KR950014170A - Process for producing epoxy resin with high impregnation and high compatibility - Google Patents

Process for producing epoxy resin with high impregnation and high compatibility Download PDF

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Publication number
KR950014170A
KR950014170A KR1019930024604A KR930024604A KR950014170A KR 950014170 A KR950014170 A KR 950014170A KR 1019930024604 A KR1019930024604 A KR 1019930024604A KR 930024604 A KR930024604 A KR 930024604A KR 950014170 A KR950014170 A KR 950014170A
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KR
South Korea
Prior art keywords
epoxy resin
glycidyl
epoxy
impregnation
compatibility
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KR1019930024604A
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Korean (ko)
Inventor
김종생
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최규원
금호쉘화학 주식회사
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Priority to KR1019930024604A priority Critical patent/KR950014170A/en
Publication of KR950014170A publication Critical patent/KR950014170A/en

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Abstract

본 발명은 에피할로히드린과 반응성을 갖는 활성 수소를 함유하는 방향족 화합물과의 반응으로 생성된 글리시딜 유도체를 변체하여 안료에 대한 고함침성과 용제에 대한 고상용성을 갖는 글리시딜 에테르계 에폭시수지를 제조하는 방법에 관한 것이다. 변체의 방법은 일정 당량의 글리시딜 유도체에 당량이 다른 글리시딜 유도체를 일정량 가하여 분자량 분포도를 조정하고, 다시 아민류와 에스테르계의 복합 화합물 또는 그 염을 일정량 가하여 기존의 글리시딜 유도체와의 전혀 새로운 에폭시 수지를 제공하는 것이다. 기존의 글리시딜 유도체를 다운 스트림 분야에 응용시, 주 원료로 사용되는 안료와 용제에 대한 함침성과 상용성의 정도및 대상 범위가 좁은 이유로 인해, 오늘날 에폭시 다운 스트림 분야에서의 신기술 개발및 환경 보호를 위한 과제중의 하나인 하이솔리드형 에폭시 조성물을 제조하는데 큰 기술적 장애가 되고있다. 특히 도료 분야에 응용시 안료와 용제에 대한 함침성과 상용성의 정도는 환경The present invention is a glycidyl ether type having a high impregnation with a pigment and a high compatibility with a solvent by transforming a glycidyl derivative produced by reaction with an aromatic compound containing active hydrogen reactive to epihalohydrin It relates to a method for producing an epoxy resin. In the modified method, a fixed amount of glycidyl derivatives having different equivalents are added to a predetermined equivalent of glycidyl derivatives to adjust the molecular weight distribution, and a predetermined amount of amines and an ester compound or salt thereof is added to the glycidyl derivatives. It is to provide an entirely new epoxy resin. When the existing glycidyl derivatives are applied in the downstream field, the development of new technology and environmental protection in the epoxy downstream field is not possible due to the impregnation and compatibility of the pigments and solvents used as the main raw materials and the narrow range of targets. There is a major technical obstacle in preparing a high solid type epoxy composition, which is one of the problems. In particular, the degree of impregnation and compatibility with pigments and solvents in the application of paints

오염의 주 요인인 용제의 사용양을 얼마나 줄일 수 있는가의 측도가 되고있다. 본 발명은 기존의 글리시딜 유도체에 비해 안료에 대한 함침성과 용제에 대한 상용성을 획기적으로 개량함으로써, 기존 에폭시 수지 응용 조성물 중 사용되는 용제의 적어도 20 중량%를 줄이고도 기존 조성물의 점도와 상당한 점도를 얻을 수 있어 에폭시 다운 스트림 분야에서의 각종 하이솔리드형 조성물을 실현하는데 주도적 역활을 할 수 있는 에폭시 수지를 제공한다.A measure of how much less solvent is used, which is a major contributor to pollution. The present invention significantly improves the impregnation of the pigment and the compatibility of the solvent compared to the conventional glycidyl derivative, thereby reducing the viscosity of the existing composition and reducing the viscosity of at least 20% by weight of the solvent used in the existing epoxy resin application composition. The present invention provides an epoxy resin that can obtain a viscosity and can play a leading role in realizing various high-solid compositions in the field of epoxy downstream.

