MX170031B - Monomeros ciclo-olefinicos polimerizados en masa que contienen agentes de soplado microencapsulados - Google Patents
Monomeros ciclo-olefinicos polimerizados en masa que contienen agentes de soplado microencapsuladosInfo
- Publication number
- MX170031B MX170031B MX016616A MX1661689A MX170031B MX 170031 B MX170031 B MX 170031B MX 016616 A MX016616 A MX 016616A MX 1661689 A MX1661689 A MX 1661689A MX 170031 B MX170031 B MX 170031B
- Authority
- MX
- Mexico
- Prior art keywords
- monomer
- blowing agent
- mass
- encapsulant
- degrees
- Prior art date
Links
- 239000000178 monomer Substances 0.000 title abstract 5
- 239000004604 Blowing Agent Substances 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 239000008393 encapsulating agent Substances 0.000 abstract 2
- 238000005649 metathesis reaction Methods 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 238000012662 bulk polymerization Methods 0.000 abstract 1
- 150000001925 cycloalkenes Chemical class 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 125000003518 norbornenyl group Chemical group C12(C=CC(CC1)C2)* 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 238000010107 reaction injection moulding Methods 0.000 abstract 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 abstract 1
- 238000002411 thermogravimetry Methods 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/22—Expandable microspheres, e.g. Expancel®
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2365/00—Characterised by the use of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
La presente invención se refiere a formulación reactiva para una reacción de polimerización en masa, que proporciona cuando menos 92 por ciento de grado de conversión de monómero a polímero en un proceso de moldeo por inyección con reacción, según se determina por análisis termogravimetrico en un termo analizador DuPont 1090, en donde todos los materiales quese volatilizan antes de alcanzar 400 grados C, se consideran monómero no-reaccionado y caracterizado proque comprende: a) al menos un monómero de cicloolefina que tiene un grupo funcional norborneno; b) un sistema catalizador de metátesis, en una cantidad capaz de polimerizar en masa dicho monómero de diclo olefina por polimerización con la apertura de anillo, y c) un agente de soplado encapsulado en donde el agente de soplado tiene un punto de ebullición por debajo de la temperatura de punto de ablandamiento del encapsulante y el encapsulante es un termoplástico resinoso sintético que: i) no activa el sistema catalizador de metátesis, ii) substancialmente es impermeable al agente de soplado, y iii) tiene un punto de ablandamiento a una temperatura por debajo de 180 grados C.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US21270388A | 1988-06-28 | 1988-06-28 | |
US07/304,215 US4891387A (en) | 1988-06-28 | 1989-01-31 | Bulk polymerized cycloolefin monomers containing microencapsulated blowing agents |
Publications (1)
Publication Number | Publication Date |
---|---|
MX170031B true MX170031B (es) | 1993-08-04 |
Family
ID=26907386
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX016616A MX170031B (es) | 1988-06-28 | 1989-06-27 | Monomeros ciclo-olefinicos polimerizados en masa que contienen agentes de soplado microencapsulados |
Country Status (7)
Country | Link |
---|---|
US (1) | US4891387A (es) |
EP (1) | EP0348852A1 (es) |
KR (1) | KR910000813A (es) |
BR (1) | BR8903179A (es) |
CA (1) | CA1327423C (es) |
DK (1) | DK318389A (es) |
MX (1) | MX170031B (es) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01225645A (ja) * | 1988-03-04 | 1989-09-08 | Junkosha Co Ltd | 低誘電率複合材料 |
CA2010319C (en) * | 1989-02-20 | 2001-03-13 | Yohzoh Yamamoto | Foamable polymer composition and foamed article |
