KR960014272A - Antifog and antifogging thermoplastic sheet on thermoplastic surface - Google Patents

Antifog and antifogging thermoplastic sheet on thermoplastic surface Download PDF

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Publication number
KR960014272A
KR960014272A KR1019950034104A KR19950034104A KR960014272A KR 960014272 A KR960014272 A KR 960014272A KR 1019950034104 A KR1019950034104 A KR 1019950034104A KR 19950034104 A KR19950034104 A KR 19950034104A KR 960014272 A KR960014272 A KR 960014272A
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South Korea
Prior art keywords
thermoplastic resin
resin sheet
agent
polymer compound
hydrophilic polymer
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KR1019950034104A
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Korean (ko)
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슈지 요시오카
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고지마 아키로
다이셀 가가쿠 고교 가부시키가이샤
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Publication of KR960014272A publication Critical patent/KR960014272A/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/054—Forming anti-misting or drip-proofing coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C09D101/08—Cellulose derivatives
    • C09D101/26—Cellulose ethers
    • C09D101/28—Alkyl ethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/22—Thermoplastic resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
    • C08J2401/08—Cellulose derivatives
    • C08J2401/26—Cellulose ethers
    • C08J2401/28—Alkyl ethers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Combustion & Propulsion (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)

Abstract

본 발명은 하기의 탁월한 효과를 나타내는 열가소성 수지 시트 표면의 흐림 방지제를 제공한다 : (1) 중기의 응축으로 인한 시트 표면의 흐림을 억제하는 효과가 지속되는 시간을 연장할 수 있다; (2) 탁월한 차단 내성 및 코팅 안정성은 직접 가열 공정에서 가열판상에서 가열하여 그 표면을 다양한 형상으로 성형시키는 가열 공정에서 흐름 방지 표면이 더 적게 박리되도록 만든다; (3) 소정의 양에서 습윤성을 갖는 다가 알코올인 혼입하므로써 탁월한 정전 방지성을 제공한다.The present invention provides an antifogging agent on the surface of a thermoplastic resin sheet which exhibits the following excellent effects: (1) It is possible to prolong the time for which the effect of suppressing the blurring of the sheet surface due to condensation of the medium period lasts; (2) excellent barrier resistance and coating stability result in less peeling of the flow-resistant surface in the heating process, which is heated on the heating plate in the direct heating process to form the surface into various shapes; (3) Providing excellent antistatic property by incorporating a polyhydric alcohol having wettability in a predetermined amount.

본 발명은 상기 흐름 방지제로 처리한 흐름 방지 열가소성 수지 시트를 제공한다. 슈크로스 지방족 에스테르와 코팅물－형성 친수성 고분자 화합물의 혼합물 100중량부를 기준으로 1 내지 15중량부의 양으로 혼입된 다가 알코올을 함유하는 열가소성 수지 시트 표면의 신규한 흐름 방지제가 제공된다. 상기 흐름 방지제로 처리한 신규한 흐림 방지 열가소성 수지 시트도 제공된다.The present invention provides a flow preventing thermoplastic resin sheet treated with the flow preventing agent. A novel anti-flow agent on the surface of a thermoplastic resin sheet containing polyhydric alcohols incorporated in an amount of 1 to 15 parts by weight based on 100 parts by weight of a mixture of sucrose aliphatic ester and a coating-forming hydrophilic polymer compound is provided. There is also provided a novel anti-fog thermoplastic resin sheet treated with the flow inhibitor.

Description

열가소성 수지 표면의 흐름 방지제 및 흐림 방지 열가소성 수지 시트Anti-flow and anti-fog thermoplastic sheet on thermoplastic surface

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (10)

