KR960011349B1 - Refractories by fusion casting - Google Patents
Refractories by fusion casting Download PDFInfo
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- KR960011349B1 KR960011349B1 KR1019930023290A KR930023290A KR960011349B1 KR 960011349 B1 KR960011349 B1 KR 960011349B1 KR 1019930023290 A KR1019930023290 A KR 1019930023290A KR 930023290 A KR930023290 A KR 930023290A KR 960011349 B1 KR960011349 B1 KR 960011349B1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
- C04B35/101—Refractories from grain sized mixtures
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/522—Oxidic
- C04B2235/5228—Silica and alumina, including aluminosilicates, e.g. mullite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/66—Specific sintering techniques, e.g. centrifugal sintering
- C04B2235/661—Multi-step sintering
- C04B2235/662—Annealing after sintering
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Mold Materials And Core Materials (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
Description
본 발명은 규석을 주재(主材)로 한 용융물의 형상 주조방법에 관한 것이다.TECHNICAL FIELD This invention relates to the shape casting method of the melt which used the silica as a main material.
이를 더욱 상세히 기술하면 용융유리에 침식(侵蝕)되지 않는 특수한 알루미나 내화물을 개발하여 이를 매몰재로 사용함으로써 수정이나 유리질의 용융물을 최초로 형상 주조방법에 의해 다양한 제품과 대량생산이 가능토록 한 것이다.In more detail, by developing a special alumina refractory that does not erode into molten glass and using it as a buried material, it is possible to mass-produce a variety of products and crystals by using the shape casting method for the first time.
통상, 수정이나 유리질을 가공할때는 원석 덩어리를 재단하고 이를 형성가공한 후 광택 작업하는 등 일부 숙련자의 경험과 기술에 의존하는 수작업의 형태가 있고 또 다른 방법으로는 상기 물질을 용융시켜 그 용융물을 형틀에 부어 굳히는 금형 주조방법이 있으나 이는 금형 제작에 따른 비용과다로 다양한 형태를 소량씩 생산할 시에는 고가품이 될 수 밖에 없고 제품의 다양화를 이룰 수 없는 등 많은 문제점이 있었다.Usually, when processing crystal or glass, there are manual forms, which depend on the experience and skills of some skilled workers, such as cutting, forming, and polishing the raw stone mass. Alternatively, the material is melted to form the melt. There is a mold casting method that is poured into the mold, but there are many problems such as expensive products and inability to diversify the product when small quantities of various forms are produced due to excessive cost according to mold production.
더욱이 현대 사회는 산업의 발달로 일상품에도 실용성 및 새로운 디자인을 요구하게 되었으며 특히 인조보석류나 유리가공제품등은 패션의 감각을 중요하게 여김으로써 제품개발 및 형상의 다양성에 대한 요구가 점차 증대되어가고 있는 것이 세계적인 추세이다.Moreover, modern society has demanded practicality and new designs for daily products due to the development of industry. Especially, artificial jewelry and glass processed products have a great sense of fashion and the demand for product development and shape diversity is gradually increasing. It is a global trend.
이러한 추세에 따라 본 발명자는 다양한 형상의 제품을 제조할 수 있는 방법을 연구하던 중 금속주조에서 통상사용되는 로스크 왁스 캐스팅「Lost wax Casting : 매몰재(埋沒材)를 이용하여 메울 공간이 들어 있는 주형을 그대로 구워낸 뒤에 속이 빈 주형속에 용융금속을 주입하는 방법」에서 힌트를 얻게 된 것이다.In accordance with this trend, the inventors of the present invention have been researching a method for manufacturing various shapes of products, and the wax wax casting which is commonly used in metal casting is used. After baking it as it is, you get a hint from "How to inject molten metal into a hollow mold."
⊙로스트 왁스 캐스팅의 기본공정은 다음과 같다.⊙ The basic process of lost wax casting is as follows.
① 디자인한 모형을 왁스로 만든다.(왁스 원형 제작)① Make the designed model out of wax.
② 매몰재인 석고를 모형 왁스 표면에 묻혀 굳을 때까지 건조시킨다.② Bury the investment material plaster on the model wax surface and dry it until it hardens.
