KR950013479B1 - A spinert for producing a hollow fiber - Google Patents

A spinert for producing a hollow fiber Download PDF

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Publication number
KR950013479B1
KR950013479B1 KR1019930012279A KR930012279A KR950013479B1 KR 950013479 B1 KR950013479 B1 KR 950013479B1 KR 1019930012279 A KR1019930012279 A KR 1019930012279A KR 930012279 A KR930012279 A KR 930012279A KR 950013479 B1 KR950013479 B1 KR 950013479B1
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South Korea
Prior art keywords
spinneret
hollow
hollow fiber
slit
producing
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KR1019930012279A
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Korean (ko)
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KR950003485A (en
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박희조
이엽우
장경진
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제일합섬주식회사
박홍기
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Publication of KR950013479B1 publication Critical patent/KR950013479B1/en

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/24Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Artificial Filaments (AREA)

Abstract

The spinneret has a triangle shape for its longitudinal section and satisfies the following conditions to produce hollow filaments. The condition is 1.0 <=a<= 3.0, 0.04<=b<=1.0, 0.5<=c<=2.0, 1.0<=h<=3.0, 15≰<=θ<=45≰, wherein, a : spinneret inner dia(mm), b : slit spacing(mm), c : slit thickness(mm), h : spinneret length(mm), θ: spinneret discharge angle(≰). The hollow filament produced through the spinneret improves heat insulation and lightens weight.

Description

중공섬유 제조용 방사구금Spinnerets for manufacturing hollow fibers

제1도는 필라멘트 1본을 형성시키는 본 발명의 방수구금공의 횡단면 확대도.1 is an enlarged cross-sectional view of a waterproofing prisoner of the present invention to form a filament.

제2도는 필라멘트 1본을 형성시키는 본 발명의 방사구금공의 종단면 확대도.Figure 2 is an enlarged longitudinal cross-sectional view of the spinneret of the present invention to form a filament.

제3(a)도, 제3(b)도, 제3(c)는 종래의 중공섬유 제조용 구금공의 횡단면 확대도3 (a), 3 (b), and 3 (c) are enlarged cross-sectional views of a conventional mold for producing hollow fibers.

제4도는 제3(a)도, 제3(b)도의 중공섬유 제조용 구금공의 종단면 확대도이다.4 is an enlarged longitudinal cross-sectional view of the hole for producing hollow fibers in FIGS. 3 (a) and 3 (b).

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

a : 방사구금공의 내접 직경(mm) b : 슬릿(SLIT)의 간격(mm)a: Internal diameter of the spinneret (mm) b: Spacing of the slits (mm)

c : 슬릿(SLIT)의 두께(mm) h : 방사 토출공의 길이(mm)c: Thickness of slit (mm) h: Length of spinning discharge hole (mm)

θ : 방사 토출공의 각도(°)θ: angle of radiation discharge hole (°)

본 발명은 열가소성 중합체를 용융방사하여 중공섬유를 제조함에 있어서, 폴리에스테르 섬유에 자연감을 부여하며, 생동감 있어서 반발탄성과 드레이프성을 부여하고, 중공부에 의한 보온성 및 경량감을 부여하기 위한 중공사 제조용 방사구금에 대한 것으로 안정한 방사상태를 유지하고, 중공율을 증대하여도 품질이 균일한 중공섬유를 제조할 수 있는 방수구금에 관한 것이다.The present invention is to produce a hollow fiber by melt spinning a thermoplastic polymer, to impart a natural sense to the polyester fiber, to impart resilience and drape in the liveness, and to provide a hollow fiber for providing insulation and light weight by the hollow portion The present invention relates to a spinneret, which maintains a stable spinning state and increases a hollow ratio, and thus relates to a waterproof collar that can produce hollow fibers of uniform quality.

중공섬유는 그 중심부의 중공부가 클수록 겉보기 비중이 작고 숭고성이 우수하며 보온성이 양호한 의류용 섬유에 적합하다.The hollow fiber has a smaller apparent specific gravity, a greater sublimeness, and is suitable for a garment fiber having good heat retention as the hollow portion at the center thereof is larger.

종래의 용융 방사법에 의한 중공섬유를 제조하기 위한 방사구금으로는 방사구금의 일부분이 끊어진 부분을 갖는 환상(제3(a)도 이나, 중공다각형 슬릿공(제3(b)도) 또는 중심부에 기체 공급부를 갖는 이중환상공(제3(c)도)등이 있는 방사구금이 많이 사용되어 왔으나 제3(a)도의 경우 양호한 중공율 보장이 되지 않아, 양호한 보온성 및 경량감 발현이 되지 않았고, 이를 개량 보완한 제3(b)도의 경우는 용융 중합체의 잠탄성 성질에 의하여 고중공 섬유를 얻기가 힘들었다.As a spinneret for manufacturing hollow fiber by the conventional melt spinning method, the annular shape having a portion where a part of the spinneret is broken is formed in the annular shape (FIG. 3 (a), the hollow polygonal slit hole (FIG. 3 (b))) Although spinnerets with double annular holes (figure 3 (c)) having a gas supply part have been used, in the case of degree 3 (a), good hollow ratio is not guaranteed, and thus, good heat retention and lightness are not expressed. In the case of the supplemented FIG. 3 (b), it was difficult to obtain a high hollow fiber due to the latent elastic properties of the molten polymer.

