KR960705105A - Papermaking machine dryer fabric - Google Patents

Papermaking machine dryer fabric

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Publication number
KR960705105A
KR960705105A KR1019960701481A KR19960701481A KR960705105A KR 960705105 A KR960705105 A KR 960705105A KR 1019960701481 A KR1019960701481 A KR 1019960701481A KR 19960701481 A KR19960701481 A KR 19960701481A KR 960705105 A KR960705105 A KR 960705105A
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KR
South Korea
Prior art keywords
fabric
monofilament
copolymer
iii
yarn
Prior art date
Application number
KR1019960701481A
Other languages
Korean (ko)
Inventor
기리쉬 엠. 바트
Original Assignee
그레이엄 더블유. 잭슨
제이더블유아이. 리미티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 그레이엄 더블유. 잭슨, 제이더블유아이. 리미티드 filed Critical 그레이엄 더블유. 잭슨
Publication of KR960705105A publication Critical patent/KR960705105A/en

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/78Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
    • D01F6/84Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyesters
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F1/00Wet end of machines for making continuous webs of paper
    • D21F1/0027Screen-cloths
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F1/00Wet end of machines for making continuous webs of paper
    • D21F1/10Wire-cloths

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)
  • Paper (AREA)
  • Woven Fabrics (AREA)

Abstract

본 발명은 성분 실의 적어도 일부분이 1, 4-디메틸올시클로헥산, 테레프탈 산 및 이소프탈 산의 코폴리머와 가수분해 안정화제의 유효한 양으로 구성되는 초지 기계 드라이어 직물에 관한 것이다. 본 발명에 있어서는 코폴리머를 제조하는데 사용되는 테레프탈 산 대 이소프탈 산의 몰비가 약 83 : 17이고, 코폴리머는 0/.75dL/g보다 큰 고유점도를 가지도록 된다. 드라이어 직물에 사용되는 다른 알려진 폴리머와 비교할 때, 상기 코폴리머는 모노필라멘트에서 가수분해성 열화에 대한 내성을 향상시키며, 양호한 결절 특성을 부여한다.The present invention relates to a papermaking machine dryer fabric, wherein at least a portion of the component yarns are composed of an effective amount of copolymer and hydrolysis stabilizer of 1, 4-dimethylolcyclohexane, terephthalic acid and isophthalic acid. In the present invention, the molar ratio of terephthalic acid to isophthalic acid used to prepare the copolymer is about 83:17, and the copolymer has an intrinsic viscosity of greater than 0 / .75 dL / g. Compared to other known polymers used in dryer fabrics, these copolymers improve the resistance to hydrolytic degradation in monofilaments and impart good nodular properties.

저밀도 폴리에틸렌을 상기 코폴리머에 선택적으로 첨가하면 표면 오염 및 오물에 대한 방오성을 높일 수 있다.Selective addition of low density polyethylene to the copolymer can increase antifouling to surface contamination and dirt.

Description

초지 기계 드라이어 직물Papermaking machine dryer fabric

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 표 2에서는 모노필라멘트에 대하여 보유된 인장 강도의 백분율을 나타낸 것이고,FIG. 1 shows the percentage of tensile strength retained relative to monofilaments in Table 2.

제2도는 표 2에서의 모노필라멘트 샘플의 인장 강도에 대한 PCDI 안정제의 효과를 나타낸 것이며,2 shows the effect of the PCDI stabilizer on the tensile strength of the monofilament samples in Table 2,

제3도는 결절 신장 및 열적 수축 사이의 관계를 나타낸 것이다.3 shows the relationship between nodular elongation and thermal contraction.