슈크로스 지방족 에스테르 혼합물과 코팅물－형성 친수성 고분자 화합물과의 혼합물 100중량부를 기준으로 1 내지 15중량부의 양으로 혼입된 다가 알코올을 함유하는 열가소성 수지 시트 표면의 흐림 방지제(anti－fogging agent).An anti-fogging agent on the surface of a thermoplastic resin sheet containing a polyhydric alcohol incorporated in an amount of 1 to 15 parts by weight based on 100 parts by weight of a mixture of the sucrose aliphatic ester mixture and the coating-forming hydrophilic polymer compound. 제1항에 있어서, 상기 코팅물－형성 친수성 고분자 화합물에 대한 상기 슈크로스 지방족 에스테르의 혼합비가 상기 친수성 고분자 화합물 100중량부를 기준으로 20 내지 80중량부의 범위인 열가소성 수지 시트 표면의 흐림 방지제.The antifogging agent according to claim 1, wherein the mixing ratio of the sucrose aliphatic ester to the coating-forming hydrophilic polymer compound is in the range of 20 to 80 parts by weight based on 100 parts by weight of the hydrophilic polymer compound. 제1항에 있어서, 상기 슈크로스 지방족 에스테르 혼합물로서 탄소수 6 내지 22의 고급 지방산과 슈크로스의 에스테르가 50% 이상의 몰 농도로 함유된 열가소성 수지 시트 표면의 흐림 방지제.The antifogging agent according to claim 1, wherein the sucrose aliphatic ester mixture contains an ester of a higher fatty acid having 6 to 22 carbon atoms and sucrose in a molar concentration of 50% or more. 제3항에 있어서, 시트 표면의 흐림 방지제.The antifogging agent according to claim 3, wherein the surface of the sheet is antifog. 제1항에 있어서, 상기 친수성 고분자 화합물이 단백질, 전분, 폴리아크릴산, 폴리아크릴산나트륨, 폴리아크릴아미드, 폴리에틸렌 옥사이드, 폴리비닐 피롤리돈, 폴리비닐 알코올, 폴리비닐아미드, 폴리아민, 알긴산, 알긴산염, 카르복시메틸셀루로스, 히드록시에틸셀룰로스 및 히드록시프로필셀룰로스로 구성된 군에서 선택되는 열가소성 수지 시트 표면의 흐림 방지제.The method of claim 1, wherein the hydrophilic polymer compound is selected from the group consisting of protein, starch, polyacrylic acid, sodium polyacrylate, polyacrylamide, polyethylene oxide, polyvinyl pyrrolidone, polyvinyl alcohol, polyvinylamide, polyamine, alginic acid, alginate, An antifogging agent on the surface of a thermoplastic resin sheet selected from the group consisting of carboxymethyl cellulose, hydroxyethyl cellulose and hydroxypropyl cellulose. 제5항에 있어서, 상기 친수성 고분자 화합물이 하기 구조식을 가진 히드록시에틸셀루로스인 열가소성 수지 시트 표면의 흐림 방지제 :The antifogging agent on the surface of a thermoplastic resin sheet according to claim 5, wherein the hydrophilic polymer compound is hydroxyethyl cellulose having the following structural formula: 상기 구조식에서, R1, R2및 R3은 각각(CH2CH2O)mH(여기서, m은 R1,R2및 R3이 동시에 H는 아닐 것을 조건으로 0 이상의 정수를 의미함)를 의미하며; n은 1 이상의 숫자를 의미한다.Wherein R 1 , R 2 and R 3 are each (CH 2 CH 2 O) m H (where m is an integer of 0 or more provided that R 1 , R 2 and R 3 are not H simultaneously) ); n means a number of 1 or more. 제1항에 있어서, 상기 다가 알코올이 탄소수 2 내지 8의 직쇄 또는 고리형 친수성 다가 알코올인 열가소성 수지 시트 표면의 흐림 방지제.The antifog agent of the surface of the thermoplastic resin sheet of Claim 1 whose said polyhydric alcohol is a C2-C8 linear or cyclic hydrophilic polyhydric alcohol. 제1항에 있어서, 상기 다가 알코올이 D－소르비톨인 열가소성 수지 시트 표면의 흐림 방지제.The antifog agent of the surface of the thermoplastic resin sheet of Claim 1 whose said polyhydric alcohol is D-sorbitol. 제1항 내지 제8항 중 어느 한 항에 따른 흐림 방지제가 적어도 한면에 도포된 열가소성 수지 시트.The thermoplastic resin sheet in which the anti-clouding agent of any one of Claims 1-8 was apply | coated on at least one surface. 제9항에 있어서, 상기 흐림 방지제의 코팅 함량이 고체 함량으로 환산하여 0.01 내지 2g/m2의 범위인 열가소성 수지 시트.The thermoplastic resin sheet according to claim 9, wherein the coating content of the antifogging agent is in a range of 0.01 to 2 g / m 2 in terms of solid content. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950034104A 1994-10-05 1995-10-05 Antifog and antifogging thermoplastic sheet on thermoplastic surface KR960014272A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP24121594 1994-10-05
JP94-241215 1994-10-05
JP7238121A JPH08157639A (en) 1994-10-05 1995-09-18 Anti-fogging agent for surface of thermoplastic resin and anti-fogging thermoplastic resin sheet
JP95-238121 1995-09-18

Publications (1)

Publication Number Publication Date
KR960014272A true KR960014272A (en) 1996-05-22

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KR1019950034104A KR960014272A (en) 1994-10-05 1995-10-05 Antifog and antifogging thermoplastic sheet on thermoplastic surface

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JP (1) JPH08157639A (en)
KR (1) KR960014272A (en)
CN (1) CN1133335A (en)
TW (1) TW349992B (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3792769B2 (en) * 1996-02-15 2006-07-05 三菱化学株式会社 Antifogging agent and resin sheet treated with antifogging agent
JP3677928B2 (en) * 1997-03-26 2005-08-03 三菱化学株式会社 Propylene resin thermoforming sheet manufacturing method
JP2000280422A (en) * 1999-03-31 2000-10-10 Chuo Kagaku Co Ltd Anti-fogging polyolefinic sheet and anti-fogging food packaging container
JP4630435B2 (en) * 2000-09-18 2011-02-09 サンディック株式会社 Styrenic resin anti-fog sheet
KR100428589B1 (en) * 2001-05-17 2004-04-27 현대공영 주식회사 Environmental affinitive functional paint, preparing method thereof and preparing method for vegetable resin utilized in the same
CN100542800C (en) * 2002-02-20 2009-09-23 旭迪爱生株式会社 Antifog plastic resin sheet material hot in nature and formed products
JP2003253241A (en) * 2002-03-04 2003-09-10 Kanebo Ltd Anti-hazing agent, and polyester laminate coated therewith and molded form
CN104877480A (en) * 2015-06-23 2015-09-02 宣乐 Antifogging agents for outdoor lamp box
CN105860930B (en) * 2016-04-05 2017-09-29 四川理工学院 Vehicle glass antirain agent and preparation method thereof when a kind of long-acting
CN109161133B (en) * 2018-08-27 2021-02-19 丹阳西联生物技术有限公司 Antifogging composite film and preparation method and application thereof
CN111423772B (en) * 2020-05-06 2021-12-28 深圳大学 Anti-fog and anti-fog coating and preparation method thereof

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Publication number Publication date
CN1133335A (en) 1996-10-16
JPH08157639A (en) 1996-06-18
TW349992B (en) 1999-01-11

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