MX171694B - , "composicion absorbente para la eliminacion de sulfuro de hidrogeno de los hidrocarburos - Google Patents

, "composicion absorbente para la eliminacion de sulfuro de hidrogeno de los hidrocarburos

Info

Publication number
MX171694B
MX171694B MX020983A MX2098390A MX171694B MX 171694 B MX171694 B MX 171694B MX 020983 A MX020983 A MX 020983A MX 2098390 A MX2098390 A MX 2098390A MX 171694 B MX171694 B MX 171694B
Authority
MX
Mexico
Prior art keywords
hydrogen sulfide
elimination
hydrocarbons
absorbent composition
fluid stream
Prior art date
Application number
MX020983A
Other languages
English (en)
Inventor
Paul Frederick Schubert
Dennis Raymond Kidd
Gary Albert Delzer
Donald Hubert Kubicek
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of MX171694B publication Critical patent/MX171694B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/14—Diatomaceous earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La presente invención se refiere a una composición absorbente, caracterizada porque consiste esencialmente de óxido de zinc, sílice, y si se desea, cuando menos un óxido metálico promotor. Un procedimiento para eliminar el sulfuro de hidrógeno de una corriente de fluído que contiene sulfuro de hidrógeno, el procedimiento está caracterizado porque comprende poner en contacto la corriente de fluído bajo condiciones de absorción adecuadas con una composición absorbente de acuerdo con las condiciones absorbentes adecuadas comprenden usualmente una temperatura en la gama de aproximadamente 150 grados C a aproximadamente 600 grados C, una presión total del sistema en la gama de aproximadamente la presión atmosferica a aproximadamente 140.61 kg/cm cuadrado y un tiempo de residencia para la corriente de fluído en presencia de la composición absorbente, en la gama de aproximadamente 10 a aproximadamente 10,000 volumenes de gas a temperatura y presión estandar por volumen de la composición absorbente por hora.
MX020983A 1989-06-07 1990-06-01 , "composicion absorbente para la eliminacion de sulfuro de hidrogeno de los hidrocarburos MX171694B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US36303089A 1989-06-07 1989-06-07
SG79794A SG79794G (en) 1989-06-07 1994-06-20 Selective removal of hydrogen sulfide over a zinc oxide and diatomite absorbing composition.

Publications (1)

Publication Number Publication Date
MX171694B true MX171694B (es) 1993-11-10

Family

ID=26664056

Family Applications (1)

Application Number Title Priority Date Filing Date
MX020983A MX171694B (es) 1989-06-07 1990-06-01 , "composicion absorbente para la eliminacion de sulfuro de hidrogeno de los hidrocarburos

Country Status (10)

Country Link
EP (1) EP0401789B1 (es)
AT (1) ATE96694T1 (es)
CA (1) CA2014560C (es)
DE (1) DE69004341T2 (es)
DK (1) DK0401789T3 (es)
ES (1) ES2059886T3 (es)
MX (1) MX171694B (es)
NO (1) NO307129B1 (es)
SG (1) SG79794G (es)
ZA (1) ZA904314B (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5281445A (en) * 1990-07-30 1994-01-25 Phillips Petroleum Company Coating of components of sulfur absorbants
ZA93401B (en) * 1992-01-27 1993-08-24 Phillips Petroleum Co Composition useful as sulfur absorption for fluid streams.
US5244641A (en) * 1992-04-28 1993-09-14 Phillips Petroleum Company Absorption of hydrogen sulfide and absorbent composition therefor
US5914292A (en) * 1994-03-04 1999-06-22 Phillips Petroleum Company Transport desulfurization process utilizing a sulfur sorbent that is both fluidizable and circulatable and a method of making such sulfur sorbent
US5439867A (en) * 1994-03-04 1995-08-08 Phillips Petroleum Company Fluidizable sulfur sorbent and fluidized sorption process
US5494880A (en) * 1994-03-23 1996-02-27 The United States Of America As Represented By The United States Department Of Energy Durable zinc oxide-containing sorbents for coal gas desulfurization
US5710089A (en) * 1995-06-07 1998-01-20 Phillips Petroleum Company Sorbent compositions
CA2177769C (en) * 1995-06-07 1999-08-24 Gyanesh P. Khare Particulate compositions that comprise zinc aluminate
US5710091A (en) * 1995-06-07 1998-01-20 Phillips Petroleum Company Sorbent compositions
US5710083A (en) * 1996-08-14 1998-01-20 Phillips Petroleum Company Process to rejuvenate spent zinc oxide sorbents
US6254766B1 (en) * 1999-08-25 2001-07-03 Phillips Petroleum Company Desulfurization and novel sorbents for same
US7175741B2 (en) 2003-07-16 2007-02-13 Weyerhaeuser, Co. Reducing odor in absorbent products
US7351328B2 (en) * 2003-07-23 2008-04-01 China Petroleum & Chemical Corporation Desulfurization and novel process for same
US7776138B2 (en) * 2008-06-12 2010-08-17 Conocophillips Company Removal of contaminants from gas streams
FR2940967B1 (fr) * 2009-01-12 2012-07-20 Inst Francais Du Petrole Preparation d'un solide a base d'oxyde de zinc utilisable pour la purification d'un gaz ou d'un liquide
CN102381924B (zh) * 2010-09-06 2013-11-27 中国石油化工股份有限公司 一种含有含硫化合物的丙烯粗产品的纯化方法
KR20130099100A (ko) * 2010-09-13 2013-09-05 필립스 66 컴퍼니 합성 가스 컨디셔닝을 수반하는 저온 내황성 타르 및 황 제거

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1537777A (fr) * 1967-07-04 1968-08-30 Pechiney Saint Gobain Particules sphéroïdales d'hydroxydes
FR2295782A1 (fr) * 1974-12-27 1976-07-23 Inst Francais Du Petrole Procede d'epuration d'un gaz contenant du sulfure d'hydrogene et masses de contact utilisables a cet effet
GB2202546B (en) * 1987-02-16 1991-07-31 Hitachi Ltd Desulfurizing agent, process for treating hydrogen sulfide-containing gas, coal gasification system and power generation system
DE3732932A1 (de) * 1987-09-30 1989-04-13 Basf Ag Zinkoxid enthaltende entschwefelungsmassen

Also Published As

Publication number Publication date
NO902500D0 (no) 1990-06-06
NO902500L (no) 1990-12-10
EP0401789B1 (en) 1993-11-03
DK0401789T3 (da) 1993-12-20
CA2014560A1 (en) 1990-12-07
ES2059886T3 (es) 1994-11-16
DE69004341T2 (de) 1994-02-24
CA2014560C (en) 1999-02-16
ZA904314B (en) 1991-03-27
EP0401789A1 (en) 1990-12-12
NO307129B1 (no) 2000-02-14
SG79794G (en) 1994-10-14
DE69004341D1 (de) 1993-12-09
ATE96694T1 (de) 1993-11-15

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