이러한 용융 중합체의 점탄성 성질에 의한 중공율 감소를 방지하기 이하여 제3(c)도와 같이 공기 공급부와 용융 중합체 공급부의 2중 환상공을 설계하여 중공섬유를 제조하면, 중앙의 공기 공급부에 의해서 방사시 중공율이 저하되는 것을 방지할 수 있으나 각 환상공의 공기 공급 정도의 차가 발생할때는 균일한 중공율을 갖는 섬유를 제조하기 힘들며, 과도하게 공기를 공급할때에는 방사단계에서 중공이 파열되어 품질상의 문제를 일으키는 경우가 있었다.In order to prevent the decrease of the hollow rate due to the viscoelastic properties of the molten polymer, as shown in FIG. It is possible to prevent the hollow rate from decreasing, but when the difference in the degree of air supply of each annular hole occurs, it is difficult to produce a fiber having a uniform hollow rate. There was a case.

따라서 ,본 발명의 목적은 이러한 단점을 해결하고, 양호한 중공부를 형성시켜 보온성 및 경량감을 부여하는 원사를 얻기 위한 방사구금을 제공함에 있다. 기존의 중공 형성 방사공은 일부가 끊어진 슬릿을 이용하여 슬릿간의 융착성을 이용하여 중공부를 형성시켰으나 중공율은 5~10%로 중공 형성율이 낮았다.Accordingly, an object of the present invention is to solve this disadvantage, and to provide a spinneret for obtaining a yarn that gives a heat retention and lightness by forming a good hollow. The existing hollow-formed spinneret formed the hollow part using the slit between the slits using a part of the broken slit, but the hollow formation rate was 5-10%, and the hollow formation rate was low.

본 발명은 이러한 문제를 해결하기 위하여 방사 구금공의 중앙부분이 삼각형이 되도록 각도를 주어 중공형성성을 높였다. 제2(a)도의 부분은 기존 구금에 비해 경사를 크게하여 용융중합체의 흐름을 원활하게 하였으며, 제2(b)도 부분의 경사로 인하여 방사토출시 기존 구금에 비해 경사를 크게 하여 용융중합체의 흐름을 원활하게 하였으며, 제2(b)도 부분의 경사로 인하여 방사토출시 기존 구금에 비해 스웰링 현상을 양호하게 하여 냉각후 연신상태에서 15~20%의 중공율을 가지는 섬유를 얻게 되었다.In order to solve this problem, the present invention increases the hollow formability by giving an angle such that the central portion of the spinneret becomes a triangle. The portion of FIG. 2 (a) has a larger slope than that of the existing detention to facilitate the flow of the molten polymer, and the flow of the molten polymer has a larger slope than the existing detention at the time of spinning due to the slope of the portion of FIG. Due to the inclination of the second part (b), the swelling phenomenon was better than that of the existing detention during spinning, resulting in a fiber having a hollow ratio of 15-20% in the stretched state after cooling.

a는 1.0≤a≤ 3.0이고, b는 0.04≤b≤ 1.0이며, a,b의 단위는 mm이다. a가 1.0mm미만이면 중공부가 작아 보온성, 경량감등이 부족하고, 3.0mm 초과이면 중공이 파괴될 위험이 있으며, 가 0.04 미만인 방사 구금은 제조가 용이하지 못하며, 1.0 초과인 경우에는 중공이 파괴될 가능성이 크게 된다. h는 1≤h/a≤ 3인데, h/a의 범위가 1보다 작으면 양호한 중공사를 얻기 힘들며, 3보다 클 경우는 방사성 저하로 작업성이 불량해진다. 또한 c는 0.5~2mm가 효과적이며, 0.5mm미만일 경우에는 중공섬유의 제조가 힘들게 되며, 2초과일 경우에는 경량감이 저하된다. θ는 15°≤θ≤ 45°인데, 15°보다 작을 경우 중공 형성성이 부족하며, 45˚보다 클 경우 방사공 제작이 어려우며, 방사시 단사절 발생이 심하여 작업성이 떨어지게 된다.a is 1.0 ≦ a ≦ 3.0, b is 0.04 ≦ b ≦ 1.0, and the units of a and b are mm. If a is less than 1.0 mm, the hollow part is small, and thus heat insulation, light weight, etc. are insufficient, and if it is more than 3.0 mm, there is a risk of breaking the hollow. The possibilities are great. h is 1 ≦ h / a ≦ 3. When the range of h / a is smaller than 1, it is difficult to obtain a good hollow fiber, and when it is larger than 3, the workability is poor due to a decrease in radioactivity. In addition, c is 0.5 ~ 2mm is effective, if less than 0.5mm the production of hollow fibers is difficult, if more than 2, the lightness is reduced. θ is 15 ° ≤ θ ≤ 45 °, if less than 15 ° hollow formability is insufficient, if it is larger than 45 ° it is difficult to manufacture the spin hole, the radiation is severe short cut occurs during workability is poor workability.

