LV10744B - Fungicidal composition - Google Patents

Description

LV 10744

OyHrHL4MflHblii COCTaB Μ3θ6ρβΤΘΗΜΘ OTHOCMTCS K ΧΜΜΜΜΘΟΚΜΜ COCTaBaM 3aUļMTbl paCTeHMM, ΚΟΗΚρβΤΗΟ, K φγΗΓΜαΜΑΗΟΜγ COCTaBy Ha OCHOBe Πρ0Μ3Β0ΑΗ0Γ0 -H-1 -6M-1H-Me-1H-Me-1H (-a) -30H 1 / Ι3βθοτθη Φυηγμκμαηβιμ cociaB Ha οοηοβθ npon3BOflHoro a3ona (1).

Eonee 6πμ3κμμ k 3asBneHH0My cociaBy senseTca cocrraB Ha οοηοβθ np0M3B0flH0r0 1- (a30H-1-ΜΠ-ΜΘΤΜΠ) -2-6θΗ3ΜΠ-Ι4ΜΚΠΟΠβΗΤ3ΗΟΠ3 (2).

OflHaKO yKa3aHHbie Φυηγμμμαημθ cociaBbi oānapaiOT ΗβηοστβτοΗΗΟΜ aKTHBHOCTbtO npH MaJlblX KOHqeHTpai4HHX.

UenblO Μ3θ6ρΘΤΘΗΜΗ ΠΒΠΗΘΤΟΗ γΒΘΠΜΗΘΗΜβ φγΗΓΜ11ΜΑΗθίί aKTHBHOCTH cocTaBa.

CnenyioiMMe npMMepbi ΜπηιοοτρΜργιοτ 3asBneHHoe πρβρποχθΗΜΘ. ΠρΜΜβρ 1 rionyweHMe 5- (4-xnop6eH3nn) -2,2-flHMeTnn-1 - (IH-1,2,4-Tpna3on -1 -μπμθτμπ) -UMKnoneHTaHona K 30 ΜΠ 6β3ΒΟΠΗΟΓΟ ΑΜΜΘΤΜΠφθρΜ3ΜΜΑ3 ΠΟδβΒΠΠΙΟΤMe βbMMe β βPMHe β , 0 r 7- (4-χπορ6θη3μπ) -4,4-αμμθτμπ-1-OKcacnnpo (2,4) remaHa. K nonyneHHOMy pacTBopy μθοπθηηο poāaBnsiOT 2.2 r HaTpneBofi conn IH-1,2,4-Tpna3ona (HHCTOTa 90%). CMecb nepeMeujHBaiOT jqBa waca npM 70 ° C. riocne oxna > KpeHMs ποπυμθηηομ peaiaiMOHHOM CMecH ee BbmMBaioT b Bopy co ribflOM m bckd CMecb 3KCTparnpyK) T STMnaueTaTOM, HTobi nonynMTb opraHHHecKMH c. OpraHMHecKMM cnoii npoMbiBaiOT Bonoii, cyiuaT 6e3BOflHbiM cyr ^ aTOM Haipns. PacTBopmenb ottohsiot H3 ocymeHHoro opraHMnecKoro cnos ΓΐρΜ ΠΟΗΜ) ΚβΗΗΟΜ Η3ΒΠβΗΜΜ. ΠοπγΗΘΗΗΒΐίί OCTaTOK nOflBepraiOT OHMCTKe χρ0Μ3Τ0Γρ3φΜΘΜ Ha κοποηκθ c ομπμκβγθπθμ h nonyHaioT 3.1 r ueneeoro nponyKTa (ΟΟΘΟΜΗΘΗΜΘ 2). ΠρΜΜβρ 2 ΠοπγΗΘΗΜβ -5- (2,4-ηΜΧηθρ6βΗ3ΜΠ) -2,2′ΡΜΜΘΤΜΠ-1 - (IH-MMMfla30n-1 -μπμθτμπ) - LļMKnoneHTaHona Β 1 8 ΜΠ 6e3BOflHOrO ΗΜΜΘΤΜΠφθρΜ3ΜΜΑ3 ΑΟδβΒΠΒΙΟΤΒΠΒΙΟΤMMM TMflpMjqa HaTpMS 6e3BOflHblM 6βΗ30ΠΟΜ) Β ΒΤΜΟΟφβρβ ΓΘΠΜΠ ΠρΜ ΠθρθΜβίυΜΒΒΗΜΜ. Κ ΠΟΠγΗΘΗΗΟΜ ΟΜΘΟΜ Ao6aBnsK3T 2.83 r IH-MMMjqa3ona m CMecb nepeMeuJMBaiOT npM κομηβτηομ TeMnepaType no npeepameHMs βμαθπθημβ ny3bipbK0B ra3a. Κ ποπυηθηηομυ pacTBOpy no KannaM πρΜΠΜΒβιοτ pacTBOp, nonyHeHHbiii pacTBopeHMeM 5,93 r 7- (2,4-flMxnop6eH3Mn) -4,4-flMMeTMn-1-OKcacnnpo (2,4) rerrHMM mp 80 ° C. riocne oxna > KfleHMB headKunoHHOM cMecH ee BbinneaioT b neaaHHyio Boqy m ποπγπθΗΗγιο CMecb 3KCTparnpyK) T STunaueTaToivi οπβ ποπυηθημβ opraHunecKoro riocne npoMbiBKM opraHunecKoro cnofl βοοομ erot cyuiaT 6θ3βοαημμ cynb $ aTOM HaipMa m pacTBOpmenb οτγοηαιοτ H3 opraHunecKoro cnoa npn ΠΟΗΜ > ΚΘΗΗΟΜ flaBneM. ΠΟΠγΗΘΗΗΜίί OCTaTOK nOflBepraiOT OHMCTKe ΧρΟΜΒΤΟΓρΒφΜΘΜ Ha ΚΟΠΟΗΚΘ c cunuKareneM m qanee nepeKpncTannn3ai4MeM M3 CMecM H-reKcaH3TnnaLieTaT. B pe3ynbiaTe nonyHaK) T 2.7 r ueneBoro προαγκτβ (οοθαμηθημθ 15). Αηοπογμηημμ očpa30M nonyHaK > T οοθαμηθημθ φορΜγπω (1):

