KR950018921A - Fiber treatment composition and preparation method thereof - Google Patents

Fiber treatment composition and preparation method thereof Download PDF

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KR950018921A
KR950018921A KR1019940038543A KR19940038543A KR950018921A KR 950018921 A KR950018921 A KR 950018921A KR 1019940038543 A KR1019940038543 A KR 1019940038543A KR 19940038543 A KR19940038543 A KR 19940038543A KR 950018921 A KR950018921 A KR 950018921A
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group
composition
acetate
ptcl
silane
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KR1019940038543A
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Korean (ko)
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알랜 코잘 제프리
리바이스 안토니
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노만 에드워드 루이스
다우 코닝 코포레이션
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Publication of KR950018921A publication Critical patent/KR950018921A/en

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/657—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2938—Coating on discrete and individual rods, strands or filaments
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/294—Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
    • Y10T428/2958—Metal or metal compound in coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2962—Silane, silicone or siloxane in coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2965—Cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2967—Synthetic resin or polymer
    • Y10T428/2969—Polyamide, polyimide or polyester

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Silicon Polymers (AREA)

Abstract

본 발명은 알릴 에스테르, 비닐 에스테르 또는 불포화 아세테이트, 오가노하이드로겐실록산, 금속촉매 및 하나 이상의 계면활성제와 하나 이상의 용매로 이루어진 그룹 중에서 선택된 분산제를 포함하는 섬유 처리용 조성물에 관한 것이다.The present invention relates to a fiber treatment composition comprising allyl ester, vinyl ester or unsaturated acetate, organohydrogensiloxane, metal catalyst and a dispersant selected from the group consisting of one or more surfactants and one or more solvents.

본 발명의 조성물은 섬유 및 직물과 같은 기재에 윤택성, 유연성, 내압성 및 방수성과 같은 유리한 특성을 부여한다.The compositions of the present invention impart advantageous properties such as moisture, flexibility, pressure resistance and water resistance to substrates such as fibers and fabrics.

Description

섬유 처리용 조성물 및 이의 제조방법Fiber treatment composition and preparation method thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (9)

