KR960014120A - 제초성 술폰아미드 유도체 - Google Patents

제초성 술폰아미드 유도체 Download PDF

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KR960014120A
KR960014120A KR1019940027152A KR19940027152A KR960014120A KR 960014120 A KR960014120 A KR 960014120A KR 1019940027152 A KR1019940027152 A KR 1019940027152A KR 19940027152 A KR19940027152 A KR 19940027152A KR 960014120 A KR960014120 A KR 960014120A
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erythro
compound
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fluoro
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KR1019940027152A
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KR0140020B1 (ko
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김대황
장해성
고영관
류재욱
홍성엽
우재춘
구동완
황인택
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강박광
재단법인 한국화학연구소
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62Oxygen or sulfur atoms
    • C07D213/70Sulfur atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46Two or more oxygen, sulphur or nitrogen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

본 발명은 제초성 술폰아미드 유도체 화합물에 관한 것으로서, 더욱 상세하게는 벼농업에 있어서 발아전및/ 또는 발아후 처리 제초제로서 유용한 에리스로 입체이성체를 갖는 다음 일반식(I)로 표시되는 술폰아미드 유도체 화합물과 이를 사용하는 새로운 방법 및 이들 화합물을 포함하는 농업적으로 적절한 조성물에 관한 것이다.
여기서 P와 Q는 서로 같거나 다른 것으로서 각각 CH 또는 N을 나타내고 P와 Q를 포함하는 아르마틱환은 벤젠 또는 피리딘환을 나타내며; R1은 H 또는를 나타내며, 여기서 R6는 C1∼C3의 알킬기, C1∼C3의 할로알킬기. C2∼C3의 알케닐기, C2∼C3의 알키닐기이고, Xa는 O, S, NH 또는 NRa기를 나타내고; R2는 C1∼C2의 알킬기이고; X와 Y는 각각 C1∼C2의 알킬기, C1∼C2의 알콕시기, C1∼C2의 할로알콕시기 또는 할로겐을 나타낸다.

Description

제초성 술폰아미드 유도체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 다음 일반식(I)로 표시되는 에리스로 입체이성체를 치환체로 갖는 술폰아미드 유도체.
    여기서 P와 Q는 서로 같거나 다른 것으로서 각각 CH 또는 N을 나타내고 P와 Q를 포함하는 아르마틱환은 벤젠 또는 피리딘환을 나타내며; R1은 H 또는를 나타내며, 여기서 R6는 C1∼C3의 알킬기, C1∼C3의 할로알킬기. C2∼C3의 알케닐기, C2∼C3의 알키닐기이고, Xa는 O, S, NH 또는 NRa기를 나타내고; R2는 C1∼C2의 알킬기이고; X와 Y는 각각 C1∼C2의 알킬기, C1∼C2의 알콕시기, C1∼C2의 할로알콕시기 또는 할로겐을 나타낸다.
  2. 제1항에 있어서, 상기 R1은 H 또는 아세틸기이고, P 및 Q는 서로 갖거나 다른 것으로서 각가 CH 또는 N이며, X와 Y는 메톡시기인 상기 일반식(I)의 술폰아미드 유도체.
  3. 제1항에 있어서, 상기 일반식(I)은 에리스로-2-(1-아세톡시-2-플루오로-n-부틸)-N-〔4,6-디메톡시-피리미딘-2-일)아미노카보닐〕-3-피리딘술폰아미드인 것.
  4. 제1항에 있어서, 상기 일반식(I)은 에리스로-N-〔4,6-디메톡시-피리미딘-2-일)아미노카보닐〕-2-(2-플루오로-1-히드록시-n-부틸)-3-피리딘술폰아미드인 것.
  5. 제1항에 있어서, 상기 일반식(I)은 에리스로-2-(1-아세톡시-2-플루오로-n-부틸)-N-〔4,6-디메톡시-피리미딘-2-일)아미노카보닐〕-3-벤젠술폰아미드인 것.
  6. 제1항에 있어서, 상기 일반식(I)은 에리스로-N-〔4,6-디메톡시-피리미딘-2-일)아미노카보닐〕-2-(2-플루오로-1-히드록시-n-부틸)벤젠술폰아미드인 것.
  7. 다음 일반식(II)로 표시되는 에리스로 입체이성체를 갖는 중간체화합물.
    여기서 R1, R2, P 및 Q는 각각 특허청구의 범위 제1항에서 정의한 바와 같다.
  8. 제7항에 있어서, 상기 일반식(II)의 화합물은 에리스로-2-(1-에세톡시-2-플루오로-n부틸)-3-피리딘술폰아미드인 것.
  9. 제7항에 있어서, 상기 일반식(II)의 화합물은 에리스로-2-(1-에세톡시-2-플루오로-n부틸)벤젠술폰아미드인 것.
  10. 다음 일반식(I)로 표시되는 술폰아미드 유도체를 유효성분으로 함유하는 제초제 조성물.
    상기 식에서, P,Q, R1, R2, X 및 Y는 각각 특허청구의 범위 제1항에서 정의한 바와 같다.
  11. 제10항에 있어서, 상기 일반식(I)의 술폰아미드 유도체는 치환기중 R1이 H 또는 아세틸기이고, Q가 CH이고 P가 N이고, X와 Y가 메톡시인 화합물을 함유하는 제초제 조성물.
  12. 제10항에 있어서, 상기 일반식(I)의 술폰아미드 유도체가 에리스로-2-(1-아세톡시-2플루오로-n-부틸)-N-4,6-디메톡시-피리미딘-2-일)아미노카보닐〕-3-피리딘술폰아미드인 것을 함유하는 제초제 조성물.
  13. 제10항에 있어서, 상기 일반식(I)의 술폰아미드 유도체가 에리스로-N-4,6-디메톡시-피리미딘-2-일)아미노카보닐〕-2-(2플루오로-1-히드록시-n-부틸)벤젠술폰아미드인 것을 함유하는 제초제 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940027152A 1994-10-24 1994-10-24 제초성 술폰아미드 유도체 KR0140020B1 (ko)

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KR1019940027152A KR0140020B1 (ko) 1994-10-24 1994-10-24 제초성 술폰아미드 유도체

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KR0140020B1 KR0140020B1 (ko) 1998-06-01

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