KR970707249A - Flat structures made of renewable materials - Google Patents

Flat structures made of renewable materials

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Publication number
KR970707249A
KR970707249A KR1019970703261A KR19970703261A KR970707249A KR 970707249 A KR970707249 A KR 970707249A KR 1019970703261 A KR1019970703261 A KR 1019970703261A KR 19970703261 A KR19970703261 A KR 19970703261A KR 970707249 A KR970707249 A KR 970707249A
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KR
South Korea
Prior art keywords
layer
flat structure
coating
weight
coating layer
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Application number
KR1019970703261A
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Korean (ko)
Inventor
자빈네 에딩거
디트마르 슐츠
수잔네 바음가르트너
베른트 카스틀
후랑크 마우러
Original Assignee
닥터 베른트 에프 펠츠, 빌헬름 슈테플
데엘베 악취언 게젤샤프트
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Publication of KR970707249A publication Critical patent/KR970707249A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/38—Layered products comprising a layer of synthetic resin comprising epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/32—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed at least two layers being foamed and next to each other
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/08—Epoxidised polymerised polyenes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D171/02—Polyalkylene oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)

Abstract

본 발명은 적어도 하나의 캐리어층(Ⅰ)과 적어도 하나의 투명피복층(Ⅱ)과; 캐리어층(Ⅰ)아래에 배치되어 화학적으로 또는 기계적으로 포말화된 포말층으로 만들어진 선택적 배면층과; 캐리어층(Ⅰ)과 피복층(Ⅱ) 사이 및 또는 캐리어층(Ⅰ)과 배면층(Ⅲ) 사이에 배치된 선택적 콤펙트층 또는 프라이밍 코팅층(초벌코팅층)(Ⅳ)으로 구성된 평편 구조물을 제공하는 것을 목적으로 하며, 그중에서 상기 층들(Ⅱ), (Ⅲ), (Ⅳ)을 위한 코팅화합물들은 a) 2 내지 6탄소원자를 함유하는 다가 지방족 앨콜들을 가지는 C8내지 C22의 사슬길이를 가지며 평균상으로 매 분자당 하나의 에폭시그룹 이상을 함유하는 불포화지방산들의 에스테르들의 에폭시화된 제품들과; (b) 매 분자당 적어도 하나의 자유 카르복실 그룹과 이중본드(Double bond)를 함유하는 폴리에테르폴리올들을 가지는 폴리카르복실산들의 부-에스테르(Sub-esters)와; c) 선택적으로, 하이드로포빙 제재; 및 d) 선택적으로, 충진제들, 안료들, 확장제들 및 보조물질들로 구성된 그룹으로부터의 또 다른 첨가물들의 조합으로부터 제조될 수 있으며, 이들 중 성분 (a) 및 (b) 는 0.33 : 1 내지 3.15 : 1의 중량비로, 특히 0.6 : 1 내지 1 : 1.4의 중량비로 채용되는 것을 특징으로 한다.The present invention provides at least one carrier layer (I) and at least one transparent coating layer (II); An optional backing layer disposed below the carrier layer (I) and made of a chemically or mechanically foamed foam layer; It is an object to provide a flat structure composed of an optional compact layer or priming coating layer (primary coating layer) (IV) disposed between the carrier layer (I) and the coating layer (II) or between the carrier layer (I) and the back layer (III). Wherein the coating compounds for the layers (II), (III) and (IV) have a chain length of C 8 to C 22 having a polyvalent aliphatic alcohol containing 2 to 6 carbon atoms Epoxidized products of esters of unsaturated fatty acids containing at least one epoxy group per molecule; (b) sub-esters of polycarboxylic acids having polyetherpolyols containing at least one free carboxyl group and a double bond per molecule; c) optionally, a hydrofoaming agent; And d) optionally, a combination of fillers, pigments, extenders and further additives from the group consisting of auxiliaries, wherein components (a) and (b) are 0.33: 1 to 3.15 It is characterized by being employed in a weight ratio of 1: 1, in particular in a weight ratio of 0.6: 1 to 1: 1.4.

