KR950029375A - Polymer Compound Compositions and Methods for Surface Treatment of Aluminum-Containing Metallic Materials - Google Patents

Polymer Compound Compositions and Methods for Surface Treatment of Aluminum-Containing Metallic Materials Download PDF

Info

Publication number
KR950029375A
KR950029375A KR1019950008908A KR19950008908A KR950029375A KR 950029375 A KR950029375 A KR 950029375A KR 1019950008908 A KR1019950008908 A KR 1019950008908A KR 19950008908 A KR19950008908 A KR 19950008908A KR 950029375 A KR950029375 A KR 950029375A
Authority
KR
South Korea
Prior art keywords
group
polymer compound
water
soluble polymer
carbon atoms
Prior art date
Application number
KR1019950008908A
Other languages
Korean (ko)
Other versions
KR0179685B1 (en
Inventor
마사유키 요시다
아오키도모유키
Original Assignee
사토미 유타카
니혼 파커라이징 가부시키가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 사토미 유타카, 니혼 파커라이징 가부시키가이샤 filed Critical 사토미 유타카
Publication of KR950029375A publication Critical patent/KR950029375A/en
Application granted granted Critical
Publication of KR0179685B1 publication Critical patent/KR0179685B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/23—Condensed phosphates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

A surface of aluminiferous metal is brought into contact at 30 DEG C to 65 DEG C for 5 to 60 seconds with a surface treatment bath with a pH of 2.0 to 6.5 that contains phosphate ion, condensed phosphate ion, and a water soluble polymer in the following weight proportions: 1 - 30 : 0.1 - 10 : 0.2 - 20. This is followed by a water rinse and drying by heating. The water soluble polymer has a chemical structure conforming with formula (I), in which (i) each of X<1> and X<2> represents a hydrogen atom, a C1 to C5 alkyl group, or a C1 to C5 hydroxyalkyl group; (ii) each of Y<1> and Y<2> represents a hydrogen atom or a moiety "Z" that conforms to formula (II) or (III), wherein each of R<1>, R<2>, R<3>, R<4>, and R<5> represents a C1 to C10 alkyl group or a C1 to C10 hydroxyalkyl group; (iii) the average value for the number of Z moieties substituted on each phenyl ring in the polymer molecule is from 0.2 to 1.0; (iv) n is an integer with a value from 2 to 50; and (v) each polymer molecule contains at least one Z moiety.

Description

알루미늄 함유 금속재료를 표면처리하기 위한 중합체 화합물 조성물 및 방법Polymer Compound Compositions and Methods for Surface Treatment of Aluminum-Containing Metallic Materials

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (7)

