KR970021341A - High Temperature Corrosion Resistant Monocrystalline Nickel-Base Super Heat-resistant Alloy - Google Patents

High Temperature Corrosion Resistant Monocrystalline Nickel-Base Super Heat-resistant Alloy Download PDF

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KR970021341A
KR970021341A KR1019950036941A KR19950036941A KR970021341A KR 970021341 A KR970021341 A KR 970021341A KR 1019950036941 A KR1019950036941 A KR 1019950036941A KR 19950036941 A KR19950036941 A KR 19950036941A KR 970021341 A KR970021341 A KR 970021341A
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weight percent
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single crystal
resistant alloy
gas turbine
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KR100391184B1 (en
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엘. 에릭슨 게리
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아론 네렌버그
케논-머스케곤 코포레이션
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/056Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 10% but less than 20%

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)

Abstract

본 발명은 다음의 원소들을 포함하는 고온 내식성 니켈-기본 내열합금에 관한 것으로서, 초내열합금은 상안정성 값(NV3B)이 약 2.45 이하이다 : 크롬 약 14.2 내지 약 15.5중량%, 코발트 약 2.0 내지 약 4.0중량%, 몰리브덴 약 0.30 내지 약 0.45중량%, 텅스텐 약 4.0 내지 약 5.0중량%, 탄탈 약 4.5 내지 약 5.8중량%, 니오브 약 0.05 내지 약 0.25중량%, 알루미늄 약 3.2 내지 약 3.6중량%, 티탄 약 4.0 내지 약 4.4중량%, 하프늄 약 0.01 내지 약 0.06중량% 및 잔여량의 니켈과 부수적인 불순물.The present invention relates to a high temperature corrosion resistant nickel-base heat resistant alloy comprising the following elements, the super heat resistant alloy having a phase stability value (N V3B ) of about 2.45 or less: about 14.2 to about 15.5 weight percent of chromium, about 2.0 to about 2.0 About 4.0 wt%, molybdenum about 0.30 to about 0.45 wt%, tungsten about 4.0 to about 5.0 wt%, tantalum about 4.5 to about 5.8 wt%, niobium about 0.05 to about 0.25 wt%, aluminum about 3.2 to about 3.6 wt%, About 4.0 to about 4.4 weight percent titanium, about 0.01 to about 0.06 weight hafnium and residual amounts of nickel and incidental impurities.

본 발명의 초내열합금으로부터 단결정 제품이 적합하게 제조될 수 있다. 제품은 가스 터빈 엔진용 부품이 될 수 있으며, 보다 특히, 부품은 가스 터빈 블레이드 또는 가스 터빈 베인이 될 수 있다.Single crystal products can be suitably produced from the super heat resistant alloy of the present invention. The product may be a part for a gas turbine engine, and more particularly, the part may be a gas turbine blade or a gas turbine vane.

Description

고온 내식성 단결정 니켈-기본 초내열합금High Temperature Corrosion Resistant Monocrystalline Nickel-Base Super Heat-resistant Alloy

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 본 발명의 1가지 실시양태와 4가지 다른 합금에 대한 3가지 노출온도에서 실시한 고온 부식성 시험결과의 도표이다,FIG. 1 is a plot of high temperature corrosive test results at three exposure temperatures for one embodiment of the invention and four different alloys.

제2도는 본 발명의 1가지 실시양태와 2가지 다른 합금에 대한 732℃(1350℉)에서 실시한 시험으로부터 얻은 고온 부식 데이터의 비교 그래프이다.2 is a comparative graph of high temperature corrosion data obtained from tests conducted at 732 ° C. (1350 ° F.) for one embodiment of the invention and two different alloys.

