KR960007391B1 - Detergent compositions - Google Patents

Abstract

This detergent contains bamboo salt, which has phase stabilizing effect and antibacterial and antifungal effect. The amount of bamboo salt is 0.5-10wt%. The detergent comprises 0.5-10wt% mixture of C10-C18 linear alkyl based anionic surfactant and fatty acid based amide substituted nonionic surfactant; 0.1-5wt% NaOH; 0.5-3.0wt% pH controller; and calcium carbonate with 10-80micrometer of size distribution. And this composition has 0.5-5.0wt% of tetrapotassium pyrophosphate as chelating component. The above pH controller is such as monoethanolamine, diethanolamine or triethanolamine.

Description

Multipurpose cleaning agent composition containing bamboo salt

The present invention relates to a multipurpose detergent composition containing bamboo salt. Specifically, the present invention relates to a multi-purpose detergent composition using bamboo salt having a phase-stable effect and a bactericidal effect in a dispersed state in a multi-purpose detergent having an abrasive component.

There are many kinds of bacteria (Bacteria), yeast and mold in the general household, and these microorganisms grow rapidly if their environmental conditions are suitable for habitat. These microorganisms remain in kitchens, sinks, bathtubs, etc., and mainly affect odors and disease stories. Accordingly, the present invention provides a multi-purpose detergent composition having a sterilizing effect of the microorganisms remaining while cleaning these places to maintain a clean residential environment and also have a great effect as a phase stabilizer of the dispersion solution.

Conventionally, disinfectants have been separately used while using inorganic substances as phase stabilizers of dispersion solutions, but in the present invention, multi-purpose cleaners containing bamboo salt and anion and nonionic surfactants, abrasives and other auxiliaries having both a stabilizing effect and a bactericidal effect It relates to a composition.

Bamboo salt is made by using bamboo and salt through the chemical method, and it removes toxins from bamboo by using cell regeneration, which produces new cells, and salt that prevents sterilization and decay by repeatedly treating the furnace with high heat. And it has been known as a elixir to maximize the efficacy. Salt used in the manufacture of bamboo salt is usually used as a natural salt, besides edible salt, rock salt, reagent grade sodium chloride and potassium chloride are used as bamboo, bamboo or cotton bamboo, but there is no need to limit the type of bamboo.

Bamboo salt used in the present invention is commercially available as bamboo and ocher, which acts on cell growth, and salt that prevents sterilization and rot, are repeatedly treated in a furnace at high heat (over 1,000 ℃) to remove toxins and maximize the effect of the drug. It is increased.

Introducing the method of electrolytic down to ancient books as a method for producing bamboo salt used in the present invention is as follows. After cutting through the sea breeze (3 years old is suitable), one side is cut and the other is blocked. After kneading, put about 1cm of red pine leaf, reinforcement mugwort, and jujube leaf, and seal it with the clay soil kneaded about 2cm at the end. Make several of these bamboos, put pines on a porcelain kiln made of ocher, sprinkle pine nuts, and set fire (room temperature above 1,000 ℃). After about 24 hours, take it out (at this time, only the salt pillar absorbing the stem of red, red pine, mugwort, and loess) is crushed finely and the salt is added to the new bamboo barrel in the same way as the first. Repeat eight times, and on the ninth, use a special stainless steel plate made underground to produce high heat (1,500 ℃ or more). Changes like This mass is bamboo salt and crushed properly.

In general, pollutants attached to residential spaces include nitrogen compounds (NOx), sulfur oxides (SOx) and other inorganic compounds remaining in the air, and organic compounds and dusts such as hydrocarbons and ketones produced in kitchen stoves. , Oil residues are attached together with bacteria, yeast and various filamentous bacteria remaining in the living space.

The method for removing contaminants of these organic and organic compounds is selected from the primary method of physical removal of force and the chemical method of anionic, nonionic surfactant and liquid (alkaline), which are cleaning functions. In the case of a multi-purpose detergent, since the abrasive contains a large amount of physical component and includes the latter chemical method, it may be combined with physical and chemical methods to exhibit excellent effects on cleaning of various contaminants and stains.

