KR960034379A - Pure composition for soluble type cutting fluid - Google Patents

Pure composition for soluble type cutting fluid Download PDF

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Publication number
KR960034379A
KR960034379A KR1019960005806A KR19960005806A KR960034379A KR 960034379 A KR960034379 A KR 960034379A KR 1019960005806 A KR1019960005806 A KR 1019960005806A KR 19960005806 A KR19960005806 A KR 19960005806A KR 960034379 A KR960034379 A KR 960034379A
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group
integer
mass
ethylene
amines
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KR1019960005806A
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KR100187648B1 (en
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히데오 요코타
토시아키 와카바야시
마사노리 아이비
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오오자와 히데지로오
닛봉 세키유 가부시키가이샤
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/30—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/32—Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
    • C10M107/34—Polyoxyalkylenes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

본 발명은 하기 (A)~(D)로 구성되는 가용성 타입의 절삭액용 순수한 조성물에 관한 것이다: (A)하기식을 갖는 15~50 질량%의 블로킹된 폴리옥시알킬렌 화합물:The present invention relates to a pure composition for a soluble type cutting fluid comprising (A) - (D): (A) from 15 to 50 mass% of a blocked polyoxyalkylene compound having the formula:

HO-(R1-O)a-(R2-O)b-(R3-O)c-H (Ⅰ)HO- (R 1 -O) a- (R 2 -O) b- (R 3 -O) c H (I)

(상기 식에서, R1및 R3각각은 프로필렌 기이고, R2는 에틸렌 기이고, a 및 c 각각은 1~40의 정수이고, b는 3~40의 정수이고, a, b 및 c의 합계는 15≤a+b+c≤100이고, (a+c)/b의 비는 1.0≤(a+c)/b≤4.0이다); (B) 1.0~15 질량%의 C8~C10지방산; (C) 알칼리 금속 수산화물, 지방족 아민, 지환식 아민, 방향족 아민, 알카놀 아민, 및 하기 식의 질소-함유 화합물로 구성되는 군:Wherein each of R 1 and R 3 is a propylene group, R 2 is an ethylene group, each of a and c is an integer of 1 to 40, b is an integer of 3 to 40, and the sum of a, b and c A + b + c? 100, and the ratio of (a + c) / b is 1.0? (A + c) / b? 4.0; (B) from 1.0 to 15 wt% C 8 ~ C 10 fatty acids; (C) a group consisting of alkali metal hydroxides, aliphatic amines, alicyclic amines, aromatic amines, alkanol amines, and nitrogen-containing compounds of the formula:

(상기 식에서, R4는 C1~C24탄화수소 기이고, R5는 에틸렌 또는 프로필렌기이고, d는 1~30의 정수이고, X는 수소, C1~C24탄화수소 기 또는 일반식-(R6-O)e(이때, R6은 에틸렌 또는 프로필렌 기이고, e는 1~30의 정수임)의 기이다)으로부터 선택되고, 상기 지방산(B)의 중화 당량을 초과하는 양으로 첨가되는 적어도 한 염기성 화합물(이때, (B)와 (C)의 합계는 1.1~85 질량% 범위내임); 및 (D) 전체 조성물을 기준으로 0~60질량%의 양으로 첨가된 물.(Wherein R 4 is a C 1 to C 24 hydrocarbon group, R 5 is an ethylene or propylene group, d is an integer of 1 to 30, X is hydrogen, a C 1 to C 24 hydrocarbon group, R 6 -O) e wherein R 6 is an ethylene or propylene group and e is an integer from 1 to 30, and wherein at least One basic compound, wherein the sum of (B) and (C) is in the range of 1.1 to 85 mass%; And (D) water added in an amount of 0 to 60 mass% based on the total composition.

본 발명의 절삭액은 공급 펌프의 부품의 기계적 마모에 대한 높은 내성, 불유쾌한 기포의 억제 및 절삭 기계에서 윤활유로부터 분리력을 포함하는 만족스러운 품질을 보유한다.The cutting fluid of the present invention possesses satisfactory quality, including high resistance to mechanical wear of parts of the feed pump, suppression of unpleasant bubbles, and separation from the lubricant in the cutting machine.

Description

가용성 타입의 절삭액용 순수한 조성물Pure composition for soluble type cutting fluid

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is a trivial issue, I did not include the contents of the text.

