MX172236B - DEMETALIZATION CATALYST AND PROCESS FOR OIL LOADS CONTAINING METALS - Google Patents

DEMETALIZATION CATALYST AND PROCESS FOR OIL LOADS CONTAINING METALS

Info

Publication number
MX172236B
MX172236B MX202341A MX20234184A MX172236B MX 172236 B MX172236 B MX 172236B MX 202341 A MX202341 A MX 202341A MX 20234184 A MX20234184 A MX 20234184A MX 172236 B MX172236 B MX 172236B
Authority
MX
Mexico
Prior art keywords
catalyst
particles
containing metals
demetallizing
metal
Prior art date
Application number
MX202341A
Other languages
Spanish (es)
Inventor
Virginia A Malik
Allen S U Li
Richard M Eccles
Michael C Chervenak
Original Assignee
Hri Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hri Inc filed Critical Hri Inc
Publication of MX172236B publication Critical patent/MX172236B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
    • C10G45/20—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles according to the "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/24—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles
    • C10G47/30—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a un material catalizador de desmetalización, útil para la desmetalización de cargas de petróleo que contienen metales, dicho catalizador comprendiendo substancialmente partículas de óxido de aluminio promovidas con óxidos de metales, seleccionados del grupo que consta de: cromo, hierro, molibdeno, titanio y tungsteno, el catalizador teniendo un contenido total de metales de 0.5 a 10 por ciento en peso y un volumen total de poros de 0.350 a 0.500 cc/g, aproximadamente, las partículas de catalizador dentro del porcentaje de 3 a 97 de todas las partículas teniendo una relación de diámetro equivalente de las partículas mayores a las menores que no excede de 2,0, aproximadamente.The present invention relates to a demetallizing catalyst material useful for demetallizing metal-containing petroleum fillers, said catalyst substantially comprising metal oxide promoted aluminum oxide particles selected from the group consisting of: chromium, iron, molybdenum, titanium and tungsten, the catalyst having a total metal content of 0.5 to 10 weight percent and a total pore volume of about 0.350 to 0.500 cc / g, the catalyst particles within the percentage of 3 to 97 of all particles having an equivalent diameter ratio of the largest to the smallest particles not exceeding approximately 2.0.

MX202341A 1983-08-10 1984-08-10 DEMETALIZATION CATALYST AND PROCESS FOR OIL LOADS CONTAINING METALS MX172236B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US52186283A 1983-08-10 1983-08-10

Publications (1)

Publication Number Publication Date
MX172236B true MX172236B (en) 1993-12-08

Family

ID=24078456

Family Applications (1)

Application Number Title Priority Date Filing Date
MX202341A MX172236B (en) 1983-08-10 1984-08-10 DEMETALIZATION CATALYST AND PROCESS FOR OIL LOADS CONTAINING METALS

Country Status (7)

Country Link
JP (1) JPS6054735A (en)
CA (1) CA1217756A (en)
DE (1) DE3428924A1 (en)
FR (1) FR2550544B1 (en)
IT (1) IT1181820B (en)
MX (1) MX172236B (en)
SE (1) SE461336B (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60232244A (en) * 1984-05-02 1985-11-18 Nippon Mining Co Ltd Catalyst for hydro-demetallization of heavy oil and demetallization of heavy oil using the same
US4888104A (en) * 1988-09-06 1989-12-19 Intevep, S.A. Catalytic system for the hydroconversion of heavy oils
US5492617A (en) * 1989-07-19 1996-02-20 Trimble; Harold J. Apparatus and method for quenching in hydroprocessing of a hydrocarbon feed stream
US5589057A (en) * 1989-07-19 1996-12-31 Chevron U.S.A. Inc. Method for extending the life of hydroprocessing catalyst
US5472928A (en) * 1989-07-19 1995-12-05 Scheuerman; Georgieanna L. Catalyst, method and apparatus for an on-stream particle replacement system for countercurrent contact of a gas and liquid feed stream with a packed bed
US5498327A (en) * 1989-07-19 1996-03-12 Stangeland; Bruce E. Catalyst, method and apparatus for an on-stream particle replacement system for countercurrent contact of a gas and liquid feed stream with a packed bed
US5916529A (en) * 1989-07-19 1999-06-29 Chevron U.S.A. Inc Multistage moving-bed hydroprocessing reactor with separate catalyst addition and withdrawal systems for each stage, and method for hydroprocessing a hydrocarbon feed stream
US5885534A (en) * 1996-03-18 1999-03-23 Chevron U.S.A. Inc. Gas pocket distributor for hydroprocessing a hydrocarbon feed stream
US5879642A (en) * 1996-04-24 1999-03-09 Chevron U.S.A. Inc. Fixed bed reactor assembly having a guard catalyst bed

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1040000B (en) * 1953-09-12 1958-10-02 Exxon Research Engineering Co Process for the production of molybdenum oxide catalysts on alumina carriers
US3634464A (en) * 1969-04-02 1972-01-11 Shell Oil Co Olefin epoxidation
US3819509A (en) * 1971-11-26 1974-06-25 Hydrocarbon Research Inc Low sulfur fuel oil from high metals containing petroleum residuum
GB1410924A (en) * 1971-12-22 1975-10-22 Shell Int Research Hydrocarbon conversion process
US3901792A (en) * 1972-05-22 1975-08-26 Hydrocarbon Research Inc Multi-zone method for demetallizing and desulfurizing crude oil or atmospheric residual oil
US3814683A (en) * 1972-06-14 1974-06-04 Gulf Research Development Co Hydrodesulfurization process with catalysts whose pore sizes are concentrated in a narrow range
US3964995A (en) * 1972-07-24 1976-06-22 Hydrocarbon Research, Inc. Hydrodesulfurization process
US3876523A (en) * 1973-08-29 1975-04-08 Mobil Oil Corp Catalyst for residua demetalation and desulfurization
US4040982A (en) * 1976-01-12 1977-08-09 Nalco Chemical Company Ozonization catalyst
NL187026C (en) * 1976-07-08 1991-05-01 Shell Int Research METHOD FOR THE METALIZATION OF HYDROCARBON OILS.
GB2011463B (en) * 1977-12-21 1982-05-19 Standard Oil Co Process for the hydrotreating of heafy hydrocarbon streams
US4328127A (en) * 1980-09-16 1982-05-04 Mobil Oil Corporation Residua demetalation/desulfurization catalyst
FR2504121A1 (en) * 1981-04-15 1982-10-22 Raffinage Cie Francaise Light olefin oligomerisation - using boron tri:fluoride catalyst on alumina support

Also Published As

Publication number Publication date
DE3428924C2 (en) 1987-12-10
SE8403958D0 (en) 1984-08-02
IT8448692A1 (en) 1986-05-09
IT1181820B (en) 1987-09-30
CA1217756A (en) 1987-02-10
FR2550544B1 (en) 1988-03-04
SE461336B (en) 1990-02-05
IT8448692A0 (en) 1984-08-03
JPS6054735A (en) 1985-03-29
FR2550544A1 (en) 1985-02-15
DE3428924A1 (en) 1985-02-28
SE8403958L (en) 1985-02-11

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