KR970021499A - Spin Finish for Synthetic Fibers and Synthetic Fibers Treated with the Spin Finish - Google Patents

Spin Finish for Synthetic Fibers and Synthetic Fibers Treated with the Spin Finish Download PDF

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KR970021499A
KR970021499A KR1019960043590A KR19960043590A KR970021499A KR 970021499 A KR970021499 A KR 970021499A KR 1019960043590 A KR1019960043590 A KR 1019960043590A KR 19960043590 A KR19960043590 A KR 19960043590A KR 970021499 A KR970021499 A KR 970021499A
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synthetic fibers
spin finish
fibers according
organic carboxylic
carboxylic acid
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KR1019960043590A
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Korean (ko)
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히로시 요시다
이치로 오자키
슈우스케 사카이
미사오 요시미
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가케히 데츠오
산요우가 세이고교 가부시키가이샤
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Priority claimed from JP29050795A external-priority patent/JP2852891B2/en
Priority claimed from JP29050695A external-priority patent/JP2852890B2/en
Application filed by 가케히 데츠오, 산요우가 세이고교 가부시키가이샤 filed Critical 가케히 데츠오
Publication of KR970021499A publication Critical patent/KR970021499A/en

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D01D5/096—Humidity control, or oiling, of filaments, threads or the like, leaving the spinnerettes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/41—Amides derived from unsaturated carboxylic acids, e.g. acrylamide
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

본 발명은 유기 카르복실산의 4차 암모늄 염으로 구성된 합성 섬유용 스핀 피니시 및 상기 스핀 피니시로 처리된 합성 섬유에 관한 것으로서, 합성 섬유를 형성 및 처리하는 단계에서 상기 스핀 섬유를 사용하면 상기 단계중에 생성될 수 있는 스컴 및 타르가 감소하고, 상기 스핀 피니시는 연신 직조된 얀을 형성 및 처리시 사용되는데, 상기 얀을 고온에서 열-처리함으로써 수행되며, 상기 스핀 피니시는 하기 일반식 (1)의 화할물 및 선택적으로 폴리에테르-형 윤활제를 포함할 수 있는 것을 특징으로 한다.The present invention relates to a spin finish for synthetic fibers composed of quaternary ammonium salts of organic carboxylic acids and to synthetic fibers treated with the spin finish, wherein the spin fibers are used during the formation and processing of synthetic fibers during the step The scum and tar that can be produced are reduced, and the spin finish is used in forming and processing the stretch woven yarn, which is performed by heat-treating the yarn at a high temperature, the spin finish of formula (1) Characterized in that it may comprise a compound and optionally a polyether-type lubricant.

(식에서, R1내지 R4각각은 1 내지 12개의 탄소원자를 갖는 알킬 또는 알케닐기이고, X-는 유기 카르복실산의 음이온이다.)(Wherein R 1 to R 4 are each an alkyl or alkenyl group having 1 to 12 carbon atoms and X − is an anion of an organic carboxylic acid.)

Description

합성 섬유용 스핀 피니시 및 상기 스핀 피니시로 처리된 합성 섬유Spin Finish for Synthetic Fibers and Synthetic Fibers Treated with the Spin Finish

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (25)