npeflCTaBneHHbie b Tačnmie I.

CneKTpbi flMP b Ta6nnL | e I M3MepeHbi c ncnonb30BaHneM TeTpaMeTMncunaHa b KasecTBe βηυτρθηηθγο cTaHflapia. 06o3HaHeHmi cneqyiomMe: S- ομγηπθτ, d - ηγδπθτ, t - τρΜΠΠΘΤ, q- KBapieT, m- MynbTMnneT, b- mnpoKaa mma, j- KOHCTaHTa B3anMoqeficTBM5i (Γ). ΙΊ3 coeflMHeHnii, npMBefleHHbix b Ta6nmje I, npeflnoHTMTenbHbiMH COeflUHeHMflMM BBnBKDTCB ΟΟΘΑΜΗΘΗΜΗ N 1 -3, 5,9-11,16,18 ΠρΜΜβρ 3. flycT.

Tpn BecoBbie nacTM (οοθπμηθημβ 1), 40 BecoBbix nacTeii rnnHbi n 57 BecoBbix nacTeii TanbKa CMeiuneaioT m M3MenbHaioT b ποροιυοκ. npMMep 4 CMaHMBaiomniicfl ποροιυοκ. Ππα ποπγΗβΗΜΒ civiaHMBaioiuerocB nopoujKa nBTbflecaT BecoBbix HacTeii the compounds (1), 5 BecoBbix HacTeii οοπμ πμγημηουπβΦοκμοποτν 3 eecosbie nat ™ ΒΠΚΜΠΟγΠΒφΟΚΜΟΠΟ ^ Ι M 42 BeCOBbie H3CTH flUaTOMOBOM 3ΘΜΓΜ CMeillUBaiOT M M3MenbHaiOT b ποροιυοκ. LV 10744 ΠρΜΜβρ 5. fpaHynbi. flna nonyMeHnyi κομπο3μρμμ b φορΜβ rpaHyn. nsiTb BecoBbix HacTePi coeflMHeHMfl (1). 43 βθοοββιχ nacTM čeHTOHma, 45 βθοοβνχ nacieM rnnHbi m 7 BecoBbix nacieM conu nnHrnHcynb $ OKncnoTbi γομογθηηο CMemneatOT n nocne poāaBneHUUM rpHiMiPaMiPaiMe ΠρΜΜβρ 6

3MynbrnpyK) uiniicfl KOHLieHTpaT / ĻBafluaTb BecoBbix nacieii coepMHeHMn (1) 10 βθοοβνχ nacieM anKMnapMnoBoro θφπρβ nonnoKCM3TMneHCop6nTaHa m 67 Becoebix HK m. AHonorMHHbiM o6pa30M nonynaioT cocTaBbi, npepciaBneHHbie b Ta6nnue 2. ΠρΜΜβρ 11

