KR960004778B1 - Method for forming a color coatings for pattern and letter of metal plates - Google Patents

Method for forming a color coatings for pattern and letter of metal plates Download PDF

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KR960004778B1
KR960004778B1 KR1019930025092A KR930025092A KR960004778B1 KR 960004778 B1 KR960004778 B1 KR 960004778B1 KR 1019930025092 A KR1019930025092 A KR 1019930025092A KR 930025092 A KR930025092 A KR 930025092A KR 960004778 B1 KR960004778 B1 KR 960004778B1
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pattern
paint
metal plate
solution
letters
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KR1019930025092A
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Korean (ko)
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KR950014359A (en
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김종선
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김종선
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/04Producing precipitations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/22Removing surface-material, e.g. by engraving, by etching
    • B44C1/227Removing surface-material, e.g. by engraving, by etching by etching

Abstract

The color coating method improves the quality of a wrist watch by obtaining a high-grade decoration. The color coating method comprises: degreasing metal with alkaline solution and rinsing with water; sensitizing and drying; attaching the patterned film and radiating ultraviolet ray; developing and heating at 200 deg.C; and etching and rinsing.

Description

금속판의 무늬 및 문자에 색도금 형성방법How to plate color on metal plate pattern and text

본 발명은 손목시계 뒷판 등과 같은 금속판을 엣칭(etching)하여 음각된 무늬 및 문자를 금도금 등 색도금으로 표출하기 위한 것으로서, 금속판의 무늬 및 문자에 색도금 형성방법에 관한 것이다.The present invention relates to a method for forming a color plate on a metal plate pattern and characters by etching a metal plate such as a back plate of a watch and the like to express the engraved pattern and characters by gold plating.

종래의 산-가용성 금속을 산수용액으로 된 용제를 이용하여 복잡한 모양과 무늬를 엣칭하는 기술은 일반화 되었다.Techniques for etching complex shapes and patterns using conventional acid-soluble metals with solvents of acidic solutions have become common.

따라서, 이러한 종래의 엣칭 방법으로 시계 뒷판 등과 같은 금속판을 엣칭하여 음각 문자 또는 음각 무늬등을 형성하므로서 무늬 및 문자가 금속판 색깔과 같은 스텐레스 자체의 색깔로만 표출되므로 문자가 돋보이지 않고 고급스런 조형미가 없어 상품으로서의 가치가 떨어지는 문제점이 있었다.Therefore, by etching the metal plate, such as the back plate of the clock by the conventional etching method such as engraved letters or intaglio patterns, the pattern and letters are expressed only in the color of the stainless steel itself, such as the color of the metal plate, so the letters do not stand out and there is no luxurious molding beauty There was a problem of low value as.

본 발명은 이러한 문제점을 해소하기 위해 창안된 것으로써, 시계 뒷판 등의 금속판에 음각 엣칭 후 금도금하여 길드페인트로 금속판을 도포시킨 후 페인트 용해액이 묻은 종이에 금속판을 문지르면 금속판상의 무늬 또는 문자 부분에만 페인트가 남고 그의 부분은 페인트가 제거된다.The present invention was devised to solve such a problem, and after engraving gold plate on the metal plate such as the back plate of the watch and coating the metal plate with guild paint, then rubbing the metal plate on the paper with the paint dissolving liquid on the metal plate pattern or letter part only. Paint remains and parts of it are removed.

이렇게 된 금속판을 금용해액에 담가 문자 외주면의 금도금을 박리시키고, 다시 음각부에 도포된 페이트를 페인트 용해액으로 제거시키면 시계 뒷판의 무늬 및 문자는 금도금 무늬 및 문자가 되고, 무늬 및 문자 외주면은 금속판 자체의 색깔을 갖게 되므로 우아하고 고급스런 장식적 효과를 갖도록 창안된 것이다.The metal plate was immersed in the gold solution, and the gold plating on the outer surface of the letter was peeled off, and the paint applied to the engraved part was removed with a paint solution.The pattern and letters on the back of the watch became gold plated and letters. It is designed to have an elegant and luxurious decorative effect because it has the color of the metal plate itself.

이하, 본 발명을 실시예에 의하여 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail by way of examples.

