LU84957A1 - PVC floor covering material - with smooth and matt zones formed using polymerisation initiators with differential curing conditions - Google Patents
PVC floor covering material - with smooth and matt zones formed using polymerisation initiators with differential curing conditions Download PDFInfo
- Publication number
- LU84957A1 LU84957A1 LU84957A LU84957A LU84957A1 LU 84957 A1 LU84957 A1 LU 84957A1 LU 84957 A LU84957 A LU 84957A LU 84957 A LU84957 A LU 84957A LU 84957 A1 LU84957 A1 LU 84957A1
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- LU
- Luxembourg
- Prior art keywords
- zone
- initiators
- coating
- different
- carried out
- Prior art date
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
- D06N7/0028—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by colour effects, e.g. craquelé, reducing gloss
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/20—Applying plastic materials and superficially modelling the surface of these materials
- B44C1/205—Applying plastic materials and superficially modelling the surface of these materials chemical modelling
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
- D06N7/0007—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by their relief structure
- D06N7/0013—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by their relief structure obtained by chemical embossing (chemisches Prägen)
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
- D06N7/0007—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by their relief structure
- D06N7/0023—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by their relief structure obtained by physical means, e.g. differential heating or differential irradiation; masking certain areas during treating
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
«"
PROCEDE DE MATIFICATION LOCALE DE REVETEMENTS SYNTHETIQUESMETHOD FOR LOCAL MATIFICATION OF SYNTHETIC COATINGS
ET PRODUITS OBTENUS.AND PRODUCTS OBTAINED.
La présente addition concerne des variantes opératoires au procédé décrit dans la demande principale.The present addition relates to operating variants of the process described in the main application.
5 Dans cette demande, on décrit un procédé destiné à obtenir des zones mates et des zones lisses sur un revêtement synthétique, caractérisé en ce qu'on dépose sur un support moussable ou non, dans une première zone, au moins ! une enduction ou impression contenant au moins un initia- 10 teur radiatif de polymérisation et, dans une deuxième zone qui peut éventuellement comprendre partiellement la I: première zone, au moins une enduction à base de monomère 1' réticulable ·, en ce qu'on effectue une prégélification et au moins localement un grainage ; en ce qu'on polymérise ; 15 le revêtement de la première zone par initiation sous un rayonnement afin de fixer son aspect et en ce qu'on effectue ensuite un gélification qui, causant la fluidification du vernis, provoque la disparition de l'aspect graine dans la zone non réticulée et éventuellement une • 20 expansion.5 In this application, a method is described intended to obtain matt and smooth areas on a synthetic coating, characterized in that it is deposited on a foamable support or not, in a first area, at least! a coating or impression containing at least one radiative polymerization initiator and, in a second zone which may optionally partially comprise the I: first zone, at least one coating based on crosslinkable monomer 1, in that performs a pre-gelation and at least locally a graining; in that it polymerizes; 15 the coating of the first zone by initiation under radiation in order to fix its appearance and in that a gelation is then carried out which, causing the thinning of the varnish, causes the disappearance of the seed appearance in the non-crosslinked zone and possibly an • 20 expansion.
i·i ·
Selon la présente addition, afin de faciliter les opérations de production du revêtement de sols ou de | murs et pouvoir initier différentiellement les étapes de ji réticulation, il est prévu que ladite deuxième zone peut i' 25 être initiée directement ou par l'intermédiaire d'un agent de transfert énergétique par voie radiative, de manière que chacune des initiations puisse être déclenchée par un effet physico-chimique qui lui est propre. De . cette manière, il devient possible de séparer les initia- 30 tions de polymérisation dans les zones en question en fonction des initiateurs et/ou des effets physico-chimiques d'initiation utilisés de telle sorte que l'énergie d'initiation de. polymérisation apportée par voie radiativ-e dans une première zone ne puisse initier la 35 polymérisation de l'autre zone.According to the present addition, in order to facilitate the operations of producing the floor covering or | walls and to be able to initiate the crosslinking steps differently, it is intended that said second zone can i 'be initiated directly or via an energy transfer agent by radiative way, so that each of the initiations can be triggered by its own physicochemical effect. From. in this way, it becomes possible to separate the polymerization initiations in the areas in question depending on the initiators and / or the physicochemical initiation effects used so that the initiation energy. polymerization brought radiatively into a first zone cannot initiate the polymerization of the other zone.
Cette séparation des effets permet donc de po-| lymériser une zone et de fixer son aspect puis de poly-w mériser la deuxième zone sans altérer l'aspect de la pre- 2 » mière zone.This separation of effects therefore makes it possible to | lymerize an area and fix its appearance then poly-w merize the second area without altering the appearance of the first area.