US5225451A (en) * | 1992-08-27 | 1993-07-06 | Astro-Valcour, Inc. | Ultra low density polyolefin foam, foamable polyolefin compositions and process for making same |
US5290822A (en) * | 1992-08-27 | 1994-03-01 | Astro-Valcour, Inc. | Ultra low density polyolefin foam, foamable polyolefin compositions and process for making same |
US5753156A (en) * | 1993-12-28 | 1998-05-19 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Process for producing non-scattering hollow plastic balloons |
US5840820A (en) * | 1995-04-13 | 1998-11-24 | The University Of North Carolina At Chapel Hill | Olefin metathesis reactions in carbon dioxide medium |
DE59610089D1 (de) | 1995-11-02 | 2003-03-06 | Ciba Sc Holding Ag | Härtbare Zusammensetzung enthaltend Cycloolefin, Silan und Füllstoff |
ES2146452T3 (es) * | 1996-03-07 | 2000-08-01 | Ciba Sc Holding Ag | Composicion reticulable que contiene un aducto de diels-alder del ciclopentadieno y una carga de relleno. |
US5998326A (en) | 1997-05-23 | 1999-12-07 | Ciba Specialty Chemicals Corp. | Two-component catalyst for ROMP |
DE10236509A1 (de) * | 2002-08-09 | 2004-02-19 | Behr Gmbh & Co. | Spritzguss-Werkstoff für Formteile |
US20060263473A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Compressed delivery system for active components as part of an edible composition |
US20080057294A1 (en) * | 2006-09-01 | 2008-03-06 | Fina Technology, Inc. | High impact polystyrene tile |
US20080057295A1 (en) * | 2006-09-01 | 2008-03-06 | Fina Technology, Inc. | Engravable board |
US20080120754A1 (en) * | 2006-11-28 | 2008-05-29 | Wind Of Trade, Llc | Hand protector with friction inducing elements |
DE102008004388A1 (de) * | 2008-01-14 | 2009-07-16 | Tesa Ag | Geschäumte, insbesondere druckempfindliche Klebemasse, Verfahren zur Herstellung sowie die Verwendung derselben |
US9011946B2 (en) | 2011-04-29 | 2015-04-21 | Intercontinental Great Brands Llc | Encapsulated acid, method for the preparation thereof, and chewing gum comprising same |
US10633484B2 (en) * | 2014-01-10 | 2020-04-28 | Materia, Inc. | Method and composition for improving adhesion of metathesis compositions to substrates |
CN110180476B (zh) * | 2019-06-11 | 2022-02-22 | 扬州工业职业技术学院 | 一种本体-自由基共聚法制备催化剂微胶囊的制备方法 |
WO2022118175A1 (en) * | 2020-12-02 | 2022-06-09 | 3M Innovative Properties Company | Curable compositions, composite foam, method of making the same, and article including the same |
EP4227327A1 (en) * | 2022-02-11 | 2023-08-16 | Telene SAS | An olefin metathesis polymerization catalyst system and curable compositions containing the catalyst system |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3515569A (en) * | 1966-11-21 | 1970-06-02 | Dow Chemical Co | Method of preparing smooth surfaced articles and articles provided by the method |
FR1535460A (fr) * | 1967-01-12 | 1968-08-09 | Charbonnages De France | Plastomères dérivés du diméthanooctahydronaphtalène et leur procédé de fabrication |
US3615972A (en) * | 1967-04-28 | 1971-10-26 | Dow Chemical Co | Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same |
US3778420A (en) * | 1970-07-27 | 1973-12-11 | Phillips Petroleum Co | Copolymers of cyclic monoolefins and cyclic polyolefin compounds |
US3819463A (en) * | 1971-11-17 | 1974-06-25 | Dow Chemical Co | Carpet and preparation thereof |
US3790545A (en) * | 1972-05-18 | 1974-02-05 | Goodrich Co B F | Preparation of high cis-content polypentenamer polymers |
US3864181A (en) * | 1972-06-05 | 1975-02-04 | Pratt & Lambert Inc | Polymer foam compositions |
US3853830A (en) * | 1973-03-02 | 1974-12-10 | Goodrich Co B F | Process for preparing polymers of cyclopentene |
US4002815A (en) * | 1973-11-05 | 1977-01-11 | The B. F. Goodrich Company | Cyclopentene-dicyclopentadiene copolymers and method of making same |