Claims (20)

다음의 원소들은 포함하고 상 안정성 값(NV3B)이 약 2.45 이하인 고온 내식성 니켈-기본 초내열합금(superalloy). 크롬 약 14.2 내지 15.5중량%, 코발트 약 2.0 내지 4.0중량%, 몰리브덴 약 0.30 내지 0.45중량%, 텅스텐 약 4.0 내지 5.0중량%, 탄탈 약 4.5 내지 5.8중량%, 니오브 약 0.05 내지 0.25중량%, 알루미늄 약 3.2 내지 3.6중량%, 티탄 약 4.0 내지 4.4중량%, 하프늄 약 0.01 내지 0.06중량% 및 니켈+부수적인 불순물 잔여량.High temperature corrosion resistant nickel-based superalloy containing the following elements and having a phase stability value (N V3B ) of about 2.45 or less. About 14.2 to 15.5 weight percent chromium, about 2.0 to 4.0 weight percent cobalt, about 0.30 to 0.45 weight percent molybdenum, about 4.0 to 5.0 weight percent tungsten, about 4.5 to 5.8 weight percent tantalum, about 0.05 to 0.25 weight percent niobium, about aluminum 3.2 to 3.6 weight percent titanium, about 4.0 to 4.4 weight percent hafnium, about 0.01 to 0.06 weight percent and nickel plus incidental impurities. 제1항에 있어서, 다음의 원소들을 추가로 포함하는 초내열합금. 탄소 약 0 내지 0.05중량%, 붕소 약 0 내지 0.03중량%, 지르코늄 약 0 내지 0.03중량%, 레늄 약 0 내지 0.25중량%, 규소 약 0 내지 0.10중량% 및 망간 약 0 내지 0.10중량%.The superalloy according to claim 1, further comprising the following elements. About 0 to 0.05 weight percent carbon, about 0 to 0.03 weight percent boron, about 0 to 0.03 weight percent zirconium, about 0 to 0.25 weight percent rhenium, about 0 to 0.10 weight percent silicon and about 0 to 0.10 weight percent manganese. 제1항에 있어서, 니오브와 하프늄의 합이 0.06중량% 내지 0.31중량%인 초내열합금.The superheat resistant alloy according to claim 1, wherein the sum of niobium and hafnium is 0.06% by weight to 0.31% by weight. 제1항에 있어서, Ti : A1 비가 1 이상인 초내열합금.The super heat resistant alloy according to claim 1, wherein the Ti: A1 ratio is 1 or more. 제1항에 있어서, 알루미늄과 티탄의 합이 7.2중량% 내지 8.0중량%인 초내열합금.The super heat resistant alloy according to claim 1, wherein the sum of aluminum and titanium is 7.2% by weight to 8.0% by weight. 제1항에 있어서, Ta : W 비가 1 이상인 초내열합금.The super heat resistant alloy according to claim 1, wherein Ta: W ratio is 1 or more. 제1항에 있어서, 내산화성이 향상된 초내열합금.The super heat resistant alloy according to claim 1, wherein the oxidation resistance is improved. 제1항의 초내열합금으로부터 제조된 단결정 제품.A single crystal product made from the super heat resistant alloy of claim 1. 제8항에 있어서, 터빈 엔진용 부품인 단결정 제품.The single crystal product according to claim 8 which is a component for a turbine engine. 제9항에 있어서, 부품이 가스 터빈 블레이드 또는 가스 터빈 베인인 제품.10. The article of claim 9, wherein the component is a gas turbine blade or gas turbine vane. 다음의 원소들을 함유하고 상 안정성 값(NV3B)이 약 2.45 이하인 니켈-기본 초내열합금으로부터 제조되는, 향상된 고온 내식성이 특징인 단결정 주물. 크롬 약 14.3 내지 15.0중량%, 코발트 약 2.5 내지 3.5중량%, 몰리브덴 약 0.35 내지 0.43중량%, 텅스텐 약 4.2 내지 4.8중량%, 탄탈 약 4.8 내지 5.4중량%, 니오브 약 0.05 내지 0.12중량%, 알루미늄 약 3.3 내지 3.5중량%, 티탄 약 4.1 내지 4.3중량%, 하프늄 약 0.02 내지 0.05중량% 및 니켈+부수적인 불순물 잔여량.A single crystal casting characterized by improved high temperature corrosion resistance, which is prepared from a nickel-based superheat resistant alloy containing the following elements and having a phase stability value (N V3B ) of about 2.45 or less. About 14.3 to 15.0 weight percent chromium, about 2.5 to 3.5 weight percent cobalt, about 0.35 to 0.43 weight percent molybdenum, about 4.2 to 4.8 weight percent tungsten, about 4.8 to 5.4 weight percent tantalum, about 0.05 to 0.12 weight percent niobium, about aluminum 3.3 to 3.5 weight percent, about 4.1 to 4.3 weight percent titanium, about 0.02 to 0.05 weight percent hafnium and nickel plus incidental impurities. 