Claims (6)

하기 (A)~(D)로 구성되는 가용성 타입의 절삭액용 순수한 조성물: (A)하기 식을 갖는 15~50 질량%의 블로킹된 폴리옥시알킬렌 화합물:A pure composition for a soluble type cutting fluid comprising (A) - (D): (A) 15 to 50 mass% of a blocked polyoxyalkylene compound having the formula: HO-(R1-O)a-(R2-O)b-(R3-O)c-H (Ⅰ)HO- (R 1 -O) a- (R 2 -O) b- (R 3 -O) c H (I) (상기 식에서, R1및 R3각각은 프로필렌 기이고, R2는 에틸렌 기이고, a 및 c 각각은 1~40의 정수이고, b는 3~40의 정수이고, a,b, 및 c의 합계는 15≤a+b+c≤100이고, (a+c)/b의 비는 1.0≤(a+c)/b≤4.0이다); (B) 1.0~15 질량%의 C8~C10지방산; (C) 알칼리 금속 수산화물, 지방족 아민, 지환식 아민, 방향족 아민, 알카놀 아민, 및 하기 식의 질소-함유 화합물로 구성되는 군:Wherein each of R 1 and R 3 is a propylene group, R 2 is an ethylene group, each of a and c is an integer of 1 to 40, b is an integer of 3 to 40, and a, b, and c The sum is 15 a + b + c 100, and the ratio of (a + c) / b is 1.0 (a + c) / b 4.0. (B) from 1.0 to 15 wt% C 8 ~ C 10 fatty acids; (C) a group consisting of alkali metal hydroxides, aliphatic amines, alicyclic amines, aromatic amines, alkanol amines, and nitrogen-containing compounds of the formula: (상기 식에서, R4는 C1~C24탄화수소기이고, R5는 에틸렌 또는 프로필렌기이고, d는 1~30의 정수이고, X는 수소, C1~C24탄화수소기 또는 일반식-(R6-O)e(이때, R6은 에틸렌 또는 프로필렌기이고, e는 1~30의 정수임)의 기이다)으로부터 선택되고, 상기 지방산(B)의 중화 당량을 초과하는 양으로 첨가되는 적어도 한 염기성 화합물(이때,(B)와 (C)의 합계는 1.1~85 질량% 범위내임); 및 (D) 전체 조성물을 기준으로 0~60질량%의 양으로 첨가된 물.(Wherein R 4 is a C 1 to C 24 hydrocarbon group, R 5 is an ethylene or propylene group, d is an integer of 1 to 30, X is hydrogen, a C 1 to C 24 hydrocarbon group, R 6 -O) e wherein R 6 is an ethylene or propylene group and e is an integer from 1 to 30, and wherein at least One basic compound, wherein the sum of (B) and (C) is in the range of 1.1 to 85 mass%; And (D) water added in an amount of 0 to 60 mass% based on the total composition. 제1항에 있어서, 상기 성분(A)의 함량이 전체 조성물을 기준으로 20~45질량%의 범위내인 가용성 타입의 절삭액용 순수한 조성물.The pure composition of claim 1, wherein the content of component (A) is in the range of 20 to 45 mass% based on the total composition. 제1항에 있어서, 상기 성분(B)가 C8-C9직쇄 또는 분지쇄 포화 지방산인 가용성 타입의 절삭액용 순수한 조성물.The pure composition of claim 1, wherein said component (B) is a C 8 -C 9 linear or branched saturated fatty acid. 제1항에 있어서, 상기 성분(B)의 함량이 전체 조성물을 기준으로 5.0~12 질량%의 범위내인 가용성 타입의 절삭액용 순수한 조성물.The pure composition of claim 1, wherein the content of component (B) is in the range of 5.0 to 12 mass% based on the total composition. 제1항에 있어서, 상기 성분(C)가 수산화나트륨, 수산화칼륨, C1~C9알카놀 아민 및 상기 일반식(Ⅱ)(이 때, R4및 X는 C1~C10직쇄 또는 분지된 알킬기, C5~C7시클로헥실기 또는 C7~C9직쇄 또는 분지쇄 알킬시클로헥실기이고, R5는 에틸렌기이고, d는 3~20의 정수임)의 질소-함유 화합물로 구성되는 군으로부터 선택된 가용성 타입의 절삭액용 순수한 조성물.The method of claim 1 wherein said component (C) is selected from the group consisting of sodium hydroxide, potassium hydroxide, C 1 -C 9 alkanolamine and said formula (II) wherein R 4 and X are C 1 -C 10 linear or branched Containing compound of the following formula (1): wherein R 1 is an alkyl group, a C 5 -C 7 cyclohexyl group or a C 7 -C 9 linear or branched alkylcyclohexyl group, R 5 is an ethylene group, and d is an integer of 3 to 20 Lt; RTI ID = 0.0 > 1, < / RTI > 희석제로서 물 및 또한 하기 (A)~(C)로 구성되는 물-기재 가용성 타입의 절삭액 조성물: (A) 하기식을 갖는 0.3~10질량%의 블로킹된 폴리옥시알킬렌 화합물:A water-based soluble type cutting fluid composition comprising water as a diluent and also comprising (A) - (C): (A) 0.3 to 10 mass% of a blocked polyoxyalkylene compound having the formula: HO-(R1-O)a-(R2-O)b-(R3-O)c-H (Ⅰ)HO- (R 1 -O) a- (R 2 -O) b- (R 3 -O) c H (I) (상기 식에서, R1및 R3각각은 프로필렌 기이고, R2는 에틸렌 기이고, a 및 c 각각은 1~40의 정수이고, b는 3~40의 정수이고, a,b, 및 c의 합계는 15≤a+b+c≤100이고, (a+c)/b의 비는 1.0≤(a+c)/b≤4.0이다); (B) 0.02~3.0 질량%의 C8~C10지방산; (C) 알칼리 금속 수산화물, 지방족 아민, 지환식 아민, 방향족 아민, 알카놀 아민, 및 하기 식의 질소-함유 화합물로 구성되는 군:Wherein each of R 1 and R 3 is a propylene group, R 2 is an ethylene group, each of a and c is an integer of 1 to 40, b is an integer of 3 to 40, and a, b, and c The sum is 15 a + b + c 100, and the ratio of (a + c) / b is 1.0 (a + c) / b 4.0. (B) of 0.02 to 3.0 mass% C 8 ~ C 10 fatty acids; (C) a group consisting of alkali metal hydroxides, aliphatic amines, alicyclic amines, aromatic amines, alkanol amines, and nitrogen-containing compounds of the formula: (상기 식에서, R4는 C1~C24탄화수소기이고, R5는 에틸렌 또는 프로필렌기이고, d는 1~30의 정수이고, X는 수소, C1~C24탄화수소기 또는 일반식-(R6-O)e(이때, R6은 에틸렌 또는 프로필렌기이고, e는 1~30의 정수임)의 기이다)으로부터 선택되고, 상기 지방산(B)의 중화 당량을 초과하는 양으로 첨가되는 적어도 한 염기성 화합물(Wherein R 4 is a C 1 to C 24 hydrocarbon group, R 5 is an ethylene or propylene group, d is an integer of 1 to 30, X is hydrogen, a C 1 to C 24 hydrocarbon group, R 6 -O) e wherein R 6 is an ethylene or propylene group and e is an integer from 1 to 30, and wherein at least One basic compound ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: It is disclosed by the contents of the first application.
KR1019960005806A 1995-03-07 1996-03-06 Neat composition for soluble-type cutting fluid KR100187648B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP07456995A JP3391930B2 (en) 1995-03-07 1995-03-07 Water-soluble cutting oil stock solution composition and water-soluble cutting oil composition
JP95-74569 1995-03-07

