KR960022747A - Polyolefin resin coating film and plant cultivation method - Google Patents

Polyolefin resin coating film and plant cultivation method Download PDF

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KR960022747A
KR960022747A KR1019950048028A KR19950048028A KR960022747A KR 960022747 A KR960022747 A KR 960022747A KR 1019950048028 A KR1019950048028 A KR 1019950048028A KR 19950048028 A KR19950048028 A KR 19950048028A KR 960022747 A KR960022747 A KR 960022747A
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polyolefin resin
coating film
sulfur
resin coating
plant
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고조 고따니
다이이찌 사까야
히데오 네까와
마꼬또 나까가하라
아끼 구도
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고오사이 아끼오
스미또모가가꾸고오교 가부시끼가이샤
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/14—Greenhouses
    • A01G9/1438—Covering materials therefor; Materials for protective coverings used for soil and plants, e.g. films, canopies, tunnels or cloches
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/10—Metal compounds
    • C08K3/105—Compounds containing metals of Groups 1 to 3 or of Groups 11 to 13 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3435—Piperidines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/04—Polyethylene
    • B32B2323/046—LDPE, i.e. low density polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/25—Greenhouse technology, e.g. cooling systems therefor

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  • Chemical & Material Sciences (AREA)
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  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Soil Sciences (AREA)
  • Environmental Sciences (AREA)
  • Greenhouses (AREA)
  • Protection Of Plants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
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Abstract

시설원예 하우스ㆍ터널재배에 있어서, 무기유활제인 토양 및/또는 식물을 처리하여도 열화가 생기지 않는 피복필름 및 재배방법을 제공하는 것이다.Facility Horticulture House and tunnel cultivation provide a coating film and a cultivation method that do not cause deterioration even after treatment with soil and / or plants as inorganic lubricants.

힌다드아민계 화합물, 하이드로 탈사이트류 화합물, 자외선 흡수제 및 폴리올레핀계 수지로부터 이룬, 무기 유황제를 사용하는 시설원예 하우스 터널재배용 폴리올레핀계 수지 피복필름 및 식물의 재배방법.A method of cultivating a polyolefin resin coating film for plant horticulture house tunnel cultivation and a plant using an inorganic sulfur agent made from a hindered amine compound, a hydrotalcite compound, an ultraviolet absorber, and a polyolefin resin.

Description

폴리올레핀계 수지 피복필름 및 식물의 재배 방법Polyolefin resin coating film and plant cultivation method

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (32)

