KR950704122A - MULTILAYER FILM STRUCTURE - Google Patents

MULTILAYER FILM STRUCTURE

Info

Publication number
KR950704122A
KR950704122A KR1019950701509A KR19950701509A KR950704122A KR 950704122 A KR950704122 A KR 950704122A KR 1019950701509 A KR1019950701509 A KR 1019950701509A KR 19950701509 A KR19950701509 A KR 19950701509A KR 950704122 A KR950704122 A KR 950704122A
Authority
KR
South Korea
Prior art keywords
film structure
coating
olefins
printing ink
film
Prior art date
Application number
KR1019950701509A
Other languages
Korean (ko)
Inventor
고든 레너드 머스클로우
로버트 빅터 포이리어
랠프 죠안느 웨버
Original Assignee
에드워드 에이치. 밸런스
모빌 오일 코오포레이숀
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/963,611 external-priority patent/US5380587A/en
Priority claimed from US07/963,610 external-priority patent/US5382473A/en
Application filed by 에드워드 에이치. 밸런스, 모빌 오일 코오포레이숀 filed Critical 에드워드 에이치. 밸런스
Publication of KR950704122A publication Critical patent/KR950704122A/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5263Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • B41M5/5272Polyesters; Polycarbonates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laminated Bodies (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)

Abstract

A printable film structure comprising a polymeric film substrate having at least one surface adherently incompatible with printing ink and having a primer coating thereon of a type which can cause destructive blocking between contacting layers of such coated films wherein the primer coating has thereon a polyester or coating of a water dissipatable printing ink base, with or without pigment, to prevent blocking.

Description

다층 필름 구조물(MULTILAYER FILM STRUCTURE)MULTILAYER FILM STRUCTURE

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (10)