US4006273A (en) * | 1975-02-03 | 1977-02-01 | Pratt & Lambert, Inc. | Washable and dry-cleanable raised printing on fabrics |
US4075138A (en) * | 1976-01-16 | 1978-02-21 | The Dow Chemical Company | Polymerization process and vinylidene chloride microspheres produced thereby |
US4136249A (en) * | 1977-12-05 | 1979-01-23 | The B. F. Goodrich Company | Ring-opened copolymers of dihydrodiclopentadiene, norbornene or alkylnorbornene, and acyclic olefin |
US4178424A (en) * | 1977-12-05 | 1979-12-11 | The Bf Goodrich Company | Cycloolefin copolymers |
US4136247A (en) * | 1977-12-05 | 1979-01-23 | The B. F. Goodrich Company | Ring-opened iso-propylnorbornene copolymers |
US4136248A (en) * | 1977-12-05 | 1979-01-23 | The B. F. Goodrich Company | Ring-opened alkylnorbornene copolymers |
US4380617A (en) * | 1982-01-20 | 1983-04-19 | The B. F. Goodrich Company | Preparation of polymers from cycloolefins |
US4568660A (en) * | 1982-01-25 | 1986-02-04 | Hercules Incorporated | Cycloolefin polymerization catalyst composition |
DE3372102D1 (en) * | 1982-01-25 | 1987-07-23 | Hercules Inc | A dicyclopentadiene thermoset polymer and a catalyst and a method for making it |
US4748216A (en) * | 1982-01-25 | 1988-05-31 | Hercules Incorporated | Purified cycloolefin polymerization composition |
US4699963A (en) * | 1982-01-25 | 1987-10-13 | Hercules Incorporated | Method of cycloolefin polymerization |
US4426502A (en) * | 1982-06-14 | 1984-01-17 | The B. F. Goodrich Company | Bulk polymerization of cycloolefins |
US4535097A (en) * | 1983-08-26 | 1985-08-13 | Hercules Incorporated | Cellular thermoset poly (dicyclopentadiene) |
US4604408A (en) * | 1983-08-26 | 1986-08-05 | Hercules Incorporated | Composition for making cellular thermoset polymerized dicyclopentadiene polymer |
US4496668A (en) * | 1983-08-26 | 1985-01-29 | Hercules Corporated | Cellular thermoset poly(dicyclopentadiene) |
US4496669A (en) * | 1983-11-17 | 1985-01-29 | Hercules Incorporated | Method of making cellular crosslinked poly(dicyclopentadiene) |
US4458037A (en) * | 1983-11-17 | 1984-07-03 | Hercules Incorporated | Method of making cellular crosslinked poly(dicyclopentadiene) |
US4598102A (en) * | 1983-11-17 | 1986-07-01 | Hercules Incorporated | Method, composition and product produced by delayed gelation in the polymerization of cycloolefins |
US4703068A (en) * | 1983-11-22 | 1987-10-27 | Hercules Incorporated | Method for making a dicyclopentadiene cross-linked polymer and the product thereof |
US4689380A (en) * | 1984-11-16 | 1987-08-25 | Hercules Incorporated | Cycloolefin copolymerization method, feed composition and product |
US4696985A (en) * | 1984-11-16 | 1987-09-29 | Hercules Incorporated | Catalyst composition for polymerization of cycloolefins |
US4701510A (en) * | 1985-12-16 | 1987-10-20 | The B.F. Goodrich Company | Polycycloolefins resistant to solvents |
-
1989
- 1989-01-31 US US07/304,215 patent/US4891387A/en not_active Expired - Fee Related
- 1989-06-21 CA CA000603502A patent/CA1327423C/en not_active Expired - Fee Related
- 1989-06-24 EP EP89111548A patent/EP0348852A1/en not_active Withdrawn
- 1989-06-27 MX MX016616A patent/MX170031B/es unknown
- 1989-06-27 DK DK318389A patent/DK318389A/da not_active Application Discontinuation
- 1989-06-28 KR KR1019890008993A patent/KR910000813A/ko not_active Application Discontinuation
- 1989-06-28 BR BR898903179A patent/BR8903179A/pt not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
US4891387A (en) | 1990-01-02 |
EP0348852A1 (en) | 1990-01-03 |
BR8903179A (pt) | 1990-05-29 |
DK318389A (da) | 1989-12-29 |
DK318389D0 (da) | 1989-06-27 |
CA1327423C (en) | 1994-03-01 |
KR910000813A (ko) | 1991-01-30 |
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