KR950008667A - Improved human freezer bar with selected fatty acid soaps and synthetic surfactants for reduced bathtub rings, improved mild properties and good foam properties - Google Patents

Improved human freezer bar with selected fatty acid soaps and synthetic surfactants for reduced bathtub rings, improved mild properties and good foam properties Download PDF

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KR950008667A
KR950008667A KR1019930017718A KR930017718A KR950008667A KR 950008667 A KR950008667 A KR 950008667A KR 1019930017718 A KR1019930017718 A KR 1019930017718A KR 930017718 A KR930017718 A KR 930017718A KR 950008667 A KR950008667 A KR 950008667A
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soap
weight
bar
weight percent
fatty acid
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KR1019930017718A
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Korean (ko)
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마리 모로니 나탈리
에든 타네리 제임스
윌리암 쉘 리챠드
레슬리 케이커 마크
엘리자베스 케어터즈 메리
알렌 길버트 로렌스
마리 프렌치 돈
루이스 캔티 제랄드
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제이코버스 코넬리스 레이서
더 프록터 앤드 갬블 캄파니
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Priority to KR1019930017718A priority Critical patent/KR950008667A/en
Publication of KR950008667A publication Critical patent/KR950008667A/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/006Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/10Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/02Floating bodies of detergents or of soaps
    • C11D2111/10

Abstract

본 발명은 선택된 포화 C14내지 C18지방산 비누 및 거품 발생 계면활성제를 포함한 개선된 냉동바형 비누에 관한 것이다. 본 발명의 바는 허용가능한 거품 발생 특성을 보유하면서도 감속된 베스터브 링 (bathtub ring) 및 개선된 순한 특성을 갖는다.The present invention is directed to an improved freezer bar soap comprising selected saturated C 14 to C 18 fatty acid soaps and foaming surfactants. The bar of the present invention has a slowed bathtub ring and improved mild properties while retaining acceptable foaming properties.

Description

감소된 베스터브 링 (bathtub ring), 개선된 순한 특성 및 양호한 거품 특성을 위한 선택된 지방산 비누 및 합성계면 활성제를 갖는 개선된 인체 세정용 냉동바 (freezer bar)Improved human freezer bar with selected fatty acid soaps and synthetic surfactants for reduced bathtub rings, improved mild properties and good foaming properties

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (13)

