KR960015657B1 - Preparation of(ionized)liquid bio-ceramics for fiber - Google Patents
Preparation of(ionized)liquid bio-ceramics for fiber Download PDFInfo
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- KR960015657B1 KR960015657B1 KR1019940000160A KR19940000160A KR960015657B1 KR 960015657 B1 KR960015657 B1 KR 960015657B1 KR 1019940000160 A KR1019940000160 A KR 1019940000160A KR 19940000160 A KR19940000160 A KR 19940000160A KR 960015657 B1 KR960015657 B1 KR 960015657B1
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- Prior art keywords
- ionized
- fiber
- silver
- liquid
- sodium
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- 239000003462 bioceramic Substances 0.000 title claims abstract description 16
- 239000007788 liquid Substances 0.000 title claims abstract description 15
- 239000000835 fiber Substances 0.000 title claims description 13
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 claims abstract description 10
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims abstract description 7
- 235000019345 sodium thiosulphate Nutrition 0.000 claims abstract description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 6
- 239000008103 glucose Substances 0.000 claims abstract description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229940119177 germanium dioxide Drugs 0.000 claims abstract description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 18
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 9
- ZSILVJLXKHGNPL-UHFFFAOYSA-L S(=S)(=O)([O-])[O-].[Ag+2] Chemical compound S(=S)(=O)([O-])[O-].[Ag+2] ZSILVJLXKHGNPL-UHFFFAOYSA-L 0.000 claims description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 5
- 229930006000 Sucrose Natural products 0.000 claims description 5
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 2
- 239000010931 gold Substances 0.000 abstract description 9
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052737 gold Inorganic materials 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 3
- 239000011176 biofiber Substances 0.000 abstract description 2
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- XSNQEMWVLMRPFR-UHFFFAOYSA-N silver nitride Chemical compound [N-3].[Ag+].[Ag+].[Ag+] XSNQEMWVLMRPFR-UHFFFAOYSA-N 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229910021607 Silver chloride Inorganic materials 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 4
- 206010028980 Neoplasm Diseases 0.000 description 3
- 201000011510 cancer Diseases 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000000752 ionisation method Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910001923 silver oxide Inorganic materials 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 238000007920 subcutaneous administration Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 2
- 101710134784 Agnoprotein Proteins 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000011447 Geum Nutrition 0.000 description 1
- 241000220313 Geum Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 description 1
- 235000013527 bean curd Nutrition 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000020411 cell activation Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 210000004392 genitalia Anatomy 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 206010034674 peritonitis Diseases 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000000191 radiation effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
- Inorganic Fibers (AREA)
- Radiation-Therapy Devices (AREA)
Abstract
Description
본 발명은 액상(이온화) 바이오세라믹스의 제조방법에 관한 것으로, 더욱 상세하게는 섬유에 응용하여 원적외선 방사 고기능성 바이오 섬유를 제조하기 위한 액상 바이오세라믹스의 제조방법에 관한 것이다.The present invention relates to a method for producing a liquid (ionized) bioceramic, and more particularly, to a method for producing a liquid bioceramic for producing far-infrared radiation-functional biofiber by applying to a fiber.
일반적으로 바이오세라믹스는 핵자기공명분광법(NMR)에 의해 증명되었듯이 물의 활성화와 신체세포의 활성화 촉진현상 및 피하심층의 온도를 상승시키는 효능으로 인하여 미세혈관 확장, 혈액순환촉진, 체내 탄산가스 및 아황산가스 등의 유해가스와 수은 및 납 등의 오염물질을 체외로 배출시키고 신진대사를 촉진시키는 역할과 동식물의 성장촉진, 식품의 선도유지와 숙성 및 맛의 증진 효과가 있는 것으로 알려져 있다.In general, bioceramics have been proven by nuclear magnetic resonance spectroscopy (NMR) to promote microvascular expansion, blood circulation, carbon dioxide, and sulfurous acid due to the effects of water activation, body cell activation, and the effect of raising the temperature of the subcutaneous layer. It is known to release harmful gases such as gas and pollutants such as mercury and lead out of the body and to promote metabolism, promote the growth of animals and plants, maintain the freshness, ripening and taste of food.