인쇄 잉크와 접착적으로 비상용성인 표면을 하나 이상 가지며, 그 위에 코팅 필름의 접촉층간에 파괴적 블로킹을 유발할 수 있는 유형의 하도제 코팅을 갖는 중합체성 필름 기재를 포함하고, 상기 하도제 코팅은 그 위에 블로킹을 방지하기 위해 안료를 함유하거나 함유하지 않는 수-소산성 인쇄 잉크 베이스의 코팅 또는 폴리에스테르를 갖는 인쇄 가능한 필름 구조물.A polymeric film substrate having at least one surface that is adhesively incompatible with the printing ink, and having a primer coating of a type that can cause disruptive blocking between the contact layers of the coating film, the primer coating thereon A printable film structure having a polyester or coating of a water-dispersible printing ink base with or without pigment to prevent blocking. 제1항에 있어서, 상기 인쇄 잉크 베이스가 25℃에서 60/40 중량부의 페놀/테트라클로로에탄 용액중에서, 용매 100ml 당 0.5g의 폴레에스테르 농도로 측정시 약 0.1이상의 고유 점도를 갖는 수-소산성 코폴리에스테르의 코팅인 필름 구조물.The water-dissipative property of claim 1 wherein the printing ink base has an intrinsic viscosity of at least about 0.1 as measured at a polyester concentration of 0.5 g per 100 ml of solvent in a 60/40 parts by weight phenol / tetrachloroethane solution at 25 ° C. 3. Film structure that is a coating of copolyester. 제1항 또는 제2항에 있어서, 상기 포콜리에스테르가 하기(a) 내지 (b)의 단량체들(또는 이들의 폴리에스테르 형성 등가물들)의 축합 생성물을 포함하는 필름 구조물 : a) 테레프탈산 60 내지 75 몰%; b) 일반식 HOOC(CH2)nCOOH(상기 식중, n은 1 내지 11임)의 하나 이상의 디카르복실산 15내지 25몰%; c) 디카르복실산 원자핵에 결합된 알칼리 금속 설포네이트기를 함유하는 하나 이상의 설포 단량체 6 이상 내지 15 몰%; 및 d) C2-11의 하나 이상의 공중합 가능한 지방족 또는 시클로 지방족 알킬렌 글리콜 약 100 몰% 의 화학양론적양.3. The film structure of claim 1, wherein the pocoester comprises a condensation product of monomers (or polyester forming equivalents thereof) of (a) to (b): a) terephthalic acid 60 to 75 mol%; b) 15 to 25 mole% of one or more dicarboxylic acids of the general formula HOOC (CH 2 ) n COOH, wherein n is 1 to 11; c) at least 6 to 15 mole% of at least one sulfo monomer containing an alkali metal sulfonate group bonded to the dicarboxylic acid nucleus; And d) stoichiometric amounts of about 100 mol% of one or more copolymerizable aliphatic or cycloaliphatic alkylene glycols of C 2-11 . 제1항 또는 제2항에 있어서, 상기 코폴리에스테르가 하기(a) 내지(d)의 단량체들(또는 이들의 폴리에스테르 형성 등가물들)의 축합 생성물을 포함하는 필름 구조물 : a) 이소프탈산 90 내지 97몰%; 및 이에 대응하여 b) 5-설프르이소프탈산 3 내지 10몰%; c) 1,4-시클로헥산디메탄올 70 내지 85몰% ; 및 이에 대응하여 d) 디에틸렌 클리콜 15 내지 30몰%.3. The film structure of claim 1, wherein the copolyester comprises a condensation product of monomers (or polyester forming equivalents thereof) of (a) to (d): a) isophthalic acid 90 To 97 mole%; And correspondingly b) 3 to 10 mol% of 5-sulfurisophthalic acid; c) 70 to 85 mol% of 1,4-cyclohexanedimethanol; And correspondingly d) 15 to 30 mole% diethylene glycol. 제1항 내지 제4항중 어느 한 창에 있어서, 상기 하도제 코팅이 산성화 및 아미노에틸화된 비닐 중합체와 에폭시 수지의 반응 생성물, 폴리(에틸렌이민), 또는 이들의 혼합물이 코팅을 포함하는 필름 구조물.5. The film structure of claim 1, wherein the primer coating comprises a reaction product of an acidified and aminoethylated vinyl polymer with an epoxy resin, poly (ethyleneimine), or a mixture thereof. . 제1항 내지 제5항중 어느 한 항에 있어서, 살기 필름 기재가 나일론, 폴리에틸렌 테레프탈레이트, 폴리카보네이트, 폴리에틸렌, 폴리프로필렌, 또는 이들중 둘 이상의 임의의 물질들의 공압출물 또는 라미네이트를 포함하는 필름 구조물.The film structure of claim 1, wherein the live film substrate comprises a coextruded or laminate of nylon, polyethylene terephthalate, polycarbonate, polyethylene, polypropylene, or any two or more of these materials. 제6항에 있어서, 상기 기재가 폴리에틸렌을 함유하는 동일 또는 상이한 스킨층을 포함하거나 포함하지 않는 폴리프로필렌; 에틸렌과 기타 올레핀의 공중합체; 프로필렌과 기타 올레핀의 공중합체; 올레핀의 삼중합체; 이들의 말레인산 무수물 개질된 중합체 또는 이들의 혼합물을 포함하는 필름 구조물.The method of claim 6, wherein the substrate comprises or is made of polypropylene with or without the same or different skin layer containing polyethylene; Copolymers of ethylene and other olefins; Copolymers of propylene and other olefins; Terpolymers of olefins; A film structure comprising maleic anhydride modified polymers thereof or mixtures thereof. 제6항 또는 제7항에 있어서, 상기 기재가 미량의 폴리에틸렌과 혼합된 폴리프로필렌; 에틸렌과 기타 올레핀의 공중합체; 프로필렌과 기타 올레핀의 공중합체; 올레핀의 삼중합체; 이들의 말레인산 무수물 개질된 중합체 또는 이들의 혼합물을 포함하는 필름 구조물.The method of claim 6 or 7, wherein the substrate is polypropylene mixed with trace amounts of polyethylene; Copolymers of ethylene and other olefins; Copolymers of propylene and other olefins; Terpolymers of olefins; A film structure comprising maleic anhydride modified polymers thereof or mixtures thereof. 제1항 내지 제8항중 어느 한 항에 있어서, 상기 코폴리에스테르 또는 잉크 베이스 함유 표면의 반대 표면상에 압감성 접착제를 갖는 필름 구조물.The film structure of claim 1, wherein the film structure has a pressure sensitive adhesive on an opposite surface of the copolyester or ink base containing surface. 인쇄 잉크와 접착적으로 비상용성인 표면을 하나 이상 가지며, 그 위에 코팅된 필름의 접촉층간에 파괴적 블로킹을 유발할 수 있는 유형의 하도제 코팅을 갖는 중합체성 필름 기재를 포함하는 인쇄 가능한 필름 구조물의 블로킹을 방지하는데 수-소산성 코폴리에스테르 코팅 또는 인쇄 잉크 베이스 코팅을 사용하는 방법.Blocking of a printable film structure comprising a polymeric film substrate having at least one surface that is adhesively incompatible with the printing ink and having a primer coating of the type that can cause disruptive blocking between the contact layers of the coated film thereon. Using a water-dispersible copolyester coating or a printing ink base coating to prevent it. ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950701509A 1992-10-20 1993-10-18 MULTILAYER FILM STRUCTURE KR950704122A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US963611 1978-11-24
US963610 1992-10-20
US07/963,611 US5380587A (en) 1992-10-20 1992-10-20 Multilayer film structure
US07/963,610 US5382473A (en) 1992-10-20 1992-10-20 Multilayer film structure
PCT/US1993/009935 WO1994008796A1 (en) 1992-10-20 1993-10-18 Multilayer film structure