바의 중량을 기준으로, Ⅰ. (A) 미리스트산비누, 팔미트산비누, 스테아르산비누 및 이들의 혼합물로 이루어진 군으로부터 선택된 포화 지방산 비누 약 75 내지 약 100중량% (총 지방산 비누 중량을 기준), 및 (B) 올레산 및 라우르산 비누 및 미량(C8, C10및 C18:2) 지방산 비누로 이루어진 군으로부터 선택된 기타 비누 0 내지 약25중량% (총 지방산 비누 중량을 기준)로 필수적으로 구성된 비누(이 비누는 약 90/10 내지 약 75/25비의 나트륨/칼륨(Na/K)비누 혼합물이다) 약 25 내지 약 70중량% Ⅱ. 거품 발생 합성 계면활성제 약 5 내지 약 30중량% 및 Ⅲ. 물 약15 내지 약 30중량%를 포함하고; 상기 롤레산 비누량이 바의 0 내지 약 10중량%이고; 상기 라우르산 비누가 바의 0 내지 약 10중량%이며; 상기 미량(C8, C10, C18:2)비누량이 바의 0 내지 약5중량%이고; 상기 Na/K 비누혼합물량이 상기 총 비뉴량의 약 95 내지 약100중량%이며; 상기 총비누 대 상기 거품 발생 합성계면 활성제가 약 5:1 내지 약 1:1의 비율을 갖는, 배스터브 링 (bathtub ring)이 감소된 거품발생 특성의 순한 인체 세정용 냉동 비누바.Based on the weight of the bar, I. (A) about 75 to about 100 weight percent (based on total fatty acid soap weight), and (B) oleic acid, selected from the group consisting of myristic acid soap, soap of palmitic acid, soap stearate, and mixtures thereof Soap consisting essentially of 0 to about 25% by weight (based on total fatty acid soap weight) of lauric acid soap and other soaps selected from the group consisting of trace (C 8 , C 10 and C 18: 2 ) fatty acid soaps Sodium / potassium (Na / K) soap mixture in a ratio of about 90/10 to about 75/25) about 25 to about 70 weight percent II. Foam generation synthetic surfactant about 5 to about 30% by weight and III. About 15 to about 30 weight percent of water; The amount of soap of rolle acid is 0 to about 10% by weight of the bar; The lauric acid soap is 0 to about 10 weight percent of the bar; The trace amount (C 8 , C 10 , C 18: 2 ) soap amount is 0 to about 5% by weight of the bar; The amount of Na / K soap mixture is about 95 to about 100 weight percent of the total amount of nugne; A mild human cleansing frozen soap bar of foaming properties with reduced bathtub ring, wherein said total soap to said foaming synthetic surfactant has a ratio of about 5: 1 to about 1: 1. 제1항에 있어서, 상기 Na/K 비누 혼합물이 약 90/10 내지 약 70/30의 비율을 가지며; 상기 총 비누가 그의 총중량을 기준으로, 0 내지 약5중량%의 Mg 및 TEA 비누로 이루어진 군으로부터 선택된 기타 비누를 포함하고; 바의 총중량을 기준으로, (a) 상기 총 지방산 비누 약 30 내지 약60중량%, (b) 비환원당 약 5 내지 약30중량%, (c) 소수성/친유성 비누 침가물 약 0.2 내지 약35중량%, 및 (d) 물 약15 내지 약25중량%를 포함하는 순한 인체 세정용 냉동비누바.The method of claim 1, wherein the Na / K soap mixture has a ratio of about 90/10 to about 70/30; The total soap comprises other soaps selected from the group consisting of 0 to about 5 weight percent Mg and TEA soap, based on their total weight; Based on the total weight of the bar, (a) about 30 to about 60 weight percent of said total fatty acid soap, (b) about 5 to about 30 weight percent per non-reducing, (c) about 0.2 to about 35 hydrophobic / lipophilic soap immersion Weight percent, and (d) about 15 to about 25 weight percent water. 제1항에 있어서, 상기 선택된 포화 지방산 비누가 상기 총 비누의 약90 내지 약100중량%의 양이고, 상기 Na/K 비누혼합물비가 90/10 내지 80/20인 순한 인체 세정용 냉동비누바.The mild human cleansing frozen soap of claim 1, wherein the selected saturated fatty acid soap is in an amount of about 90 to about 100 weight percent of the total soap and the Na / K soap mixture ratio is 90/10 to 80/20. 제2항에 있어서, 상기 선택된 포화 지방산 비누가 상기 총 비누의 약 95 내지 약 100중량%의 양인 순한 인체 세정용 냉동비누바.3. The gentle human cleansing soap of claim 2, wherein said selected saturated fatty acid soap is in an amount of about 95% to about 100% by weight of said total soap. 