지금까지는 분말 세라믹스를 접착제와 암모니아수 또는 양이온기를 갖는 수지를 분산시켜 이를 섬유제품에 이용하여 왔으나, 이들 제품들은 분말 세라믹스로 인해 섬유표면이 거칠고 가루가 발생되며 도트방식이나 분사방식에 의한 생산으로 섬유제품의 염색성 제한과 제품의 다양성을 상실하였으며, 고온의 열을 가하여야만 원적외선 방사율이 높아지는 경향이 있다.Until now, powder ceramics have been used in textile products by dispersing resins having an adhesive and ammonia water or cationic groups.However, these products have a rough fiber surface and powder due to powder ceramics. The loss of dyeability and the diversity of products have been lost, and far-infrared emissivity tends to increase only when high temperature is applied.
따라서 본 발명자들은 상기 분말 세라믹스의 단점을 해소하기 위하여 분말 세라믹스를 이온화하여 액상 바이오세라믹스를 제조하기에 이르렀다. 즉, 무색, 무취, 무독성의 액상 바이오세라믹를 제조함으로써 이 액상 바이오세라믹스를 섬유제품에 응용할 경우 섬유제품의 당야화와 섬유의 생명인 유연성을 향상시킬 수 있었으며, 염색의 제한성을 제고시켰다.Accordingly, the present inventors have ionized the powder ceramics to produce a liquid bioceramic to solve the disadvantages of the powder ceramics. In other words, by producing colorless, odorless and non-toxic liquid bioceramic, the application of the liquid bioceramic to the fiber product could improve the sugarification of the fiber product and the vitality of the fiber and improved the restriction of dyeing.
이하, 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.
본 발명은 규산소다, 알루미늄소다, 산화나트륨, 치오황산나트륨, 이산화게르마늄 및 정제 포도당, 상백당을 각각 20~40℃에서 용해한 후 혼합하고, 금을 염화금산(HAuCl4·4H2O)으로 이온화한 것과 질산은을 치오황산은(Ag2S2O2)으로 이온화한 것을 상기 혼합액에 첨가한 후 15~20℃에서 48~72시간 유지시킴을 특징으로 하는 액상(이온화) 바이오세라믹스의 제조방법에 관한 것이다.In the present invention, sodium silicate, aluminum soda, sodium oxide, sodium thiosulfate, germanium dioxide, purified glucose, and white sugar are dissolved at 20 to 40 ° C., respectively, mixed, and gold is ionized with gold chloride (HAuCl 4 · 4H 2 O). And silver nitrate ionized with silver thiosulfate (Ag 2 S 2 O 2 ) is added to the mixture and maintained for 48 to 72 hours at 15 to 20 ℃ characterized in that the method for producing a liquid (ionized) bioceramic will be.
상기 정제포도당 및 상백당, 그리고 치오황산액은 금속원소의 촉매제로 이용하는 것이며, 즉 금속원소의 액화 촉매역할과 금속원소의 이온결합을 원활히 하여 주며, 공기중의 산소를 다량 흡입하여 물의 활성화를 촉진시켜 준다.The purified glucose, white sugar, and thiosulfate solution are used as catalysts for metal elements, that is, they facilitate the liquefaction catalyst role of metal elements and ionic bonds of metal elements, and promote the activation of water by inhaling large amounts of oxygen in the air. Let it be.
또한 공지된 바와 같이 용융은은 많은 양의 산소를 흡수하는 성질이 있으며 냉각시키면 산소를 그대로 방출하는 성질을 갖고 있다.As is well known, molten silver has a property of absorbing a large amount of oxygen, and has a property of releasing oxygen as it is cooled.
따라서 이온화된 액상은을 섬유에 침지가공한 후 1차로 70~80℃에서 건조한 후 2차로 100~120℃의 열을 가하게 되면 산소를 다량 흡수, 방출하는 성질을 갖게 되므로 본 발명은 이러한 원리를 이용한 것이다.Therefore, the ionized liquid silver is immersed in the fiber and dried first at 70-80 ° C. and then heated at 100-120 ° C. for the second time, thereby absorbing and releasing a large amount of oxygen. will be.