Claims (25)

실의 적어도 일부분이 1, 4-디메틸올시클로헥산, 테레프탈 산 이소프탈 산의 코폴리머로 구성되는 모노필라멘트인 초지기계 드라이버 직물로서, 상기 모노필라멘트에서; i) 코폴리머에서 테레프탈 산 대 이소프탈 산의 몰비가 약 83 : 17이고, ⅱ) 코폴리머의 고유점도가 30℃에서 60 : 40 중량비의 페놀과 1,1,2,2-테트라클로로 에탄 내에서 ASTM 표준 방법 D-4603-86으로 측정하였을 때, 0.75dL/g보다 크고, ⅲ) 코폴리머가 유효한 양의 가수분해 안정제를 포함하고, ⅳ) 단순한 외벌 매듭으로 결절이 형성된 모노필라멘트 샘플의 파단시 신장량을 측정하였을 때, 적어도 약 10%의 결절 신장을 나타내며, 그리고 ⅴ) 200℃에서의 모노필라멘트의 열적 수축은 적어도 약 1%인 초지 기계 드라이어 직물.A papermaking machine driver fabric, wherein at least a portion of the yarn is a monofilament consisting of a copolymer of 1, 4-dimethylolcyclohexane, terephthalic acid isophthalic acid, wherein the monofilament; i) the molar ratio of terephthalic acid to isophthalic acid in the copolymer is about 83:17, and ii) the intrinsic viscosity of the copolymer in 60:40 weight ratio of phenol and 1,1,2,2-tetrachloroethane at 30 ° C. Rupture of a monofilament sample larger than 0.75 dL / g, as measured by ASTM standard method D-4603-86, iii) the copolymer contains an effective amount of a hydrolysis stabilizer, and iii) nodules formed with a simple single knot. Papermaking machine dryer fabric, exhibiting at least about 10% nodular elongation when measured, and iii) thermal contraction of monofilament at 200 ° C. is at least about 1%. 제1항에 있어서, 코폴리머의 고유가 점도는 약 0.75 내지 1.5dL/g인 직물.The fabric of claim 1 wherein the high oil viscosity of the copolymer is about 0.75 to 1.5 dL / g. 제1항에 있어서, 코폴리머에 함유된 안정제의 양이 약 0.4 내지 5중량%인 직물.The fabric of claim 1 wherein the amount of stabilizer contained in the copolymer is from about 0.4 to 5 weight percent. 제1항에 있어서, 열적 수축이 약 1,5 내지 10%이고 결절 신장은 적어도 약 10%인 직물.The fabric of claim 1, wherein the thermal contraction is about 1,5 to 10% and the nodule stretch is at least about 10%. 제4항에 있어서, 열적 수축이 약 3 내지 5%인 직물.The fabric of claim 4 wherein the thermal shrinkage is about 3 to 5%. 제5항에 있어서, 열적 수축이 약 4%인 직물.6. The fabric of claim 5 wherein the thermal shrinkage is about 4%. 제1항에 있어서, 구성 모노필라멘트를 직조하여 직물을 형성토록 한 직물.The fabric of claim 1, wherein the woven monofilament is woven to form a fabric. 제1항에 있어서, 코폴리머로 구성되는 코일 및 힌지 사로부터 조합형성된 직물.The fabric of claim 1, wherein the fabric is a combination formed from a coil and a hinge yarn composed of a copolymer. 실의 적어도 일부분이 1, 4-디메틸옥시클로헥산, 테레프탈 산 및 이소프탈 산의 코폴리머와 저밀도 폴리에틸렌의 유효한 양의 혼합물로 구성되는 모노필라멘트인 초지기계 드라이어 직물로서, 상기 모노필라멘트에서; ⅰ) 포콜리머에서 테레프탈 산 대 이소프탈 산의 몰비가 약 83 : 17이고, ⅱ) 코폴리머의 고유점도가 30℃에서 60 : 40 중량비의 페놀과 1,1,2,2-테트라클로로에탄 내에서 ASTM 표준 방법 D-4603-86으로 측정하였을 때, 0.75dL/g보다 크고, ⅲ) 코폴리머가 유효한 양의 가수분해 안정제를 포함하고, ⅳ) 단순한 외벌 매듭으로 결절이 형성된 모노필라멘트 샘플의 파단시 신장량 측정하였을 때, 적어도 약 10%의 결절 신장을 나타내며, 그리고 ⅴ) 200℃에서의 모노필라멘트의 열적수축은 적어도 약 1%인 초지 기계 드라이어 직물.A papermaking dryer fabric, wherein at least a portion of the yarn is a monofilament consisting of a mixture of a copolymer of 1, 4-dimethyloxcyclohexane, terephthalic acid and isophthalic acid and an effective amount of low density polyethylene, wherein said monofilament; Iii) the molar ratio of terephthalic acid to isophthalic acid in the pocolimer is about 83:17, and ii) the intrinsic viscosity of the copolymer is 60:40 weight ratio of phenol and 1,1,2,2-tetrachloroethane at 30 ° C. (I) greater than 0.75 dL / g, as measured by ASTM standard method D-4603-86, iii) a copolymer comprising an effective amount of a hydrolytic stabilizer, iii) a nodular monofilament sample formed with a simple single knot. A papermaking machine dryer fabric having a nodule elongation of at least about 10% as measured by elongation at break, and i) a thermal shrinkage of monofilament at 200 ° C. at least about 1%. 제9항에 있어서, 폴리에틸렌을 약 0.5 내지 15중량% 포함하는 직물.10. The fabric of claim 9 comprising about 0.5 to 15 weight percent polyethylene. 