MX150276A - PROCEDURE FOR THE PREPARATION OF FLUORATED POLYMERS - Google Patents

PROCEDURE FOR THE PREPARATION OF FLUORATED POLYMERS

Info

Publication number
MX150276A
MX150276A MX173171A MX17317178A MX150276A MX 150276 A MX150276 A MX 150276A MX 173171 A MX173171 A MX 173171A MX 17317178 A MX17317178 A MX 17317178A MX 150276 A MX150276 A MX 150276A
Authority
MX
Mexico
Prior art keywords
groups
side chains
pendant side
polymers
chains containing
Prior art date
Application number
MX173171A
Other languages
Spanish (es)
Inventor
Walther Gustav Grot
Charles John Molnar
Paul Raphael Resnick
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of MX150276A publication Critical patent/MX150276A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2287After-treatment
    • C08J5/2293After-treatment of fluorine-containing membranes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Fluorinated ion exchange polymers which have both pendant side chains containing carboxylic groups and pendant side chains which contain sulfonyl groups, when used in the form of membranes to separate the anode and cathode compartments of an electrolysis cell, permit operation at high current efficiency. They are made by oxidation of flourinated polymers which have pendant side chains containing sulfinic groups, or both sufinic and sulfonyl groups. The fluorinated polymers which have pendant side chains containing sulfinic groups, or both sufinic and sulfonyl groups, are in turn made from fluorinated polymers which have pendant side chains containing sulfonyl halide groups by reduction with, for example, hydrazine. Fluorinated ion exchange polymers which have pendant side chains containing -OCF2COOR groups and also pendant side chains which contain sulfonyl groups can also be made by copolymerization of a mixture of monomers, one of which is a vinyl monomer which contains the indicated carboxylic group; and also by treatment of a polymer which contains -OCF2CF2SO3H or salts thereof with a combination of fluorine and oxygen.
MX173171A 1977-04-20 1978-04-19 PROCEDURE FOR THE PREPARATION OF FLUORATED POLYMERS MX150276A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US78972677A 1977-04-20 1977-04-20

Publications (1)

Publication Number Publication Date
MX150276A true MX150276A (en) 1984-04-10

Family

ID=25148510

Family Applications (1)

Application Number Title Priority Date Filing Date
MX173171A MX150276A (en) 1977-04-20 1978-04-19 PROCEDURE FOR THE PREPARATION OF FLUORATED POLYMERS

Country Status (15)

Country Link
JP (1) JPS53132094A (en)
AU (1) AU525395B2 (en)
BE (1) BE866122A (en)
BR (1) BR7802434A (en)
CA (1) CA1126443A (en)
DE (1) DE2817315A1 (en)
FR (2) FR2388013B1 (en)
GB (4) GB1604176A (en)
IL (1) IL54539A (en)
IT (1) IT1094088B (en)
MX (1) MX150276A (en)
NL (1) NL7804220A (en)
NZ (1) NZ187022A (en)
SU (1) SU784786A3 (en)
ZA (1) ZA782224B (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1061477B (en) * 1975-07-09 1983-02-28 Asahi Chemical Ind CATIONI EXCHANGER MEMBRANE ON ITS PREPARATION AND USE
US4200711A (en) * 1977-04-25 1980-04-29 Tokuyama Soda Kabushiki Kaisha Process for preparing fluorine-containing polymers having carboxyl groups
US4329434A (en) * 1979-05-31 1982-05-11 Asahi Kasei Kogyo Kabushiki Kaisha Novel fluorinated cation exchange membrane and process for producing the same
US4329435A (en) * 1979-05-31 1982-05-11 Asahi Kasei Kogyo Kabushiki Kaisha Novel fluorinated copolymer with tridihydro fluorosulfonyl fluoride pendant groups and preparation thereof
JPS5672190A (en) * 1979-11-20 1981-06-16 Toyo Soda Mfg Co Ltd Cation exchange membrane for electrolysis of alkali metal halogenide
JPS5792028A (en) * 1980-11-29 1982-06-08 Asahi Chem Ind Co Ltd Fluorocarbon cation exchange membrane
GB2302693B (en) * 1995-06-26 1999-03-10 Tokuyama Corp Fluorine-containing resin molded articles
DE10209784A1 (en) * 2001-09-01 2003-12-04 Univ Stuttgart Inst Fuer Chemi Oligomers and polymers containing sulfinate groups and process for their preparation
JP4621536B2 (en) * 2005-04-20 2011-01-26 旭化成イーマテリアルズ株式会社 Method for producing electrolyte membrane with excellent chemical stability
CN103370345B (en) * 2010-12-17 2016-06-29 3M创新有限公司 The oligomer of highly fluorinated sulfinic acid and co-oligomer and salt thereof
JP5866375B2 (en) * 2010-12-17 2016-02-17 スリーエム イノベイティブ プロパティズ カンパニー Fluorine-containing polymers containing sulfinate-containing molecules
CN103354814B (en) * 2010-12-17 2017-04-26 3M创新有限公司 Partially fluorinated polysulfinic acids and their salts
DE102021131511A1 (en) 2021-12-01 2023-06-01 Bayerische Motoren Werke Aktiengesellschaft Cathode with a fluorine-containing polymer and a solid-state battery with the cathode
CN115073660B (en) * 2022-07-25 2022-12-30 中海油天津化工研究设计院有限公司 Integrated thickening agent for fracturing and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3853721A (en) * 1971-09-09 1974-12-10 Ppg Industries Inc Process for electrolysing brine
US3853720A (en) * 1972-10-24 1974-12-10 Ppg Industries Inc Electrolysis of brine using permeable membranes comprising fluorocarbon copolymers
IT1061477B (en) * 1975-07-09 1983-02-28 Asahi Chemical Ind CATIONI EXCHANGER MEMBRANE ON ITS PREPARATION AND USE
JPS5284191A (en) * 1975-12-30 1977-07-13 Asahi Glass Co Ltd Improved f-contg. cation exchange resin membrane