금과 질산은의 이온화액은 섬유의 용도에 따라 상호 가감조절할 수 있다.The ionization liquid of gold and silver nitrate can be adjusted to each other depending on the use of the fiber.
귀금속물인 금을 이온화한 것은 주사액으로 사용하여 암성 복막염, 암성 녹막염, 성기암의 치료용으로 사용되고 있는 바, 이것은 몸속의 유기물과 화합하여 태양에너지인 원적외선의 심달력(深達力)으로 인해 낮은 온도에 2배의 열기식(熱氣式) 고온방사로 인해 피하심층의 온도를 상승시키는 효과가 있기 때문이다.The ionization of gold, a precious metal substance, is used as an injection solution to treat cancer peritonitis, cancer rustitis, and genital cancer, which is combined with organic matter in the body and is low due to the deep-cardiac power of far-infrared rays, solar energy. This is because there is an effect of raising the temperature of the subcutaneous layer due to the thermal high-temperature spinning twice as high.
따라서 본 발명에서는 이러한 원리를 이용하여 금을 이온화하였으며, 은은 자외선 방사능은 다른 금속보다 약하지만 적외선과 가시광선의 반사능이 최대이며, 전기 및 열전도율은 금속중 최대라고 알려져 있다.Therefore, in the present invention, gold is ionized using this principle, and silver has a weaker ultraviolet radiation than other metals, but reflects infrared and visible light at maximum, and electrical and thermal conductivity is known to be the largest of metals.
또한 규소는 가장 우수한 반도체 소재로 짧은 파장에까지 유효하게 작용하는 고기능성 원료인 것이다.In addition, silicon is the most advanced semiconductor material, and is a highly functional raw material that works effectively to a short wavelength.
따라서 본 발명에서는 이들 귀금속 및 반도체 소재들을 액상화하여 액상 바이오세라믹스를 제조하였으며, 이 액상 바이오세라믹스를 섬유소재에 가공처리하면 새로운 고기능성 원적외선 방사 바이오세라믹스 섬유의 신소재화가 가능하다.Therefore, in the present invention, these precious metals and semiconductor materials are liquefied to produce a liquid bioceramic. When the liquid bioceramic is processed into a fiber material, a new material of a new high-functional far-infrared radiation bioceramic fiber is possible.
이하, 본 발명을 공정별로 더욱 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail by process.
① 규산소다, 알루미늄소다, 산화나트륨, 치오황산나트륨, 이산화게르마늄 및 정제포도당, 상백당을 각각 20~40℃에서 용해한다.① Dissolve sodium silicate, aluminum soda, sodium oxide, sodium thiosulfate, germanium dioxide, refined glucose, and white sugar at 20 ~ 40 ℃.
② 상기 각 성분을 용해한 용액을 혼합한다.② Mix the solution which melt | dissolved each said component.
③ 금을 염화금산(HAuCl4·4H2O)으로 이온화한다.③ Ionize gold with gold chloride (HAuCl 4 · 4H 2 O).
④ 질산은을 치오황산은(Ag2S2O2)으로 이온화한다.④ Ionize silver nitrate with silver thiosulfate (Ag 2 S 2 O 2 ).
⑤ 상기 ②용액에 ③ 및 ④를 첨가한다.⑤ Add ③ and ④ to the above ② solution.
⑥ ⑤의 용액을 상온(15~20℃)에서 48~72시간 유지하여 방치한다.⑥ Keep solution ⑤ at room temperature (15 ~ 20 ℃) for 48 ~ 72 hours.
상기와 같은 제조공정을 거치면 금속원소와 유기화합물과의 치환반응에 의해 이온평등 및 금속의 혼합평등을 이루게 되며 원료의 숙성이 완료되면 액상(이온화) 바이오세라믹스 원액이 제조되게 되는 것이다.Through the manufacturing process as described above to achieve the ionic equality and the mixing equality of the metal by the substitution reaction of the metal element and the organic compound, the liquid (ionization) bioceramic stock solution is prepared when the maturation of the raw material is completed.