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KR960034379A true KR960034379A (en) 1996-10-22
KR100187648B1 KR100187648B1 (en) 1999-06-01

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3267894B2 (en) * 1997-05-26 2002-03-25 協同油脂株式会社 Water-soluble oil for metal processing
JPH11279581A (en) * 1998-03-26 1999-10-12 Kyodo Yushi Co Ltd Metal processing water soluble oil
JP3910790B2 (en) * 2000-09-07 2007-04-25 協同油脂株式会社 Water-soluble metal processing oil
JP4808855B2 (en) 2001-03-23 2011-11-02 協同油脂株式会社 Lubricant composition
TW593669B (en) 2001-11-21 2004-06-21 Ciba Sc Holding Ag Aqueous functional fluids with antioxidants
JP2006096951A (en) * 2004-09-30 2006-04-13 Kyodo Yushi Co Ltd Water-soluble machining oil, slurry, and machining method
JP2007099906A (en) * 2005-10-05 2007-04-19 Asahi Glass Co Ltd Water-soluble metal forming fluid composition
US20090149359A1 (en) * 2007-12-10 2009-06-11 Hundley Lloyd E Formulation of a metal working fluid
JP5576615B2 (en) * 2009-03-11 2014-08-20 出光興産株式会社 Metalworking fluid
JP5502349B2 (en) * 2009-03-13 2014-05-28 出光興産株式会社 Water based lubricant
JP5785625B2 (en) * 2014-01-14 2015-09-30 出光興産株式会社 Metalworking fluid
CN108285824A (en) * 2017-12-22 2018-07-17 上海康达新能源材料有限公司 A kind of hard brittle material multi-wire saw coolant liquid
CN108277078B (en) * 2018-03-23 2020-09-01 江苏乐美新材料科技有限公司 Cooling agent for linear cutting, cooling liquid and application thereof

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JPH08239683A (en) 1996-09-17
KR100187648B1 (en) 1999-06-01
TW373018B (en) 1999-11-01
JP3391930B2 (en) 2003-03-31

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