제2항에 있어서, 바의 중량을 기준으로, 상기 선택된 포화 지방산 비누(미리스트산 비누, 스테아르산 비누 및 팔미트산 비누)의 양이 약30 내지 약50정량%이고, 상기 비환원당이 약 5 내지 약20중량%, 바람직하게는 약10 내지 약 20중량%이고, 상기 소수성/친유성 물질이 약2 내지 약25중량%이고, 상기 무이 약 20 내지 약 25중량%인 순한 인체 세정용 냉동비누바.The amount of the selected saturated fatty acid soap (myritic acid soap, stearic acid soap, and palmitic acid soap) is about 30 to about 50% by weight based on the weight of the bar, wherein the non-reducing sugar is about 5 to about 20% by weight, preferably about 10 to about 20% by weight, about 2 to about 25% by weight of the hydrophobic / lipophilic material, about 20 to about 25% by weight of the radish Soap Bar. 제5항에 있어서, 순한 거품발생 합성 계면활성제 약 10 내지 약 30중량%를 함유하는 순한인체 세정용 냉동비누바.6. The frozen human soap of claim 5, comprising from about 10% to about 30% by weight of a mild foaming synthetic surfactant. 제1항에 있어서, 바의 중량을 기준으로, 상기 지방산 비누 약30 내지 약50중량%를 포함하고, 상기 지방산 비누/합성 계면활성제 비가 3:1 내지 1, 5:1인 순한 인체 세정용 냉동비누바.The mild human cleansing tablet of claim 1 comprising about 30 to about 50 weight percent of said fatty acid soap, based on the weight of the bar, wherein said fatty acid soap / synthetic surfactant ratio is 3: 1 to 1, 5: 1. Soap Bar. 제2항에 있어서, 바의 중량을 기준으로 상기 지방산 비누 약30 내지 약50중량%, 상기 비환원당 약 5 내지 약20중량%, 상기 소수성/친유성 물질 약 5 내지 약 20중량% 및 상기 물 약 20 내지 약 25중량%를 포함하는 순한 인체 세정용 냉동비누바.3. The method of claim 2, wherein the fatty acid soap is about 30 to about 50 weight percent based on the weight of the bar, about 5 to about 20 weight percent per non-reducing, about 5 to about 20 weight percent of the hydrophobic / lipophilic material and the water A mild human cleansing frozen vinuba comprising from about 20 to about 25% by weight. 제1항에 있어서, 상기 바의 중량을 기준으로, 상기 총지방산 비누 약 30 내지 약 50중량%, 상기 비환원당 약 5 내지 약 20중량%, 상기 소수성/친유성 물질 약 5 내지 약 20중량% 및 상기 물 약 20 내지 약 25중량%를 포함하는 순한 인체 세정용 냉동비누바.The method according to claim 1, wherein about 30 to about 50 weight percent of the total fatty acid soap, about 5 to about 20 weight percent per non-reducing, about 5 to about 20 weight percent of the hydrophobic / lipophilic material, based on the weight of the bar And about 20 to about 25% by weight of water. 바의 중량을 기준으로, Ⅰ. 미리스트산 비누, 팔미트산 비누, 스테아르산 비누 및 이들의 혼합물로 구성된 군으로부터 선택된 포화 지방산 비누로 필수적으로 구성되고 약 90/10 내지 약 75/25비의 나트륨/칼륨(Na/K) 비누 혼합물인 총지방산 비누 약 25 내지 약 70중량%, Ⅱ. 거품 발생 합성 계면활성제 약 30중량%, 및 Ⅲ. 물 약15 내지 약 30중량%를 포함한 비누조성물(여기서, 상기 총지방산 비누와 상기 거품발생 합성계면 활성제는 약 5:1 내지 약 1:1의 비를 갖는다)을 제조하고자, 상기 지방산 비누와 상기 기타 비누 바 성분들을 약 65 내지 약 74℃(약 150 내지 약 165°F)의 온도에서 혼합하고, 동일 반응계내에서 약 52 내지 약 57℃(125 내지 135°F)의 초기온도 및 약 85내지 약 99℃(185 내지 210°F)의 최종온도에서 비누를 제조하는 제1단계; 스크래핑된 벽의 열교환기내에서 제1단계의 혼합물을 약 85 내지 약 99℃(약 175 내지 약210°F)의 초기온도에서 약 46 내지 약 66℃(약 115 내지 약 155℃)의 최종 온도로 냉각시켜 상기 혼합물을 부분적으로 결정화시키는 제2단계, 및 제2단계의 냉각된 혼합물을 이동 벨트상으로 압출시켜 연질 플러그를 만들고, 이 플러그를 더 냉각시켜 완전히 결정화시킨다음, 성형하여 바를 형성시킴을 포함하는 냉동바의 제조방법.Based on the weight of the bar, I. Sodium / potassium (Na / K) soap consisting essentially of a saturated fatty acid soap selected from the group consisting of myristic acid soaps, palmitic acid soaps, stearic acid soaps, and mixtures thereof, in a ratio of about 90/10 to about 75/25. About 25 to about 70 weight percent total fatty acid soap in mixture, II. About 30% by weight foaming synthetic surfactant, and III. To prepare a soap composition comprising about 15% to about 30% by weight of water, wherein the total fatty acid soap and the foaming synthetic surfactant