MA27505A1 - PHOTOACOUSTIC DETECTION METHOD FOR MEASURING THE CONCENTRATION OF A NON-HYDROCARBON COMPONENT OF A GAS MIXTURE CONTAINING METHANE - Google Patents

PHOTOACOUSTIC DETECTION METHOD FOR MEASURING THE CONCENTRATION OF A NON-HYDROCARBON COMPONENT OF A GAS MIXTURE CONTAINING METHANE

Info

Publication number
MA27505A1
MA27505A1 MA27960A MA27960A MA27505A1 MA 27505 A1 MA27505 A1 MA 27505A1 MA 27960 A MA27960 A MA 27960A MA 27960 A MA27960 A MA 27960A MA 27505 A1 MA27505 A1 MA 27505A1
Authority
MA
Morocco
Prior art keywords
gas mixture
hydrocarbon component
concentration
gas
measuring
Prior art date
Application number
MA27960A
Other languages
French (fr)
Inventor
Zsolt Bor
Arpad Mohacsi
Gabor Szabo
Zoltan Bozoki
Sandor Puskas
Miklos Szakall
Original Assignee
Mol Magyar Olaj & Gazipari Rt
Univ Szegedi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mol Magyar Olaj & Gazipari Rt, Univ Szegedi filed Critical Mol Magyar Olaj & Gazipari Rt
Publication of MA27505A1 publication Critical patent/MA27505A1/en

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036Specially adapted to detect a particular component
    • G01N33/0047Specially adapted to detect a particular component for organic compounds
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/1702Systems in which incident light is modified in accordance with the properties of the material investigated with opto-acoustic detection, e.g. for gases or analysing solids
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/1702Systems in which incident light is modified in accordance with the properties of the material investigated with opto-acoustic detection, e.g. for gases or analysing solids
    • G01N2021/1704Systems in which incident light is modified in accordance with the properties of the material investigated with opto-acoustic detection, e.g. for gases or analysing solids in gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Combustion & Propulsion (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)
  • Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)

Abstract

La présente invention a trait à un procédé de détection photo-acoustique pour mesurer la concentration d'un composant non hydrocarboné d'un mélange gazeux contenant du méthane. Le procédé est essentiellement caractérisé en ce que le spectre d'absorption photo-acoustique pour le mélange gazeux est enregistré sur une gamme de longueurs d'ondes sélectionnées pendant que le mélange gazeux circule en continu à travers l'appareil de mesure, et ensuite pour la détermination de la concentration du composant non hydrocarboné le spectre ainsi obtenu est utilisé en combinaison avec un signal photo-acoustique généré par une cellule de référence (3) remplie d'un gaz ayant des propriétés prédéterminées. Le mélange gazeux contenant du méthane et le composant non hydrocarboné sont, de préférence, choisis pour constituer du gaz naturel destiné à être évacués vers des conduits de gaz et de vapeur d'eau, respectivement. L'invention permet ainsi une détection à haute précision, même dans des conditions industrielles, de la teneur en vapeur d'eau présente dans des concentrations aussi faibles qu'environ 0,5 ppm dans du gaz naturel.The present invention relates to a photo-acoustic detection method for measuring the concentration of a non-hydrocarbon component of a gas mixture containing methane. The method is essentially characterized in that the photoacoustic absorption spectrum for the gas mixture is recorded over a range of selected wavelengths while the gas mixture flows continuously through the measuring device, and then for the determination of the concentration of the non-hydrocarbon component the spectrum thus obtained is used in combination with a photo-acoustic signal generated by a reference cell (3) filled with a gas having predetermined properties. The methane-containing gas mixture and the non-hydrocarbon component are preferably chosen to constitute natural gas intended to be evacuated to gas and steam conduits, respectively. The invention thus allows high precision detection, even under industrial conditions, of the water vapor content present in concentrations as low as about 0.5 ppm in natural gas.

