KR970004390Y1 - Acidity water manufacturing apparatus - Google Patents

Acidity water manufacturing apparatus Download PDF

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KR970004390Y1
KR970004390Y1 KR2019940010825U KR19940010825U KR970004390Y1 KR 970004390 Y1 KR970004390 Y1 KR 970004390Y1 KR 2019940010825 U KR2019940010825 U KR 2019940010825U KR 19940010825 U KR19940010825 U KR 19940010825U KR 970004390 Y1 KR970004390 Y1 KR 970004390Y1
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water
radicals
acidic
anode
electrolytic cell
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KR950033219U (en
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최인환
요시아끼 마쓰오
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최인환
요시아끼 마쓰오
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/46185Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only anodic or acidic water, e.g. for oxidizing or sterilizing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4612Controlling or monitoring
    • C02F2201/4615Time

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

내용없음.None.

Description

산성수 생성장치Acid water generator

본 고안은 산성수 생성장치에 관한 것으로, 특히 비유수(非流水) 방법에 의해 전해조를 저수조로 병용하여 휴대용으로 구성토록한 산성수 생성장치에 관한 것이다.The present invention relates to an acidic water generator, and more particularly, to an acidic water generator configured to be portable by using an electrolytic cell together with a reservoir by a non-flowing water method.

종래의 장치로 나와 있는 것은, 본 고안자에 의하여 발명한 일본 공개특허공보 평3-98690호이 것이 나와 있다.As a conventional apparatus, Japanese Unexamined Patent Application Publication No. Hei 3-98690 is invented by the inventor.

상기의 본 고안자에 의한 선발명은 격벽에 의해 구분된 양극실과 음극실측에 전해액을 채우고, 전해액에 직류 전압을 인가함으로서 전해 생성수를 연속제조하는 원리가 나와 있다.According to the above-described invention of the present inventors, there is a principle of continuously producing electrolytic generated water by filling an electrolyte in the anode and cathode chambers separated by partition walls and applying a DC voltage to the electrolyte.

이 전해액은 식용수에 전해질을 용해하고, 전해하여 전해 생성수를 얻는데 적당한 전기전도도가 되도록 조정된다. 상기의 전해질로서는 식염이나 염화칼륨을 이용하는 일이 많다.This electrolyte is adjusted so that the electrolyte is dissolved in the drinking water, and it is electrolytically suitable for obtaining electrolytically generated water. As the electrolyte, salt and potassium chloride are often used.

그리고, 직류전압에 전압을 인가시키면 음극(-) 근방에서 수소 이온이 환원되어 수소가스가 발생하고 전해액중의 수소 이온이 소비된다. 수소이온 이외의 양이온은 수소 이온쌍을 형성하고, 음극실의 용액은 차츰 염기성으로 된다.When a voltage is applied to the DC voltage, hydrogen ions are reduced in the vicinity of the negative electrode (-) to generate hydrogen gas, and the hydrogen ions in the electrolyte are consumed. Cations other than hydrogen ions form hydrogen ion pairs, and the solution in the cathode chamber gradually becomes basic.

한편, 양극 근방에서는 전해액 중의 수산이온이 환원되어 산소가스가 발생하고 전해액 중의 수산이온이 소비된다. 수산이온 이외의 음이온은 수소와 산을 형성하고 양극실의 용액은 산성을 띄게 된다. 그리하여 물이 전기 분해된다.On the other hand, in the vicinity of the anode, the hydroxyl ions in the electrolyte are reduced to generate oxygen gas, and the hydroxide ions in the electrolyte are consumed. Anions other than hydroxyl ions form acid with hydrogen, and the solution in the anode chamber becomes acidic. Thus the water is electrolyzed.

이와 같이 하여 연속 생성된 염기성 이온수는 맛이 좋고, 칼슘이온이 풍부하게 함유된다. 또한 활성이 높으므로 체내에 들어오면 여러 가지의 노폐물을 용해하여 체외로 배출할 수 있다. 이러한 점으로 건강에 유익한 음료수로서 기대되어 왔었다.The basic ionized water produced in this way has a good taste and contains abundant calcium ions. In addition, since the activity is high, the various wastes can be dissolved and released into the body when entering the body. In this regard, it has been expected as a beverage that is beneficial to health.

그러나 종래의 이와 같은 전해 방법은 유수(流水) 방법을 채용하고 있어, 수도물 또는 샘물을 사용하는 경우, 수도설비의 배관이 필요하고 또한 수도설비와 연결하는 각종의 여러 연결구 부속품이 필요하게 된다. 한편, 경우에 따라서는 수도설비의 배관이 불가능한 경우도 있어 이럴 경우에는 사용이 불가능하여 사용상 장소적인 제한이 많이 따르는 단점이 있다.However, such a conventional electrolytic method employs a running water method, and in the case of using tap water or spring water, piping of water facilities is required, and various various connector fittings for connecting to the water facilities are required. On the other hand, in some cases it is impossible to pipe the water supply facility in this case is impossible to use, there is a disadvantage in that a lot of place restrictions in use.