Description

고함침성과 고상용성을 가진 에폭시 수지의 제조 방법Process for producing epoxy resin with high impregnation and high compatibility

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (5)

적어도 글리시딜 에테르계 에폭시 수지를 변체하고, 이를 이용하여 글리시딜 에테르계 다운 스트림 응용분야에서의 안료에 대한 고함침성과 용제에 대한 고상용성을 실현하는 방법에 있으서, (1)적어도 에폭시 당량 범위가 525내지 590g/eq 미만인 글리시딜 에테르계 수지에 (2)에폭시 당량이 180내지 200g/eq미만인 글리시딜 에테르계 수지를 5내지 28중량%미만으로 첨가하여 에폭시 당량이 380내지 480g/eq미만인 글리시딜 에테르계 수지를 제조하는 방법. (3)아민류와 에스테르계의 복합 화합물 또는 염을 3중량%또는 그 미만으로 첨가하여 에폭시 당량이 400내지 500g/eq 미만인 변체된 글리시딜 에테르계 에폭시 수지를 제조하는 방법.A method of at least modifying a glycidyl ether-based epoxy resin and using it to realize high impregnation for a pigment and high compatibility with a solvent in a glycidyl ether-based downstream application, comprising: (1) at least epoxy (2) To a glycidyl ether resin having an equivalent range of 525 to less than 590 g / eq, (2) an epoxy equivalent of 380 to 480 g by adding a glycidyl ether resin having an epoxy equivalent of less than 180 to 200 g / eq to less than 5 to 28% by weight. A method for producing a glycidyl ether resin of less than / eq. (3) A method of producing a modified glycidyl ether epoxy resin having an epoxy equivalent weight of 400 to less than 500 g / eq by adding an amine and an ester compound or salt at 3% by weight or less. 제1항에 있어서, 단계(1)에서 에폭시 당량 범위가 적어도 525내지 590g/eq미만인 글리시딜계 에폭시 수지를 사용하는 것을 특징으로 하는 방법.A process according to claim 1, wherein in step (1) a glycidyl epoxy resin is used having an epoxy equivalent range of at least 525 to less than 590 g / eq. 제1항에 있어서, 단계(2)에서 에폭시 당량 범위가 적어도 180내지 200g/eq미만인 글리시딜계 에폭시 수지를 5내지 28중량%미만으로 사용하는 것을 특징으로 하는 방법.The process according to claim 1, wherein in step (2) a glycidyl epoxy resin having an epoxy equivalent range of at least 180 to less than 200 g / eq is used at less than 5 to 28 wt%. 제1항에 있어서, 단계(3)에서 아민류와 에스테르계의 복합 화합물 또는 그 염을 사용하여 글리시딜 에테르계 에폭시 수지를 변체시키는 것을 특징으로 하는 방법.The method according to claim 1, wherein the glycidyl ether-based epoxy resin is transformed in step (3) using a complex compound of amines and esters or a salt thereof. 제4항에 있어서, 단계(3)에서 아민류와 에스테르계의 복합 화합물 또는 그 염을 3중량%도는 그미만으로 사용하여 글리시딜 에테르계 에폭시 수지를 변체시키는 것을 특징으로 하는 방법.The method according to claim 4, wherein the glycidyl ether-based epoxy resin is transformed using less than 3% by weight of the amines and ester-based complex compound or salt thereof in step (3). ※ 참고사항 최초출원 내용에 의하여 공개하는 것임.※ Note The disclosure is based on the initial application.
KR1019930024604A 1993-11-18 1993-11-18 Process for producing epoxy resin with high impregnation and high compatibility KR950014170A (en)

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KR1019930024604A KR950014170A (en) 1993-11-18 1993-11-18 Process for producing epoxy resin with high impregnation and high compatibility

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Application Number Priority Date Filing Date Title
KR1019930024604A KR950014170A (en) 1993-11-18 1993-11-18 Process for producing epoxy resin with high impregnation and high compatibility

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KR950014170A true KR950014170A (en) 1995-06-15

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