MA27960A 2002-05-24 2004-11-23 PHOTOACOUSTIC DETECTION METHOD FOR MEASURING THE CONCENTRATION OF A NON-HYDROCARBON COMPONENT OF A GAS MIXTURE CONTAINING METHANE MA27505A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
HU0201751A HU225660B1 (en) 2002-05-24 2002-05-24 Method for photoacoustic measurement of concentration of non hydrocarbon component of gas mixture containing methane

Publications (1)

Publication Number Publication Date
MA27505A1 true MA27505A1 (en) 2005-09-01

Family

ID=89980449

Family Applications (1)

Application Number Title Priority Date Filing Date
MA27960A MA27505A1 (en) 2002-05-24 2004-11-23 PHOTOACOUSTIC DETECTION METHOD FOR MEASURING THE CONCENTRATION OF A NON-HYDROCARBON COMPONENT OF A GAS MIXTURE CONTAINING METHANE

Country Status (9)

Country Link
EP (1) EP1511987A1 (en)
AU (1) AU2003232375A1 (en)
DE (1) DE10392663T5 (en)
EG (1) EG23784A (en)
HU (1) HU225660B1 (en)
MA (1) MA27505A1 (en)
RU (1) RU2336518C2 (en)
TN (1) TNSN04232A1 (en)
WO (1) WO2003100393A1 (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7132661B2 (en) 2000-08-28 2006-11-07 Spectrasensors, Inc. System and method for detecting water vapor within natural gas
DE102005030151B3 (en) * 2005-06-28 2006-11-02 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Photo-acoustic free-field detector for measuring air, gas and liquid flows has optical and acoustic mirrors arranged in position where local maximum sound pressure is present for generating acoustic energy based on output of acoustic sensor
JP2008545134A (en) * 2005-07-06 2008-12-11 コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ Photoacoustic spectroscope
HU226449B1 (en) * 2005-11-14 2008-12-29 Univ Szegedi Method and device for selective determining contaminating components of a gaseous sample on photoacoustic principle using distant exciting wavelengths
US7679059B2 (en) * 2006-04-19 2010-03-16 Spectrasensors, Inc. Measuring water vapor in hydrocarbons
US7511802B2 (en) 2006-05-26 2009-03-31 Spectrasensors, Inc. Measuring trace components of complex gases using gas chromatography/absorption spectrometry
WO2008048994A2 (en) * 2006-10-18 2008-04-24 Spectrasensors, Inc. Detection of moisture in refrigerants
US7508521B2 (en) 2007-03-14 2009-03-24 Spectrasensors, Inc. Pressure-invariant trace gas detection
CA2683802C (en) 2007-04-11 2017-09-05 Spectrasensors, Inc. Reactive gas detection in complex backgrounds
EP2591383B1 (en) * 2010-07-08 2019-01-16 Halliburton Energy Services, Inc. Method and system of determining constituent components of a fluid sample in a downhole tool
US8848191B2 (en) 2012-03-14 2014-09-30 Honeywell International Inc. Photoacoustic sensor with mirror
DE102012217479B3 (en) * 2012-09-26 2013-10-24 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Gas sensor for determining concentration of target gas in measurement gas e.g. industrial process gas, has resonant portion that is excited by photo-acoustic signal in reference gas volume so that resonant portion is oscillated
DE102014108424B3 (en) * 2014-06-16 2015-06-11 Johann Wolfgang Goethe-Universität Non-invasive substance analysis
US10643008B2 (en) 2014-11-11 2020-05-05 Spectrasensors, Inc. Target analyte detection and quantification in sample gases with complex background compositions
EP3495800B1 (en) 2015-12-09 2023-09-20 DiaMonTech AG Apparatus and method for analyzing a material
EP3524962A1 (en) 2015-12-09 2019-08-14 Diamontech GmbH Device and method for analysing a material
CN111566466A (en) * 2017-08-11 2020-08-21 阿里尔科学创新有限公司 Real-time monitoring of the concentration of substances, in particular ammonia, in fish ponds and similar environments
CN110441241B (en) * 2019-07-31 2023-01-06 中国电力科学研究院有限公司 Performance evaluation device and method for photoacoustic spectroscopy multi-component gas analysis instrument
US11460416B2 (en) 2020-09-30 2022-10-04 Saudi Arabian Oil Company Method for measuring oil in water using multi-frequency microwave measurements

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0685728B1 (en) * 1994-06-04 2002-12-11 Orbisphere Laboratories Neuchatel Sa Photoacoustic analyzer

Also Published As

Publication number Publication date
HU225660B1 (en) 2007-05-29
WO2003100393A1 (en) 2003-12-04
HUP0201751A2 (en) 2003-12-29
RU2336518C2 (en) 2008-10-20
DE10392663T5 (en) 2005-09-01
EG23784A (en) 2007-08-13
HU0201751D0 (en) 2002-08-28
RU2004137093A (en) 2005-07-20
AU2003232375A8 (en) 2003-12-12
EP1511987A1 (en) 2005-03-09
AU2003232375A1 (en) 2003-12-12
TNSN04232A1 (en) 2007-03-12

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