제10항에 있어서, 폴리에틸렌을 약 1 내지 7중량% 포함하는 직물.The fabric of claim 10 comprising from about 1 to 7 weight percent polyethylene. 제9항에 있어서, 코폴리머의 고유 점도가 약 0.75 내지 1.5dL/g인 직물.10. The fabric of claim 9 wherein the copolymer has an inherent viscosity of about 0.75 to 1.5 dL / g. 제9항에 있어서, 코폴리머에 함유된 안정제의 양이 약 0.4 내지 5중량%인 직물.10. The fabric of claim 9 wherein the amount of stabilizer contained in the copolymer is from about 0.4 to 5 weight percent. 제9항에 있어서, 열적 수축이 약 1.5 내지 10%이고 결절 신장은 적어도 약 10%인 직물.The fabric of claim 9 wherein the thermal contraction is about 1.5 to 10% and the nodule stretch is at least about 10%. 제14항에 있어서, 열적 수축이 약 3 내지 5%인 직물.15. The fabric of claim 14 wherein the thermal shrinkage is about 3 to 5%. 제15항에 있어서, 열적 수축이 약 4%인 직물.The fabric of claim 15 wherein the thermal contraction is about 4%. 제9항에 있어서, 구성 모노필라멘트를 직조하여 직물을 형성토록 한 직물.10. The fabric of claim 9, wherein the woven monofilament is woven to form a fabric. 제9항에 있어서, 코폴리머로 구성되는 코일 및 힌지 사로부터 조합형성된 직물.10. The fabric of claim 9, wherein the fabric is formed from a coil and a hinge yarn consisting of a copolymer. 1, 4-디메틸옥시클로헥산, 테레프탈 산 및 이소프탈 산의 코폴리머와 섬유의 결절 특성을 향상시키는데 유효한 저밀도 폴리에틸렌의 유효한 양의 혼합물을 포함하는 모노필라멘트로서, 상기 모노필라멘트에서; ⅰ) 코폴리머에서 테레프탈 산 대 이소프탈 산의 몰비가 약 83 : 17이고, ⅱ) 코폴리머의 고유점도가 30℃에서 60 : 40 중량비의 페놀과 1,1,2,2-테트라클로로에탄 내에서 ASTM 표준 방법 D-4603-86으로 측정하였을 때, 0.75dL/g보다 크고, ⅲ) 코폴리머가 유효한 양의 가수분해 안정제를 포함하고, ⅳ) 단순한 외벌 매듭으로 결절이 형성된 모노필라멘트 샘플의 파단시 신장량 측정하였을 때, 적어도 약 10%의 결절 신장을 나타내며, 그리고 ⅴ) 200℃에서의 모노필라멘트의 열적 수축이 적어도 약 1%인 모노필라멘트.A monofilament comprising an effective amount of a mixture of 1, 4-dimethyloxcyclohexane, terephthalic acid and isophthalic acid and an effective amount of low density polyethylene effective to improve the nodular properties of the fiber, wherein said monofilament is in said monofilament; Iii) the molar ratio of terephthalic acid to isophthalic acid in the copolymer is about 83:17, and ii) the intrinsic viscosity of the copolymer in 60:40 weight ratio phenol and 1,1,2,2-tetrachloroethane at 30 ° C. Rupture of a monofilament sample larger than 0.75 dL / g, as measured by ASTM standard method D-4603-86, iii) the copolymer contains an effective amount of a hydrolysis stabilizer, and iii) nodules formed with a simple single knot. When measured by elongation at time, exhibiting at least about 10% nodular elongation, and iii) monofilaments having a thermal contraction of at least about 1% of the monofilament at 200 ° C. 제19항에 있어서, 폴리에틸렌을 약 0.5 내지 15중량% 포함하는 모노필라멘트.20. The monofilament of claim 19 comprising about 0.5 to 15 weight percent polyethylene. 제19항에 있어서, 폴리에틸렌을 약 1 내지 7중량% 포함하는 모노필라멘트.20. The monofilament of claim 19 comprising about 1 to 7 weight percent polyethylene. 제19항에 있어서, 코폴리머의 고유 점도가 약 0.75 내지 1.5dL/g인 모노필라멘트.20. The monofilament of claim 19 wherein the copolymer has an intrinsic viscosity of about 0.75 to 1.5 dL / g. 제19항에 있어서, 코폴리머에 함유된 안정제의 양이 약 0.4 내지 약 5중량%인 모노필라멘트.20. The monofilament of claim 19 wherein the amount of stabilizer contained in the copolymer is from about 0.4 to about 5 weight percent. 제19항에 있어서, 스펀 얀, 멀티필라멘트 얀 또는 편조사인 모노필라멘트.20. The monofilament of claim 19 which is a spun yarn, multifilament yarn or braided yarn. 제19항에 따른 모노필라멘트의 일부분을 포함하는 스펀 얀, 멀티필라멘트 얀 또는 편조사.Spun yarn, multifilament yarn or braid comprising a portion of the monofilament according to claim 19. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019960701481A 1994-08-04 1995-07-11 Papermaking machine dryer fabric KR960705105A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US28572194A 1994-08-04 1994-08-04
US08/285,721 1994-08-04
PCT/CA1995/000417 WO1996004422A1 (en) 1994-08-04 1995-07-11 Paper machine dryer fabrics