시계 뒷판 등의 금속판 완제품을 약알카리 용액으로 탈지 후 물로 여러번 세척한 다음 감광액 처리하여 건조하고, 무늬 및 문자가 도안된 필름을 시계 뒷판 표면에 부착한 후 자외선 조사하여 문자를 형성한 후, 필름을 제거하여 현상시켜 약 200℃에서 열처리하므로서 감광액이 시계 뒷판 등의 금속판에 견고히 부착되도록 한다.Finished metal plate products such as clock face plate with weak alkali solution, washed several times with water, dried by treatment with photoresist, and attached to the surface of the face of the watch and printed on the surface of the watch face. Remove and develop to heat treatment at about 200 ℃ so that the photoresist is firmly attached to the metal plate, such as the back of the watch.

이렇게 된 본 발명의 시계 뒷판에 형성된 무늬 및 문자 외주면의 감광액을 붓 또는 락카 등으로 수정한 후 공기에 의한 자연 건조시켜 염화제2칠용액에 7분-14분간 담가 엣칭하게 된다.After modifying the photoresist of the pattern and the outer peripheral surface of the character formed on the back of the clock of the present invention with a brush or lacquer, it is naturally dried by air and immersed for 7 minutes to 14 minutes in a second chloride solution.

무늬 및 문자 형성방법으로는 실크인쇄, 패드인쇄 또는 레이저를 이용하여 무늬 및 문자를 형성할 수도 있다.Patterns and characters may be formed using silk printing, pad printing, or laser to form patterns and characters.

이렇게 엣칭되어 무늬 및 문자가 형성된 시계 뒷판을 물로 세척하고, 다시 가성소오다로 탈지시킨 후 물로 여러번 세척하여 강산 용액에 초음파 엣칭, 세척을 거쳐 부식을 조밀하게 한 후 통상의 방법으로 금도금하여 건조한다.The etched back plate formed with patterns and letters is washed with water, degreased with caustic soda, and then washed several times with water to densify corrosion by ultrasonic etching and washing with strong acid solution, and then gold-plated and dried in the usual way. .

이때, 금도금 이외의 각종 도금에도 다양하게 적용할 수 있다.At this time, it can be variously applied to various platings other than gold plating.

도금시 시계 뒷판 음각 무늬 및 문자 뿐만 아니라 그 외주면에도 금도금이 이루어지므로 금도금된 시계 뒷판을 물세척 건조 후 길드페인트로 시계 뒷판 전면을 도포하여 페인트 용해액이 묻은 종이에 페인트가 도포된 시계 뒷판을 대응시켜 문지르면 음각 무늬 및 문자에 도포된 페인트만 남고 그 외주면의 페인트는 제거된다.When plating, gold plating is applied to the outer surface of the watch as well as the intaglio pattern and text, so that the gold-plated watch backplate is dried with water and then the front of the watch backplate is coated with a guild paint. If you rub it, only the paint applied to the intaglio pattern and the character is left, and the paint on the outer peripheral surface is removed.

이때, 페인트 용해액이 묻은 종이에 페인트가 도포된 시계 뒷판을 대응시켜 문질러서 페인트를 제거하는 방법 대신에 회전 연마포에 대응 마찰시켜 제거할 수도 있다.At this time, instead of a method of removing the paint by rubbing the clock back plate coated with paint on the paper on which the paint dissolving liquid is applied, it may be removed by corresponding friction with the rotary polishing cloth.

따라서 시계 뒷판을 30~50℃의 금용해액(금 박리액)에 담가 음각 무늬 및 문자 이외에 도포된 금을 박리시키게 되며, 음각 무늬 및 문자에 도금된 금은 표면에 페인트가 도포되어 있으므로 박리되지 않는다.Therefore, the back of the watch is immersed in the gold solution (gold stripping solution) of 30 ~ 50 ℃ to peel off the gold coated in addition to the intaglio pattern and characters, and the gold plated on the intaglio and characters are not peeled off because the paint is applied to the surface Do not.