③ ②를 오븐소성로에 넣어 가열하면 왁스가 녹아서 밖으로 흘러나와 ②의 속은 처음의 왁스 모형대로 빈 공간이 생긴다.③ ② is put in the oven firing furnace and the wax melts and flows out. ② The inside of ② creates an empty space as the wax figure.
④ ③에 금속을 녹여서 주입시킨다.④ Dissolve the metal in ③ and inject it.
⑤ 금속이 식어 굳어지면 굳은 매몰재를 부수고 성형된 금속물을 꺼낸다.⑤ When the metal cools and hardens, crush the hard investment material and take out the molded metal.
⑥ 주조물(성형된 금속물)의 표면에 광택을 낸다.⑥ Gloss the surface of casting (molded metal).
이러한 절차로 왁스를 사용하여 만든 모형을 가지고 주조물을 만들 수 있다. 금속가공에 이용되는 로스트 왁스 캐스팅 법은 매몰재가 석고이므로 금속류의 용융물에는 잘 침식(侵蝕)되지 않으나 용융유리에는 침식되어 규석을 주재로 한 용융물의 형상주조 방법에는 이용할 수 없었다.This procedure allows casting to be made from a model made using wax. In the lost wax casting method used for metal processing, since the investment material is gypsum, it is hardly eroded by the melt of metals, but it is eroded by molten glass and cannot be used in the shape casting method of the melt mainly made of silica.
그 이유는 규석을 주재로 한 용융물의 온도가 1600℃ 정도임에 비해 매몰재의 성분이 물리적으로 분해되는 온도가 786℃이고 815℃ 이상 온도가 상승하면 유화개스가 발생하여 이 개스가 주조물의 표면을 변색시키기 때문이다. 따라서 용융유리를 주조하기 위해서는 1600℃ 이상에서도 전혀 침식되지 않는 내화물질을 밝혀내고 이를 제조하여야만 하였다.The reason for this is that the temperature of the melt, which is mainly silica, is about 1600 ° C, whereas the temperature at which the components of the investment material are physically decomposed is 786 ° C and the temperature rises above 815 ° C. This is because it discolors. Therefore, in order to cast molten glass, it was necessary to find and manufacture a refractory material that does not erode at all even at 1600 ° C or higher.
본 발명자는 수년간 수 없이 반복실험 끝에 용융유리에 안정하고 그 침식되지 않는 매몰제를 개발하여 비로소 본 발명은 완성하게 되었다.After several years of repeated experiments, the inventors have developed a investment agent that is stable to molten glass and that does not erode.
용융유리의 주조에 적합한 매몰재는 그 물성이 첫째, 용융점이 1600℃ 이상이어야 하고 둘째, 경도가 커서 내마모성이 커야 한다. 셋째, 기계적 강도가 우수해야 하며 넷째, 기공율이 아주 적으며 기밀질 조직(機密質 組織)을 갖어야 하며 다섯째, 열전도율이 매우 양호해야 하며 여섯째, 화학적 저항성이 커야 한다.The investment material suitable for casting molten glass should have the physical properties of first, melting point of 1600 ° C or higher, and second, large hardness and high wear resistance. Third, the mechanical strength should be excellent. Fourth, the porosity should be very low, the airtight structure should be possessed. Fifth, the thermal conductivity should be very good. Sixth, the chemical resistance should be large.
상기의 조건을 충족시킬 수 있는 물질로는 다음의 것이 있다.The following materials can satisfy the above conditions.
1) 半融 알루미나(Sintered alumina)내화물1) Sintered alumina refractories
순도 99.3%∼99.8%의 알루미나를 1750℃ 이상에서 소결시킨 것으로 독일제품 Sinterkorund가 있다.Sinterkorund, a German product, is obtained by sintering alumina with a purity of 99.3% to 99.8% at 1750 ° C or higher.
