KR950008595A - 나일론에 대한 할로중합체의 접착 - Google Patents
나일론에 대한 할로중합체의 접착 Download PDFInfo
- Publication number
- KR950008595A KR950008595A KR1019940022581A KR19940022581A KR950008595A KR 950008595 A KR950008595 A KR 950008595A KR 1019940022581 A KR1019940022581 A KR 1019940022581A KR 19940022581 A KR19940022581 A KR 19940022581A KR 950008595 A KR950008595 A KR 950008595A
- Authority
- KR
- South Korea
- Prior art keywords
- parts
- halopolymer
- talc
- carbon black
- hose
- Prior art date
Links
- 239000004677 Nylon Substances 0.000 title 1
- 229920001778 nylon Polymers 0.000 title 1
- 239000006229 carbon black Substances 0.000 claims abstract 5
- 239000000454 talc Substances 0.000 claims abstract 5
- 229910052623 talc Inorganic materials 0.000 claims abstract 5
- 239000004952 Polyamide Substances 0.000 claims abstract 3
- 229920002647 polyamide Polymers 0.000 claims abstract 3
- 239000000203 mixture Substances 0.000 claims 6
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims 4
- 239000003795 chemical substances by application Substances 0.000 claims 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 2
- 229920001971 elastomer Polymers 0.000 claims 2
- 150000002978 peroxides Chemical class 0.000 claims 2
- 230000003014 reinforcing effect Effects 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 239000011593 sulfur Substances 0.000 claims 2
- -1 bromobutyl Chemical group 0.000 claims 1
- 229920005557 bromobutyl Polymers 0.000 claims 1
- 229920005556 chlorobutyl Polymers 0.000 claims 1
- 239000003431 cross linking reagent Substances 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical group C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 claims 1
- GPNLWUFFWOYKLP-UHFFFAOYSA-N s-(1,3-benzothiazol-2-yl)thiohydroxylamine Chemical class C1=CC=C2SC(SN)=NC2=C1 GPNLWUFFWOYKLP-UHFFFAOYSA-N 0.000 abstract 1
- YWWOEPOBDHZQEJ-UHFFFAOYSA-N s-(4-cyclohexyl-1,3-benzothiazol-2-yl)thiohydroxylamine Chemical compound C1=CC=C2SC(SN)=NC2=C1C1CCCCC1 YWWOEPOBDHZQEJ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/43—Compounds containing sulfur bound to nitrogen
- C08K5/44—Sulfenamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/10—Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/18—Layered products comprising a layer of natural or synthetic rubber comprising butyl or halobutyl rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
- F16L11/12—Hoses, i.e. flexible pipes made of rubber or flexible plastics with arrangements for particular purposes, e.g. specially profiled, with protecting layer, heated, electrically conducting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/72—Cured, e.g. vulcanised, cross-linked
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2597/00—Tubular articles, e.g. hoses, pipes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polyamides (AREA)
Abstract
본 발명은 경화된 상태로 폴리아미드에 대해 탁월한 접착성을 나타내는 신규한 배합된 경화성 할로중합체를 제공한다.
경화성 할로중합체는 바람직하게 사이클로헥실 벤조티아졸 설펜아미드 또는 관련된 벤조티아졸 설펜아미드의 사용과 함께 활석에 대한 카본 블랙의 균형에 기인한 우수한 접착력을 성취한다.
본 발명은 특수 호스 및 벨트의 제조에 대단히 바람직하다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- 가교결합제로서의 비스-디에노필, 알칼리 및/또는 알칼리 토산화물, 과산화물 또는 황 경화제, 약 25 내지 약 70부의 카본 블랙 및 약 8 내지 약70부의 활석과 배합된 할로중합체 100부를 특징으로 하는, 경화된 상태로 폴리아미드에 대해 개선된 접착성을 나타낼수 있는 할로중합체의 경화성 조성물.
- 제1항에 있어서, 상기 경화제가 N-사이클로헥실-2-벤조티아졸 설펜아미드인 조성물.
- 제1항에 있어서, 상기 할로중합체가 클로로부틸 고무인 조성물.
- 제1항에 있어서, 상기 카본 블랙이 약 35 내지 약 55부이고, 상기 활석이 약 30 내지 약55부인 조성물.
- 비스-디에노필, 알칼리 및 알칼리 토산화물 및 이들의 혼합물군중에서 선택된 할로겐 중화제, 과산화물 또는 황 경화제 및 할로중합체 100부를 기준으로 배합된, 약 25 내지 약70부의 카본 블랙 및 약 8 내지 약70부의 활석 충전제를 함유하는 경화된 할로중합체 층으로 피복된 폴리아미드 내부 코어를 특징으로 하는 호스.
