LV14019B - Heavy concrete - Google Patents

Heavy concrete Download PDF

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Publication number
LV14019B
LV14019B LVP-09-123A LV090123A LV14019B LV 14019 B LV14019 B LV 14019B LV 090123 A LV090123 A LV 090123A LV 14019 B LV14019 B LV 14019B
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Latvia
Prior art keywords
manufacture
concrete
steel
particles
size
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LVP-09-123A
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Latvian (lv)
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LV14019A (en
Inventor
Viktors Mironovs
Vjačeslavs Zemčenkovs
Aleksandrs Korjakins
Genādijs ŠAHMENKO
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Rīgas Tehniskā Universitāte
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Priority to LVP-09-123A priority Critical patent/LV14019B/en
Publication of LV14019A publication Critical patent/LV14019A/en
Publication of LV14019B publication Critical patent/LV14019B/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/34Metals, e.g. ferro-silicon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/14Waste materials; Refuse from metallurgical processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to the area of manufacture of building materials, in particular to manufacture of heavy concrete. It is offered new material - heavy concrete, which contains metal filling compound with following structure (on weight): 10-20 % ferrous or steel powder with the size of particles 15¸100 micrommeters, 20-30 % steel rolling scale with the size of particles 5¸20 micrometers, 50-70 % steel waste from sheet punching with the size of particles 1,0¸5,0 mm. The received concrete has density from 3000 to 4500 kg/m3 and strength on compression after 28 days up to 50 MPa. A waste formed on filters in metallurgical manufacture can be used as an iron powder. The offered decision in comparison with known allows to receive following advantages of a material: technical (it makes possible to manufacture a material with the raised density and stability against radiation); economic (it makes possible to get lower cost of a material due to use of waste of metallurgical and machine-building manufacture); ecological (it makes possible to use production wastes rationally for manufacturing products with high technical parameters and provide radiological protection).

Description

Piedāvātais izgudrojums attiecas uz būvmateriālu ražošanas jomu, konkrēti - uz smagā betona ražošanas jomu.The present invention relates to the field of construction materials, in particular to the production of heavy concrete.

Būvniecībā plaši izmanto normālo betonu ar blīvumu 2000 līdz □Normal concrete with a density of 2000 to □ is widely used in construction

2600 kg/m izžāvētā stāvoklī [1]. Tajā kā pildvielu izmanto kalnu iežus (dolomītu, granītu, diabāzu), kuriem ir vidēji liels īpatnējais svars [2].2600 kg / m in the dried state [1]. It is based on aggregate rock (dolomite, granite, diabase) of medium specific gravity [2].

Ir zināms smagais betons ar metāla pildvielām, kura sastāvā ir metāla skaidas, virpskaidas vai metalurģijas lietišķie atlikumi, tādi kā metalurģiskie sārņi [3]. Tādam betonam ir paaugstināts blīvums un augsta dilšanas izturība. To izmanto, piemēram, betona grīdu izgatavošanai rūpniecībā [4]. Smago betonu ar blīvumu, lielāku par 2600 kg/m , izmanto hidrotehniskajā būvniecībā, kā arī aizsardzībai pret radioaktivitātes iedarbību.Heavy concrete with metal fillers containing metal shavings, shavings or metallurgical residues such as metallurgical slag is known [3]. Such concrete has high density and high abrasion resistance. It is used, for example, in the manufacture of concrete floors in industry [4]. Heavy concrete with a density greater than 2600 kg / m is used in hydraulic engineering as well as for protection against radioactivity.

Vistuvākais piedāvātajam risinājumam ir betons [5] (prototips), kurā kā metāla pildviela izmantota velmēšanas pļāva. Velmēšanas plāvā ir liels materiāla daļiņu blīvums - līdz 5,1-5,3 g/m3, kas veicina galīgo betona blīvuma paaugstināšanu. Tādu betonu izmanto aizsardzībai iekārtās pret radioaktīvo iedarbību, kā arī smaga balasta un enkuru izgatavošanai. Minētā materiāla trūkums ir:Closest to the proposed solution is concrete [5] (prototype), which uses a rolling filler as a metal filler. The rolling bed has a high material particle density of up to 5.1-5.3 g / m 3 , which contributes to the final increase in concrete density. Such concrete is used in equipment for protection against radioactivity, as well as for the production of heavy ballast and anchors. The disadvantages of this material are:

• palielināts cementa izlietojums;• increased use of cement;

•3 • blīvums nepārsniedz 3000 kg/m .• 3 • Density not exceeding 3000 kg / m.