성분으로서 (a) 인산이온, (b) 축합인산이온, 및 (c)다음 식(I)의 다수의 중합 단위:As components, (a) phosphate ions, (b) condensed phosphate ions, and (c) a plurality of polymerized units of formula (I): 〔상기식에서 X1및 X2는 각각 상호 독립적으로 수소원자, 1내지 5개의 탄소원자를 갖는 알킬기 및 1 내지 5개의 탄소원자를 갖는 히드록시알킬기로 구성된 군으로 부터 선택되는 일원을 나타내며: Y1및 Y2는 각각 상호 독립적으로 수소원자 및 다음식(Ⅱ) 및 (Ⅲ)으로 표시되는 치환기 Z로 구성된 군으로부터 선택되는 일원을 나타내며 :[Wherein X 1 and X 2 each independently represent a member selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 5 carbon atoms and a hydroxyalkyl group having 1 to 5 carbon atoms: Y 1 and Y 2 each independently represents a member selected from the group consisting of a hydrogen atom and a substituent Z represented by the following formulas (II) and (III): (식중에서 R1, R2, R3, R4및 R5는 각각 상호 독립적으로 1 내지 10개의 탄소원자를 갖는 알킬기 및 1 내지 10개의 탄소원자를 갖는 히드록시알킬기로 구성된 군으로부터 선택되는 일원을 나타낸다), 중합 단위의 각 벤젠고리에 결합된 치환기 Z는 상호 동일하거나 상이할 수 있으며, 중합 단위의 각 벤젠고리에 결합된 치환기 Z의 수평균치는 0.2 내지 1.0이다〕로 이루어지는 적어도 하나의 수용성 중합체 화합물을 함유하며, 수용성 중합체 화합물(c)은 평균 중합도가 2 내지 50이며, 인산이온(a), 축합인산이온(b) 및 수용성 중합체 화합물 (c)는 혼합 중량비 (a) : (b) : (c)가 1 내지 30 : 0.1 내지 10 : 0.1 내지 20으로 존재하는 것을 특징으로 하는 알루미늄 함유 금속 재료를 표면처리하기 위한 수성 조성물.Wherein R 1 , R 2 , R 3 , R 4 and R 5 each independently represent a member selected from the group consisting of alkyl groups having 1 to 10 carbon atoms and hydroxyalkyl groups having 1 to 10 carbon atoms At least one water-soluble polymer compound comprising The water-soluble polymer compound (c) has an average degree of polymerization of 2 to 50, and the phosphate ions (a), the condensed phosphate ions (b) and the water-soluble polymer compound (c) have a mixed weight ratio (a): (b): ( c) is 1 to 30: 0.1 to 10: 0.1 to 20, the aqueous composition for surface treatment of the aluminum-containing metal material. 제1항에 있어서, 인산이온은 인산, 인산 알칼리 금속 및 인산 암모늄으로 구성된 군으로부터 선택되는 적어도 하나의 일원으로부터 유도되는 것을 특징으로 하는 수성 조성물.The aqueous composition of claim 1 wherein the phosphate ion is derived from at least one member selected from the group consisting of phosphoric acid, alkali metal phosphates and ammonium phosphate. 제1항에 있어서, 축합인산이온은 피로인산, 트리폴리인산, 테트라폴리인산 및 상기 산의 알칼리 금속 및 암모늄 염으로 구성된 군으로부터 선택되는 적어도 하나의 일원으로부터 유도되는 것을 특징으로 하는 수성 조성물.The aqueous composition of claim 1 wherein the condensed phosphate ion is derived from at least one member selected from the group consisting of pyrophosphoric acid, tripolyphosphoric acid, tetrapolyphosphoric acid and alkali metal and ammonium salts of the acid. (A)성분으로서 (a)인산이온 (b)축합인산이온, 및 (c)적어도 하나의 수용성 중합체 화합물을 포함하는, pH가 6.5이하인 표면처리 수용액을 30℃ 내지 65℃의 온도에서 5 내지 60초의 전체 접촉시간동안 알루미늄 함유 금속재료의 표면에 접촉시키는 단계, 상기 수용성 중합체 화합물은(c)은 식(I)의 다수의 중합 단위:(A) A surface-treated aqueous solution having a pH of 6.5 or less comprising (a) phosphate ions (b) condensed phosphate ions, and (c) at least one water-soluble polymer compound at a temperature of 30 to 65 ° C, 5 to 60 Contacting the surface of the aluminum-containing metal material for a total contact time of seconds, wherein the water-soluble polymer compound (c) comprises a plurality of polymerized units of formula (I): 〔상기식에서 X1및 X2는 각각 상호 독립적으로 수소원자, 1내지 5개의 탄소원자를 갖는 알킬기 및 1 내지 5개의 탄소원자를 갖는 히드록시알킬기로 구성된 군으로 부터 선택되는 일원을 나타내며: Y1및 Y2는 각각 상호 독립적으로 수소원자 및 다음식 (Ⅱ) 및 (Ⅲ)으로 표시되는 치환기 Z로 구성된 군으로부터 선택되는 일원을 나타내며:[Wherein X 1 and X 2 each independently represent a member selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 5 carbon atoms and a hydroxyalkyl group having 1 to 5 carbon atoms: Y 1 and Y 2 each independently represents a member selected from the group consisting of a hydrogen atom and a substituent Z represented by the following formulas (II) and (III): (식중에서 R1, R2, R3, R4및 R5는 각각 상호 독립적으로 1 내지 10개의 탄소원자를 갖는 알킬기 및 1 내지 10개의 탄소원자를 갖는 히드록시알킬기로 구성된 군으로부터 선택되는 일원을 나타낸다), 중합 단위의 각 벤젠고리에 결합된 치환기 Z는 상호 동일하거나 상이할 수 있으며, 중합 단위의 각 벤젠고리에 결합된 치환기 Z의 수평균치는 0.2 내지 1.0이다〕로 이루어지는 적어도 하나의 수용성 중합체 화합물을 함유하며, 수용성 중합체 화합물(c)은 평균 중합도가 2 내지 50이며, 인산이온(a), 축합인산이온(b) 및 수용성 중합체 화합물 (c)는 혼합 중량비 (a) : (b) : (c)가 1 내지 30 : 0.1 내지 10 : 0.1 내지 20으로 존재하며, (B)알루미늄 함유 금속재료표면상의 생성된 수지 피막층을 물로 세척하는 단계; 및 (C)세척된 수지 피막층을 가열 건조시키는 단계로 구성되는 것을 특징으로 하는 알루미늄금속재료를 표면처리하기 위한 방법.Wherein R 1 , R 2 , R 3 , R 4 and R 5 each independently represent a member selected from the group consisting of alkyl groups having 1 to 10 carbon atoms and hydroxyalkyl groups having 1 to 10 carbon atoms At least one water-soluble polymer compound comprising The water-soluble polymer compound (c) has an average degree of polymerization of 2 to 50, and the phosphate ions (a), the condensed phosphate ions (b) and the water-soluble polymer compound (c) have a mixed weight ratio (a): (b): ( c) is 1 to 30: 0.1 to 10: 0.1 to 20, and (B) washing the resulting resin film layer on the surface of the aluminum-containing metal material with water; And (C) heating and drying the washed resin film layer. 제4항에 있어서, 표면처리액은 인산이온(a) 1 내지 30ｇ/리터, 출합인산이온 0.1 내지 10ｇ/리터 및 수용성 중합체 화합물(c) 0.1 내지 20ｇ/리터를 함유하며, pH가 2.0 내지 6.5인 것을 특징으로 하는 방법.The surface treatment liquid according to claim 4, wherein the surface treatment liquid contains 1 to 30 g / liter of phosphate ion (a), 0.1 to 10 g / liter of extracted phosphate ion and 0.1 to 20 g / liter of water-soluble polymer compound (c), and has a pH of 2.0 to 6.5. Method characterized in that. 제4항에 있어서, 알루미늄 함유 금속재료를 표면처리액에 5내지 60초동안 침지하는 것을 특징으로 하는 방법.The method according to claim 4, wherein the aluminum-containing metal material is immersed in the surface treatment liquid for 5 to 60 seconds. 제4항에 있어서, 표면처리액을 2내지 5초의 간격으로, 둘 이상의 단계로 분무시간과 간격시간을 합쳐서 5 내지 60초동안 알루미늄 함유 금속재료표면에 분무하는 것을 특징으로 하는 방법.The method according to claim 4, wherein the surface treatment liquid is sprayed on the surface of the aluminum-containing metal material for 5 to 60 seconds at intervals of 2 to 5 seconds, in combination with the spraying time and the interval time in two or more steps. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950008908A 1994-04-15 1995-04-15 Surface treating composition for metallic material containing aluminum and surface treatment KR0179685B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP94-077219 1994-04-15
JP6077219A JP2771110B2 (en) 1994-04-15 1994-04-15 Surface treatment composition for aluminum-containing metal material and surface treatment method