Avantageusement, l'initiation de polymérisation de la deuxième zone par voie radiative directe ou par l'intermédiaire d'un agent de transfert énergétique peut 5 etre effectuée par un rayonnement X ou par un faisceau d'électrons.Advantageously, the initiation of polymerization of the second zone by direct radiative route or by means of an energy transfer agent can be carried out by X-ray radiation or by an electron beam.
Afin que l’agent de transfert énergétique puisse exercer pleinement son effet, celui-ci doit agir sur un produit pour lequel une mobilité suffisante du monomère réticulable est assurée.In order for the energy transfer agent to be able to fully exert its effect, it must act on a product for which sufficient mobility of the crosslinkable monomer is ensured.
Cette condition est la mieux réalisée du point : de vue industriel à chaud en soumettant le produit dans ; " un four, de préférence le four dans lequel on réalise de manière classique la gélification et/ou l'expansion éven-15 tuelle ou immédiatement à la sortie de ce four quand le produit est encore à une température suffisante.This condition is best achieved from the industrial point of view of hot by subjecting the product to; "An oven, preferably the oven in which gelation and / or expansion is carried out in the conventional manner or immediately upon exiting this oven when the product is still at a sufficient temperature.
De cette manière, on peut provoquer la polymérisation dans la première zone par les techniques décrites dans le brevet principal et ensuite la polymérisation \ 20 dans la deuxieme zone par les moyens physico-chimiques t | adéquats, et ceci sans modifications importantes des lig- f nés de production de revêtement de sol existantes.In this way, the polymerization in the first zone can be brought about by the techniques described in the main patent and then the polymerization in the second zone by the physicochemical means t | without significant modifications to existing flooring production lines.
f On choisira bien entendu les différents effets • d'initiation utilisés dans les zones respectives de ma- 25 . nière à pouvoir disposer d'effets initiatifs suffisamment différents pour obtenir l'effet souhaité. A titre d'exemple, il pourrait être difficile de maîtriser une opération dans laquelle deux initiateurs UV différents,f We will of course choose the different initiation effects used in the respective areas of ma- 25. denial of having sufficiently different initial effects to obtain the desired effect. For example, it could be difficult to master an operation in which two different UV initiators,
i c'est-à-dire déclenchés par des plages de radiations UVi i.e. triggered by ranges of UV radiation
30 differentes, seraient utilises car la séparation des effets dans le spectre UV serait difficile à réaliser.30 different would be used because the separation of the effects in the UV spectrum would be difficult to achieve.
Les monomères utilisés, les techniques d'application localisées dans les différentes zones et, de manière générale, l'ensemble du processus technologique est identique, mutatis mutandis à ce qui a été décrit dans le brevet principal.The monomers used, the application techniques located in the different zones and, in general, the whole technological process is identical, mutatis mutandis to what has been described in the main patent.
V? h ’ : 3 φ ;ί La technique à mettre en oeuvre pour réaliser l'initiation dans ladite deuxième zone par voie t radiative en utilisant comme monomère le triméthyl- acrylate de triméthylolpropane peut être celle décrite I 5 par exemple par Salmon et Loan J. Appl. Polym. Sei., 16, i 671 (1972) » : y Γ- i';,!V? h ': 3 φ; ί The technique to be used to carry out initiation in said second zone by the radiative t route using trimethyl trimethylolpropane trimethyl acrylate as monomer can be that described I 5 for example by Salmon and Loan J. Appl. Polym. Sci., 16, i 671 (1972) ”: y Γ- i ';,!
Iv,.Iv ,.
