KR950014119A - Spirooxazine Compounds and Methods for Making the Same - Google Patents

Spirooxazine Compounds and Methods for Making the Same Download PDF

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Publication number
KR950014119A
KR950014119A KR1019930024310A KR930024310A KR950014119A KR 950014119 A KR950014119 A KR 950014119A KR 1019930024310 A KR1019930024310 A KR 1019930024310A KR 930024310 A KR930024310 A KR 930024310A KR 950014119 A KR950014119 A KR 950014119A
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KR
South Korea
Prior art keywords
ring
spirooxazine
substituted
derivative
general formula
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Application number
KR1019930024310A
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Korean (ko)
Inventor
손일환
오상근
Original Assignee
장흥규
대림산업 주식회사
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Priority to KR1019930024310A priority Critical patent/KR950014119A/en
Publication of KR950014119A publication Critical patent/KR950014119A/en

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Abstract

본 발명은 트리메틸인돌린 또는 인돌레니움 유도체와 니트로조 아렌유도체를 반응시켜 얻은 다음 구조식의 포토크로믹 특성을 갖는 새로운 스피로옥사진계 화합물 및 그의 제조방법에 관한 것이다.The present invention relates to a novel spirooxazine compound having a photochromic property of the following structural formula obtained by reacting trimethylindolin or an indolenium derivative with a nitrozo arene derivative, and a method for preparing the same.

상기식에서 Rl은 탄소수 9∼20개의 알킬기이고, A환은 치환 또는 무치환된 벤젠환 그리고 B환은 치환 또는 무치환된 퀴놀린(quinoline)환을 표시한다. 이러한 구조식을 갖는 화합물은 스피로옥사진을 기본 구조로 하여 헤테로 원소를 도입함과 동시에 이른 탄소수가 많은 사슬형으로 하여 일광이나 자외선에 노출시 변색의 정도를 증가시키고 각종 용매 또는 폴리머메트릭스에서의 필림 형성도를 향상시킬 수 있다.Wherein R 1 is an alkyl group having 9 to 20 carbon atoms, ring A represents a substituted or unsubstituted benzene ring, and ring B represents a substituted or unsubstituted quinoline ring. Compounds having such structural formulas have a spirooxazine as a basic structure to introduce hetero elements and at the same time have a high carbon number chain to increase the degree of discoloration upon exposure to sunlight or ultraviolet rays and to form films in various solvents or polymer matrices. Can improve the degree.

Description

스피로옥사진 화합물 및 그의 제조방법Spirooxazine Compounds and Methods for Making the Same

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (2)

일반식(Ⅳ)로 표시되는 스피로옥사진 화합물Spirooxazine Compounds Represented by General Formula (IV) 여기에서, 단 R,은 탄수소 9∼20개의 알킬기, A환은 치환 또는 무치환된 벤젠화 그리고 B환은 치환 또는 무치환된 퀴놀린환임. A, B환은 치환체는 수소, 탄소수 1∼5개의 알킬기, 알콕시기, 할로겐기, 카르복실기, 니트로기인 스피로옥사진화합물이다.Wherein R, is an alkyl group of 9-20 carbohydrates, A ring is substituted or unsubstituted benzeneization and B ring is a substituted or unsubstituted quinoline ring. A, B ring is a spirooxazine compound whose substituent is hydrogen, a C1-C5 alkyl group, an alkoxy group, a halogen group, a carboxyl group, and a nitro group. 일반식(I) 또는 (Ⅱ)로 표시된 인돌린 또는 인돌레니움 유도체에 염기성 물질 및 일반식(Ⅲ)으로 표시된 퀴놀린의 니트로조 화합물 유도체를 첨가 혼합하여 반응시켜 생성된 일반식(Ⅳ)로 표시되는 스피로옥사진 화합물의 제조방법.Represented by the general formula (IV) produced by the addition and mixing of a basic substance and a nitrozo compound derivative of quinoline represented by the general formula (III) to an indolin or an indolenium derivative represented by the general formula (I) or (II) Method for producing a spirooxazine compound. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930024310A 1993-11-16 1993-11-16 Spirooxazine Compounds and Methods for Making the Same KR950014119A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019930024310A KR950014119A (en) 1993-11-16 1993-11-16 Spirooxazine Compounds and Methods for Making the Same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019930024310A KR950014119A (en) 1993-11-16 1993-11-16 Spirooxazine Compounds and Methods for Making the Same

Publications (1)

Publication Number Publication Date
KR950014119A true KR950014119A (en) 1995-06-15

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Family Applications (1)

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KR1019930024310A KR950014119A (en) 1993-11-16 1993-11-16 Spirooxazine Compounds and Methods for Making the Same

Country Status (1)

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KR (1) KR950014119A (en)

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