상기 ③의 이온화과정은 금을 왕수(농염산에 농질산을 섞은 용액)에 녹여 염화금산으로 이온화한다.In the ionization process of ③, gold is dissolved in aqua regia (a solution of concentrated hydrochloric acid and concentrated nitric acid) and ionized with gold chloride.
또한 상기 ④의 이온화과정을 상세히 설명하면 다음과 같다.In addition, the ionization process of ④ described in detail as follows.
질산은 10g을 물 100cc에 용해한 후, 이 액에 염화나트륨 20g을 물 50~60cc에 용해하여 혼합하면 순두부처럼 하얀 염화은이 생성되어 침전이 생기며, 이 침전물을 분리하여 물로 2~3회 세척한 후 분리된 염화은에 약 2배량의 물을 첨가하고 치오황산나트륨 약 20g을 염화은에 첨가하여 약 30~40℃로 20~30분 저어주며 가열하면 완전히 용해되어 투명한 치오황산은 수액이 된다.After dissolving 10g of silver nitrate in 100cc of water, and mixing 20g of sodium chloride in 50 ~ 60cc of water and mixing it with this solution, white silver chloride is produced like pure tofu, and this precipitate is separated and washed 2 ~ 3 times with water. Add about twice the amount of water to silver chloride, add about 20g of sodium thiosulfate to silver chloride, stir at about 30 ~ 40 ℃ for 20 ~ 30 minutes, and dissolve completely when heated. Transparent thiosulfate becomes sap.
치오황산은의 수액을 사용하는 것은 섬유에 침지가공하여도 제품에 손상을 주지 않으며 변질되지 않기 때문이다.The use of the sap solution of silver thiosulfate does not damage the product even if it is immersed in the fiber.
산화은이나 질산은을 사용하는 경우도 있으나 이들은 햇빛이나 열을 받게 되면 흑변하므로 백색섬유원료 제품이나 염색에 민감한 섬유에는 사용이 불가능하다.Although silver oxide and silver nitrate may be used, they may turn black when subjected to sunlight or heat, and thus may not be used for white fiber raw materials or dye-sensitive fibers.
특히 질산은은 유기물에 접촉하면 산화은으로 변하므로 본 발명에서는 질산은을 염화은으로 제조한 후 염화은에 치오황산나트륨을 혼합하여 치오황산은 수액으로 제조하는 것이다.In particular, since silver nitrate is changed to silver oxide when it comes into contact with an organic substance, silver nitrate is prepared by silver chloride and then sodium thiosulfate is mixed with silver chloride to prepare silver thiosulfate as sap.
또한 ⑥의 공정에서 48~72시간 유지하는 이유는 48시간 미만에서는 이온화가 완전히 진행되지 않아 방사효율이 저하되며, 72시간을 초과하여도 더 이상의 이온화가 진행되지 않기 때문이다.In addition, the reason for maintaining 48-72 hours in the process of ⑥ is that ionization does not proceed completely under 48 hours because the radiation efficiency is lowered, and even more than 72 hours does not proceed further ionization.
이하, 본 발명을 실시예에 의거 더욱 상세히 설명하면 다음과 같은 바, 본 발명이 실시예로 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to the following Examples, but the present invention is not limited to the Examples.
<실시예><Example>
① 아래의 원료를 각각 20~40℃에서 용해한 후 혼합하였다.① The following raw materials were dissolved at 20 to 40 ° C. and then mixed.
… 아 래 …… Below…
규산소다 15gSodium Silicate 15g
알루미늄소다 5g5g aluminum soda
산화나트륨 3gSodium oxide 3g
치오황산나트륨 10g10 g sodium thiosulfate
이산화게르마늄 3gGermanium Dioxide 3g
정제포도당 및 상백당 10g10 g of refined glucose and white sugar
② 금(Au) 5g을 염화금산(HAuCl4·4H2O)으로 이온화하였다.② 5 g of gold (Au) was ionized with geum chloride (HAuCl 4 · 4H 2 O).