유기 카르복실산의 4차 암모늄 염으로 구성된 것을 특징으로 하는 합성 섬유용 스핀 피니시.Spin finish for synthetic fibers, characterized by consisting of quaternary ammonium salts of organic carboxylic acids. 제1항에 있어서, 상기 유기 카르복실산의 4차 암모늄 염이 3차 아민과 디알킬 탄산염의 반응을 통해 수득되는 반응 생성물을 유기 카르복실산과 반응시킴으로써 수득된 반응 생성물인 것을 특징으로 하는 합성 섬유용 스핀 피니시.The synthetic fiber according to claim 1, wherein the quaternary ammonium salt of the organic carboxylic acid is a reaction product obtained by reacting the reaction product obtained through the reaction of the tertiary amine with the dialkyl carbonate with the organic carboxylic acid. Spin finish for the dragon. 제1항에 있어서, 상기 염을 구성하고 있는 유기 카르복실산이 모노카르복실산 또는 디카르복실산인 것을 특징으로 하는 합성 섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 1, wherein the organic carboxylic acid constituting the salt is monocarboxylic acid or dicarboxylic acid. 제1항에 있어서, 상기 염을 구성하고 있는 유기 카르복실산이 말레산, 프탈산 및 2-에틸헥사노산으로부터 하나 이상 선택되는 것을 특징으로 하는 함성 섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 1, wherein the organic carboxylic acid constituting the salt is at least one selected from maleic acid, phthalic acid and 2-ethylhexanoic acid. 제1항에 있어서, 상기 유기 카르복실산의 4차 암모늄 염의 양이 0. 1 내지 5중량%인 것을 특징으로 하는 합성 섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 1, wherein the amount of the quaternary ammonium salt of the organic carboxylic acid is 0.01 to 5% by weight. 제1항에 있어서, 합성 섬유용 스핀 피니시가 폴리에테르-형 윤활제를 추가로 포함하고 있는 것을 특징으로 하는 합성 섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 1, wherein the spin finish for synthetic fibers further comprises a polyether-type lubricant. 제1항에 있어서, 상기 폴레에테르-형 윤활제의 함량이 70 내지 99.5중량%인 것을 특징으로 하는 합성섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 1, wherein the content of the polyether-type lubricant is 70 to 99.5% by weight. 제1항에 있어서, 합성 섬유용 스핀 피니시가 부분적으로 배향된 폴리에스테르 얀의 연신 직조된 얀을 처리시 사용되는 것을 특징으로 하는 합성 섬유용 스핀 피니시.A spin finish for synthetic fibers according to claim 1, wherein the spin finish for synthetic fibers is used in treating a stretched woven yarn of a partially oriented polyester yarn. 제1항에 있어서, 상기 유기 카르복실산의 4차 암모늄염이 하기 일반식(1)의 화합물인 것을 특징으로 하는 합성 섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 1, wherein the quaternary ammonium salt of the organic carboxylic acid is a compound of the following general formula (1). (식에서, R1내지 R4각각은 1 내지 12개의 탄소원자를 갖는 알킬 또는 알케닐기이고, X-는 유기 카르복실산의 음이온이다.)(Wherein R 1 to R 4 are each an alkyl or alkenyl group having 1 to 12 carbon atoms and X − is an anion of an organic carboxylic acid.) 제9항에 있어서, 상기 일반식(1)의 화합물이 3차 아민과 디알킬 탄산염의 반응을 통해 수득된 반응 생성물을 유기 카르복실산과 반응시킴으로써 제조된 반응 생성물인 것을 특징으로 하는 합성 섬유용 스핀 피니시.10. The spin for synthetic fibers according to claim 9, wherein the compound of formula (1) is a reaction product prepared by reacting a reaction product obtained through the reaction of a tertiary amine with a dialkyl carbonate with an organic carboxylic acid. Finish. 제9항에 있어서, 상기 화합물을 구성하는 유기 카르복실산이 모노카르복실산 또는 디카르복실산인 것을 특징으로 하는 합성 섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 9, wherein the organic carboxylic acid constituting the compound is monocarboxylic acid or dicarboxylic acid. 제9항에 있어서, 상기 화합물을 구성하고 있는 유기 카르복실산이 말레산, 프탈산 및 2-에틸헥사노산으로부터 하나 이상 선택되는 것을 특징으로 하는 합성 섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 9, wherein the organic carboxylic acid constituting the compound is at least one selected from maleic acid, phthalic acid and 2-ethylhexanoic acid. 제9항에 있어서, 상기 일반식(1)의 화합물의 양이 0.1 내지 5중량%인 것을 특징으로 하는 합성 섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 9, wherein the amount of the compound of the formula (1) is 0.1 to 5% by weight. 제9항에 있어서, 합성 섬유용 스핀 피니시가 폴리에테르-형 윤활제를 추가로 포함하고 있는 것을 특징으로 하는 함성 섬유용 스핀 피니시.10. The spin finish for synthetic fibers according to claim 9, wherein the spin finish for synthetic fibers further comprises a polyether-type lubricant. 