제11항에 있어서, 다음의 원소들을 추가로 포함하는 단결정 주물. 탄소 약 0 내지 0.5중량%, 붕소 약 0 내지 0.03중량%, 지르코늄 약 0 내지 0.03중량%, 레늄 약 0 내지 0.25중량%, 규소 약 0 내지 0.10중량% 및 망간 약 0 내지 0.10중량%.12. The single crystal casting of Claim 11 further comprising the following elements. About 0 to 0.5 weight percent carbon, about 0 to 0.03 weight percent boron, about 0 to 0.03 weight percent zirconium, about 0 to 0.25 weight percent rhenium, about 0 to 0.10 weight percent silicon and about 0 to 0.10 weight percent manganese. 제11항에 있어서, 니오브와 하프늄이 합이 0.06중량% 내지 0.31중량%인 단결정 주물.12. The single crystal casting of claim 11 wherein the niobium and hafnium add up to 0.06% to 0.31% by weight. 제11항에 있어서, 알루미늄과 티탄의 합이 7.2중량% 내지 8.2중량%인 단결정 주물.12. The single crystal casting of claim 11 wherein the sum of aluminum and titanium is between 7.2 weight percent and 8.2 weight percent. 제11항에 있어서, Ti : Al 비와 Ta : W 비가 둘 다 1 이상인 단결정 주물.The single crystal casting of claim 11 wherein the Ti: Al ratio and the Ta: W ratio are both at least one. 제11항에 있어서, 내산화성이 향상된 단결정 주물.The single crystal casting of claim 11, wherein the oxidation resistance is improved. 제11항에 있어서, 크리이프-파열강도가 향상된 단결정 주물.The single crystal casting of claim 11, wherein the creep-rupture strength is improved. 제11항에 있어서, 가스 터빈 블레이드 또는 가스 터빈 베인인 단결정 주물.12. The single crystal casting of claim 11 which is a gas turbine blade or gas turbine vane. 다음의 원소들을 함유하고 상 안정성 값(NV3B)이 약 2.45 이하인 니켈-기본 초내열합금으로부터 제조된, 향상된 고온 내식성이 특징인 단결정 주물. 브롬 약 14.5중량%, 코발트 약 3.0중량%, 몰리브덴 약 0.40중량%, 텅스텐 약 4.4중량%, 탄탈 약 4.95중량%, 니오브 약 0.10중량%, 알루미늄 약 3.40중량%, 티탄 약 4.2중량%, 하프늄 약 0.04중량%, 탄소 약 0 내지 0.05중량%, 붕소 약 0 내지 0.03중량%, 지르코늄 약 0 내지 0.03중량%, 레늄 약 0 내지 0.25중량%, 규소 약 0 내지 0.10중량%, 망간 약 0 내지 0.10중량% 및 니켈 잔여량.(여기서, 니오브와 하프늄의 합은 0.06중량% 내지 0.31중량%이고, 알루미늄과 티탄의 합은 7.2중량% 내지 8.0중량%이며, Ti : Al 비는 1 이상이고, Ta : W 비는 1 이상이다)A single crystal casting characterized by improved high temperature corrosion resistance made from a nickel-based superheat resistant alloy containing the following elements and having a phase stability value (N V3B ) of about 2.45 or less. Bromine about 14.5%, cobalt about 3.0%, molybdenum about 0.40%, tungsten about 4.4%, tantalum about 4.95%, niobium about 0.10%, aluminum about 3.40%, titanium about 4.2%, hafnium about 0.04 weight%, about 0 to 0.05 weight% carbon, about 0 to 0.03 weight% boron, about 0 to 0.03 weight% zirconium, about 0 to 0.25 weight% rhenium, about 0 to 0.10 weight% silicon, about 0 to 0.10 weight manganese % And nickel remaining amount. Rain is 1 or more) 제19항에 있어서, 가스 터빈 블레이드 또는 가스 터빈 베인인 단결정 주물.20. The single crystal casting of claim 19 which is a gas turbine blade or gas turbine vane. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950036941A 1995-10-25 1995-10-25 High Temperature Corrosion Resistance Single Crystal Nickel Based Superalloy KR100391184B1 (en)

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