힌다드아민계 화합물, 하이드로탈사이트류 화합물, 자외선 흡수제 및 폴리올레핀계 수지로부터 이루어지고, 무기유황제로 토양 및/또는 식물을 처리하는 시설원예 하우스ㆍ터널 재배에 사용되는 것을 특징으로 하는 폴리올레핀계 수지 피복 필름.Polyolefin resin coating comprising a hindered amine compound, a hydrotalcite compound, an ultraviolet absorber, and a polyolefin resin, and used for planting horticulture houses and tunnels for treating soil and / or plants with inorganic sulfur. film. 제1항에 있어서, 폴리올레핀계 수지 피복필름 중의 힌다드아민계 화합물이 0.02 내지 5중량% 하이드로탈사이트류 화합물이 0.1 내지 25중량%, 및 자외선 흡수제가 0.01 내지 3중량%인 것을 특징으로 하는 폴리올레핀계 수지 피복필름.2. The polyolefin according to claim 1, wherein the hindered amine compound in the polyolefin resin coating film is from 0.02 to 5% by weight of the hydrotalcite compound, from 0.1 to 25% by weight, and the ultraviolet absorber is from 0.01 to 3% by weight. Resin coated film. 제2항에 있어서, 폴리올레핀계 수지 피복필름이 적어도 2이상의 층으로 이루어진 다층 구성인 것을 특징으로 하는 폴리올레핀계 수지 피복필름.The polyolefin resin coating film according to claim 2, wherein the polyolefin resin coating film has a multilayered structure composed of at least two layers. 제3항에 있어서, 폴리올레핀계 수지 피복필름이 3층으로 된 것을 특징으로 하는 폴리올레핀계 수지 피복필름.The polyolefin resin coating film according to claim 3, wherein the polyolefin resin coating film has three layers. 제2항 또는 제3항에 있어서, 폴리올레핀계 수지가 폴리에틸렌, 에틸렌-α-올레핀 공중합체 및 에틸렌-아세트산 비닐공중합체로부터 선택되는 적어도 1종인 것을 특징으로 하는 폴리올레핀계 수지 피복필름.The polyolefin resin coating film according to claim 2 or 3, wherein the polyolefin resin is at least one selected from polyethylene, ethylene-α-olefin copolymers and ethylene-vinyl acetate copolymers. 제5항에 있어서 폴리올레핀이 밀도 0.93g/㎠ 이하의 저밀도 폴리에틸렌인 것을 특징으로 하는 폴리올레핀계 수지 피복필름.The polyolefin resin coating film according to claim 5, wherein the polyolefin is a low density polyethylene having a density of 0.93 g / cm 2 or less. 제1항에 있어서, 무기유황제가 석회유황합체 , 유황분제, 수화유황제, 유황훈연제 및 석회유황 에어졸로 부터 선택된 적어도 1종인 것을 특징으로 하는 폴리올레핀계 수지 피복필름.The polyolefin resin coating film according to claim 1, wherein the inorganic sulfur agent is at least one selected from lime sulfur copolymers, sulfur powders, hydrated sulfur agents, sulfur smokers and lime sulfur aerosols. 폴리올레핀계 수지필름으로 피복이 된 시설원예 하우스ㆍ터널내에서 토양 및/또는 식물을 무기유황제로 처리하는 방법에 있어서, 그 필름이 힌다드아민계 화합물, 하디드로탈사이트류 화합물, 자외선 흡수제 및 폴리올레핀계 수지로 부터 이루어진 것을 특징으로 하는 폴리올레핀계 수지 피복필름인 방법.In a method for treating soil and / or plants with an inorganic sulfur agent in a facility gardening house tunnel covered with a polyolefin resin film, the film is a hindered amine compound, a harddrotalcite compound, an ultraviolet absorber, and a polyolefin. A method of coating a polyolefin resin coating film, characterized in that made from a resin. 제8항에 있어서, 폴리올레핀계 수지 피복필름 중의 힌다드아민계 화합물이 0.02 내지 5중량%, 하이드로탈사이드류 화합물이 0.1 내지 25중량%, 및 자외선 흡수제가 0.01 내지 3중량%인 것을 특징으로 하는 방법.The polyolefin-based resin coating film according to claim 8, wherein the hindered amine compound is 0.02 to 5% by weight, the hydrotalcide compound is 0.1 to 25% by weight, and the ultraviolet absorber is 0.01 to 3% by weight. Way. 제9항에 있어서, 폴리올레핀계 수지 피복필름이 적어도 2 이상의 층으로 된 다층 구성인 것을 특징으로 하는 방법.10. The method according to claim 9, wherein the polyolefin-based resin coated film has a multilayer structure of at least two or more layers. 제10항에 있어서, 폴리올레핀계 수지 피복필름이 3층으로 된 것을 특징으로 하는 방법.The method according to claim 10, wherein the polyolefin resin coating film has three layers. 