(A) 알릴 에스테르, 비닐 에스테르 또는 불포화 아세테이트; (B) 하나 이상의 오가노하이드로겐실록산; (C) Ⅷ족 금속 촉매; 및 (D) 계면활성제 및 용매로 이루어진 그룹으로부터 선택된 분산제를 포함하는 섬유 처리용 조성물.(A) allyl ester, vinyl ester or unsaturated acetate; (B) one or more organohydrogensiloxanes; (C) a Group VIII metal catalyst; And (D) a dispersant selected from the group consisting of surfactants and solvents. 제1항에 있어서, (A)가 알릴 아세테이트, 린알릴 아세테이트 및 이소프로페닐 아세테이트로 이루어진 그룹 중에서 선택되는 조성물.The composition of claim 1 wherein (A) is selected from the group consisting of allyl acetate, linallyl acetate, and isopropenyl acetate. 제1항에 있어서, (B)가 비스(트리메틸실록시)디메틸 디하이드로겐디실록산, 디페닐디메틸디실록산, 디페닐테트라키스(디메틸실록시)디실록산, 헵타메틸하이드로겐트리실록산, 헥사메틸디하이드로겐트리실록산, 메틸하이드로겐사이클로실록산, 메틸트리스(디메틸하이드로센실록시)실란, 펜타메틸펜타 하이드로겐사이클로펜타실록산, 펜타메틸하이드로겐디실록산, 페닐트리스(디메틸하이드로겐실록시)실란, 폴리메틸하이드로겐실록산, 테트라키스(디메틸하이드로겐실록시)실란, 테트라메틸테트라하이드로겐사이클로테트라실록산, 테트라메틸디하이드로겐디실록산 및 메틸하이드로겐디메틸실록산 공중합체로 이루어진 그룹중에서 선택되는 조성물.The method of claim 1, wherein (B) is bis (trimethylsiloxy) dimethyl dihydrogendisiloxane, diphenyldimethyldisiloxane, diphenyltetrakis (dimethylsiloxy) disiloxane, heptamethylhydrogentrisiloxane, hexamethyldi Hydrogentrisiloxane, Methylhydrogencyclosiloxane, Methyltris (dimethylhydrosensiloxy) silane, Pentamethylpenta Hydrogencyclopentasiloxane, Pentamethylhydrogendisiloxane, Phenyltris (dimethylhydrogensiloxy) silane, Polymethyl A composition selected from the group consisting of hydrogensiloxane, tetrakis (dimethylhydrogensiloxy) silane, tetramethyltetrahydrocyclocyclotetrasiloxane, tetramethyldihydrogendisiloxane and methylhydrogendimethylsiloxane copolymer. 제1항에 있어서, (C)가 RhCl3,ClRh(PPh3)3,H2PtCl6,1,3-디비닐 테트라메틸 디실록산과 H2PtCl6의 착물 및 H2PtCl6의 알킨 착물로 이루어는 그룹중에서 선택되는 조성물.The complex of claim 1, wherein (C) is a complex of RhCl 3 , ClRh (PPh 3 ) 3 , H 2 PtCl 6 , 1,3-divinyl tetramethyl disiloxane with H 2 PtCl 6 and an alkyne complex of H 2 PtCl 6 . The composition is selected from the group consisting of. 제1항에 있어서, (C)가 미소캡슐화된 경화 촉매인 조성물.The composition of claim 1 wherein (C) is a microencapsulated curing catalyst. 제1항에 있어서, (D)가 폴리옥시에틸렌 알킬 에테르, 폴리옥시에틸렌 알킬페놀 에테르, 폴리옥시에틸렌 알킬 에스테르, 폴리옥시에틸렌 소르비탄 알킬 에스테르, 폴리에틸렌글리콜, 폴리프로필렌 글리콜, 폴리옥시알킬렌 글리콜 개질된 폴리실록산, 알킬트리메틸암모늄 하이드록사이드, 디알킬디메틸암모늄 하이드록사이드, 메틸폴리옥시에틸렌 코코암모늄 클로라이드 및 디팔미틸 하이드록시에틸암모늄 메토설페이트, 노닐페닐 및 옥틸 페놀의 폴리에톡시에테르, 폴리에틸렌 글리콜의 트리메틸놀에테르, 알콜 및 지방산의 모노에스테르, 에톡시화 아민, 메틸렌 클로라이드 및 아세토니트릴로 이루어진 그룹중에서 선택되는 조성물.The polyoxyethylene alkyl ether, polyoxyethylene alkylphenol ether, polyoxyethylene alkyl ester, polyoxyethylene sorbitan alkyl ester, polyethylene glycol, polypropylene glycol, polyoxyalkylene glycol modified according to claim 1 Polysiloxane, alkyltrimethylammonium hydroxide, dialkyldimethylammonium hydroxide, methylpolyoxyethylene cocoammonium chloride and dipalmityl hydroxyethylammonium methosulfate, polyethoxyether of nonylphenyl and octyl phenol, polyethylene glycol A composition selected from the group consisting of trimethylol ethers, monoesters of alcohols and fatty acids, ethoxylated amines, methylene chloride and acetonitrile. 제1항에 있어서, (D)가 메틸렌 클로라이드, 아세토니트릴, 톨루엔, 크실렌, 백색 주정 및 염소화 탄화수소로 이루어진 그룹 중에서 선택되는 조성물.The composition of claim 1 wherein (D) is selected from the group consisting of methylene chloride, acetonitrile, toluene, xylene, white spirits and chlorinated hydrocarbons. (Ⅰ) 제1항에 따르는 섬유 처리용 조성물을 제조하는 단계;(Ⅱ) 단계(Ⅰ)로부터의 조성물을 기재에 적용시키는 단계; 및 (Ⅲ) 이러한 기재를 가열하는 단계들을 포함하여, 기재를 처리하는 방법.(I) preparing a fiber treating composition according to claim 1; (II) applying the composition from step (I) to a substrate; And (III) heating the substrate. 방직 섬유 또는 직물로 이루어진 그룹 중에서 선택된, 제8항의 방법에 의해 처리되는 기재.A substrate treated by the method of claim 8 selected from the group consisting of textile fibers or fabrics. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940038543A 1993-12-30 1994-12-29 Fiber treatment composition and preparation method thereof KR950018921A (en)

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US08/176,557 US5413724A (en) 1993-12-30 1993-12-30 Fiber treatment compositions and methods for the preparation thereof
US08/176557 1993-12-30

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US5514418A (en) 1996-05-07
EP0661400A1 (en) 1995-07-05
US5413724A (en) 1995-05-09
TW305895B (en) 1997-05-21
US5665471A (en) 1997-09-09
JPH07252775A (en) 1995-10-03

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