KR970042612A - Method for Improvement of Fluidized Bed Reaction System Using Unsupported Catalyst. - Google Patents

Method for Improvement of Fluidized Bed Reaction System Using Unsupported Catalyst. Download PDF

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Publication number
KR970042612A
KR970042612A KR1019960066625A KR19960066625A KR970042612A KR 970042612 A KR970042612 A KR 970042612A KR 1019960066625 A KR1019960066625 A KR 1019960066625A KR 19960066625 A KR19960066625 A KR 19960066625A KR 970042612 A KR970042612 A KR 970042612A
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KR
South Korea
Prior art keywords
fluidized bed
reactor
improvement
reaction system
bed reaction
Prior art date
Application number
KR1019960066625A
Other languages
Korean (ko)
Inventor
그레고리 구디 마크
쿠티스 윌리엄즈 클라크
제임스 쉬렉 데이비드
토드 웬젤 티모시
Original Assignee
카렌 존슨-위진즈
유니온 카바이드 케미칼스 앤드 플라스틱스 테크놀로지 코포레이션
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Publication date
Application filed by 카렌 존슨-위진즈, 유니온 카바이드 케미칼스 앤드 플라스틱스 테크놀로지 코포레이션 filed Critical 카렌 존슨-위진즈
Publication of KR970042612A publication Critical patent/KR970042612A/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

본 발명은 재순환 스트리임을 그것의 이슬점 이하로 냉각시키고 그 결과 생성된 두개-상을 가지는 스트리임을 반응기로 되돌아가게 하여 재순환 스트리임의 이슬점 이상의 바람직한 온도로 유동 베드를 유지시키도록 함으로써 발열 중합 반응을 이용한는 유동층 반응기에서 중합체 생성의 공시 수득량을 중가시키기 위한 공정에 관한 것이다.The present invention utilizes an exothermic polymerization reaction by cooling the recycle stream below its dew point and returning the resulting bi-phase stream to the reactor to maintain the fluidized bed at a desired temperature above the dew point of the recycle stream. It relates to a process for weighting the published yield of polymer production in a reactor.

Description

비담지된 촉매를 이용한 유동 베드 반응 시스템의 개선방법.Method for Improvement of Fluidized Bed Reaction System Using Unsupported Catalyst.

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (1)

반응조건하에서 비담지된 용해성 촉매가 존재하는 기체상 반응기를 통과하는 기체 스트리임을 연속적으로 통과시키고, 중합체 생성물 및 미반응 유동체를 제거하고, 기체와 포집된 액체의 두개-상을 가지는 혼합물을 형성하도록 상기 미반응 유동체중 일부분 또는 모두를 냉각시키고, 상기 중합되어 생성물로서 제거되는 그러한 단량체를 보충하기 위하여 충분한 부가적 단량체와 함께 상기 두개-상을 가지는 혼합물을 상기 반응기에 재도입시킴으로써 하나 또는 그 이사의 유동체 단량체로 부터 기체상 반응기에서 중합체를 생성시키고, 냉각단계를 포함하여 개선된 것을 특징으로 하는 연속 공정.Under reaction conditions to continuously pass a gas stream through a gas phase reactor in which an unsupported soluble catalyst is present, remove the polymer product and unreacted fluid, and form a two-phase mixture of gas and trapped liquid Cooling one or both of the unreacted fluids and reintroducing the two-phase mixture into the reactor with sufficient additional monomers to replenish such monomers that are polymerized and removed as product Continuous process, characterized in that the polymer is produced from a fluid monomer in a gas phase reactor, including the cooling step.
KR1019960066625A 1995-12-18 1996-12-17 Method for Improvement of Fluidized Bed Reaction System Using Unsupported Catalyst. KR970042612A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US868395P 1995-12-18 1995-12-18
US60/008.683 1995-12-18

Publications (1)

Publication Number Publication Date
KR970042612A true KR970042612A (en) 1997-07-24

Family

ID=21733077

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960066625A KR970042612A (en) 1995-12-18 1996-12-17 Method for Improvement of Fluidized Bed Reaction System Using Unsupported Catalyst.

Country Status (7)

Country Link
KR (1) KR970042612A (en)
AU (1) AU7541196A (en)
BR (1) BR9606061A (en)
CA (1) CA2193147A1 (en)
HU (1) HUP9603501A3 (en)
TW (1) TW503244B (en)
ZA (1) ZA9610606B (en)

Also Published As

Publication number Publication date
BR9606061A (en) 1998-09-01
AU7541196A (en) 1997-06-26
TW503244B (en) 2002-09-21
ZA9610606B (en) 1998-09-18
CA2193147A1 (en) 1997-06-19
HUP9603501A3 (en) 1999-05-28
HU9603501D0 (en) 1997-02-28
HUP9603501A2 (en) 1998-06-29

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