In the detergent composition of the present invention, in order to remove various microorganisms, bamboo salt, which has an excellent bactericidal effect and serves as a control aid for phase stabilization of a dispersion solution containing a dispersant, was mixed with an anion and a nonionic surfactant.

In general, suitable abrasives have a MOS hardness of 1 to 4, and 4 or more materials are reluctant to be applied due to the possibility of scratches on the target material. Among them, Calcite having Morse hardness 3 is most widely used (UK Patent No. 1345118), and especially in the case of calcium metasilicate, it is formed in a wide range of fields from not only soft cotton containing glass fibers but also hard surfaces such as sinks. It has been reported to be eligible for stain removal (US Pat. No. 4,181,633). In addition, depending on the type of abrasive may exhibit a number of properties, depending on the size of the abrasive (particle size) can be observed a variety of properties.

In general, dispersion means that solid particles in a dispersed phase are dispersed in a liquid in a dispersion medium, and in the case of 1 to 10 nm (10 ^-9 m) of small particles depending on the particle size, the dispersion is called a colloidal dispersion system and the particle size is usually dispersed at about 100 nm or more. These phases are called "suspensions", and if the sedimentation is caused by gravity, this phenomenon is determined by the specific gravity difference between the particles and the dispersion medium (Japan Kao Corporation, Surfactant p68-78). It is also affected by the potential of the particle's surface charge and conduction to dispersion. Factors affecting dispersion include particle size, surface charge of particles, viscosity of solution, temperature, and specific gravity difference between dispersion and particles, which are described in detail in the following equation (Ⅰ). The smaller, the slower the sedimentation rate, the higher the viscosity, the smaller the difference in density between the dispersion and the particles, the slower the sedimentation rate. (Japanese Kao Corporation Surfactant)

More specifically, the multi-purpose detergent composition according to the present invention uses bamboo salt for viscosity control purposes and sterilization purposes, which are fatal to phase stability, and its amount is suitably 0.5 to 10 parts by weight based on the total amount of the composition. In case of using less than 0.5 parts by weight of bamboo salt, the effect is insignificant, and when using more than 10 parts by weight, the viscosity may change rather adversely affect the phase stability.

The general purpose detergent composition according to the present invention is a mixture of a linear alkyl anionic surfactant having 12 to 18 carbon atoms and a fatty acid amide-substituted nonionic surfactant having a substituted sulfuric acid group of 0.5 to 10 parts by weight, NaOH to 0.1 to 5 parts by weight, pH It may contain 1.0 to 3.0 parts by weight of a regulator and a calcium carbonate having an average particle size distribution of 10 to 80 micro.

In the cleaning composition of the present invention, in order to remove organic and inorganic contaminants, a physical method using an abrasive component as a primary removal method and an anion and nonionic surfactant compound as a secondary removal method are used. As an abrasive, a natural calcium carbonate having a MOS hardness of 3 and abundantly used was used. The particle size is preferably 10 to 80 microns with an average particle size having excellent cleaning power without giving a fatal trace, and the amount of the abrasive used is 20 to 60 parts by weight. Suitable. In the case where the abrasive is used in an amount of 20 parts by weight or less, the cleaning power cannot be expected. When the abrasive is used in an amount of 60 parts by weight or more, it is difficult to prepare a dispersion solution because of excessive dispersoids.

0.5-10 parts by weight of a mixture of a linear anionic surfactant having 12 to 18 carbon atoms and a nonionic surfactant for viscosity control to impart an electric double layer to the dispersion together with a cleaning function. It is good. When the anionic and nonionic surfactant mixture is used in less than 0.5 parts by weight, the effect is insignificant, and when it is 10 parts by weight or more, it is difficult to use due to excessive bubble formation.