③ 질산은(AgNO3) 10g을 치오황산은(Ag2S2O2)으로 이온화하였다.③ 10 g of silver nitrate (AgNO 3 ) was ionized with silver thiosulfate (Ag 2 S 2 O 2 ).
①의 혼합액에 ② 및 ③을 가하고 20℃에서 72시간 유지, 방치하여 1의 이온화된 액상 바이오세라믹스를 제조하였다.② and ③ are added to the mixed solution of ① and maintained at 20 ° C. for 72 hours, and left to stand 1 Ionized liquid bioceramic was prepared.
본 발명에 의해 제조된 액상 바이오세라믹스 원액은 영하 15℃에서도 결빙되지 않으며, 20℃에서 장기 보관하여도 무색, 무취로 부패, 변질되지 않으며 방사효과가 유지되는 특성이 있다.The liquid bioceramic stock solution prepared according to the present invention does not freeze at minus 15 ° C., and does not rot or deteriorate as colorless or odorless even after long-term storage at 20 ° C., and has a radiation effect.
Claims (1)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019940000160A KR960015657B1 (en) | 1994-01-06 | 1994-01-06 | Preparation of(ionized)liquid bio-ceramics for fiber |
| US08/369,514 US5571460A (en) | 1994-01-06 | 1995-01-06 | Liquid composition emitting far infrared rays and method for preparation thereof |
| PCT/IB1995/000107 WO1995018882A1 (en) | 1994-01-06 | 1995-01-06 | Liquid composition emitting far infrared rays and method for preparation thereof |
| AU15886/95A AU1588695A (en) | 1994-01-06 | 1995-01-06 | Liquid composition emitting far infrared rays and method for preparation thereof |
| JP7000640A JP2637054B2 (en) | 1994-01-06 | 1995-01-06 | Liquid phase far-infrared radiation composition and method for producing the same |
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| KR1019940000160A KR960015657B1 (en) | 1994-01-06 | 1994-01-06 | Preparation of(ionized)liquid bio-ceramics for fiber |
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| KR950023615A KR950023615A (en) | 1995-08-18 |
| KR960015657B1 true KR960015657B1 (en) | 1996-11-20 |
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| US (1) | US5571460A (en) |
| JP (1) | JP2637054B2 (en) |
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| KR200167725Y1 (en) * | 1996-10-09 | 2000-02-01 | 성덕수 | A light bulb fluorescent lamp for weakening the strength of electronic field and emitting the far infrared rays |
| KR20030062602A (en) * | 2002-01-17 | 2003-07-28 | 안정주 | Prosuction of Function Fibers |
| US20040149299A1 (en) * | 2003-01-30 | 2004-08-05 | Kim Jae-Wook | Wig cap |
| JP2007107156A (en) * | 2005-10-17 | 2007-04-26 | Kb Seiren Ltd | Fabric having blood flow-promoting effect and fiber product using the same |
| US8409466B2 (en) * | 2010-09-13 | 2013-04-02 | Hyung Jun Kim | Composition comprising ionized germanuim dioxide, method of making and use thereof |
| CN108823985B (en) * | 2018-06-29 | 2020-10-27 | 河南迪怡疗护科技开发有限公司 | Medical antibacterial quilt cover convenient to fill |
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| US3857054A (en) * | 1973-07-11 | 1974-12-24 | Westinghouse Electric Corp | Discharge device and method for generating near infrared radiations |
| US4071465A (en) * | 1977-04-18 | 1978-01-31 | Westinghouse Electric Corporation | Deep-red emitting phosphor |
| JP2624291B2 (en) * | 1988-04-08 | 1997-06-25 | 松下電器産業株式会社 | Far infrared heater |
| KR940000032B1 (en) * | 1990-10-19 | 1994-01-05 | 주식회사 삼우원적외선 | Disinfectant bioceramic composition |
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