KR950703280A - Herbicidal Benzene Compounds - Google Patents

Herbicidal Benzene Compounds Download PDF

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Publication number
KR950703280A
KR950703280A KR1019950700914A KR19950700914A KR950703280A KR 950703280 A KR950703280 A KR 950703280A KR 1019950700914 A KR1019950700914 A KR 1019950700914A KR 19950700914 A KR19950700914 A KR 19950700914A KR 950703280 A KR950703280 A KR 950703280A
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South Korea
Prior art keywords
alkyl
halogen
optionally substituted
och
sch
Prior art date
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KR1019950700914A
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Korean (ko)
Inventor
카누 마간브하이 파텔
Original Assignee
미리암 디.메코너헤이
이.아이.듀폰 디 네모아 앤드 캄파니
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Application filed by 미리암 디.메코너헤이, 이.아이.듀폰 디 네모아 앤드 캄파니 filed Critical 미리암 디.메코너헤이
Publication of KR950703280A publication Critical patent/KR950703280A/en

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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
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    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
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    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C07D213/64—One oxygen atom attached in position 2 or 6
    • C07D213/643—2-Phenoxypyridines; Derivatives thereof
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Abstract

본 발명은 바람직하지 못한 식물의 성장을 억제하기 위한 치환 벤젠 화합물 유효량을 포함하는 제초성 조성물 및 사용 방법에 관한 것이다.The present invention relates to herbicidal compositions and methods of use comprising an effective amount of a substituted benzene compound for inhibiting the growth of undesirable plants.

Description

제초성 벤젠 화합물(Herbicidal Benzene Compounds)Herbicidal Benzene Compounds

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (9)