Piedāvātā risinājuma mērķis ir radīt smago betonu un tā izgatavošanas paņēmienu, kas nodrošina blīvuma paaugstināšanu līdz 3500 - 4500 kg/m3, kā arī dilšanas izturību.The aim of the proposed solution is to create heavy concrete and its production method, which provides increase of density up to 3500 - 4500 kg / m 3 , as well as abrasion resistance.

Mērķa sasniegšanai tiek piedāvāts betons ar metāla pildvielu, kuras sastāvā ir (masas %): 10 līdz 20% metāla pulvera, 20 līdz 30% velmēšanas pļāvās un 50 līdz 70% tērauda izštancējumu.To accomplish this, concrete with metal filler containing (by weight) 10 to 20% metal powder, 20 to 30% rolling mills and 50 to 70% steel extrusion is offered.

Metāla pulveris nodrošina gatavā materiāla īpatnējās masas paaugstināšanos. Ieteicams izmantot dzelzs pulveri, piemēram, ASC 100.29 ar daļiņu izmēru 15-20 pm, kā arī metāla pulveru ražošanas filtru lietišķos atlikumus.The metal powder provides an increase in the specific mass of the finished material. The use of iron powders, such as ASC 100.29 with a particle size of 15-20 pm, as well as industrial residues of metal powder production filters is recommended.

Ieteicams vienlaicīgi kā pildvielu izmantot dzelzs pulveri (ar daļiņu izmēru 10 līdz 20 pm), sasmalcinātu velmēšanas pļāvu (ar daļiņu izmēru 100 līdz 300 pm) un tērauda štancēšanas lietišķos atlikumus (ar daļiņu izmēru 1 līdz 5 mm).It is recommended to use iron powder (particle size 10 to 20 pm), crushed rolling mead (particle size 100 to 300 pm) and steel stampings (particle size 1 to 5 mm) as filler at the same time.

Piedāvātā materiāla sastāva varianti un tā izgatavošanas paņēmiens apskatīts tālāk sekojošajos 1. un 2. piemērā.Variations of the composition of the proposed material and the method of its preparation are discussed in Examples 1 and 2 below.

1. piemērs - smagais betons ar paaugstinātu blīvumu (3000 līdz 3200 kg/m3) un izturību pret spiedi līdz 50 MPa pēc 28 dienāmExample 1 - Heavy concrete with high density (3000 to 3200 kg / m 3 ) and compressive strength up to 50 MPa after 28 days

Betona sastavs ir sekojošs (masas daļas):Concrete composition is as follows (parts by weight):

cements CEM1 42,5 N - cement CEM1 42,5 N - 1,00, 1.00, kvarca smilts - quartz sand - 0,65, 0.65, tērauda pļāva - steel mower - 3,95, 3.95, dzelzs pulveris - iron powder - 0,00, 0.00, ūdens - water - 0,55, 0.55, superplastifikators - superplasticizer - 0,015, 0.015, ūdens cementa attiecība - water cement ratio - 0,55. 0.55.

2. piemērs - smagais betons ar paaugstinātu blīvumu (4000 līdz 4300 kg/m3) un izturību pret spiedi līdz 40 - 43 MPa pēc 28 dienāmExample 2 - Heavy Duty Concrete with Heavy Density (4000 to 4300 kg / m 3 ) and Compressive strength up to 40 - 43 MPa after 28 days

Betona sastāvs ir sekojošs (masas daļās):Concrete composition is as follows (in parts by weight):

cements CEM1 42,5 N - 1,00, tērauda pļāva - 3,49, tērauda štancēšanas lietišķie atlikumi - 2,69, dzelzs pulveris - 1,62, ūdens - 0,62, superplastifikators - 0,016, ūdens cementa attiecība - 0,62cement CEM1 42.5 N - 1.00, steel mead - 3.49, steel stamping applied residues - 2.69, iron powder - 1.62, water - 0.62, superplasticizer - 0.016, water cement ratio - 0, 62

Maisījumu izgatavošanas tehnoloģija ir sekojoša. Izejmateriālus nosver ar precizitāti +1%, 1 minūti pārmaisa sausā veidā standarta (gravitācijas vai pannas tipa) betona maisītājā. Pievieno ūdeni un maisa vēl 3 līdz 4 minūtes.The technology for the preparation of mixtures is as follows. The raw materials are weighed to an accuracy of + 1%, stirred dry for 1 minute in a standard (gravity or pan type) concrete mixer. Add water and stir for another 3 to 4 minutes.