Publications (2)

Publication Number Publication Date
KR950029375A true KR950029375A (en) 1995-11-22
KR0179685B1 KR0179685B1 (en) 1999-02-18

Family

ID=13627747

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950008908A KR0179685B1 (en) 1994-04-15 1995-04-15 Surface treating composition for metallic material containing aluminum and surface treatment

Country Status (13)

Country Link
EP (1) EP0757725B1 (en)
JP (1) JP2771110B2 (en)
KR (1) KR0179685B1 (en)
CN (1) CN1092246C (en)
AT (1) ATE184331T1 (en)
BR (1) BR9507365A (en)
CA (1) CA2187795A1 (en)
DE (1) DE69512049T2 (en)
ES (1) ES2136844T3 (en)
MY (1) MY113052A (en)
TW (1) TW404975B (en)
WO (1) WO1995028509A1 (en)
ZA (1) ZA953031B (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997003226A1 (en) * 1995-07-10 1997-01-30 Nippon Paint Co., Ltd. Metal surface treatments, method for treating metal surface, and surface-treated metallic material
JP3620893B2 (en) * 1995-07-21 2005-02-16 日本パーカライジング株式会社 Surface treatment composition for aluminum-containing metal and surface treatment method
US6059896A (en) * 1995-07-21 2000-05-09 Henkel Corporation Composition and process for treating the surface of aluminiferous metals
JP3544761B2 (en) * 1995-10-13 2004-07-21 日本パーカライジング株式会社 Surface treatment composition for aluminum-containing metal material and surface treatment method
DE19621184A1 (en) * 1996-05-28 1997-12-04 Henkel Kgaa Zinc phosphating with integrated post-passivation
JPH101782A (en) * 1996-06-13 1998-01-06 Nippon Paint Co Ltd Metallic surface treating agent, treatment and surface treated metallic material
JPH1046101A (en) * 1996-08-01 1998-02-17 Nippon Parkerizing Co Ltd Coated metallic material prepared by forming undercoat for film lamination on the surface of metallic material and its production
JPH10182916A (en) * 1996-10-21 1998-07-07 Nippon Paint Co Ltd Metal surface-treating composition containing acrylic resin and containing n-heterocycle, treatment by using the same and treated metal material
FR2769325B1 (en) * 1997-10-08 1999-12-03 Cfpi Ind ACID BATH FOR ZINC PHOSPHATATION OF METAL SUBSTRATES, CONCENTRATE FOR THE PREPARATION OF THE BATH AND PHOSPHATATION METHOD USING THE SAME
JPWO2002061175A1 (en) * 2001-01-31 2004-06-03 日本パーカライジング株式会社 Surface treatment agent for metal material and surface treatment method
JP2004076024A (en) * 2002-08-09 2004-03-11 Nippon Paint Co Ltd Aluminum base material treatment method and product
JP2010013677A (en) 2008-07-01 2010-01-21 Nippon Parkerizing Co Ltd Chemical conversion liquid for metal structure and surface treatment method
CN102983419A (en) * 2011-09-07 2013-03-20 崔骥 Grounding device and grounding method
CN106591817B (en) * 2016-11-08 2019-01-29 高林 Heavy metal free object discharges treating liquid for surface of iron or steel and preparation method thereof
WO2019074068A1 (en) * 2017-10-12 2019-04-18 日本パーカライジング株式会社 Surface treatment agent, method for producing aluminum alloy material for cans, said aluminum alloy material having surface-treated coating film, and aluminum alloy can body and can lid using same