유효량의 하기 일반식 Ⅰ또는 Ⅱ의 화합물 이들의 농학상 적합한 염과 계면활성체, 고체 또는 액체 회석계 중 1종 이상을 포함하는, 바람직하지 못한 식물의 성장 억제 조성물.An effective amount of the growth inhibitory composition of an undesirable plant, comprising an effective amount of a compound of the general formula (I) or (II) below, an agriculturally suitable salt thereof, and at least one of a surfactant, a solid or a liquid lime system. 상기 식 중, R1은 Cl, Br, , OCH3, OCHF3, OCF3또는 NO2이고, R2는 CN, CO2R4, CHO, C(X)NR17R16, C(S)OR6, C≡CH, CHR19OR20, CH=NOR7, CH=CR21R22, C(할로겐)=NOR7, C(NH2)=NOR7, C(CN)=NOR7, CHR19(할로겐), CHR19CN, CHR19C(=O)NH2, CHR19CO2H이거나, 또는 질소, 황 또는 산소중 1개 이상을 포함하고 CH3, CF3, OCH3,SCH3또는 할로겐 중 1개 이상으로 임의 치환된 5원 헤테로시클릭 고리이고, R3는 n-프로필 또는 C4-C7알킬 ; OR16, SR9, NR14R15, CO2(C1-C2알킬) 또는 페닐(여기서, 패닐은 CH3, CF3, OCH3, SCH3또는 할로겐중 1개 이상으로 임의 치환됨)로 치환된 C1-C2알킬 ; C3-C6시클로알킬 ; CH2(C3-C6시클로알킬) ; 각각 CH3, CF3,OCH3, SCH3또는 할로겐 중 1개 이상으로 임의 치환된 페닐, 피리딜, 티에닐, 푸릴, 피라졸릴 또는 티아졸릴 ; 할로겐 또는 CO2(C1-C2알킬)중 1개 이상으로 임의치환된 C2-C6알케닐 ; OR12;SR13;NR14R15;C(=X)R12;Wherein R 1 is Cl, Br,, OCH 3 , OCHF 3 , OCF 3 or NO 2 , and R 2 is CN, CO 2 R 4 , CHO, C (X) NR 17 R 16 , C (S) OR 6 , C≡CH, CHR 19 OR 20 , CH = NOR 7 , CH = CR 21 R 22 , C (halogen) = NOR 7 , C (NH 2 ) = NOR 7 , C (CN) = NOR 7 , CHR 19 (halogen), CHR 19 CN, CHR 19 C (= 0) NH 2, CHR 19 CO 2 H, or contain one or more of nitrogen, sulfur or oxygen, and include CH 3 , CF 3 , OCH 3, SCH 3 or A 5 membered heterocyclic ring optionally substituted with one or more of halogen, R 3 is n-propyl or C 4 -C 7 alkyl; OR 16 , SR 9 , NR 14 R 15 , CO 2 (C 1 -C 2 alkyl) or phenyl, wherein panyl is optionally substituted with one or more of CH 3 , CF 3 , OCH 3 , SCH 3 or halogen C 1 -C 2 alkyl substituted with; C 3 -C 6 cycloalkyl; CH 2 (C 3 -C 6 cycloalkyl); Phenyl, pyridyl, thienyl, furyl, pyrazolyl or thiazolyl optionally substituted with one or more of CH 3 , CF 3, OCH 3 , SCH 3 or halogen, respectively; C 2 -C 6 alkenyl optionally substituted with one or more of halogen or CO 2 (C 1 -C 2 alkyl); OR 12 ; SR 13 ; NR 14 R 15 ; C (= X) R 12 ; ;또는 O-N=R30R31이고, ; Or ON = R 30 R 31 , R4는 H, C1-C2 알킬,또는이고,R 4 is H, C1-C2 alkyl, or ego, R6, R7, R8, R8, R10및 R11은 각각 H 또는 C1-C2알킬이고, R12은 각각 할로겐, OR8, SR9, CO2R23, C(O)NR24R23, CN, Si(CH3)3, C(R26)(OR27)(OR28) 또는 NR10R11중 1개 이상으로 임의 치환된 C1-C10알킬 ; 1-2개의 질소, 1개의 산소 및 1개의 황으로부터 선택된 헤테르 원자를 1 내지 2개 함유하고 각 고리가 F, Cl, Br, CH3, CF3, COH, 및 CN으로부터 선택된 1 내지 2개의 치환체로 임의 치환된 5원 또는 6원 헤테로시클릭 고리로 치환된 C1-C3알킬 ; C3-C6알킬 ; C3-C6알케닐 ; 또는 각각 CH3, CF3, OCH3, OR29, SCH3또는 할로겐 중 1개 이상으로 임의 치환된 페닐 또는 벤질이고, R14및 R15는 각각 H 또는 C1-C2알킬이거나, 또는 함께 이들이 결합된 질소원자를 공유하여 CH3,CH3, OCH3SCH3또는 할로겐 중 1개 이상으로 임의 치환된 피롤릴, 피페리디닐, 모르폴리닐, 피라졸릴 또는 이미다졸릴 고리를 형성할 수 있고, R16은 H, C1-C8알킬 ; CH3, CF3, OCH3, SCH3또는 할로겐 중 1개 이상으로 임의 치환된 벤질 ; 또는 CH3, CF3, OCH3, SCH3또는 할로겐 중 1개 이상으로 임의 치환된 패닐이고, R17은 H, C1-C2알킬, 또는 CH3, CF3, OCH3, SCH3또는 할로겐 중 1개 이상으로 임의 치환된 패닐이고, R18은 H, C1-C2알킬, C3-C6시클로알킬, CH2(C3-C6시클로알킬), O(C1-C4알킬), O-알릴이거나, 또는 R17과 함께 -(CH2)4-, -(CH2)5- 또는 -(CH2CH2OCH2CH2)-일 수 있고, R19는 H 또는 C1-C2알킬이고, R20은 H 또는 C(O)CH3이고, R21및 R19는 H 도는 C1-C2알킬이고, R20은 H 또는 C(O)CH3이고, R21및 R22는 각각 H, CN, CO2R4, C(X)NR17R18또는 할로겐이고, R23, R24, R25페닐이고, R27및 R28은 각각 C1-C3알킬이거나, 또는 1내지 2개의 CH3로 임의 치환된 -(CH2)2- 또는 -(CH2)3-일 수 있고, X는 0또는 S이고, R29는 각각 CH3, CF3, OCH3, SCH3또는 할로겐 중 1개 이상으로 임의 치환된 패닐, 피리딜, 티아졸릴, 피라졸릴 또는 피톨릴이고, R30및 R31은 각각 H, C1-C10알킬 ; 또는 CH3, CF3, OCH3, SCH3또는 할로겐 중 1개 이상으로 임의 치환된 패닐이다.R 6 , R 7 , R 8 , R 8 , R 10 and R 11 are each H or C 1 -C 2 alkyl and R 12 is halogen, OR 8 , SR 9 , CO 2 R 23 , C (O) C 1 -C 10 alkyl optionally substituted with one or more of NR 24 R 23 , CN, Si (CH 3 ) 3 , C (R 26 ) (OR 27 ) (OR 28 ) or NR 10 R 11 ; 1 to 2 heteroatoms selected from 1-2 nitrogen, 1 oxygen and 1 sulfur, each ring having 1 to 2 selected from F, Cl, Br, CH 3 , CF 3 , COH, and CN C 1 -C 3 alkyl substituted with a 5- or 6-membered heterocyclic ring optionally substituted with a substituent; C 3 -C 6 alkyl; C 3 -C 6 alkenyl; Or phenyl or benzyl, each optionally