Publications (1)

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KR960705105A true KR960705105A (en) 1996-10-09

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EP (1) EP0722520A1 (en)
JP (1) JPH09503562A (en)
KR (1) KR960705105A (en)
AU (1) AU2919195A (en)
BR (1) BR9506303A (en)
CA (1) CA2172407A1 (en)
FI (1) FI961504A0 (en)
MX (1) MX9601301A (en)
NO (1) NO961349D0 (en)
WO (1) WO1996004422A1 (en)
ZA (1) ZA956183B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6231976B1 (en) 1997-08-28 2001-05-15 Eastman Chemical Company Copolyester binder fibers
CA2301522A1 (en) 1997-08-28 1999-03-04 Eastman Chemical Company Improved copolymer binder fibers
EP1029120B1 (en) * 1997-11-06 2003-08-13 Eastman Chemical Company Copolyester binder fibers
WO2017172313A1 (en) 2016-03-31 2017-10-05 Dow Global Technologies Llc Biscarbodiimides and polycarbodiimides and method for their preparation

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5822567B2 (en) * 1975-05-23 1983-05-10 旭化成株式会社 polyester monofilament
DE69031037T3 (en) * 1989-04-24 2008-05-21 Albany International Corp. papermaker
DE4307392C2 (en) * 1993-03-10 2001-03-29 Klaus Bloch Monofilament with increased hydrolysis resistance based on polyester for use in technical fabrics and processes for its manufacture
US5464890A (en) * 1993-11-12 1995-11-07 Shakespeare Company Polyester monofilaments extruded from a high temperature polyester resin blend with increased resistance to hydrolytic and thermal degradation and fabrics thereof

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AU2919195A (en) 1996-03-04
NO961349L (en) 1996-04-02
JPH09503562A (en) 1997-04-08
ZA956183B (en) 1996-03-08
NO961349D0 (en) 1996-04-02
WO1996004422A1 (en) 1996-02-15
CA2172407A1 (en) 1996-02-15
FI961504A (en) 1996-04-03
FI961504A0 (en) 1996-04-03
MX9601301A (en) 1998-11-29
BR9506303A (en) 1997-08-05
EP0722520A1 (en) 1996-07-24

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