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4433015A (en) * 1982-04-07 1984-02-21 Parker Chemical Company Treatment of metal with derivative of poly-4-vinylphenol
US4795506A (en) * 1986-07-26 1989-01-03 Detrex Corporation Process for after-treatment of metals using 2,2-bis(4-hydroxyphenyl)alkyl poly derivatives
JPH03207766A (en) * 1990-01-10 1991-09-11 Nippon Parkerizing Co Ltd Surface treatment of tin di can
AU647498B2 (en) * 1990-06-19 1994-03-24 Henkel Corporation Liquid composition and process for treating aluminium or tin cans to impart corrosion resistance and reduced friction coefficient
JPH04187782A (en) * 1990-11-21 1992-07-06 Nippon Parkerizing Co Ltd Surface treating solution for di can made of tin plate

Also Published As

Publication number Publication date
CN1112166A (en) 1995-11-22
DE69512049T2 (en) 2000-04-27
WO1995028509A1 (en) 1995-10-26
EP0757725A4 (en) 1997-07-30
EP0757725B1 (en) 1999-09-08
KR0179685B1 (en) 1999-02-18
CA2187795A1 (en) 1995-10-26
AU685938B2 (en) 1998-01-29
EP0757725A1 (en) 1997-02-12
JPH07278836A (en) 1995-10-24
ES2136844T3 (en) 1999-12-01
ATE184331T1 (en) 1999-09-15
DE69512049D1 (en) 1999-10-14
ZA953031B (en) 1995-12-21
AU2232995A (en) 1995-11-10
TW404975B (en) 2000-09-11
MY113052A (en) 2001-11-30
CN1092246C (en) 2002-10-09
BR9507365A (en) 1997-10-07
JP2771110B2 (en) 1998-07-02

Similar Documents

Publication Publication Date Title
KR950029375A (en) Polymer Compound Compositions and Methods for Surface Treatment of Aluminum-Containing Metallic Materials
US4992116A (en) Method and composition for coating aluminum
US4433015A (en) Treatment of metal with derivative of poly-4-vinylphenol
JP2768556B2 (en) Non-chromic passivation of metal substrates
US5125989A (en) Method and composition for coating aluminum
DE69620767D1 (en) COMPOSITION AND METHOD FOR TREATING ALIMINUM METAL SURFACES
US4795506A (en) Process for after-treatment of metals using 2,2-bis(4-hydroxyphenyl)alkyl poly derivatives
US4714752A (en) 2,2-bis (4 hydroxyphenyl) alkyl poly derivatives for use in after-treatment of conversion coated metals
US4000012A (en) Anticorrosive coating of steel
AU653566B2 (en) Composition and method for treating tin plated steel surface
US3136663A (en) Compositions and methods for preservation of metals
KR970021375A (en) Polymer Compound Compositions and Methods for Surface Treatment of Aluminum-Containing Metallic Materials
US3723162A (en) Pretreatment of metal surfaces
US4917737A (en) Sealing composition and method for iron and zinc phosphating process
US5039362A (en) Titanium free composition and process for activating metal surfaces prior to zinc phosphating
CA2085489A1 (en) Liquid composition and process for treating aluminum or tin cans to impart corrosion resistance and mobility thereto
US3400023A (en) Composition for preservation of metals, process and article
US5733386A (en) Polymer composition and method for treating metal surfaces
JP2994428B2 (en) Composition for treating phosphate film and treatment method
MX9604750A (en) Composition and process for treating the surface of aluminiferous metals.
IL33267A (en) Method and compositions for inhibiting scale in saline water evaporators
TH13325A (en)
TH10943B (en)

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20061020

Year of fee payment: 9

LAPS Lapse due to unpaid annual fee