Piedāvātajam risinājumam ir sekojošas priekšrocības attiecībā pret zināmajiem:The proposed solution has the following advantages over the known ones:

tehniskās (nodrošina blīvuma palielināšanu, izturību pret radiāciju); ekonomiskās (dod iespēju samazināt betona sastāvdaļu izmaksas uz metalurģijas un mašīnbūves lietišķo atlikumu rēķina);technical (provides density, radiation resistance); economic (enables to reduce the cost of concrete components at the expense of metallurgy and mechanical waste);

ekoloģiskās (dod iespēju utilizēt lietišķos atlikumus metalurģijas izdedžu veidā, lietišķos atlikumus no filtriem).ecological (makes it possible to utilize the applied residues in the form of metallurgical slag, the applied residues from filters).

Izmantotie informācijas avoti:Used information sources:

1. LVS EN 206-1:2000. Betons. 1. daļa: Tehniskie noteikumi, darbu izpildījums, ražošana un atbilstība.1. LVS EN 206-1: 2000. Concrete. Part 1: Technical regulations, performance, production and conformity.

2. R. Chundelly, R. Geeno Building Construction Handbook. Britsh Library Catalogig in Publication Data. 2001, pp 347.2. R. Chundelly, R. Geeno Building Construction Handbook. Britsh Library Catalogig in Publication Data. 2001, pp. 347.

3. Qasrawi H., Shalabi F., Asi I. Use of low CaO unprocessed Steel slag in concrete as fīne aggregate. - Construction and Building materiāls, No 23 (2009), pp. 1118-1125.3. Qasrawi H., Shalabi F., Asi I. Use of low CaO unprocessed steel slag in concrete as a finite aggregate. - Construction and Building Materials, No 23 (2009), p. 1118-1125.

4. Hummel. Das Beton ABC. Schwerbeton. Leichbeton. 1959.4. Hummel. Das Beton ABC. Schwerbeton. Leichbeton. 1959

5. Eisen kiesbeton nach neuer Schwerbetonrezeptur. Steinbuch und Sandgrube. 2008 (prototips)5. Eisen kiesbeton nach neuer Schwerbetonrezeptur. Steinbuch und Sandgrube. 2008 (prototype)

Claims (2)

PretenzijasClaims 1. Smagais betons ar metāla pildvielu, kas atšķiras ar to, ka kā metāla pildviela izmantota materiālu kombinācija (% no masas):1. Heavy concrete with metal filler, characterized in that the combination of materials (% by weight) is used as metal filler: - dzelzs vai tērauda pulveris ar daļiņu izmēru no 15 līdz 100 pm 10 līdz 20%;- iron or steel powder with a particle size of 15 to 100 µm, 10 to 20%; - tērauda velmēšanas pļāva ar daļiņu izmēru no 5,0 līdz 20 pm - 20 līdz 30%;- steel rolling mill with particle size from 5.0 to 20 pm - 20 to 30%; - slokšņu tērauda štancēšanas lietišķie atlikumi ar daļiņu izmēru no 1,0 līdz 5,0 mm - 50 līdz 70%.- Stripping residues of strip steel with a particle size of 1.0 to 5.0 mm - 50 to 70%. 2. Smagais betons saskaņā ar 1. punktu, kas atšķiras ar to, ka kā metāla pulveris izmantots metalurģiskās ražošanas filtru lietišķie putekļveida atlikumi.Heavy concrete according to claim 1, characterized in that the metallic powder used is a dusty residue from metallurgical production filters.
LVP-09-123A 2009-07-03 2009-07-03 Heavy concrete LV14019B (en)

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LV14019B true LV14019B (en) 2010-01-20

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