Ha Monoflbie Bcxopbi niueHMLļbi b ciapMM BToporo riHCTa 16 pacieHMM Ha Γοριυοκ m 3 ropuiKa Ha onbīTHoii πβππΗκβ, KOTopbie BbipaiiļMBanM c ncnonb30BaHneM Herna3ypnpoBaHHbix τοριυκοΒ pnaMeipoM 10 cm, ηθηοομπμ 5 μπ Ha Γοριυοκ bophom cycneH3HM cocTaea EXAMPLE 4 flocne npocbixaHMn Ha B03joiyxe ηθηθοθηηογο pa36aBneHHoro KOHpeHTpaTa H Bcxopbi b ropiuKax HaHocnnn pa36pbi3rnBaHneM cycneH3nio πθτημχ Erysiphe graminis f. m.p. tritici KOTopbie cočnpann Ha nopa > xeHHbix nncTbax nmeHMUbi, m ropiuKM Bbipep > KHBann npM TeMnepaType ot 20 po 24 ° C b τθηθημθ 24 nacoB b ycnoBnax BbicoKoPMBiKMBiKM Ha 10 m 12 peHb nocne 3apa > xeHMB pacTpocTpaHeHMe 3a6oneBaHMn Ha Bcxopax nuieHMpbi opeHMBanM b% no ΟΤΗΟΙΡβΗΜΚ) K ΚΟΗΤρΟΠΚ) (Heo6pa60TaHHblM paCTeHHBM).

Pe3ynbTaTbi npepciaBneHbi b Ta6nnue 3. npHMep 12

Ha pacTeHHa orypqoB b CTapMM BToporo nuCTa opho pacieHMe b ropuiKe m 3 ropujKa Ha οπητηομ pennHKe, KOTopbie BbipaiuMBanM b Herna3ypnp0BaHHbix ropuuKax pnaMeTpoM 10 caHTMMeipoB, HaHOCMriM 5 μπ Ha Γοριυοκ pa36aBneHHoro cociaBa, EXAMPLE 4 Nocni cyujKM nMCTbeB Ha Ha B03pyxe HMX HaHOCMmi c noMotpbK ) kmctu onopbi Spharotheca fuliginea c nopa * eHHbix 6one3HbK > nMCTbeB orypqoB.

Hepe3 9 m 11 ρηθμ nocne 3apa > KeHnn onpepennnM Kax b npMMepe 11.

Pe3ynbTaTbi npepciaBneHbi b Ta6nnue 4. ΠρΜΜβρ 13

Ha Monopbie Bcxopbi niueHMpbi b CTapMM BToporo nMCTa no 16 pacieHMM Ha Γοριυοκ, no τρπ ropiuKa Ha οπντηομ ρβππΗκβ KOTopbie BbipaiuMBanM b

Herna3npoBaHHbix ropiuKax anaMeTpoM 10 caHTMMeTpoB, HaHOcunn pa36pbi3rnBaHneM 5 μπ Ha roprnoK pa36aBneHHoro cociaBa npMMepa 4.

Ilocne cyujKM HaHeceHHoro cociaBa na B03flyxe Ha Bcxoflbi b ropiuKax HaHocnnn pa36pbi3rnBaHneM cycneH3nio πθτημχ CNOP Puccinia recondita co6paHHbix co CMopiyeHHbix nMCTbee nmeHMUbi, m ropuiKM coqep > KanM NPH 20-23 ° C B ΤβΗβΗΜβ 24 HACOBA B yCJ10BHflX BbICOKOM BfiaJKHOCTM, Β 38ΤΘΜ rOpUJKM ΟΟΤβΒΠΑΠΜ B τθππμμθ. Hepe3 7 m 11 αηθμ nocne 3apax < eHMH onpeqenann pacnpocTpaHeHMe 3a6oneBaHna Ha pacTeHMJix nmeHMUbi (Kax b npMMepe 11) flaHHbie npeflCTaBneHbi b Ta6nMue 5. 14Π

Ha nHCTba $ aconn ο6ηκηοβθηηομ b CTaqnn nepBoro nMCTa, BbipaujeHHoPi b Herna3npoBaHHbix ropiuKax flMaMeipoM 10 cm, HaHOCMHM no 5 μπ Ha roprnoK pa36aBneHoro 4 pa36aBneHoro. Nocni npocbixaHna Ha B03qyxe HaHeceHHoro cociaBa b aempanbHOM nacTM nMCTa pacTeHMM npMKneMBanM xpyrnbiM cpe3 Arap HMaMeTpoM 4 mm, coqep > KainMM rpMČKM Botrytis cinerea, KOTopbie npeABapMTenbHO BbipaiiļMBanM β τθηθημθ τρβχ ΑΗθίί NPM 20 ° C c Mcnonb30BaHMeM arapoBOM cpeflbi, c nočaBneHMeM caxapa, coqep > KaiiļeM KapTO0enbHbiM 6ynbOH. PacTeHMa Bbiqep > KMBanM npM TeMnepaiype 20-22 ° C b ycnoBM? Ix BbicoKoii Bna > KHOCTM. Ha τρβΤΜΐί qeHb Nocni 3apaxeHMH onpenennnM CTeneHb 3a6oneBaHMn XAX b EXAMPLE 1 JHaHHbie npencTBneHbi b TaOnMue 6 ΠρΜΜβρ 15 B Ka > KflbiM Herna3MpoBaHHbiM roprnoK ρΜβΜβτροΜ 10 cm BbiceBanM 16 ceMAH pMca m Korqa paccaqa pMca nocTMrana cTajļMM 4-5 nMCTa Ha Hee HaHOCMnM pa36pbi3TMBaHMeM pa36aBneHHbiM cocTaB EXAMPLE 4 Nocni cyuiKM Ha Ha B03qyxe nMCTb * ηοηοομπμ pa36pbi3PMBaHMeM cycneH3Mio CNOP Cochliobulus miyabeanus, 3apaHee BbipameHHbix qnn stom qenM M3 pacneTa 5 μπ Ha ropujoK.nofl ΜΜκροβκοποΜ co KpaTHbiM 1500 yBenMHeHMeM b none MMKpocKona HaxoflMHM b cycneH3MM 15 CNOP γρμ6κοβ.

