KR960000900A - Silylpropylamine and its preparation method and uses - Google Patents

Silylpropylamine and its preparation method and uses Download PDF

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Publication number
KR960000900A
KR960000900A KR1019940014746A KR19940014746A KR960000900A KR 960000900 A KR960000900 A KR 960000900A KR 1019940014746 A KR1019940014746 A KR 1019940014746A KR 19940014746 A KR19940014746 A KR 19940014746A KR 960000900 A KR960000900 A KR 960000900A
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KR
South Korea
Prior art keywords
formula
general formulas
silylpropylamine
chloride
iii
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Application number
KR1019940014746A
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Korean (ko)
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KR0142144B1 (en
Inventor
정일남
유복렬
석미연
이병구
Original Assignee
김은영
한국과학기술연구원
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Priority to KR1019940014746A priority Critical patent/KR0142144B1/en
Priority to JP6298364A priority patent/JP2781143B2/en
Publication of KR960000900A publication Critical patent/KR960000900A/en
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Publication of KR0142144B1 publication Critical patent/KR0142144B1/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0896—Compounds with a Si-H linkage
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring

Abstract

본 발명은 새로운 유기규소 화합물인 일반식(I)과 (Ⅱ)의 실릴프로필아민 및 그의 제조방법과 식물의 진균성 질명에 대한 살균제로서 그의 용도에 관한 것이다.The present invention relates to silylpropylamines of the general formulas (I) and (II), which are new organosilicon compounds, and methods for their preparation and their use as fungicides against fungal diseases of plants.

상기 식에서, X1과 X2는 각각 독립적으로 수소 또는 C1-C4의 알킬기, 페닐, 페녹시, 플루오로, 클로로, 브로모이며, R은 수소 또는 메틸기이고, Z는 메틸렌, 에틸렌, 산소 또는 비어 있고 이어져 있는 경우를 표시하며, R1과 R2는 메틸, 알릴, 부틸, 페닐 4-클로로페닐, 4-플루오르페닐, 히드록시, 트리메틸실록시기이고, n은 4 또는 5를 나타낸다.Wherein X 1 and X 2 are each independently hydrogen or an alkyl group of C 1 -C 4 , phenyl, phenoxy, fluoro, chloro, bromo, R is hydrogen or methyl, and Z is methylene, ethylene, oxygen Or when empty and connected, R 1 and R 2 are methyl, allyl, butyl, phenyl 4-chlorophenyl, 4-fluorophenyl, hydroxy, trimethylsiloxy group, and n represents 4 or 5.

Description

실릴프로필아민과 이들의 제조방법 및 용도Silylpropylamine and its preparation method and uses

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (6)

