KR960701953A - LOW GLOSS POLYMER BLEND COMPOSITIONS - Google Patents

LOW GLOSS POLYMER BLEND COMPOSITIONS

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Publication number
KR960701953A
KR960701953A KR1019950704376A KR19950704376A KR960701953A KR 960701953 A KR960701953 A KR 960701953A KR 1019950704376 A KR1019950704376 A KR 1019950704376A KR 19950704376 A KR19950704376 A KR 19950704376A KR 960701953 A KR960701953 A KR 960701953A
Authority
KR
South Korea
Prior art keywords
weight
copolymer
parts
monovinylidene aromatic
composition
Prior art date
Application number
KR1019950704376A
Other languages
Korean (ko)
Inventor
헨리쿠스 제이. 엠. 반 듀크
사라다 피. 나마타
마틴 제이. 게스트
Original Assignee
스티븐 에스. 그레이스
더 다우 케미칼 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 스티븐 에스. 그레이스, 더 다우 케미칼 캄파니 filed Critical 스티븐 에스. 그레이스
Publication of KR960701953A publication Critical patent/KR960701953A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

본 발명은 저광택과 함께 개선된 가공성 및 우수한 물리적 성질을 갖는 열가소성 중합체 블렌드 조성물을 제공하며, 이 블렌드는 폴리카보네이트 중합체, 적은 수준의 에폭시 그룹-함유 공중합체, 괴상(mass) 공정에 의해 제조되고 고무-개질된 하나 이상의 모노비닐리덴 방향족 공중합체, 유화(emulsion) 공정에 의해 제조되고 고무-개질된 하나 이상의 모노비닐리덴 방향족 공중합체, 및 선택적으로 모노비닐리덴 방향족 공중합체를 포함한다.The present invention provides a thermoplastic polymer blend composition having low gloss with improved processability and good physical properties, which blend is made by polycarbonate polymer, low level epoxy group-containing copolymer, mass process and rubber One or more monovinylidene aromatic copolymers modified, one or more monovinylidene aromatic copolymers produced and rubber-modified by an emulsion process, and optionally monovinylidene aromatic copolymers.

Description

저광택 중합체 블렌드 조성물(LOW GLOSS POLYMER BLEND COMPOSITIONS)LOW GLOSS POLYMER BLEND COMPOSITIONS

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (10)

(A) 35 내지 90 중량부의 방향족 카보네이트 중합체; (B) 1 내지 99중량%의 괴상(mass) 중합된 고무-개질된 공중합체(B1), 1 내지 99중량%의 유화(emulsion) 중합된 고무-개질된 공중합체(B2), 및 0 내지 98중량%의 모노비닐리덴 방향족 공중합체(B3)를 포함하는, 10 내지 65 중량부의 모노비닐리덴 방향족 공중합체의 혼합물; 및 (C) 0.1 내지 15중량부의 에폭시-함유 알렌 공중합체를 포함하는, 개선된 유동 특성을 갖는 저광택 열가소성 블렌드 조성물.(A) 35 to 90 parts by weight of aromatic carbonate polymer; (B) 1 to 99% by weight of mass polymerized rubber-modified copolymer (B1), 1 to 99% by weight of emulsion polymerized rubber-modified copolymer (B2), and 0 to A mixture of 10 to 65 parts by weight of monovinylidene aromatic copolymer, comprising 98% by weight of monovinylidene aromatic copolymer (B3); And (C) 0.1 to 15 parts by weight of an epoxy-containing allene copolymer. 제1항에 있어서, 성분(A) 대 성분(B)의 비율이 40:60 내지 85:15인 조성물.The composition of claim 1 wherein the ratio of component (A) to component (B) is 40:60 to 85:15. 제1항에 있어서, 1 내지 10 중량부의 성분(C)를 포함하는 조성물.The composition of claim 1 comprising 1 to 10 parts by weight of component (C). 제1항에 있어서, 2 내지 8 중량부의 성분(C)를 포함하는 조성물.The composition of claim 1 comprising 2 to 8 parts by weight of component (C). 제1항에 있어서, 모노비닐리덴 방향족 공중합체가 스티렌 또는 알파 메틸 스티렌을 포함하는 모노비닐리덴 방향족 단량체, 및 아크릴로니트릴, 메틸 메타크릴레이트, 말레산 무수물 또는 N-페닐 말레이미드를 포함하는 공단량체로부터 유도되는 조성물.The process of claim 1 wherein the monovinylidene aromatic copolymer comprises a monovinylidene aromatic monomer comprising styrene or alpha methyl styrene and a co-containing acrylonitrile, methyl methacrylate, maleic anhydride or N-phenyl maleimide. Compositions Derived from Monomers. 제1항에 있어서, 유화 중합된 고무-개질된 공중합체가 스티렌/아크릴로니트릴 그래프트된 고무 및 메틸메타크릴레이트/스티렌 그래프트된 탄성중합체를 포함하는 조성물.The composition of claim 1 wherein the emulsion polymerized rubber-modified copolymer comprises styrene / acrylonitrile grafted rubber and methylmethacrylate / styrene grafted elastomer. 제1항에 있어서, 에폭시-함유 알켄 공중합체가 에틸렌, 글리시딜 메타크릴레이트와, 선택적으로 비닐아세테이트 또는 메틸 아크릴레이트를 포함하는, 하나 이상의 추가의 에틸렌계 불포화 화합물의 공중합체를 포함하는 조성물.The composition of claim 1, wherein the epoxy-containing alkene copolymer comprises a copolymer of ethylene, glycidyl methacrylate, and one or more additional ethylenically unsaturated compounds, optionally including vinyl acetate or methyl acrylate. . 제1항에 있어서, 에폭시-함유 알켄 공중합체가 글리시딜 메타크릴레이트를 포함하는 조성물.The composition of claim 1, wherein the epoxy-containing alkene copolymer comprises glycidyl methacrylate. 제1항에 있어서, 40 내지 85 중량부의 방향족 카보네이트 중합체; 15 내지 60 중량부의 모노비닐리덴방향족 공중합의 혼합물(B); 및 1 내지 10중량부의 에폭시-함유 알켄 공중합체를 포함하는 조성물.The method of claim 1, wherein 40 to 85 parts by weight of the aromatic carbonate polymer; A mixture (B) of 15 to 60 parts by weight of monovinylidene aromatic copolymer; And 1 to 10 parts by weight of an epoxy-containing alkene copolymer. 제9항에 있어서, 20 내지 80중량%의 괴상 중합된 고무-개질된 공중합체(B1); 80 내지 20중량%의 유화중합된 고무-개질된 공중합체(B2); 및 0 내지 60중량%의 모노비닐리덴 방향족 공중합체(B3)를 포함하는 조성물.10. The process of claim 9, wherein the bulk polymerized rubber-modified copolymer (B1) is from 20 to 80% by weight; 80-20% by weight of the emulsion polymerized rubber-modified copolymer (B2); And 0 to 60% by weight of monovinylidene aromatic copolymer (B3). ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950704376A 1993-04-08 1994-04-07 LOW GLOSS POLYMER BLEND COMPOSITIONS KR960701953A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US4554693A 1993-04-08 1993-04-08
US08/045,546 1993-04-08
PCT/US1994/003854 WO1994024210A1 (en) 1993-04-08 1994-04-07 Low gloss polymer blend compositions