Publications (1)

Publication Number Publication Date
KR950704122A true KR950704122A (en) 1995-11-17

Family

ID=27130454

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950701509A KR950704122A (en) 1992-10-20 1993-10-18 MULTILAYER FILM STRUCTURE

Country Status (11)

Country Link
EP (1) EP0665787B1 (en)
JP (1) JP3507496B2 (en)
KR (1) KR950704122A (en)
AT (1) ATE182845T1 (en)
AU (1) AU679701B2 (en)
CA (1) CA2146354C (en)
DE (1) DE69325914T2 (en)
ES (1) ES2134274T3 (en)
SG (1) SG89229A1 (en)
TR (1) TR28367A (en)
WO (1) WO1994008796A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0014397D0 (en) * 2000-06-13 2000-08-02 Avecia Ltd Process
JP5155103B2 (en) * 2008-11-05 2013-02-27 旭化成エレクトロニクス株式会社 Switched capacitor circuit and pipelined A / D converter

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3230175A (en) * 1963-04-01 1966-01-18 Du Pont Stabilized trichloroethylene and a process for treating metals therewith
US4214039A (en) * 1979-04-23 1980-07-22 Mobil Oil Corporation Polypropylene film with primer of a water dispersed epoxy resin coating
US4525419A (en) * 1983-05-16 1985-06-25 American Hoechst Corporation Copolyester primed plastic film
JPS62187092A (en) * 1986-02-13 1987-08-15 Mitsubishi Yuka Fine Chem Co Ltd Thermal transfer recording sheet
US5066434A (en) * 1988-06-16 1991-11-19 Mobil Oil Corporation Method of forming a multilayer heat sealable film
US5006598A (en) * 1990-04-24 1991-04-09 Eastman Kodak Company Water-dispersible polyesters imparting improved water resistance properties to inks
US5171625A (en) * 1991-01-31 1992-12-15 Ici Americas Inc. All polyester film composite useful for credit and identification cards
JPH05177775A (en) * 1992-01-06 1993-07-20 Yamato Esuron Kk Surface coating film

Also Published As

Publication number Publication date
DE69325914D1 (en) 1999-09-09
WO1994008796A1 (en) 1994-04-28
ES2134274T3 (en) 1999-10-01
ATE182845T1 (en) 1999-08-15
TR28367A (en) 1996-05-30
EP0665787B1 (en) 1999-08-04
DE69325914T2 (en) 1999-12-02
AU5363194A (en) 1994-05-09
JP3507496B2 (en) 2004-03-15
SG89229A1 (en) 2002-06-18
AU679701B2 (en) 1997-07-10
CA2146354C (en) 2004-07-06
CA2146354A1 (en) 1994-04-28
EP0665787A1 (en) 1995-08-09
JPH08505237A (en) 1996-06-04

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