Cpa3y nocne 3apaxeHMn ropuiKM noMemanM b KaMepy MHOKynMpoBaHMH Ha flBa flHn b ycnoBMnx bmcokom Bnax < HOCTM npM TeMnepaType 25 ° C, nocne nero mx nepeHOCMHM b Tenn. Ha 5-ii neHb nocne 3apax < eHMn oueHMBanM 3φφβκτΜΒΗοσΠί cociaBa xax b npMMepe 11.

Pe3ynbTaTbi npeacTaBneHbi b TačnMue 7. ΠρΜΜβρ 23

OnbīTbi ηροΒΟΑΜΠΜ no μθτοαμκθ npMMepa 11, ho Mcnonb30BanM cocTaB npMMepa 6. Pe3ynbTatbi npeflCTaeneHbi b TačnMLje 8. EN 10744 npMMepbi 24

OnblTbl ΠρΟΒΟΡΜΠΜ ΠΟ ΜβΤΟΡΜΚβ npMMepa 13, HO MCn0Hb30BanM COCTaB npMMepa 6. Pe3ynbTaTbi npeacTaBneHbi b TaOnmje 9.

IlpuMepbi 25

OnblTbl npOBOflHHH ΠΟ ΜβΤΟΑΜΚβ npMMepa 11, HO MCnonb30BanM COCTaB npMMepa 9. Pe3ynbTaTbi npepcTaBneHbi b Ta6nMqe 10 ilpMMep 26

OnblTbl npOBOflM / iM no μθτοπμκθ npMMepa 13, ho Mcnonb30BanM cocTaa npMMepa 9. Pe3ynbTaTbi npeflCTaBneHbi b TaānMue 11. ΠρΜΜβρ 27

OnblTbl ηροΒορΜΠΜ no ΜβτορΜκβ npMMepa 13, ho Mcnonb30Ba / iM cocTaB npMMepa 4. Pe3ynbTaTbi npencTaBneHbi b Ta6nMue 12. ΠρΜΜβρ 28

OnbīTbi προΒορΜΠΜ from ΜβτορΜκβ npMMepa 11, ho Mcnonb30BanM cocTae npMMepa 4. Pe3ynbTaTbi npepcTaBneHbi b TačnMue 13. ΠρΜΜβρ 29

OnbīTbi προΒορΜΠΜ from ΜβτορΜκβ npMMepa 13, ho Mcnonb30BanM cocTaB npMMepa 5. Pe3ynbTaTbi npMBepeHbi b Ta6nML | e 14. ΠρΜΜβρ 30

OnblTbl npoBOflMJiM no ΜβτορΜκβ npMMepa 11, ho Mcno / ib30Ba / iM cocTaB npMMepa 5. flaHHbie npepcTaBneHbi b TaānMue 15. ΠρΜΜβρ 31

OnblTbl ηροΒορΜΠΜ no ΜβτορΜκβ npMMepa 13, ho Mcnonb30Ba / iM cocTae npMMepa 8. flaHHbie npencTaBneHbi b Ta6nnue 16. ΠρΜΜβρ 32

OnblTbl npoBOflMJiM no ΜβτορΜκβ npMMepa 14, ho Mcnonb30BanM cocTaB npMMepa 10. flaHHbie npepcTaBneHbi b TačnMue 17. ΠρΜΜβρ 33

OnblTbl npOBOflMnM no μθτοαμκθ npMMepa 13, ho Mcnonb3oeanM cocTae npMMepa 10. flaHHbie npepcTaB / ieHbi b Tafirmue 18. ΠρΜΜβρ 34

OnblTbl ηροΒορΜΠΜ no ΜβτορΜκβ npMMepa 11, ho Mcnonb30Ba / iM cocTaB npMMepa 10. flaHHbie npencTaBneHbi b TačnMue 19.