have a ratio of about 5: 1 to about 1: 1. The other soap bar components are mixed at a temperature of about 65 to about 74 ° C. (about 150 to about 165 ° F.) and in situ at an initial temperature of about 52 to about 57 ° C. (125 to 135 ° F.) and about 85 to about 85 ° C. Preparing a soap at a final temperature of about 99 ° C. (185-210 ° F.); In the heat exchanger of the scraped wall, the mixture of the first stage is brought from an initial temperature of about 85 to about 99 ° C. (about 175 to about 210 ° F.) to a final temperature of about 46 to about 66 ° C. (about 115 to about 155 ° C.). A second step of cooling to partially crystallize the mixture, and the cooled mixture of the second step is extruded onto a moving belt to produce a soft plug, which is further cooled to fully crystallize, and then shaped to form a bar. Method of manufacturing a freezing bar comprising. 제10항에 있어서, 제1단계엇 슈크로즈 약 5 내지 약 30중량%를 첨가하는 방법.The method of claim 10, wherein about 5% to about 30% by weight of the first step sucrose is added. 제10항에 있어서, 상기 제1단계의 혼합물을 통기시킨 후 냉각하는 방법.The method of claim 10, wherein the mixture of the first step is aerated and then cooled. 바의 중량을 기준으로, Ⅰ. (A) 미리스트산비누, 팔미트산비누, 스테아르산비누 및 이들의 혼합물로 이루어진 군으로부터 선택된 포화 지방산 비누 약 75 내지 약 100중량%(총 지방산 비누 중량을 기준), 및 (B) 올레산 및 라우르산 비누 및 미량(C8,C10및 C18:2) 지방산 비누로 이루어진 군으로 부터 선택된 기타 비누 0 내지 약25중량%(총 지방산 비누 중량을 기준)로 필수적으로 구성된 비누(이 비누는 약90/10내지 약 75/25비의 나트륨/칼륨(Na/K)비누 혼합물이다) 약 25 내지 약 70중량% Ⅱ. 거품 발생 합성 계면활성제 약 5 내지 약 30중량% 및 Ⅲ. 비환원당 약 5 내지 약 30중량%, 및 Ⅳ. 물 약 15 내지 약 30중량%를 포함하고; 상기 올레산 비누량이 바의 0 내지 약 10중량%이고; 상기 라우르산 비누량이 바의 0 내지 약 10중량%이고; 상기 미량(C8,C10,C18:2)비누량이 바의 0 내지 약5중량%이고; 상기 총비누 대 상기 거품 발생 합성계면 활성제가 약 5:1 내지 약 1:1의 비율을 갖는, 배스터브 링이 감소된 거품 발생 특성의 순한 인체 세정용 냉동 비누바.Based on the weight of the bar, I. (A) about 75 to about 100 weight percent (based on total fatty acid soap weight) of saturated fatty acid soap selected from the group consisting of soap of myristic acid, soap of palmitic acid, soap of stearate and mixtures thereof, and (B) oleic acid and Soap consisting essentially of 0 to about 25% by weight (based on total fatty acid soap weight) of lauric acid soap and other soaps selected from the group consisting of trace (C 8 , C 10 and C 18: 2 ) fatty acid soaps Is a sodium / potassium (Na / K) soap mixture in a ratio of about 90/10 to about 75/25) about 25 to about 70 weight percent II. Foam generation synthetic surfactant about 5 to about 30% by weight and III. About 5 to about 30 weight percent of non-reducing sugar, and IV. About 15 to about 30 weight percent of water; The amount of oleic acid soap is 0 to about 10% by weight of the bar; The amount of lauric acid soap is 0 to about 10 weight percent of the bar; The trace amount (C 8 , C 10 , C 18: 2 ) soap amount is 0 to about 5% by weight of the bar; A mild human cleansing frozen soap bar of reduced foaming properties with a reduced bathtub ring, wherein the total soap to foaming synthetic surfactant has a ratio of about 5: 1 to about 1: 1. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930017718A 1993-09-04 1993-09-04 Improved human freezer bar with selected fatty acid soaps and synthetic surfactants for reduced bathtub rings, improved mild properties and good foam properties KR950008667A (en)

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