또한 연속적으로 많은 량의 처리수를 양산하여야 하므로 용량이 커지게 되고 처리장치의 구조도 복잡하게 되며, 원하는 소정의 염기성 또는 산성의 처리수를 얻는 것이 어려운 단점이 있다.In addition, since a large amount of treated water must be continuously produced, the capacity is increased and the structure of the processing apparatus is complicated, and it is difficult to obtain a desired basic or acidic treated water.

본 고안은 상기한 점을 감안하여 안출한 것으로, 본 고안에서는 휴대용으로 제조가능토록 구성하고, 처리되는 생성수는 시간제어장치에 의하여 편리하게 또한 소망하는 정확한 산성 또는 알칼리성을 갖도록 할 수 있게 한 것이다.The present invention has been devised in view of the above points, and in the present invention, it is configured to be manufactured in a portable manner, and the generated water to be treated is conveniently made to have a desired accurate acid or alkalinity by a time controller. .

제1도는 본 고안에 따른 장치의 구성 원리를 개략 나타내는 도면1 schematically shows the principle of construction of the device according to the present invention.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

1 : 양극실 2 : 음극실1: anode chamber 2: cathode chamber

3 : 양극 4 : 음극3: anode 4: cathode

5 : 격벽 6 : 시간제어장치5: bulkhead 6: time control device

상기 목적을 달성하기 위한 본 고안에 따른 산성수 생성장치의 주요 구성은, 제1도에서 보듯이, 양극실(1)과, 음극실(2)과, 그리고 반투성의 격벽(5)으로 이루어지는 전해조를 저수조로 구성한다. 즉 격벽(5)을 중간에 주고 두개의 공간이 형성되게 한다. 예로써, 격벽(5)의 좌측은 산성수가 생성되어 저장되는 저수조가되게 하고, 반대로 격벽(5)을 중심으로 우측은 알카리수가 생성되어 저장되는 공간이 되도록 한다. 제1도는 본 고안에 따른 장치의 원리를 설명하기 위한 도면으로 구조적으로 특히 한정되는 것은 아니다.The main configuration of the acidic water generating device according to the present invention for achieving the above object, as shown in Figure 1, the electrolytic cell consisting of the anode chamber 1, the cathode chamber 2, and the semi-permeable partition wall (5) It consists of a reservoir. That is, the partition 5 is placed in the middle and two spaces are formed. For example, the left side of the partition wall 5 is a reservoir for acidic water generated and stored, and on the contrary, the right side of the partition wall 5 is an alkaline water generated and stored. 1 is a view for explaining the principle of the device according to the present invention is not particularly limited structurally.

본 고안에 따른 장치는, 반투성의 격벽을 매개로하여 마련된 음극실()측 전해조와 양극실(1)측 전해조에, 즉 두 저수조에 처리하고자 하는 물과 함께 희박 전해질 용액을 채운다. 희박 전해질용액으로는 염화나트륨(식염수), 염화칼륨등이 전해질로서 용해되므로 음극실과 양극실에 직류전압을 인가하면, 전해에 의하여 OH 라디칼 또는 C1 라디칼이 생성되어 전해생성수를 보유할 수 있다.The apparatus according to the present invention fills a lean electrolyte solution with water to be treated in a cathode chamber () side electrolytic cell and an anode chamber (1) side electrolyte tank provided through a semipermeable partition wall, that is, two reservoir tanks. As lean electrolyte solution, sodium chloride (saline), potassium chloride, etc. are dissolved as an electrolyte, and when a direct current voltage is applied to the cathode chamber and the anode chamber, OH radicals or C1 radicals are generated by electrolysis to retain the electrolyzed water.

또한, 본 고안에서는 전해조의 양극(3) 및 음극(4)에 설정된 시간동안 전압 인가되도록 시간제어장치(6)를 연결하여, 시간제어장치(6)의 시간 설정에 따라 전해에 의한 생성수가 OH 라디칼 또는 C1 라디칼의 함유량이 조절되도록 한다.In addition, in the present invention, by connecting the time control device 6 so that the voltage is applied to the positive electrode 3 and the negative electrode 4 of the electrolytic cell for a predetermined time, the water generated by electrolysis according to the time setting of the time control device 6 is OH. Allow the content of radicals or C1 radicals to be controlled.