다음 일반식(I)과 (Ⅱ)로 표시되는 실릴프로필아민 화합물;Silylpropylamine compounds represented by the following general formulas (I) and (II); 상기싱서, X1과 X2는 각각 독립적으로 수소 또는 C1-C4의 알킬기, 페닐, 페녹시, 플루오르, 클로로, 브로모이며, R은 수소 또는 메틸기이고, Z는 메틸렌, 에틸렌, 산소 또는 비어 있고 이어져 있는 경우를 표시하며, R1과 R2는 메틸, 알릴, 부틸, 페닐,4-클로로페닐, 4-플루오르페닐, 히드록시, 트리메틸실록시기이고, n은 4 또는 5를 나탄내다.In the above, X 1 and X 2 are each independently hydrogen or an alkyl group of C 1 -C 4 , phenyl, phenoxy, fluorine, chloro, bromo, R is hydrogen or methyl, Z is methylene, ethylene, oxygen or Empty and subsequent cases are indicated, R 1 and R 2 are methyl, allyl, butyl, phenyl, 4-chlorophenyl, 4-fluorophenyl, hydroxy, trimethylsiloxy groups, n represents 4 or 5. 다음 일반식(Ⅲ)과 (IV)로 표시되는 실릴프로필클로라이드 화합물 :The silylpropyl chloride compounds represented by the following general formulas (III) and (IV): 상기식에서 X1,X2,R1,R2및 n은 각각 제1항에 정의된 것과 같다.Wherein X 1 , X 2 , R 1 , R 2 and n are the same as defined in claim 1, respectively. 2,6-디메틸모르폴린, 피페리딘, 헥사메틸렌이민 및 피롤리딘중의 한가지에 NaI를 넣고 제2항의 일반식 (Ⅲ)과 (IV)의 실릴프로필클로라이드와 반응시키는 것으로 이루어진 제1항의 일반적(I)과 (Ⅱ)의 실릴프로필아민 화합물의 제조방법.The method of claim 1, wherein NaI is added to one of 2,6-dimethylmorpholine, piperidine, hexamethyleneimine and pyrrolidine and reacted with the silylpropyl chloride of general formulas (III) and (IV) of claim 2. Process for the preparation of silylpropylamine compounds of general (I) and (II). 다음 일반식(V)의 1,4,4-트리클로로-6-아릴-4-6-실라헵탄을 다음 일반식(VI)과 (VⅡ)의 그리냐르 시약과 반응시키거나 클로로트리메틸실란과 공가수분해시키는 것으로 이루어진 제2항의 일반식(Ⅲ)의 실릴플로필클로라이드 화합물의 제조방법;Next, 1,4,4-trichloro-6-aryl-4-6-silaheptane of the general formula (V) is reacted with Grignard reagent of the following general formulas (VI) and (VII), or co-coated with chlorotrimethylsilane A process for preparing the silyl flofil chloride chloride of formula (III) according to claim 2; 상기식에서 X1,X2,R1,및 R2는 제1항에 정의된 것과 같고 X는 염소 또는 브롬 원소이다.Wherein X 1 , X 2 , R 1 , and R 2 are as defined in claim 1 and X is a chlorine or bromine element. 다음 일반식(V)의 1,4,4-트리클로로-6-아릴-4-실라헵탄을 다음 일반식(Ⅷ)의 디그리냐르 시약과 반응시키는 것으로 이루어진 제2항의 일반식(IV)의 실릴프로필클로라이드 화합물의 제조방법:The silyl of formula (IV) of claim 2 consisting of reacting 1,4,4-trichloro-6-aryl-4-silaheptane of formula (V) with the diggrinir reagent of formula Process for preparing propylchloride compound: XMg(CH)2)nMgX 일반식(Ⅷ)XMg (CH) 2 ) n MgX general formula (Ⅷ) 상기식에서 X1,X2,R1,및 R2는 제1항에 정의된 것과 같고 X는 염소 또는 브롬 원소이며, n=4,5이다.Wherein X 1 , X 2 , R 1 , and R 2 are as defined in claim 1 and X is a chlorine or bromine element, n = 4,5. 주성분이 제1항의 실리프로필아민 화합물로 이루어진 식물의 진균성 질병에 효과적인 살균제.A fungicide effective for fungal diseases of plants, whose main component is the silylpropylamine compound of claim 1. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940014746A 1994-06-25 1994-06-25 Method for preparing for silylproplylamine KR0142144B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
KR1019940014746A KR0142144B1 (en) 1994-06-25 1994-06-25 Method for preparing for silylproplylamine
JP6298364A JP2781143B2 (en) 1994-06-25 1994-12-01 Silylpropylamine derivative, production method thereof and fungicide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019940014746A KR0142144B1 (en) 1994-06-25 1994-06-25 Method for preparing for silylproplylamine

Publications (2)

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KR960000900A true KR960000900A (en) 1996-01-25
KR0142144B1 KR0142144B1 (en) 1998-07-01

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100022792A1 (en) * 2006-09-14 2010-01-28 Qionghua Shen Synthetic process for cyclic organosilanes
US7714089B2 (en) * 2007-12-13 2010-05-11 The Goodyear Tire & Rubber Company Functionalized monomers and functionalized rubbery polymers made therewith

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* Cited by examiner, † Cited by third party
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DD259344A5 (en) * 1986-04-11 1988-08-24 Ciba-Geigy Ag,Ch MICROBICIDE MEDIUM
AU605920B2 (en) * 1987-10-21 1991-01-24 Atochem North America, Inc. Morpholinyl silanes and use for control of plant diseases caused by fungi

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JPH0812681A (en) 1996-01-16
JP2781143B2 (en) 1998-07-30
KR0142144B1 (en) 1998-07-01

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