이렇게 무늬 및 외주면의 금을 박리시킨 후 물세척 건조하여 다시 음각 무늬 및 문자 부분에 남아 있는 페인트를 페인트 용해액으로 제거하면 무늬 및 문자 부분에만 금도금된 시계 뒷판을 얻게 된다.When the gold on the pattern and the outer circumferential surface is peeled off and then washed with water, the paint remaining on the engraved pattern and the text portion is removed with a paint solution to obtain a gold plated watch back plate only on the pattern and the text portion.

이렇게 된 본 발명의 실시예를 간단히 요약하면 다음과 같다.Briefly summarized embodiments of the present invention as follows.

[실시예 1]Example 1

시계 뒷판을 약알카리 용액으로 탈지 후 물세척→건조→감광액처리 및 건조→무늬 및 문자도안 필름을 시계 뒷판 표면에 부착→자외선조사(무늬 및 문자형성)→필름제거 후 현상→약 200℃에서 열처리→무늬 및 문자 외주면수정→자연건조→염화제2칠 용액에 7분~14분간 엣칭→물세척→가성소오다로 탈지→물세척→강산용액에 초음파엣칭,세척→금도금(통상의 방법)→물세척 및 건조→길드페인트도포→신나 등 페인트 용해액이 묻은 종이에 문질러 페인트제거→30~50℃의 금용해액으로 금박리→물세척 및 건조→신나 등 페인트 용해액으로 음각 문자부의 페인트 제거→완제품.Degrease the back of the watch with a weak alkali solution, and then wash the water → Dry → Treat the photoresist and dry it → Attach the pattern and the text to the back of the watch → UV irradiation (pattern and text formation) → Remove the film and develop → Heat treatment at about 200 ℃ → Modifying the outer surface of letters and letters → Natural drying → Etching 7--14 minutes in two-color chloride solution → Washing with water → Degreasing with caustic soda → Washing with water → Ultrasonic etching with strong acid solution, washing → Gold plating (normal method) → Water washing and drying → Guild paint application → Rubbing on paper with paint solution such as thinner to remove paint → Gold peeling with gold solution of 30 ~ 50 ℃ → Water washing and drying → Paint removal of negative character with paint solution such as thinner → Finished product.

[실시예 2]Example 2

시계 뒷판을 약알카리 용액으로 탈지 후 물세척→건조→무늬 및 문자도안 실크인쇄→약 200℃에서 열처리→무늬 및 문자외주면 수정→자연건조→염화제2칠 용액에 7-14분간 엣칭→물세척→가성소오다로 탈지→물세척→강산용액에 초음파 엣칭,세척→금도금(통상의 방법)→물세척 및 건조→길드페인트로 도포→신나 등 페인트 용해액이 묻은 종이에 문질러 페인트 제거→30-50℃의 금용해액으로 금박리→물세척 및 건조→신나등 페인트 용해액으로 음각 문자부의 페인트 제거→완제품.Degreasing the back of the watch with a weak alkaline solution, and then washing with water → drying → printing patterns and texts Silk printing → heat treatment at about 200 ° C → modifying patterns and texts circumferentially → natural drying → etching in salt paint solution for 7-14 minutes → washing with water → Degreasing with caustic soda → Washing water → Ultrasonic etching and washing in strong acid solution → Gold plating (normal method) → Washing and drying water → Applying with guild paint → Rubbing on paper with paint solution such as thinner and removing paint → 30- Gold stripping → water washing and drying → paint removal of engraved character part with paint solution such as thinner → finished product.

[실시예 3]Example 3

시계 뒷판을 약알칼리 용액으로 탈지 후 물세척→문자 및 무늬 도안 패드인쇄→약 200℃에서 열처리→무늬 및 문자 외주면수정→자연건조→염화제2칠 용액에 7-14분간 엣칭→물세척→가성소오다로 탈지→물세척→강산 용액에 초음파 엣칭,세척→금도금(통상의 방법)→물세척 및 건조→길드페인트도포→신나 등 페인트 용해액이 묻은종이에 문질러 페인트 제거→30-50℃의 금용해액으로 금박리→물세척 및 건조→신나 등 페인트 용액으로 음각 문자부의 페인트 제거→완제품.Degrease the back of the watch with a weak alkaline solution, and then wash the water → Print letters and patterns on the pad → Heat treatment at about 200 ° C → Modify the outer surface of the letters and letters → Natural drying → Etch for 7-14 minutes in a two-chloride solution → Water washing → Caustic Deodorizing with Soda → Washing → Ultrasonic etching to strong acid solution, washing → Gold plating (normal method) → Washing and drying → Gild paint application → Paint on paper with paint solution such as thinner to remove paint → 30-50 ℃ Gold peeling → Gold cleaning with water soluble solution → Drying → Paint removal of engraved letter part with paint solution such as thinner → Finished product.