제9항 또는 제10항에 있어서, 폴리올레핀계 수지가 폴리에틸렌, 에틸렌-α-올레핀 공중합체 및 에틸렌 아세트산 비닐 공중합체로부터 선택되는 적어도 1종인 것을 특징으로 하는 방법.The method according to claim 9 or 10, wherein the polyolefin resin is at least one selected from polyethylene, ethylene-α-olefin copolymers and ethylene vinyl acetate copolymers. 제12항에 있어서, 폴리올레핀계 수지가 밀도 0.93g/㎠ 이하의 저밀도 폴리에틸렌인 것을 특징으로 하는 방법.The method according to claim 12, wherein the polyolefin resin is a low density polyethylene having a density of 0.93 g / cm 2 or less. 제8항에 있어서, 무기유황제가 석회유황합제, 유황분제, 수화유황제, 유황훈연제 및 석회유황 에어졸에서 선택되는 적어도 1종인 것을 특징으로 하는 방법.9. The method of claim 8, wherein the inorganic sulfur agent is at least one selected from lime sulfur mixtures, sulfur powders, hydrated sulfur agents, sulfur smokers, and lime sulfur aerosols. 폴리올레핀계 수지 필름으로 피복이 된 시설원예 하우스ㆍ터널내에서, 적어도 한번 토양 및/또는 식물을 무기유황제로 처리하는 식물의 재배방법에 있어서, 그 필름이 힌다드아민계 화합물, 하이드로탈사이드류 화합물, 자외선 흡수재 및 폴리올레핀계 수지로 된 것을 특징으로 하는 폴리올레핀계 수지 피복필름인 식물의 재배 방법.In a plant horticulture house tunnel covered with a polyolefin resin film, a method of cultivating a plant in which the soil and / or the plant is treated with an inorganic sulfur agent, wherein the film is a hindered amine compound or a hydrotalside compound. And a UV absorber and a polyolefin resin, wherein the plant is a polyolefin resin coated film. 제15항에 있어서, 폴리올레핀계 수지 피복필름 중의 힌다드아민계 화합물이 0.02 내지 5중량%, 하이드로탈사이트류 화합물이 0.1 내지 25중량% 및 자외선 흡수제가 0.01 내지 3중량%인 것을 특징으로 하는 식물의 재배방법.The plant according to claim 15, wherein the hindered amine compound in the polyolefin resin coating film is 0.02 to 5% by weight, the hydrotalcite compound is 0.1 to 25% by weight and the ultraviolet absorber is 0.01 to 3% by weight. Method of cultivation. 제16항에 있어서, 폴리올레핀계 수지 피복필름이 적어도 2이상의 층으로 된 다층 구성인 것을 특징으로 하는 식물의 재배방법.The plant cultivation method according to claim 16, wherein the polyolefin resin coating film has a multi-layer structure composed of at least two layers. 제17항에 있어서, 폴리올레핀계 수지 피복필름이 3층으로 된 것을 특징으로 하는 식물의 재배방법.18. The plant cultivation method according to claim 17, wherein the polyolefin resin coating film has three layers. 제16항 또는 제17항에 있어서, 폴리올레핀계 수지가 폴리에틸렌, 에틸렌-α-올레핀 공중합체 및 에틸렌-아세트산 비닐공중합체로부틱 선택되는 적어도 1종인 식물 재배방법.The plant cultivation method according to claim 16 or 17, wherein the polyolefin resin is at least one selected from polyethylene, ethylene-α-olefin copolymer and ethylene-vinyl acetate copolymer. 제19항에 있어서, 폴리올레핀계 수지가 밀도 0.93g/㎠ 이하의 저밀도 폴리에틸렌인 것을 특징으로 하는 식물의 재배방법.The plant cultivation method according to claim 19, wherein the polyolefin resin is low density polyethylene having a density of 0.93 g / cm 2 or less. 제15항에 있어서, 무기유황제가 석회유황합제, 유황분제, 수화유황제, 유황훈연제 및 석회유황 에어졸에서 선택되는 적어도 1종인 것을 특징으로 하는 식물의 재배방법.16. The method for cultivating a plant according to claim 15, wherein the inorganic sulfur agent is at least one selected from lime sulfur mixture, sulfur powder, hydrated sulfur agent, sulfur smoker and lime sulfur aerosol. 제15항에 있어서, 식물이 과수류인 것을 특징으로 하는 재배방법.The method of cultivation according to claim 15, wherein the plant is a fruit tree. 제15항에 있어서, 식물이 딸기, 멜론, 수박, 오이, 장미, 국화인 것을 특징으로 하는 재배방법.The method of claim 15, wherein the plant is a strawberry, melon, watermelon, cucumber, rose, chrysanthemum. 시설원예 하우스ㆍ터널내에서 적어도 한번, 토양 및/또는 석물을 무기유황제로 처리하는 시설원예 하우스ㆍ터널 재배에 있어서, 힌다드아민계 화합물, 하이드로탈사이트류 화합물, 자외선 흡수제 및 폴리올레핀계 수지로부터 이루어진 폴리올레핀계 수지 피복필름을 시설원예 하우스ㆍ터널의 피복필름으로 사용하는 것을 특징으로 하는 방법.Facility horticulture House tunnel for treating soil and / or stone with inorganic sulfur at least once in a house tunnel, comprising a hindered amine compound, a hydrotalcite compound, an ultraviolet absorber and a polyolefin resin. A method characterized by using a polyolefin resin coating film as a coating film of a facility horticulture house tunnel. 