TaKMM o6pa30M BbmeneHHbie cocTaBbi oānapaioT BbicoKoti aKTMBHOCTbio npM Manbix κοΗΜβΗτρβίίΜΒχ.

Taānmļa 1 ΦΜ3ΜΚ0 - ΧΜΜΜΗΘΟΚΜΘ CBOMCTBa ΟΟΘΠΜΗΘΗΜΜ (1) Τμπ T. ππ. Οπθκτρ ΑΜΠ (ΟβΟΙβ, δ μπη.α.) ο 00 Ν- _ «Ο Ο. α > φ1 ο. 3 g ο ο »5 co ΙΟ X -ιη χ S-cn 'ο Ο -σι co ° -ΐ ΟΟ ο " & ο rX υΓ co 3 Οο CO CN ο '00 CN r- " Iο 00 X τ- cf CN Ο οο 'CO οο 00

X οο οο 00 ο cn οο " οο σ >

οο CN £; Τ- " ° -. οο " X ιό οο οο ο " CN οο 00 Ο < Ν - I CN t οη Ο

οη CN 00 II > - ^ X «Η ΟΝ 00 ο οο ο ο " ο 'όο' h > > · οο χ 'χ χ α

o " < n S Ν 'οό π S I- I m X X C0 Ν' CO οο 05 ΟΟ h- ι ο 00 co "

X X CO CN cf cf CO CNo o T- " K o co X X CO CN u (S o r-- 00 03 o " co " N- oo co oo

Xo co 0 X ΓΟΟ o, SCO - co CO N- " «X 1« 3? £ co --c cn X r- 'co) oč oo CO o ^ -r- " X - cn

X CN co cnT co -Γ c ° co co -. CN o o co 00 N- co I co oo

Xo X co o " - co co o o co

cn CN

CD (Liic., 2H), 3.60 (c, 1H), 4.20 (c, 2H), 6.93-7.50 (Μ4H) 7.97 (c, 1H), 8.17 ( c, 1H)

C X Μ cn οα α ω ο ο

ο I o I Ν 'o I N " co N · ΟΟ

CN CO X Ο οο X Οο Xο CO Xο ΟΝ co Xo oo Xo co Xo co Xo oo Xo co X o co 00

TaSnuga 1 / npoflonaceHne / co

ID

CO

CM

X X i— TT ££ co r-o - < r co " i-. '() o r-cm oo c \ i CD, «-» s, ^ X X co cd

CN CO < N ^ -oo o " o " I-- co σ > co o " X X CO 1- cS cT i-- o Γ- 00 o " co " CO co N- co m m co Xo co X o co co co f-- 'X co

X X 00 T- Shfe. cm '^ t, -c ^ X CD

X ^^ X 2 " CN u cn 7Γ TT CO CM l Γ-

Γ CM o «s co o o ° 0 T- " co " is cf 3 o o 00 O o " ^ o in τ ι 05 N " X o

00 I co X o co Xo s; X co o n- O Ι-Γ 'ί co o O [- T- co' XX CO CN (S (S s s 00 - lO co

Tf co

CD X o m N- co X o co X o co

CO co, C CD X co co X co cj 3 o, co T «oo 'co - 2-i CO < J & 8 o CO CMo " co co LO co o. M · co Xo co Xo

CD X X Γ '»n ·

O f-f- CM r- ί co Γ ια

X X & CO CM '· _ r- O, ii, CM Γ-O CO X £ co ^ o o °°. ° l o * co 'lO co T— I M · co co o_ Ν' co X o co Xo

X LO u, CM oo 'o 0o_ CN 1o CDo' X co X CM cfX co - o 3 rt | -, ^ 5®. X Γ ιο CM. cm 'Γ — o X co cf co 00 co co co X o C M " co X o co X o O its Γ- t-5 ld r- " 12 X co CM t— r co ’o3 LV 10744 4-P CH Β-ΤΜΠ 104-106 0.87 (c, 3H), 1 , 03 (c, 3H), 1.17-3.03 (μ, 8H), 4.10 (c, 2H), 6.70-7.27 (μ, 6H), 7.73 (u.c. 1H) co Xo co Xo

CM co ^ x X ™ in d < D CM CM - σ > X f *. CM_ O ^ ^ ^.-C X r I ® M ™ CM co "

Tachnug 1 / npOflonaceHMe / - -

CD

LO

CO

CM < S Sh. ^ f'-ο ® 'co' gs d3 CD 'l CD o co_ cm " (£ CM CD KX d3 XX X Tf CM ^ Ξ {S < £ Š "-S M- CO10 χ X cm; = T-" d; iīX in co CO N cnU co '^ X x CM CO £ £ «o &quot.; co " r-