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Claims (9)
Priority Applications (30)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
LU84957A LU84957A1 (en) | 1983-08-11 | 1983-08-11 | PVC floor covering material - with smooth and matt zones formed using polymerisation initiators with differential curing conditions |
IE968/84A IE55252B1 (en) | 1983-04-25 | 1984-04-18 | Process for the local matting of synthetic coverings and products obtained |
NO841604A NO164646C (en) | 1983-04-25 | 1984-04-18 | PROCEDURE FOR INCLUDING MATT AND GLOSSARY ZONES ON A SYNTHETIC COAT. |
IE967/84A IE55251B1 (en) | 1983-04-25 | 1984-04-18 | Process for the local matting of synthetic coverings and products obtained |
NO841605A NO164647C (en) | 1983-04-25 | 1984-04-18 | PROCEDURE FOR AA TO GET MATS AND GLOSSY ZONES ON A SYNTHETIC COAT. |
IT8420662A IT1209533B (en) | 1983-04-25 | 1984-04-20 | LOCAL OPACIZATION PROCEDURE OF SYNTHETIC COATINGS, PRODUCTS OBTAINED. |
IT8420663A IT1209535B (en) | 1983-04-25 | 1984-04-20 | PROCEDURE FOR OBTAINING MATT AREAS ON SYNTHETIC COATINGS AND RELATED PRODUCTS OBTAINED. |
AT84104555T ATE28761T1 (en) | 1983-04-25 | 1984-04-21 | PROCESSES FOR LOCAL MATTING OF SYNTHETIC COATINGS AND THE PRODUCTS OBTAINED IN THE WAY. |
EP84104554A EP0126314B1 (en) | 1983-04-25 | 1984-04-21 | Process for locally matting synthetic coatings, and products obtained |
EP84104555A EP0123308B1 (en) | 1983-04-25 | 1984-04-21 | Process for locally matting synthetic coatings, and products obtained |
DE8484104555T DE3465208D1 (en) | 1983-04-25 | 1984-04-21 | Process for locally matting synthetic coatings, and products obtained |
DE8484104554T DE3465354D1 (en) | 1983-04-25 | 1984-04-21 | Process for locally matting synthetic coatings, and products obtained |
AT84104554T ATE28910T1 (en) | 1983-04-25 | 1984-04-21 | PROCESSES FOR LOCAL MATTING OF SYNTHETIC COATINGS AND THE PRODUCTS OBTAINED. |
GR74484A GR81939B (en) | 1983-04-25 | 1984-04-24 | |
PT78481A PT78481B (en) | 1983-04-25 | 1984-04-24 | PROCESS FOR LOCAL MATIFICATION OF SYNTHETIC COATINGS |
CA000452584A CA1251764A (en) | 1983-04-25 | 1984-04-24 | Selectively depositing polymerization initiator and applying crosslinkable monomer on coated support for covering |
FR8406410A FR2544634B1 (en) | 1983-04-25 | 1984-04-24 | METHOD FOR LOCAL MATIFICATION OF SYNTHETIC COATINGS AND PRODUCTS OBTAINED |
JP59081245A JPH0615233B2 (en) | 1983-04-25 | 1984-04-24 | Localized surface roughening method for synthetic coatings |
GR74485A GR81940B (en) | 1983-04-25 | 1984-04-24 | |
PT78482A PT78482B (en) | 1983-04-25 | 1984-04-24 | PROCESS FOR LOCAL MATIFICATION OF SYNTHETIC COATINGS |
CA000452583A CA1251763A (en) | 1983-04-25 | 1984-04-24 | Selectively depositing polymerization initiator and applying crosslinkable monomer on coated support for covering |
FR8406411A FR2544635B1 (en) | 1983-04-25 | 1984-04-24 | METHOD FOR LOCAL MATIFICATION OF SYNTHETIC COATINGS AND PRODUCTS OBTAINED |
ES532396A ES532396A0 (en) | 1983-04-25 | 1984-04-25 | PROCEDURE FOR OBTAINING MATTE ZONES AND SMOOTH ZONES IN A SYNTHETIC COATING |
DK206984A DK168744B1 (en) | 1983-04-25 | 1984-04-25 | Method for local matting of synthetic coatings |
US06/603,842 US4617222A (en) | 1983-04-25 | 1984-04-25 | Process for obtaining areas of distinctive appearance on synthetic coverings and the product derived therefrom |
DK206884A DK168743B1 (en) | 1983-04-25 | 1984-04-25 | Method for local matting of synthetic coatings |
US06/603,843 US4608294A (en) | 1983-04-25 | 1984-04-25 | Process for obtaining areas of distinctive appearance on synthetic coverings and the product derived therefrom |
ES532397A ES8503574A1 (en) | 1983-04-25 | 1984-04-25 | Process for locally matting synthetic coatings, and products obtained. |
US07/096,348 USRE33069E (en) | 1983-04-25 | 1987-09-11 | Process for obtaining areas of distinctive appearance on synthetic coverings and the product derived therefrom |
US07/096,642 USRE33599E (en) | 1983-04-25 | 1987-09-11 | Process for obtaining areas of distinctive appearance on synthetic coverings and the product derived therefrom |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
LU84957 | 1983-08-11 | ||
LU84957A LU84957A1 (en) | 1983-08-11 | 1983-08-11 | PVC floor covering material - with smooth and matt zones formed using polymerisation initiators with differential curing conditions |
Publications (1)
Publication Number | Publication Date |
---|---|
LU84957A1 true LU84957A1 (en) | 1985-04-24 |
Family
ID=19730133
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
LU84957A LU84957A1 (en) | 1983-04-25 | 1983-08-11 | PVC floor covering material - with smooth and matt zones formed using polymerisation initiators with differential curing conditions |
Country Status (1)
Country | Link |
---|---|
LU (1) | LU84957A1 (en) |
-
1983
- 1983-08-11 LU LU84957A patent/LU84957A1/en unknown
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