2) 半融 알루미나 점화전 애자(點火栓 碍子)2) 자 alumina pre-ignition insulator (點火 栓 碍 子)
3) 용융주조 내화물(fused cast refractories)3) fused cast refractories
알루미나 質을 원료로 전호로(電弧爐)에서 완전히 용해시킨 후 주조성형하여 응고시켜 결정조직을 갖게 한 것으로 미국의 모노플락스K(Harbison-Carborundum 社가 제조한 용융주조 내화물 중에서 특히 부식에 뛰어난 저항성을 지닌 크롬-알루미나 내화물을 지칭하는 상표임)가 있다.It is a material that melts alumina as a raw material completely in an electric furnace and then casts and solidifies it to have a crystal structure. It is particularly resistant to corrosion among the molten refractories manufactured by Harbison-Carborundum of the United States. Chrome-alumina refractory).
이하 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.
매몰재의 제조Manufacture of investment material
상기한 반융 알루미나 내화물, 반융 알루미나 점화전 애자 및 모노플락스K(Harbison-Carborundum 社가 제조한 용융주조 내화물 중에서 특히 부식에 뛰어난 저항성을 지닌 크롬-알루미나 내화물을 지칭하는 상표임)에서 선택한 1종의 알루미나 내화물의 본말 100중량부에 액상 접착제인 뮤라이트 10중량부와 물 400중량부를 혼합하여 몰탈형의 매몰재를 제조하였다.1 type of alumina selected from the above semi-fused alumina refractories, semi-fused alumina pre-ignition insulators and monoflox K (a trademark of chrome-alumina refractories having a particularly high resistance to corrosion, among melt-cast refractory manufactured by Harbison-Carborundum) Mortar mortar was prepared by mixing 10 parts by weight of the murite as a liquid adhesive and 400 parts by weight of water to 100 parts by weight of the end of the refractory.
이하 본 발명의 실시예를 기술하나 그 실시예로 본 발명을 한정하는 것은 아니다.Examples of the present invention are described below, but the present invention is not limited to the examples.
실시예 1Example 1
반달형상의 모형을 왁스로 만든 후, 모노플라스K 분말 100g에 뮤라이트 10g과 물 400g을 혼합한 액상의 매몰재를 모형 왁스 표면에 코팅시키고 굳을 때까지 건조시킨다. 爐內에서 800℃로 3시간 동안 가열한 후 서서히 온도를 낮추어 350℃에서 30분간 유지시키고 냉각하여 왁스 모형과 똑같은 빈 공간을 형성시켰다.After the vandal-shaped model is made of wax, a liquid investment material, in which 100 g of monoplace K powder, 10 g of mulite and 400 g of water is mixed, is coated on the surface of the model wax and dried until it solidifies. After heating at 800 ° C. for 3 hours at room temperature, the temperature was gradually lowered, maintained at 350 ° C. for 30 minutes, and cooled to form an empty space exactly like a wax figure.
1600℃에서 용해된 수정의 용융물을 주입시키고 식어 굳어진 후 매몰재를 부수고 성형된 주조물을 꺼내어 표면을 광택처리하여 반달형상의 수정 주조물을 제조하였다.After the melt of crystal melted at 1600 ° C. was injected and cooled, the buried material was crushed, the molded casting was taken out, and the surface was polished to prepare a semi-moon shaped quartz casting.
실시예 2Example 2
실시예 1에서 사용한 모노플락스K 분말 대신에 Sinterkorund의 분말을 사용한 것 이외에는 실시예 1과 동일한 방법으로 실시하여 반달형상의 수정 주조물을 제조하였다.A semi-dal shaped quartz casting was prepared in the same manner as in Example 1 except that Sinterkorund powder was used instead of the monoflox K powder used in Example 1.
실시예 3Example 3
매몰재로 모노플락스K 분말 대신에 점화전 애자를 미분말로 사용한 것 이외에는 실시예 1과 동일하게 실시하여 동일한 제품을 제조하였다.The same product was prepared in the same manner as in Example 1 except that the insulator was used as a fine powder instead of the monoflox K powder as the investment material.
실시예 4Example 4
실시예 1과 동일하게 실시하되 수정 용융액 대신에 일반유리 용융액을 사용하여 반달형상의 유리 제품을 얻었다.In the same manner as in Example 1, but using a common glass melt instead of a crystal melt to obtain a semi-moon-shaped glass product.
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