CM < ^ o co co 00 CO O o " cm 't " -

1 ^ CM i CD CM c s I- i m _CM 0 1 -Μ · _ cm " co X Ū

co X O co 00 o

Xo X 1 and co X o co Xo. CD X T-

CD - -H-S " χ oo cm m

LD CD cm " 1 CD c r- o_ and "

- x and? r CM

CO l " ·· 3 CM X CO o. CM d X ^ co rt. d ° -o gN ° m o CM co co

X O

h- _CM 0 1 CM CO X o co X o

LD

co d > o ^ | 3 CM ^^ X X CM CD CJ £ o h »< Η CM_ ^ CM * ^ άϊ o. CD O II

CO

o «t CD I " - " co " ii > Xχ 'Γ. CM O, d oo w o CN co " CM ± m 9 co " 5 > - >. £ £ x '-3 d CM O Ioo _CM O I it cm " CO X o

CD New 1 - CM CM. - O X U) CD < JjŽ co " co CM? «R * - 3 o - 'T- " rf -oo " co in " * -z II M- > - co " g > d X -3 cm inoo ^ o " 3 CD τ ι 00

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00 in cm " oo CM_ cm 'X CD o oo co II M- > h- 'X So CM II d > ® X σ > cm CD d

and CM_ cm " loo CM and cd 'II > - Xco

Ifi cd cd " D D o " (? 2H), 3.60 (c, 1H), 3.99 (? 1H, Y = 14), 4.39 (? 1H, Y = 14), 6.97 (? 2H, Y = 9), 8.00 (c, 1H) 8.18 (c, 1H), 7.24 (fl 2H) Y = 9) CD r-I mi * »cs Ι Ο t co X o oo 00

Ta6nnqa 1 / προαοπμθημθ /

CO U5 O " co

CM cn co oo co co '^ co τ - < r r · -. . r-. while X > T CM i * -. σι cm < -X M C0 'r ~ CO r- · cm " (D «. Cn ®.X o ·» - ^ 3 co VO > 05 X «co, _c 5i o ·% oo r. X 3: CM ^ < = t o " CM σ > r- rr ®» II > > I x '^ CM = E ct CM σ > cm " XI CM go cm ", - CO X Tf " h- ^ _- ~ o co - x cm " ^ - 5 ο Έ co cr > K 00 oo " II > - S'i e ^ 2 S ^ to CM CMjj * - m oo ±: ffS · ® coT ^ i ^ X co c \ jn ~ «dX 5 ^ 00 co 5 · ® ®. 5co " o. o X o r- o £ Īs ® 7 i ”CO x • CM T- ^ K„ - XX lO CM 2 tS rTfe X 05 t- co o " 00 Iσ > h ~ cs ffl 0 1

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CM • 00 CO X CM T-

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Tachnnua 4

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Tanuaua 5

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Ta6nnua5 / προροπχθΗΜθ / 1 ..... _ ... 2. ________________ 3 68 125 100 69 125 100 70 125 100 71 125 100 72 125 100 73 125 100 74 125 100 75 125 90 76 125 90 ΤρΜββΜΜΘφΟΗ 125 95 (M3BeCTHblft) KOHTpOJlb 0 (6e3 οδρββοτκΜ)

Tachnmja 6

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Ta6nnqa6 / προηοπχΘΗΜβ / 1 2 3 33 500 85 37 500 100 38 500 100 39 500 75 41 500 100 42 500 100 44 500 100 45 500 100 46 500 70 47 500 60 48 500 100 49 500 100 50 500 100 54 500 100 55 500 100 56 500 95 57 500 70 58 500 70 59 500 80 60 500 80 61 500 85 62 500 100 63 500 100 64 500 80 65 500 100 66 500 60 67 500 100 68 500 60 69 500 100 70 500 65 71 500 100 72 500 100 73 500 80 74 500 60 75 500 85

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TaSnuua 7

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Tachnnua 8

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Tachnnua 9

CoeflMHeHMe N ° KoHLļeHTpaMMfl, H. Ha ΜΠΗ. 3 ammHbiū 3φφθκτ,% 1 2 3 1 125 100 2 125 95 3 125 100 4 125 95 5 125 100 9 125 100 13 125 100 14 125 100 15 125 95 16 125 100 18 125 100 23 125 100 24 125 100 29 125 100 30 125 100 33 125 100 37 .125 100 38 125 100 50 125 100 63 125 100 69 125 100 71 125 100 ΚθΗΤρθ / lb 0 0 (6e3 o6pa6oTKM)