즉, 상기와 같이 저수조로 구성한 전해조 내의 물은 저수되어 있는 상태에서 시간제어장치(6)에 의해 미리 결정된 시간동안 전해가 계속되도록 하되 그 시간의 설정에 따라 소정의 산성수 또는 알카리수로 만들 수 있는 편리함이 있다. 예로써, 시간의 설정을 7분 또는 그 이상으로 하면, 그 만큼 전해가 많이 되어 산성도가 PH 2.7정도 또는 그 이상이 되도록 산성수를 생성시킬 수 있다.That is, the water in the electrolytic cell constituted by the reservoir as described above is allowed to continue the electrolysis for a predetermined time by the time controller 6 in the state of being stored, but can be made into a predetermined acidic or alkaline water according to the setting of the time There is convenience. For example, when the time is set to 7 minutes or more, the acidic water can be generated so that the electrolysis is increased by that much and the acidity is about pH 2.7 or more.

그리고 생성된 물 내에서, 불안정 이온 종류인 OH 라디칼 및 C1 라디칼이 만약 분해되는 경우 즉, 원하는 소정의 라디칼을 갖지 못한 경우에는 다시 전해조내에 투입하여 시간 설정에 의한 전해조절로 원하는 일정한 농도를 갖도록 하는 것이 가능하다.In the generated water, if the unstable ion species, OH radicals and C1 radicals, are decomposed, that is, they do not have the desired predetermined radicals, they are put back into the electrolytic cell to have a desired constant concentration by electrolysis control by time setting. It is possible.

한편, 이와 같이 하여 제조된 일정 농도의 산성생성수 중에 함유된 OH 라디칼 또는 C1 라디칼은 반응성이 매우 크기 때문에, 이 세포막의 파괴나 단백질의 산화 분해를 행함으로서 각종의 세균류들에 대한 살균효과를 발휘하게 된다.On the other hand, OH radicals or C1 radicals contained in the acidic water produced at a certain concentration are thus highly reactive, thus exhibiting bactericidal effects on various bacteria by destroying the cell membrane or performing oxidative degradation of proteins. Done.

하기의 실시예는 본 고안의 장치에 의하여 생성된 산성생성수의 살균효과를 살펴보기 위한 시험이다.The following example is a test to see the sterilization effect of the acidic water produced by the device of the present invention.

(실시예 1)(Example 1)

원수(源水)를 양극실(1) 및 음극실(2)에 부어넣고 1%의 염화나트륨을 용해하여, 반투성의 격벽(5)을 매개로 하여, 양극(3) 및 음극(4)을 통하여 직류전압 15V를 인가하고, 시간제어장치(6)에 의해 1분간 전류를 흐르게 하여, OH 라디칼 또는 C1 라디칼을 생성시켜 방치하였다. 그리고, 3일 후에 상기와 같이 생성된 산성수를 저수조에서 일부 채취하여 대장균 및 일반세균에 대한 살균력을 시험하여 보았다.Raw water is poured into the anode chamber 1 and the cathode chamber 2, and 1% sodium chloride is dissolved, through the semi-permeable partition 5, through the anode 3 and the cathode 4 A DC voltage of 15 V was applied, and current was allowed to flow for 1 minute by the time controller 6 to generate and leave OH radicals or C1 radicals. And, after three days, the acidic water produced as described above was partially collected in the water tank and tested for bactericidal activity against E. coli and general bacteria.

이하 그의 결과를 나타낸다.The results are shown below.

먼저, 105의 균 현탁액을 조정하여, 이를 상기와 같이 채취한 산성수와 혼합하여 그의 시간 경과에 따른 살균특성을 조사한 경우 아래와 같았다.First, the bacterial suspension of 10 5 was adjusted and mixed with the acidic water collected as described above to investigate the sterilization characteristics over time as follows.

30초 1분 10분 1시간30 seconds 1 minute 10 minutes 1 hour

대장균 0 0 0 0Escherichia coli 0 0 0 0

일반세균 1020 0 0General bacteria 10 2 0 0 0

(실시예 2)(Example 2)

원수(源水)를 양극실(1) 및 음극실(2)에 넣고, 1%의 염화나트륨을 용해하여, 반투성의 격벽(5)을 매개로 하여, 양극(3) 및 음극(4)을 통하여 직류전압 15V를 인가하고, 시간제어장치(6)에 의해 1분간 전류를 흐르게 하여, OH 라디칼 또는 C1 라디칼을 생성시키고 저수조내의 물을 30일 동안 방치하여 두었다. 그런후, 생성된 산성수 일부를 저수조에서 채취하여 그 산성수의 대장균 및 일반세균에 대한 살균효과를 살펴 보았다.Raw water is placed in the anode chamber 1 and the cathode chamber 2, and 1% of sodium chloride is dissolved, through the semipermeable partition 5, through the anode 3 and the cathode 4; A DC voltage of 15V was applied, and current was flowed by the time controller 6 for 1 minute to generate OH radicals or C1 radicals, and the water in the reservoir was left for 30 days. Then, some of the generated acidic water was collected from the reservoir and the sterilizing effect of the acidic water against E. coli and general bacteria was examined.