Description

재생가능한 재료로된 평편 구조물Flat structures made of renewable materials

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

제1도는 본 발명에 의한 평면 구조물의 일실시예를 나타내는 도면이다.1 is a view showing an embodiment of a planar structure according to the present invention.

Claims (18)

적어도 하나의 캐리어층(Ⅰ)과; 적어도 하나의 투명 피복층(Ⅱ)과; 캐리어층(Ⅰ)아래에 배치되어 화학적 또는 기계적으로 포말화된 포말층으로 만들어진 선택적 배면층과(Ⅲ)과; 캐리어층(Ⅰ)과 피복측(Ⅱ) 사이 및/또는 캐리어층(Ⅰ)과 배면층(Ⅲ) 사이에 배치된 선택적 콤팩트 또는 프라이밍 코팅층(Ⅳ)으로 구성되어지되, 상기 층들(Ⅱ), (Ⅲ), (Ⅳ)을 위한 코팅화합물들은 : a) 2 내지 6탄소원자를 함유하는 다가 지방족 앨콜들을 가지는 C8내지 C22의 사슬길이를 가지며 평균상으로 매 분자당 하나의 에폭시그룹 이상을 함유하는 불포화지방산들의 에스테르들의 에폭시화된 제품들과; b) 매 분자당 적어도 하나의 자유 카르복실 그룹과 이중 본드를 함유하는 폴리에테르폴리올들을 가지는 폴리카르복실산들의 부-에스테르와; c) 선택적으로, 하이드로포빙 제재와; d) 선택적으로, 충진제들, 안료들, 확장제들 및 보조 물질들로 구성된 그룹으로부터의 또 다른 첨가물들과; 로 이루어진 조합으로부터 제조 가능하며 이들중 성분 (a) 및 (b)는 0.6 : 1 내지 1 : 1.4의 중량비로 채용되는 것을 특징으로 하는 평편 구조물.At least one carrier layer (I); At least one transparent coating layer (II); An optional backing layer (III) disposed below the carrier layer (I) and made of a chemically or mechanically foamed foam layer; Consisting of an optional compact or priming coating layer (IV) disposed between the carrier layer (I) and the covering side (II) and / or between the carrier layer (I) and the back layer (III), wherein the layers (II), ( Coating compounds for III) and (IV) are: a) chain lengths of C 8 to C 22 with polyvalent aliphatic alcohols containing 2 to 6 carbon atoms and on average containing at least one epoxy group per molecule Epoxidized products of esters of unsaturated fatty acids; b) a sub-ester of polycarboxylic acids having polyetherpolyols containing at least one free carboxyl group and a double bond per molecule; c) optionally, a hydrofoaming agent; d) optionally, further additives from the group consisting of fillers, pigments, extenders and auxiliary materials; It can be produced from a combination consisting of a flat structure, characterized in that the components (a) and (b) are employed in a weight ratio of 0.6: 1 to 1: 1.4. 제1항에 있어서, 화학적 엠보싱을 위하여 상기 피복층(Ⅱ)아래에 화학적 포말층(Ⅴ)이 형성되어 있는 것을 특징으로 하는 평편 구조물.The flat structure according to claim 1, wherein a chemical foam layer (V) is formed under the coating layer (II) for chemical embossing. 제1항 또는 제2항에 있어서, 불포화, 경화가능한 락카 방식들의 보호층(Ⅵ)은 피복층위에 배치되고, 그중에 락카 방식들을 위한 폴리머들 또는 코폴리머들은 폴리아크릴레이트들, 폴리메타아크릴레이트들, 폴리우레탄들 및 그 혼합물들의 그룹으로부터 선택된 것을 특징으로 하는 평편 구조물.3. The protective layer (VI) of the unsaturated, curable lacca schemes is disposed on the coating layer, wherein the polymers or copolymers for the lacca schemes are polyacrylates, polymethacrylates, A flat structure characterized in that it is selected from the group of polyurethanes and mixtures thereof. 제1항에 있어서, 상기 성분 b)의 폴리카르복실산은 2 내지 10탄소원자를 포함하는 것을 특징으로 하는 평편 구조물.2. The flat structure of claim 1, wherein the polycarboxylic acid of component b) comprises from 2 to 10 carbon atoms. 