Ta6nnua 10

CoeflMHeHMe N ° KoHueHTpaMMfl, H. Ha ΜΠΗ. 3amMTHblM ΘφφθΚΤ,% 1 2 3 1 125 100 2 125 95 3 125 100 4 125 95 5 125 100 9 125 100 13 125 95 14 125 95 15 125 100 16 125 100 18 125 100 23 125 100 24 125 100 29 125 100 30 125 100 33 125 100 37 125 100 38 125 100 50 125 100 63 125 100 69 125 100 71 125 100 KOHTponb (6e3 o6pa6oTKn) 0 0 EN 10744

Tanuaua 11 ΟοββΜΗΘΗΜβ N ° KoHMempauMfl, H. Ha ΜΠΗ. 3ammHbiii 3φφΘΚΤ,% 1 2 3 1 125 100 2 125 95 3 125 100 4 125 95 5 125 100 9 125 100 13 125 95 14 125 95 15 125 100 16 125 100 18 125 100 23 125 100 24 125 100 29 125 100 30 125 100 33 125 100 37 125 100 38 125 100 50 125 100 63 125 100 69 125 100 71 125 100 KOHTponb (6e3 oāpaāoTKM) 0 0

Ta6nnua 12

CoeflUHeHne N ° KoHuempaLiMfl, H. Ha ΜΠΗ. 3amnTHbiii 3φφθκτ,% 1 2 3 1 3 100 2 3 100 3 3 100 4 3 100 5 3 100 9 3 100 13 3 100 14 3 95 15 3 90 16 3 100 18 3 100 23 3 100 24 3 95 29 3 100 30 3 100 33 3 100 37 3 100 38 3 100 50 3 100 63 3 100 69 3 100 71 3 100 Komporib 0 0 (6e3 o6pa6oTKM) LV 10744

Danuaua 13 CoeflMHeHne fl03a, Kr / ra 3amnTHbiii θφφθκτ,% 1 3 100 2 3 100 3 3 100 4 3 100 5 3 100 9 3 100 13 3 100 14 3 95 15 3 90 16 3 100 18 3 100 23 3 100 24 3 95 29 3 100 30 3 100 33 3 100 37 3 100 38 3 100 50 3 100 63 3 100 69 3 100 71 3 100 KOHTpOnb (6Θ3 o6pa6oTKn) 0 0

Ta6nnua 14

CoennHeHne N ° KoHaempauMfl, H. Ha ΜΠΗ. 3amMTHblii 3φφθΚΤ,% 1 2 3 1 3 100 2 3 90 3 3 100 4 3 85 5 3 100 9 3 100 13 3 80 14 3 80 15 3 85 16 3 100 18 3 100 23 3 100 24 3 85 29 3 100 30 3 100 33 3 95 37 3 100 38 3 100 50 3 100 63 3 100 69 3 100 71 3 100 KOHTpOJlb 0 0 (5e3 o6pa6oTKn) LV 10744

Tanuaua 15th

CoeflMHeHne N ° KomiempauMfl, H. Ha ΜΠΗ. 3ammHbm 3φφβκτ,% 1 2 3 1 3 100 2 3 98 3 3 100 4 3 90 5 3 100 9 3 100 13 3 90 14 3 95 15 3 85 16 3 100 18 3 100 23 3 100 24 3 95 29 3 100 30 3 100 33 3 95 37 3 100 38 3 100 50 3 100 63 3 100 69 3 100 71 3 100 KoHTponb 0 0 (6e3 očpaSoTKM)

Tanuaua 16th

CoeflMHeHMe Ν ° KoHueHTpaiļMB, H. Ha ΜΠΗ. 3amMTHblM 3φφθκτ,% 7.8 15.6 1 2 3 1 100 100 3 75 100 9 100 100 16 85 90 55 90 95 Αχ / Μ3ΒΘ0ΤΗ0 / 30 70 Cxxx / Μ3ΒΘ0ΤΗ0 / 20 65 flxxxx / Μ3ΒΘ0ΤΗ0 / 0 10 X / ΟΟΘΟΜΗΘΗΜΘ Α:

χχ / CoeflMHeHne Β:

ΠροηοΓΟΚΘΗΐΊΘ κ Ta6nnLie 16 χχχ / Οοθαμηθημθ C:

χχχχ / CoeflMHeHne fl:

TaSnuua 17 Οοθαμηθημθ KoHLļeHTpaMMfl, HaCTM / ΜΠΗ 3amnTHbiii 3φφθκτ,% 13 500 100 15 500 90 48 500 100 49 500 100 p ** 500 15 (H3BeCTH0) 0 **** 500 10 (M3BeCTH0) c *** 500 30 (M3B8C) ) 500 40 ΠροοοπίΚθΗΜθ κ Tacnnue 17 χχ / CoeflMHeHne Γ:

XXX / ϋΟΘΑΜΗΘΗΜΘ C:

CI χχχχ / CoeflMHeHne Η:

Ta6nmja 18

CoeflUHeHne N ° KoHueHTpauna, H. Ha ΜΠΗ. 3aiHMTHblii 3φφθΚΤ,% 1 2 3 1 125 100 2 125 100 3 125 100 4 125 99 5 125 100 9 125 100 13 125 95 14 125 90 15 125 95 16 125 100 18 125 100 23 125 100 24 125 95 29 125 100 30 125 100 33 125 100 37 125 100 38 125 100 50 125 100 63 125 100 69 125 100 71 125 100 LV 10744

Tachnnua 19 Οοθαμηθημθ N ° KoHLteHTpauMfl, H. Ha ΜΓΙΗ. 3aiMMTHblii 3φφΘΚΤ,% 1 2 3 1 125 100 2 125 100 3 125 100 4 125 95 5 125 100 9 125 100 13 125 100 14 125 95 15 125 95 16 125 100 18 125 100 23 125 100 24 125 100 29 125 100 30 125 100 33 125 100 37 125 100 38 125 100 50 125 100 63 125 100 69 125 100 71 125 100 LV 10744

ΦΟΡΜΥΠΑ M30EPETEHMR

OyHrm4MaHblii COCTaB, COflep > KaiHMM aKTMBHbIM ΜΗφΜΡΜβΗΤ- npOM3BOflHOe 1- (a3on-1'Hn-methyl) -2-6eH3nn-Lim < noneHTaHona m LļeneByio no6aBKy, οτπμη3κμμμμοπ τθμ, hto c uenbīo yBenMHeHMn 3κτμβηοοτμ, b KanecTBe npoM3BOflHoro 1- (a3on- nn-MeTnn) -2-6eH3nn-umaioneHTaHona conep > BMD οοθρμηθημθ 0opiviynbi

b κοτοροΜ R-! m R2 - BOflopon, C1-C5 - a / iKkin, pendant ycnoBMM, hto orhh M3 3tmx pannKa / ιθΒ ηθ Βορορορ,

Xn- Bopopofl, b ποποχθημθ 2 φτορ, b ποπο > κθημθ 4 φτορ, χπορ, 6ρθΜ, C1-C4 - anKnn, Φθημπ μπμ χπορ β ποπο > κθημμ 2 μ 4 μπμ φτορ β ποπο > κθημμ 2 μ χπορ Β ποποχθημμ 4; Α - aTOM a30Ta annn CH - rpynna, npn cnepyioiMeM οοοτηοιιιθημμ κομποηθητοβ, β βθο.%: AKTMBHbIM ΜΗφΜΑΜΘΗΤ 3-50 ueneean počaBKa ocTanbHoe LV 10744 ΡΕΦΕΡΑΤ

OnMcaHbi npon3BoqHoe a3ona, npencTaBneHHoe φορΜγποΡί (1) R2 R '

b κοτοροίί R ^ m R2 οοοτβθτοτβθηηο npencTaBn «K) T cočoii anKM / ibHyfo rpynny c 1-5 yrnepopHbiMM 3τομ3μμ μπμ aTOM BOflopona; X npepcTaBniieT aTOM ramreHa, anKnnbHyio rpynny c 1-5 ymepoflHbiMM aTOMaMM wnn Φθημπβηυιο rpynny; n npeflCTaBnaeT co6oti uenoe HMcno ot 0 after 2 μ A npepcTaBnfleT οοδοίί aTOM μπμ CH npw ycnoBnn, mto R "! ηθ ββπαθτοβ 3τομομ BOflopona, ecriM R2 αβπβθτοη 3τομομ Bopopoaa; cnoco6 ποπυηθημβ npon3BOflHoro a3ona, npencTaBneHHoro φορΜγηοΡί (1); κομπο3Μ- | με prm noneBOflCTBa m caflOBOflCTBa, comep > i < aiuafl npon3BOflHoe a3ona, npencTaBneHHoii φορΜγποΡΙ (1).

Claims (1)

A fungicidal composition comprising the active ingredient 1- (azol-1-yl-methyl) -2-benzylcyclopentanol derivative and a target additive, characterized in that, in order to increase its activity, the fungicidal composition is as 1- (azol-1-yl-). the methyl) -2-benzyl-cyclopentanol derivative contains a compound of the formula wherein R ¹ and R ² are hydrogen, C 1-5 alkyl, with the proviso that R ¹ and R ² are not simultaneously hydrogen; Xn is a hydrogen atom, but if it is in the 2 nd position a fluorine atom, In position 4, fluorine, chlorine, bromine, C 1-4 alkyl or phenyl, or chlorine in position 2 and 4, or fluorine in position 2 and chlorine in position 4; A is nitrogen, allyl, CH-, with the following percentages by weight of components: active ingredient - 3-50 additives - rest.