In the detergent composition of the present invention, 0.5 to 5 parts by weight of TKPP (tetrapotassium pyrophosphate) is used to impart a chelating effect. When using less than 0.5 parts by weight of TKPP, the effect is insignificant, and when using more than 5 parts by weight may adversely affect the phase stability.

The caustic soda used in the detergent composition of the present invention is used to neutralize the linear anionic surfactant, and pH adjusting agents such as MEA (monoethanolamine), DEA (dieethanolamine), and TEA (triethanolamine) are neutralized. Used to keep the liquidity alkaline. In addition, it is preferable to use 0.5 to 3 parts by weight of the pH adjuster, when the pH adjuster is used less than 0.5 parts by weight liquid is not alkaline, when used by more than 3 parts by weight is strongly alkaline to be harmful to the human body There is.

In addition, the detergent composition of the present invention uses a small amount of silicone oil which does not affect the phase stability while improving the feeling of use when cleaning contaminants, and a small amount of antifoaming agent to prevent excessive foaming, and also uses a fragrance and a dye to sense The effect can be enhanced.

Hereinafter, the present invention will be described in detail by way of examples.

[Examples 1 to 4]

Next, according to the composition of Table 1 in order to put in water and thoroughly stirred to prepare an abrasive containing phase stable multi-purpose cleaner.

TABLE 1

Using the compositions of the above examples and comparative examples, the bubble measurement test method (KSM-2709), phase stability test method (self test method), gloss measurement method (KS M-2743), pH measurement method (KS A-5105) ), The evaluation of the polishing force measurement method (AXTM-2486-79, physical properties measurement) was performed.

1. Evaluation method of bubble

○: 200 ml or less

×: 200ml or more

2. Phase stability test method

○: 3 mm or less

×: 3mm or more

3. How to measure glossiness

4. pH-value notation

6 ~ 8: Neutral

9 ~ 11 or less: weak alkaline

11 or more: alkaline

5. Evaluation method of abrasive force

6. Evaluation of bactericidal power

Bacteria, yeast, molds are supported and evaluated after being left at 40 ℃ for 24 hours

○: sterilization ×: growth

7. Measurement method of phase stability

Temperature 50 ℃ (error ± 0.1 ℃) Visually discriminated after 4 weeks in hot air circulation incuvbator. (Check the phase separation length in cm from the upper layer.)

The test results are shown in Table 2 below.

TABLE 2

As shown in Table 2, the composition of Examples 1 to 3 to which the bactericidal component Bardaq 203 Am was applied or the bamboo salt was applied, but the foaming, phase stability, bactericidal power, glossiness, liquidity, polishing power, etc. were excellent. When a small amount or an excessive amount of phase separation was induced, in particular, a small amount of Comparative Example 4 had no sterilizing power as well as phase separation.

Therefore, even if the weight of each composition applied to the composition is changed, the phase stability of the composition itself may be induced because it greatly affects the phase stability.

Claims (7)

A versatile detergent composition comprising bamboo salt. The multipurpose detergent composition according to claim 1, wherein the salt contains 0.5 to 10 parts by weight. The method according to claim 1, wherein 0.5 to 10 parts by weight of a mixture of a linear alkyl anionic surfactant having 12 to 18 carbon atoms and a fatty acid amide-substituted nonionic surfactant substituted with a sulfuric acid group, 0.1 to 5 parts by weight of NaOH, and a pH adjusting agent 0.5 A phase stability enhanced multipurpose detergent composition comprising calcium carbonate having from about 3.0 parts by weight and a particle size distribution of 10 to 80 microns. The multi-purpose detergent composition according to claim 1 or 3, which contains 0.5 to 5 parts by weight of the chelating component TKPP. The multipurpose cleaner composition according to claim 3, wherein the pH adjusting agent is monoethanolamine, diethanolamine or triethanolamine. 4. The multipurpose detergent composition according to claim 3, wherein the nonionic surfactant has 12 to 18 carbon atoms and 1 to 2 amides are substituted. The multipurpose cleaner composition according to any one of claims 1 to 3, which contains a silicone oil, a fragrance, a dye and an antifoaming agent.