상술한 방사구금을 이용하여 방사한 중공섬유는 자연스럽고 생동감이 있으며, 보온성 및 경량감이 있다.Hollow fiber spun by using the spinneret described above is natural, lively, warm and lightweight.

다음의 실시예 및 비교예는 본 발명을 좀더 구체적으로 설명하는 것이지만 본 발명의 범주를 한정하지는 않는다.The following examples and comparative examples further illustrate the invention but do not limit the scope of the invention.

[실시예 1]Example 1

고유점도가 0.65 인 PET를 285℃에서 용융하여 제1도 및 제2도에 도시한 방사구금을 이용하여 중공섬유를 방사했다. 방사공의 형성은 0.15mm의 슬릿 간격(b)을 유지하고, 방사구금의 내접직경(a) 1.5㎜, 슬릿의 두께(c) 0.5mm, θ는 30°, h/a는 2인 방사공을 사용했다. 본 발명의 방사구금을 이용하여 방사한 원사의 물리적 특성은 표 1과 같다.PET having an intrinsic viscosity of 0.65 was melted at 285 ° C. to spun hollow fibers using spinnerets shown in FIGS. 1 and 2. The formation of the spin hole maintains the slit spacing (b) of 0.15 mm, the spinneret has an internal diameter (a) of 1.5 mm, a thickness of the slit (c) of 0.5 mm, θ is 30 ° and h / a is 2 Was used. Physical properties of the yarn spun by using the spinneret of the present invention are shown in Table 1.

[비교실시예 1]Comparative Example 1

실시예 1과 동일한 조건의 PET및 방사조건에서 θ를 10°로 하고, h/a를 2로 하여 방사하였고, 원사의 물리적 특성은 표1과 같다.In the same conditions as in Example 1 PET and spinning conditions, θ was 10 ° and h / a was 2, and the physical properties of the yarns are shown in Table 1.

[표 1]TABLE 1

* 평가방법* Assessment Methods

1)발발성과 드레이프성 : 숙련자 20명에 의해 평가1) Outbreak and Drape: evaluated by 20 skilled workers

2)보온성 및 경량감 : 중공률로 평가2) Warmth and lightness: evaluated by hollow rate

중공율 20% 초과 양호, 10~20%보통, 10%미만 불량.Hollow rate over 20% Good, 10 ~ 20% Normal, Less than 10%

3)방사성 : 풀보빈(Full Bobbin)을 95% 초과 양호, 95~90보통, 90% 미만 불량.3) Radioactivity: Good than 95% of full bobbin, 95 ~ 90 normal, less than 90% poor.

4) 4)

Claims (1)

방사구금의 종단면 형상이 삼각형을 이루고 있으며, 다음의 조건을 모두 만족시키는 중공섬유 제조용 방사구금.A spinneret for the production of hollow fibers in which the longitudinal section of the spinneret is triangular and satisfies all of the following conditions. 1.0≤a≤3.0………………………………………………(1)1.0? A? … … … … … … … … … … … … … … … … … (One) 0.04≤b≤1.0……………………………………………(2)0.04 ≦ b ≦ 1.0... … … … … … … … … … … … … … … … … (2) 0.5≤c≤2.0………………………………………………(3)0.5? C? … … … … … … … … … … … … … … … … … (3) 1.0≤h/a≤3.0……………………………………………(4)1.0 ≦ h / a ≦ 3.0... … … … … … … … … … … … … … … … … (4) 15˚≤θ≤45˚…………………………………………(5)15 ° ≤θ≤45 ° … … … … … … … … … … … … … … … (5) 여기서,here, a : 방사구금공의 내접직경(㎜) b : 슬릿(SLIT)의 간격(㎜)a: Internal diameter of the spinneret (mm) b: Spacing of the slits (mm) c : 슬릿(SLIT)의 두께(㎜) h : 방사토출공의 길이(㎜)c: thickness of the slits (mm) h: length of the discharge hole (mm) θ : 방사 토출공의 각도(˚)θ: angle of radiation discharge hole (°)
KR1019930012279A 1993-07-01 1993-07-01 A spinert for producing a hollow fiber KR950013479B1 (en)

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KR100419470B1 (en) * 1996-10-22 2004-05-07 주식회사 휴비스 Polyester and production of high-hollowness polyester fiber using the same
KR100408541B1 (en) * 1996-12-31 2004-03-20 주식회사 새 한 Method of manufacturing fibril polyester fiber, and spinneret therefor
KR100496477B1 (en) * 1997-09-19 2005-10-13 주식회사 코오롱 Polyester polymer polymerization device

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