Also Published As

Publication number Publication date
FR2485024B1 (en) 1985-08-02
BR7802434A (en) 1979-01-16
NZ187022A (en) 1981-03-16
ZA782224B (en) 1979-04-25
FR2388013B1 (en) 1985-08-02
SU784786A3 (en) 1980-11-30
GB1604175A (en) 1981-12-02
GB1604173A (en) 1981-12-02
GB1604176A (en) 1981-12-02
GB1604174A (en) 1981-12-02
AU3516878A (en) 1979-10-25
FR2388013A1 (en) 1978-11-17
JPS53132094A (en) 1978-11-17
IT7822495A0 (en) 1978-04-19
JPS6147843B2 (en) 1986-10-21
CA1126443A (en) 1982-06-22
IL54539A (en) 1983-03-31
IL54539A0 (en) 1978-07-31
BE866122A (en) 1978-10-19
IT1094088B (en) 1985-07-26
NL7804220A (en) 1978-10-24
FR2485024A1 (en) 1981-12-24
DE2817315A1 (en) 1978-11-02
AU525395B2 (en) 1982-11-04

Similar Documents

Publication Publication Date Title
MX150276A (en) PROCEDURE FOR THE PREPARATION OF FLUORATED POLYMERS
KR830006474A (en) Improved Hybrid Ion Exchange Membrane
ATE11153T1 (en) IMPROVED SULFONIC ACID MEMBRANES FOR AN ELECTROLYTIC CELL.
JPS5439833A (en) Diaphragm for galvanic cell
AU538113B2 (en) Solid-solution plastic electrolytes
SE7703520L (en) ELECTROLYSIS OF ALKALIMETAL HALID SOLUTION
FR2275298A1 (en) COMPOSITE CATION EXCHANGER MEMBRANE AND ITS USE IN THE ELECTROLYSIS OF AN ALKALINE METAL HALOGENIDE
BR8103718A (en) ELECTRIC CELL WITH A PERFECTED MEMORY OF IONIC EXCHANGE AND OPERATION PROCESS
NZ187023A (en) Fluorinated ion-exchanger polymers
GB1197588A (en) Improvements in Rechargeable Non-Aqueous Alkali Metal-Halogen Electrochemical Cells
JPS577166B2 (en)
ES478573A1 (en) their preparation and their use in the electrolysis of sodium chloride.
FR2032421A1 (en) Under-water metal/oxygen element with - sealed cathode allowing ingress of dissolved
FR2334768A2 (en) Electrolytic cell contg cation exchanger diaphragm - of graft copolymer contg polyolefine and hydroxy-styrene
GB574870A (en) Improvements in or relating to electrodes for use in electrolytic cells
JPS5829802B2 (en) fluoropolymer fluoropolymer
JPS5164496A (en) Aminhenseimaku oyobi koreoshosuruensooarukaridenkaiso
JPS538689A (en) Preparation of ion-exchange membrane
JPS55131187A (en) Manufacture of alkali hydroxide
JPS5625985A (en) Anode for alkali chloride electrolysis
IT1150151B (en) Selectively permeable fluoro-polymer cation-exchange membrane
JPS5665989A (en) Electrolysis method of alkali metal halogenide
JPS5625984A (en) Anode for alkali chloride electrolysis
GT198062089A (en) IMPROVEMENTS IN A NON-AQUEOUS ELECTROLYTE ELECTROCHEMICAL GENERATOR