제9항에 있어서, 상기 폴리에테르-형 윤활제의 함량이 70 내지 99.5중량%인 것을 특징으로 하는 합성섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 9, wherein the content of the polyether-type lubricant is 70 to 99.5% by weight. 제9항에 있어서, 합성 섬유용 스핀 피니시가 부분적으로 배향된 폴리에스테르 얀의 연신 직조된 얀을 처리시 사용되는 것을 특징으로 하는 합성 섬유용 스핀 피니시.10. Spin finish for synthetic fibers according to claim 9, wherein the spin finish for synthetic fibers is used in treating a stretched woven yarn of partially oriented polyester yarns. 제9항에 있어서, 상기 일반식(1)의 R1내지 R4이 1 내지 5개의 탄소원자를 갖는 알킬 또는 알케닐기인 것을 특징으로 하는 합성 섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 9, wherein R 1 to R 4 in the general formula (1) are alkyl or alkenyl groups having 1 to 5 carbon atoms. 제17항에 있어서, 상기 일반식(7)의 화합물이 3차 아민과 디알킬 탄산염의 반응을 통해 수득된 반응 생성물을 유기 카르복실산과 반응시킴으로써 제조된 반응생성물인 것을 특징으로 하는 합성 섬유용 스핀 피니시.18. The spin for synthetic fibers according to claim 17, wherein the compound of formula (7) is a reaction product prepared by reacting a reaction product obtained through the reaction of a tertiary amine with a dialkyl carbonate with an organic carboxylic acid. Finish. 제17항에 있어서, 상기 화합물을 구성하는 유기 카르복실산이 모노카르복실산 또는 디카르복실산인 것을 특징으로 하는 합성 섬유용 스핀 피니시.The spin finish for synthetic fibers according to claim 17, wherein the organic carboxylic acid constituting the compound is monocarboxylic acid or dicarboxylic acid. 제17항에 있어서, 상기 화합물을 구성하는 유기 카르복실산이 말레산, 프탈산 및 2-에틸헥사노산으로부터 하나 이상 선택되는 것을 특징으로 하는 합성 섬유용 스핀 피니시.18. The spin finish for synthetic fibers according to claim 17, wherein the organic carboxylic acid constituting the compound is at least one selected from maleic acid, phthalic acid and 2-ethylhexanoic acid. 제17항에 있어서, 상기 일반식(1)의 화합물의 양이 0.1 내지 5중량%인 것을 특징으로 하는 합성 섬유용스핀 피니시.18. The spin finish for synthetic fibers according to claim 17, wherein the amount of the compound of the formula (1) is 0.1 to 5% by weight. 제17항에 있어서, 합성 섬유용 스핀 피니시가 폴리에테르-형 윤활제를 추가로 포함하는 것을 특징으로하는 합성 섬유용 스핀 피니시.18. The spin finish for synthetic fibers according to claim 17, wherein the spin finish for synthetic fibers further comprises a polyether-type lubricant. 제17항에 있어서, 상기 폴리에테르-형 윤활제의 함량이 70 내지 99.5중량%인 것을 특징으로 하는 합성섬유용 스핀 피니시.18. The spin finish for synthetic fibers according to claim 17, wherein the content of the polyether-type lubricant is 70 to 99.5% by weight. 제17항에 있어서, 합성 섬유용 스핀 피니시가 부분적으로 배향된 폴리에스테르 얀의 연신 직조된 얀을 처리시 사용되는 것을 특징으로 하는 함성 섬유용 스핀 피니시.18. The spin finish of claim 17, wherein the spin finish for synthetic fibers is used in treating a stretched woven yarn of partially oriented polyester yarns. 제1항 내지 제24항 중 어느 한 항에 따른 합성 성유용 스핀 피니시로 처리된 것을 특징으로 하는 합성섬유.A synthetic fiber characterized in that treated with a synthetic finish spin finish according to any one of claims 1 to 24. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019960043590A 1995-10-11 1996-10-02 Spin Finish for Synthetic Fibers and Synthetic Fibers Treated with the Spin Finish KR970021499A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP95-290506 1995-10-11
JP29050795A JP2852891B2 (en) 1995-10-11 1995-10-11 Spinning oil for synthetic fibers
JP95-290507 1995-10-11
JP29050695A JP2852890B2 (en) 1995-10-11 1995-10-11 Oil for synthetic fibers

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KR970021499A true KR970021499A (en) 1997-05-28

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CN101845752B (en) * 2010-05-07 2012-05-02 周建芳 Polyester fast spinning POY (Polyester Pre-Oriented Yarn) ultrafine denier filament finish
CN102127859B (en) * 2011-01-18 2012-05-09 东华大学 Spinning finish for degradable stent fiber for human bodies
CN102277732B (en) * 2011-06-21 2013-02-27 竹本油脂(苏州)有限公司 Treating agent for regenerative synthetic fibers and method thereof for treating regenerative synthetic fibers
CN103614906A (en) * 2013-10-31 2014-03-05 安徽东锦化纤科技有限公司 Regenerated terylene short fiber compound oil agent

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