[실시예 4]Example 4

시계 뒷판을 약알칼리 용액으로 탈지 후 물세척→건조→레이저를 이용 무늬 및 문자도안→염화제 2칠 용액에 7-14분간 엣칭→물세척→흑도금 또는 금도금(통상의 방법)→길드페인트도포→신나 등 페인트 용해액이 묻은 종이에 문질러 페인트제거→30-50℃의 금용해액으로 금박리→세척 및 건조→신나 등 페인트 용해액으로 음각 문자부의 페인트제거→완제품으로 완성된다.Degrease the back of the watch with a weak alkaline solution, and then rinse with water and dry with a laser. Pattern and letter design → Etch in a 7-color chloride solution for 7-14 minutes → Water washing → Black or gold plating (ordinary method) → Guild paint application → Rub the paper with paint dissolving liquid, such as thinner, to remove the paint → gold peeling with 30-50 ℃ gold dissolving solution → washing and drying → paint dissolving with thinner such as thinner → finished product.

이와 같이 본 발명은 시계 뒷판 등의 금속판에 무늬 문자를 형성함에 있어서 금도금 등의 원하는 색깔의 무늬 및 문자를 형성하므로서 문자와 무늬를 돋보이게 하여 더욱 명확하게 나타낼 수 있고, 고급스런 장식미를 표출시킬 수 있게 된 효과를 갖게 되었다.As described above, the present invention forms a pattern and a character of a desired color such as gold plating in forming a pattern character on a metal plate such as a watch back plate, thereby making the character and pattern stand out more clearly and expressing a high-quality decoration. It has become effective.

Claims (5)