제4항에 있어서, 상기 폴리카르복실산은 디카르복실산인 것을 특징으로 하는 평편 구조물.The flat structure of claim 4, wherein the polycarboxylic acid is dicarboxylic acid. 제1항 내지 제5항에 있어서, 상기 디카르복실산은 이타코닉산, 말레인산, 푸마린산, 그들의 무수화물들 및 그들의 혼합물들로 구성된 그룹으로부터 선택된 어느 하나인 것을 특징으로 하는 평편 구조물.6. The flat structure of claim 1, wherein the dicarboxylic acid is any one selected from the group consisting of itaconic acid, maleic acid, fumaric acid, their anhydrides and mixtures thereof. 7. 제1항 내지 제6항에 있어서, 12 내지 34중량퍼센트의 하이드로포빙 제제가 에폭시화된 오일 및 반-에스테르에 대하여, 피복층(Ⅱ)을 위한 화합물속에 함유된 것을 특징으로 하는 평편 구조물.7. The flat structure of claim 1, wherein 12 to 34 weight percent of the hydrofoaming formulation is contained in the compound for coating layer (II), relative to the epoxidized oil and semi-ester. 제1항 내지 제7항에 있어서, 2중량퍼센트 이하의 충전제가 피복층을 위한 코팅화합물속에 함유된 것을 특징으로 하는 평편 구조물.8. The flat structure of claim 1, wherein up to 2 percent by weight of filler is contained in the coating compound for the coating layer. 제1항 내지 제7항에 있어서, 20 내지 50중량퍼센트의 충전제, 특히 40중량퍼센트의 충전제가, 에폭시화된 오일 및 반-에스테르에 대하여, 콤팩트층 또는 프라이밍 코팅층을 위한 코팅 화합물속에 함유된 것을 특징으로 하는 평편 구조물.The process according to claim 1, wherein 20 to 50 percent by weight of filler, in particular 40 percent by weight, is contained in the coating compound for the compact or priming coating layer, for epoxidized oils and semi-esters. Characterized in that the flat structure. 제1항 내지 제6항에 있어서, 60 내지 100중량퍼센트의 충전제, 특히 80중량퍼센트의 충전제가, 에폭시화된 오일 및 반-에스테르에 대하여, 화학적으로 포말화된 포말층(Ⅴ)을 위한 코팅 화합물속에 함유된 것을 특징으로 하는 평편 구조물.The coating for foam layer (V) according to claims 1 to 6, wherein 60 to 100% by weight of the filler, in particular 80% by weight, of the filler is chemically foamed against epoxidized oils and semi-esters. Flat structure, characterized in that contained in the compound. 제1항 내지 제6항에 있어서, 10중량퍼센트까지의 충전제가 에폭시화된 오일 및 반-에스테르에 대하여, 기계적으로 포말화된 포말층을 위한 코팅화합물속에 존재하는 것을 특징으로 하는 평편 구조물.The flat structure of claim 1, wherein up to 10 percent by weight of the filler is present in the coating compound for the mechanically foamed foam layer, relative to the epoxidized oil and semi-ester. 제1항 내지 제11항에 있어서, 아크릴레이트들, 폴리메틸메타아크릴레이트들, 아마인유, 경화촉진제들, 포말화 제제들의 그룹으로부터의 기타 처리-조정된 보조물들 및 폴리올들, 요소, 아연, 납 또는 카드뮴 화합들의 그룹으로부터의 킥커들이 15중량퍼센트까지의 양으로 코팅화합물들속에 존재하는 것을 특징으로 하는 평편 구조물.12. The process according to claim 1, wherein the polyols, urea, zinc, acrylates, polymethylmethacrylates, linseed oil, hardeners, other processing-adjusted aids from the group of foaming agents. Wherein the kickers from the group of lead or cadmium compounds are present in the coating compounds in an amount of up to 15 weight percent. 