먼저, 105의 균 현탁액을 조정하여, 30일 동안 방치하여 두었다가 일부 채취한 소량의 산성수와 혼합하였다. 그리고 시간 경과에 따른 살균특성을 조사한 경우 아래와 같다.First, the bacterial suspension of 10 5 was adjusted, left for 30 days, and mixed with a small amount of acidic water collected. And the case of examining the sterilization characteristics over time is as follows.

30초 1분 10분 1시간30 seconds 1 minute 10 minutes 1 hour

대장균 0 0 0 0Escherichia coli 0 0 0 0

일반세균 1030 0 0General bacteria 10 3 0 0 0

상기의 실시예에서 보듯이, 본 고안에 따른 산성수 생성장치의 시간제어장치(6)에 의하여 단지 1분간만 전해 처리하여도, 생성된 산성수는 거의 1달간이나 살균특성을 그대로 유지하고 있음을 확인할 수 있고, 그의 살균력은 균과 혼합시 단, 1분만 경과하여도 세균을 전부 죽일 수 있는 살균효과를 나타내었다.As shown in the above embodiment, even after only 1 minute electrolytic treatment by the time control device 6 of the acid water generator according to the present invention, the generated acid water maintains sterilization characteristics for almost 1 month. It can be confirmed, and its sterilizing power when mixed with the bacteria, but showed a bactericidal effect that can kill all bacteria even after 1 minute.

이상에서 살펴본 바와 같은 본 고안에 따른 산성수 생성장치에 의하면, 전해조 자신이 저수조가 되므로 특별히 저수 탱크를 필요치 않으며, 전체적으로 간단한 구조로 제조 가능하므로 휴대용으로 제작하기가 매우 용이한 장점이 있다.According to the acidic water generating device according to the present invention as described above, since the electrolytic cell itself becomes a water tank, it does not need a water tank in particular, and can be manufactured with a simple structure as a whole, so it is very easy to manufacture portable.

그리고, 시간제어장치(6)에 의하면 처리되는 생성수의 산성도를 단지 시간 조절의 제어에 의하여 가능하므로 소망의 원하는 정확한 산성도를 갖는 처리수로서 생성하기가 매우 용이한 장점이 있고, 또 처리되어진 산성 생성수는 대장균 및 일반세균의 살균 효과도 매우 우수한 것으로 나타났다.Further, according to the time controller 6, since the acidity of the treated water to be treated is possible only by controlling the time, there is an advantage that it is very easy to generate as the treated water having the desired precise acidity desired, and the treated acidity. The produced water also showed very good bactericidal effect of E. coli and general bacteria.

따라서, 본 고안에 의하여 처리된 생성수는 건강을 위한 음료용 외에 하나의 기능수로서의 역할을 할 수 있어, 예로써, 구강소독, 환부세척 등에 적용할 수 있고, 또한 이는 부작용이 없고 인체에 무해하므로 의료계 등의 여러 산업상 용도로, 또는 인체에 적용하여 활용할 수 있어 그의 이용 가치는 매우 놓은 것이다.Therefore, the generated water treated by the present invention can play a role as a functional water in addition to the drink for health, for example, can be applied to oral disinfection, affected area, etc., which also has no side effects and harmless to the human body Therefore, it can be applied to various industrial uses such as the medical field, or applied to the human body, and its use value is very laid.

Claims (1)

공지의 양극실과, 음극실과, 그리고 반투성의 격벽을 포함하는 전해조를 갖춘 산성수 생성장치에 있어서, 전해조의 반투성 격벽을 중심으로 처리수를 수용가능하게 저수조를 구성하고, 전해조의 양극(3) 및 음극(4)에는 설정된 시간동안 전압인가되도록 하는 시간제어장치(6)를 연결하여, 시간제어장치(6)의 시간조절에 따라 라디칼을 달리In an acidic water generating apparatus having a known anode chamber, a cathode chamber, and an electrolytic cell including a semipermeable partition, the storage tank is configured to accommodate the treated water around the semipermeable partition of the electrolytic cell, and the anode (3) and The cathode 4 is connected to a time control device 6 for applying a voltage for a set time, and radicals are changed according to the time control of the time control device 6. 하는 생성수가 생성되게 구성한 것을 특징으로 하는 산성수 생성장치.An acidic water generator, characterized in that configured to generate generated water.
KR2019940010825U 1994-05-16 1994-05-16 Acidity water manufacturing apparatus KR970004390Y1 (en)

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