금속판에 도안 필름을 이용하여 인쇄하고 엣칭 후 금도금하는 공지의 방법에 있어서, 시계 뒷판 등의 탈지된 금속판에 감광액처리, 건조 후 무늬 및 문자도안 필름을 부착하고 자외선 조사하여 무늬 및 문자를 형성한 다음 필름제거 후 현상하여 약 200℃에서 열처리한 다음, 자연건조시켜 염화제2칠 용액에 7-14분간 엣칭시켜 물세척, 가성소오다탈지, 물세척, 강산용액에 초음파엣칭, 세척순으로 실시한 후 통상의 방법으로 금도금시켜 다시 물세척 및 건조 후 길드페인트도포하여 페인트 용해액이 묻은 종이에 금속판을 문질러 길드페인트를 제거시켜 30-50℃의 금용해액에 무늬 및 문자 이외의 금도금을 박리시키고, 음각 무늬 및 문자부의 페인트를 제거하여 완제품을 얻게 되는 금속판의 무늬 및 문자에 색도금 형성방법.In a known method of printing using a pattern film on a metal plate and gold plating after etching, a photoresist treatment, a pattern and a letter pattern film are attached to a degreased metal plate such as a clock face plate, dried, and irradiated with ultraviolet rays to form a pattern and a character. After removing the film, it is developed, heat-treated at about 200 ℃, and then dried naturally and etched in a 2nd chloride solution for 7-14 minutes, followed by water rinsing, caustic soda degreasing, water rinsing, and ultrasonic etching and washing with strong acid solution. Gold plating is carried out by usual method, and after washing with water and drying, guild paint is applied. Rubbing the metal plate on the paper with paint dissolving solution to remove the guild paint, peeling gold plating other than patterns and characters from the gold solution at 30-50 ° C, Method of forming color plating on metal plate's pattern and letters to get finished product by removing intaglio and character part's paint. 제1항에 있어서, 시계 뒷판 등의 탈지된 금속판에 무늬 및 문자도안 된 실크인쇄지를 부착하여 무늬 및 문자를 형성한 후 실크인쇄지를 제거 후 현상하여 약 200℃에서 열처리하여 자연건조시켜 염화제2칠 용액에 7-14분간 엣칭시키는 방법으로 무늬 및 문자를 형성시켜 금속판의 무늬 및 문자에 색도금 형성방법.The method according to claim 1, wherein the printed sheet is printed on a degreased metal plate such as a clock face plate to form a pattern and letters, and then the silk print paper is removed and developed. Forming a pattern and letters by etching in a 7-7 minutes in the fill solution to form a color plating on the pattern and letters of the metal plate. 제1항에 있어서, 시계 뒷판 등의 탈지된 금속판에 패드인쇄하여 무늬 및 문자를 형성한 후 약 200℃로 열처리하여 자연건조시켜 염화제2칠 용액에 7-14분간 엣칭시키는 방법으로 무늬 및 문자를 형성시켜 금속판의 무늬 및 문자에 색도금 형성방법.The method of claim 1, wherein after printing the pads on a degreased metal plate such as a clock face plate to form a pattern and letters, heat treatment at about 200 ° C. to dry them naturally, and to etch the 7-chloride solution for 7-14 minutes. Forming a color plating method on the metal plate pattern and letters. 제1항에 있어서, 금속판에 흑도금(검정색)한 후 레이저로 무늬 및 문자를 도안하여 염화제2칠 용액에 7-14분간 엣칭 후 다시 흑도금하여 길드페인트로 도포하여 페인트 용해액이 묻은 종이에 문질러 길드페인트를 제거시켜 30-50℃의 용해액에 무늬 및 문자 이외의 흑도금을 박리시키고, 음각 무늬 및 문자부의 페인트를 신나 등 페인트 용해액으로 제거하므로써, 흑색 무늬 및 문자가 형성된 제품을 얻게 된 금속판의 무늬 및 문자에 색도금 형성방법.The method of claim 1, after the black plate (black) on the metal plate, the pattern and the character with a laser, etched in the chlorine chloride solution for 7-14 minutes, then black-plated and applied with a guild paint rubbed on a paper with paint solution A metal plate obtained by removing a guild paint by peeling black plating other than patterns and characters into a solution of 30-50 ° C. and removing paint of the engravings and characters with a paint solution such as thinner. How to form color plating on the pattern and characters of the. 제4항에 있어서, 엣칭된 금속판에 레이저로 무늬 및 문자를 도안하여 염화제2칠 용액에 7-14분간 엣칭 후 다시 금도금하여 길드페인트로 도포한 후 회전연마포에 대응마찰시켜 길드페인트를 제거시켜 30-50℃의 용해액에 무늬 및 이외의 금도금을 박리시키고, 음각 무늬 및 문자부의 페인트를 신나 등 페인트 용해액으로 제거하므로서 금도금 문자가 형성된 제품을 얻게 된 금속판의 무늬 및 문자에 색도금 형성방법.The etched metal plate is laser patterned and printed on the etched metal plate, and then etched in a 2nd chloride solution for 7-14 minutes, then gold-plated and coated with a guild paint to remove friction from the guild paint. The pattern and other gold plating were peeled off at 30-50 ° C., and the metal plate pattern and letters were obtained by removing the engraved pattern and the paint of the letter part with a paint melter such as thinner. Way.
KR1019930025092A 1993-11-24 1993-11-24 Method for forming a color coatings for pattern and letter of metal plates KR960004778B1 (en)

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KR100952146B1 (en) * 2009-08-06 2010-04-13 삼성유리공업 주식회사 Method and apparatus for manufacturing solid decoration pannel

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KR100496268B1 (en) * 2002-12-06 2005-06-17 박영철 The printing method at silicon wafer making use of the semiconductor etching process
CN114054968B (en) * 2021-11-16 2023-11-14 贵州航天电子科技有限公司 Method for engraving and paint embedding of thin-plate disc-shaped hard aluminum bottom plate part

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100952146B1 (en) * 2009-08-06 2010-04-13 삼성유리공업 주식회사 Method and apparatus for manufacturing solid decoration pannel

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