substituted with one or more of CH 3 , CF 3 , OCH 3 , OR 29 , SCH 3 or halogen, and R 14 and R 15 are each H or C 1 -C 2 alkyl, or together They may share a bound nitrogen atom to form a pyrrolyl, piperidinyl, morpholinyl, pyrazolyl or imidazolyl ring optionally substituted with one or more of CH 3, CH 3 , OCH 3 SCH 3 or halogen R 16 is H, C 1 -C 8 alkyl; Benzyl optionally substituted with one or more of CH 3 , CF 3 , OCH 3 , SCH 3 or halogen; Or panyl optionally substituted with one or more of CH 3 , CF 3 , OCH 3 , SCH 3 or halogen, R 17 is H, C 1 -C 2 alkyl, or CH 3 , CF 3 , OCH 3 , SCH 3 or Panyl optionally substituted with one or more of halogen, R 18 is H, C 1 -C 2 alkyl, C 3 -C 6 cycloalkyl, CH 2 (C 3 -C 6 cycloalkyl), O (C 1 -C 4 alkyl), O-, or allyl, or together with R 17 - (CH 2) 4 -, - (CH 2) 5 - or - (CH 2 CH 2 OCH 2 CH 2) - may be, R 19 is H Or C 1 -C 2 alkyl, R 20 is H or C (O) CH 3 , R 21 and R 19 are H or C 1 -C 2 alkyl, and R 20 is H or C (O) CH 3 , R 21 and R 22 are H, CN, CO 2 R 4 , C (X) NR 17 R 18 or halogen, R 23 , R 24 , R 25 phenyl, and R 27 and R 28 are each C 1- C 3 alkyl, or — (CH 2 ) 2 — or — (CH 2 ) 3 — optionally substituted with 1 to 2 CH 3 , X is 0 or S, and R 29 is each CH 3 , CF At least one of 3 , OCH 3 , SCH 3 or halogen Substituted phenyl, pyridyl, thiazolyl, pyrazolyl or phytolyl, and R 30 and R 31 are each H, C 1 -C 10 alkyl; Or panyl optionally substituted with one or more of CH 3 , CF 3 , OCH 3 , SCH 3 or halogen. 제1항에 있어서, R1이 Cl, Br 또는 I이고, R2가 CN, CO2H, CO2CH3, C02CH2CH3, CHO, C(O)NH2,- C(O)NHCH3, C(O)N(CH3)2, CH2OH 또는 CH=NOR7이고, R3이 n-프로필 ; C4-C7알킬 ; CH3, CF3, OCH3, SCH3또는 할로겐 중 1개 이상으로 임의 치환된 패닐로 치환된 C2알킬 ; CH2(C3-C6시클로알킬) ; CH3, CF3, OCH3, SCH3또는 할로겐 중 1개 이상으로 임의 치환된 페닐 ; 또는 OR12이고, R12가 C2-C4알킬인 것인 조성물.The compound of claim 1, wherein R 1 is Cl, Br or I, and R 2 is CN, CO 2 H, CO 2 CH 3 , CO 2 CH 2 CH 3 , CHO, C (O) NH 2 , —C (O ) NHCH 3 , C (O) N (CH 3 ) 2 , CH 2 OH or CH = NOR 7 , R 3 is n-propyl; C 4 -C 7 alkyl; C 2 alkyl substituted with phenyl optionally substituted with one or more of CH 3 , CF 3 , OCH 3 , SCH 3 or halogen; CH 2 (C 3 -C 6 cycloalkyl); Phenyl optionally substituted with one or more of CH 3 , CF 3 , OCH 3 , SCH 3 or halogen; Or OR 12 and R 12 is C 2 -C 4 alkyl. 제2항에 있어서, R1이 Cl 또는 Br이고, R22CN, CO2H 또는 C(O)NH2이고, R3이 C4-C7알킬, CH2(C3-C6시클로알킬) 또는 OR12인 것인 조성물The compound of claim 2, wherein R 1 is Cl or Br, R 2 2 CN, CO 2 H or C (O) NH 2 , and R 3 is C 4 -C 7 alkyl, CH 2 (C 3 -C 6 cycloalkyl ) Or OR 12 제1항에 있어서, 화합물이 2-클로로-4-(2-메틸프로폭시)벤즈아미드인 것인 조성물The composition of claim 1 wherein the compound is 2-chloro-4- (2-methylpropoxy) benzamide 제1항 기재의 조성물 유효량을 보호되어야 할 장소에 사용하는 것을 포함하는, 바람직하지 못한 식물의 성장 억제 방법.A method of inhibiting undesirable plant growth, comprising using an effective amount of the composition of claim 1 in a place to be protected. 제2항 기재의 소정물 유효량을 보호되어야 할 장소에 사용하는 것을 포함하는 , 바람직하지 못한 식물의 성장 억제 방법.A method for inhibiting growth of undesirable plants, comprising using an effective amount of a substance according to claim 2 in a place to be protected. 제3항 기재의 소정물 유효량을 보호되어야 할 장소에 사용하는 것을 포함하는 , 바람직하지 못한 식물의 성장 억제 방법.A method for inhibiting undesirable plant growth, comprising using an effective amount of the substance according to claim 3 in a place to be protected. 제4항 기재의 소정물 유효량을 보호되어야 할 장소에 사용하는 것을 포함하는 , 바람직하지 못한 식물의 성장 억제 방법.A method for inhibiting growth of undesirable plants, comprising using an effective amount of the substance according to claim 4 in a place to be protected. 제4항 기재의 소정물 유효량을 보호되어야 할 장소에 사용하는 것을 포함하는 , 바람직하지 못한 식물의 성장 억제 방법.A method for inhibiting growth of undesirable plants, comprising using an effective amount of the substance according to claim 4 in a place to be protected. ※ 참고사항: 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the original application.
KR1019950700914A 1992-09-09 1993-09-02 Herbicidal Benzene Compounds KR950703280A (en)

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