Publications (1)

Publication Number Publication Date
KR960701953A true KR960701953A (en) 1996-03-28

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Application Number Title Priority Date Filing Date
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Country Status (5)

Country Link
EP (1) EP0693095A1 (en)
JP (1) JPH08508783A (en)
KR (1) KR960701953A (en)
CA (1) CA2159351A1 (en)
WO (1) WO1994024210A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019212222A1 (en) * 2018-04-30 2019-11-07 롯데첨단소재(주) Thermoplastic resin composition and molded article comprising same
KR20190125950A (en) * 2018-04-30 2019-11-07 롯데첨단소재(주) Thermoplastic resin composition and article including same

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0714941B1 (en) * 1994-11-21 1998-02-04 General Electric Company Impact modified alpha-alkyl vinyl aromatic-vinyl cyanide copolymer compositions
JP2002105299A (en) * 2000-09-29 2002-04-10 Asahi Kasei Corp Polycarbonate flame-retardant resin composition
KR100376279B1 (en) * 2000-11-06 2003-03-17 금호케미칼 주식회사 A resin compositions having impact, thermal resistance and good processibility
JP4679011B2 (en) * 2001-09-27 2011-04-27 三菱エンジニアリングプラスチックス株式会社 Polycarbonate resin composition
US6849687B2 (en) * 2002-08-01 2005-02-01 Bayer Polymers Llc Thermoplastic composition having low gloss appearance
DE102005058836A1 (en) 2005-12-09 2007-06-14 Bayer Materialscience Ag Polycarbonate molding compositions
US8222350B2 (en) 2007-02-12 2012-07-17 Sabic Innovative Plastics Ip B.V. Low gloss polycarbonate compositions
US8222351B2 (en) 2007-02-12 2012-07-17 Sabic Innovative Plastics Ip B.V. Low gloss polycarbonate compositions
CN101469120B (en) * 2007-12-25 2012-10-17 上海普利特复合材料股份有限公司 Low brightness, high impact and high flowablity polycarbonate composition
KR101453772B1 (en) 2010-10-22 2014-10-21 제일모직 주식회사 Polycarbonate resin composition and molded product using the same

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US4444950A (en) * 1982-03-15 1984-04-24 Sumitomo Naugatuck Co., Ltd. Thermoplastic resin composition
US4526926A (en) * 1983-04-22 1985-07-02 The Dow Chemical Company Low gloss carbonate polymer blends
DE3615608A1 (en) * 1986-05-09 1987-11-12 Basf Ag THERMOPLASTIC MOLDING DIMENSIONS BASED ON POLYCARBONATE, 2 GRAFT BLENDER POLYMERISATS DIFFERENT GRAIN BASE (ASA + AES) AND VINYLAROMATE / COPOLYMERISATE CONTAINING
WO1991013119A1 (en) * 1990-02-21 1991-09-05 Exxon Chemical Limited Impact modified thermoplastic polyester
JP2955944B2 (en) * 1990-03-29 1999-10-04 三菱レイヨン株式会社 Thermoplastic resin composition with improved fatigue properties
DE4122871A1 (en) * 1990-11-29 1992-06-04 Bayer Ag ABS MOLDS

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019212222A1 (en) * 2018-04-30 2019-11-07 롯데첨단소재(주) Thermoplastic resin composition and molded article comprising same
KR20190125950A (en) * 2018-04-30 2019-11-07 롯데첨단소재(주) Thermoplastic resin composition and article including same

Also Published As

Publication number Publication date
CA2159351A1 (en) 1994-10-27
WO1994024210A1 (en) 1994-10-27
EP0693095A1 (en) 1996-01-24
JPH08508783A (en) 1996-09-17

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