제1항 내지 제6항, 제10항 또는 제12항에 있어서, 상기 에폭시화된 오일 및 반-에스테르에 대하여, 포말화 제제의 15중량퍼센트까지가 화학적으로 포말화된 포말층(Ⅴ)을 위한 코팅화합물속에 함유된 것을 특징으로 하는 평편 구조물.The foam layer (V) according to claim 1, wherein up to 15% by weight of the foaming agent, based on the epoxidized oil and semi-ester, Flat structure, characterized in that contained in the coating compound for. 제1항 내지 제13항에 있어서, 상기 에폭시화된 오일 및 반-에스테르에 대하여 10-1% 내지 10-2%의 건조제가 피복층을 위한 코팅화합물속에 존재하는 것을 특징으로 하는 평편 구조물.14. Flat structure according to claim 1, characterized in that 10-1% to 10-2% desiccant is present in the coating compound for the coating layer relative to the epoxidized oil and semi-ester. 제14항에 있어서, 상기 평편구조물은 AL, Li, Ca, Fe, Mg, Mn, Pb, Zn, Zr, Ce, Co의 금속들을 개별적으로 함유하거나 또는 그의 혼합물들의 화합물들을 함유하는 것을 특징으로 하는 평편 구조물.15. The method of claim 14, wherein the flat structure individually contains metals of AL, Li, Ca, Fe, Mg, Mn, Pb, Zn, Zr, Ce, Co or compounds of mixtures thereof. Flat structures. 제1항 내지 제13항에 있어서, 쵸크, 황산 바륨, 규산, 카올린, 활석 또는 톱밥, 코르트 먼지, 유리, 직물 또는 유리섬유들 또는 공장섬유들로부터의 광물 충전제들은 코팅 화합물속에 함유하거나 또는 충전제들로서 코팅화합물들로 가공되는 것을 특징으로 하는 평편 구조물.The mineral fillers according to claim 1, wherein the mineral fillers from chalk, barium sulfate, silicic acid, kaolin, talc or sawdust, cort dust, glass, textile or glass fibers or plant fibers are contained in the coating compound or Flat structures characterized in that they are processed into coating compounds. 제1항 내지 제7항에 있어서, 폴리에틸렌 왁스, 피셔-트롭쉬 경질 파라핀들, 동물 왁스들, 공장 왁스들 또는 광물 왁스들이 하이드로포빙 제제로서 존재하는 것을 특징으로 하는 평편 구조물.8. The flat structure of claim 1, wherein polyethylene wax, Fischer-Tropsch hard paraffins, animal waxes, factory waxes or mineral waxes are present as hydrofoaming formulations. 제1항 내지 제17항에 있어서, 상기 구조물은 플로어 피복체들 또는 타일인 것을 특징으로 하는 평편 구조물.18. Flat structure according to claim 1, wherein the structure is floor coverings or tiles. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019970703261A 1994-11-15 1995-11-15 Flat structures made of renewable materials KR970707249A (en)

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DE19906832C2 (en) * 1999-02-18 2003-06-26 Dlw Ag Continuous process for the production of a crosslinked binder based on unsaturated fatty acids and / or fatty acid esters, the binder and its use
DE19934036A1 (en) * 1999-07-21 2001-01-25 Dlw Ag Production of a flat article for use as a floor covering, comprises pre-crosslinking a mixture of an epoxidizing product of carboxylic acid ester(s) with crosslinker(s), molding to give flat surface and curing using second agent
DE10126122C2 (en) * 2001-05-29 2003-05-15 Armstrong Dlw Ag Flexible flooring with a regenerative, dirt-repellent surface
DE102006055398A1 (en) * 2006-11-22 2008-05-29 Dracowo Forschungs- Und Entwicklungs Gmbh Lining material based on native epoxide, where the material is constructed multilayerly and the material layer is bounded by an epoxide resin intermediate layer from native epoxide resin
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