any of claims 1 to 10, further characterized in that the product for hair styling is a wax product with spray or a foam wax product comprising a spray device or a device for foam and a composition comprising at least one of said polyesters of fully esterified di- or oligosaccharides. 16. The use according to claim 15, further characterized in that the hair styling product comprises a mechanical pumping device with an atomizing cap or a foam cap. 1

7. The use according to claim 16, further characterized in that the composition comprises from 5 to 60% by weight of at least one wax or a substance similar to wax. 1

8. The use according to claim 15, further characterized in that the product comprises a pressure resistant package with an atomization cap or a cap for foam and a composition contained in the pressure resistant package, the composition comprises 5 at 60% by weight of at least one wax or a substance similar to wax and at least one propellant. The use according to claim 18, further characterized in that the composition is liquid at room temperature and comprises from 10 to 50% by weight of at least one wax or a substance similar to wax, and from 5 to 60% by weight of at least one hydrophobic liquefied propellant selected from the group comprising propane, n-butane, isobutane and fluorinated hydrocarbons. 20. The use according to any of the preceding claims, further characterized in that the fully esterified di- or oligosaccharide polyester is employed in an amount of 0.01 to 60% by weight of the total composition. 21. A treatment method for hair; characterized in the method because it comprises the steps of: a) providing a product for hair styling as defined in any of the preceding use claims; b) apply the composition contained in the product for styling the hair to the hair; and c) arranging or arranging the hair according to a styling without rinsing it later. 22. A treatment method for hair; the method comprises the steps of: a) providing a hair styling product selected from foam wax products for hair styling and hair wax products for styling hair, as defined in any of the preceding claims; these products comprise a composition containing at least one of the aforementioned fully esterified di- or oligosaccharide polyesters in combination with a foaming device or an atomization device; b) atomize the composition directly on the hair root in the scalp.