제24항에 있어서, 폴리올레핀계 수지 피복필름 중의 힌다드아민계 화합물이 0.02 내지 5중량%, 하이드로 탈사이트류 화합물이 0.1 내지 25중량% 및 자외선 흡수제가 0.01 내지 3중량%인 폴리올레핀계 수지 피복필름을 피복필름으로서 사용하는 것을 특징으로 하는 방법.25. The polyolefin resin coating film according to claim 24, wherein the hindered amine compound in the polyolefin resin coating film is 0.02 to 5 wt%, the hydrotalcite compound is 0.1 to 25 wt%, and the ultraviolet absorber is 0.01 to 3 wt%. Using as a coating film. 제25항에 있어서, 적어도 2이상의 층으로 된 다층 구성인 폴리올레핀계 수지 피복필름을 피복필름으로서 사용하는 것을 특징으로 하는 방법.The method according to claim 25, wherein a polyolefin resin coating film having a multilayer structure of at least two or more layers is used as the coating film. 제26항에 있어서, 3층으로 된 폴리올레핀계 수지 피복필름을 피복필름으로서 사용하는 것을 특징으로 하는 방법.The method according to claim 26, wherein the three-layer polyolefin resin coating film is used as the coating film. 제27항에 있어서, 폴리올레핀계 수지가 폴리에틸렌, 에틸렌-α-올레핀 공중합체 및 에틸렌-아세트산 비닐공중합체로부터 선택된 적어도 1종인 폴리올레핀계 수지 피복필름을 피복필름으로서 사용하는 것을 특징으로 하는 방법.The method according to claim 27, wherein the polyolefin resin is at least one member selected from polyethylene, ethylene-α-olefin copolymer, and ethylene-vinyl acetate copolymer as a coating film. 제28항에 있어서, 폴리올레핀계 수지가 밀도 0.93g/㎠ 이하의 저밀도 폴리에틸렌인 폴리올레핀계 수지 피복필름을 피복필름으로서 사용하는 것을 특징으로 하는 방법.The method according to claim 28, wherein the polyolefin resin is a low density polyethylene having a density of 0.93 g / cm 2 or less, and a polyolefin resin coating film is used as the coating film. 제24항에 있어서, 무기유황제가 석회유황합체, 유황분제, 수화유황제, 유황훈연제 및 석회유황 에어졸에서 선택되는 적어도 1종으로 처리하는 시설원예 하우스ㆍ터널재배에 있어서, 힌다드아민계 화합물, 하이드로탈사이트류 화합물, 자외선 흡수제 및 폴리올레핀계 수지로 이루어진 폴리올레핀제 수지 피복필름을 시설원예 하우스ㆍ터널의 피복필름으로 사용하는 것을 특징으로 하는 방법.The horticultural compound according to claim 24, wherein the inorganic sulfur agent is a hindered amine-based compound for treating at least one selected from a lime sulfur copolymer, a sulfur powder, a hydrated sulfur agent, a sulfur smoker, and a lime sulfur aerosol. A method of using a polyolefin resin coating film made of a hydrotalcite compound, an ultraviolet absorber, and a polyolefin resin as a coating film of a facility horticulture house tunnel. 제24항에 있어서, 시설원예 하우스ㆍ터널재배로 재배되는 식물이 과수류인 시설원예 하우스ㆍ터널재배에 있어서, 힌다드아민계 화합물, 하이드로탈사이트류 화합물, 자외선 흡수제 및 폴리올레핀계 수지로부터 이루어진 폴리올레핀계 수지 피복필름을 시설원예 하우스ㆍ터널의 피복필름으로서 사용하는 것을 특징으로 하는 방법.25. The polyolefin plant according to claim 24, wherein the plant cultivated by the plant horticulture house tunnel cultivation is a fruit tree, wherein the plant is a fruit tree. A method characterized by using a resin coated film as a coating film of a facility horticulture house tunnel. 제24항에 있어서. 시설원예 하우스ㆍ터널재배에서 재배되는 식물이 딸기, 멜론, 수박, 오이, 장미, 국화인 시설원예 하우스ㆍ터널재배에 있어서, 힌다드아민계 화합물, 하이드로탈사이드류 화합물, 자외선 흡수제 및 폴리올레핀계 수지로 된 폴리올레핀계 수지 피복필름을 시설원예 하우스ㆍ터널의 피복필름으로서 사용되는 것을 특징으로 하는 방법.The method of claim 24. In the horticultural house-tunnel cultivation, the plants grown in the horticultural house-tunnel cultivation are strawberries, melons, watermelons, cucumbers, roses, and chrysanthemums. A polyolefin resin coated film comprising a polyolefin resin coating film is used as a coating film for a facility gardening house tunnel. ※ 참고사항 :최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
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