- 제5항에 있어서, 상기 할로중합체 층이 강화부재 또는 강화층 및 또다른 고무 덮개층으로 피복된 호스.
- 제5항에 있어서, 상기 경화된 할로중합체가 브로모부틸 고무인 호스.
- 벨트의 일부로서 제작된 제1항의 경화성 조성물.
- 제5항에 있어서, 상기 카본 블랙이 약 35 내지 약 55부이고, 상기 활석이 약 30 내지 약 55부인 호스.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/118,344 | 1993-09-09 | ||
US08/118,344 US5462091A (en) | 1993-09-09 | 1993-09-09 | Adhesion of halopolymers to nylon |
Publications (2)
Publication Number | Publication Date |
---|---|
KR950008595A true KR950008595A (ko) | 1995-04-19 |
KR100307697B1 KR100307697B1 (ko) | 2001-12-01 |
Family
ID=22378002
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019940022581A KR100307697B1 (ko) | 1993-09-09 | 1994-09-08 | 할로중합체의 경화성 조성물 및 이로부터 제조된 호스 |
Country Status (9)
Country | Link |
---|---|
US (1) | US5462091A (ko) |
EP (1) | EP0643095B1 (ko) |
JP (1) | JP3547490B2 (ko) |
KR (1) | KR100307697B1 (ko) |
CN (1) | CN1063464C (ko) |
BR (1) | BR9403470A (ko) |
CA (1) | CA2112623C (ko) |
DE (1) | DE69416063T2 (ko) |
ES (1) | ES2128474T3 (ko) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6155305A (en) * | 1994-08-29 | 2000-12-05 | Sumner; Glen R. | Offshore pipeline with waterproof thermal insulation |
EP0881419B1 (en) * | 1996-02-20 | 2003-01-29 | Kabushiki Kaisha Meiji Gomu Kasei | Refrigerant conveying hose |
DE19837497A1 (de) | 1998-08-13 | 2000-02-24 | Trinova Aeroquip Gmbh | Flexibler strangförmiger Hohlkörper |
WO2000009929A1 (de) | 1998-08-13 | 2000-02-24 | Aeroquip Zweigniederlassung Der Aeroquip-Vickers International Gmbh | Flexibler strangförmiger hohlkörper |
DE19837498A1 (de) | 1998-08-13 | 2000-02-24 | Trinova Aeroquip Gmbh | Flexibler strangförmiger Hohlkörper |
DE19837494A1 (de) | 1998-08-13 | 2000-02-24 | Trinova Aeroquip Gmbh | Flexibler strangförmiger Hohlkörper |
US5957164A (en) * | 1998-09-10 | 1999-09-28 | Aeroquip Corporation | Refrigerant hose |
US6170532B1 (en) | 1999-01-26 | 2001-01-09 | Aeroquip Corporation | Flexible hose |
JP2001049063A (ja) | 1999-08-06 | 2001-02-20 | Tokai Rubber Ind Ltd | ゴム組成物、ゴム−樹脂積層体及び不透過性ホース |
US6585047B2 (en) | 2000-02-15 | 2003-07-01 | Mcclung, Iii Guy L. | System for heat exchange with earth loops |
US6896054B2 (en) * | 2000-02-15 | 2005-05-24 | Mcclung, Iii Guy L. | Microorganism enhancement with earth loop heat exchange systems |
US6267172B1 (en) | 2000-02-15 | 2001-07-31 | Mcclung, Iii Guy L. | Heat exchange systems |
JP2002005346A (ja) * | 2000-04-21 | 2002-01-09 | Bridgestone Corp | 冷媒輸送用ゴムホース |
EP1148283A3 (en) * | 2000-04-21 | 2003-04-02 | Bridgestone Corporation | Refrigerant transporting rubber hose |
US7063181B1 (en) * | 2000-04-27 | 2006-06-20 | Dana Corporation | Fluid-borne noise suppression in an automotive power steering system |
JP4761416B2 (ja) * | 2000-09-27 | 2011-08-31 | 株式会社ブリヂストン | 冷媒輸送用ゴムホース |
CN1257797C (zh) * | 2001-01-15 | 2006-05-31 | 大赛璐-德固萨株式会社 | 复合物和其制备方法 |
JP2003056761A (ja) | 2001-08-09 | 2003-02-26 | Tokai Rubber Ind Ltd | 振動吸収性ゴムホース |
GB2398357B (en) * | 2003-02-12 | 2006-09-20 | Luk Lamellen & Kupplungsbau | Hydraulic system |
BRPI0402583A (pt) * | 2003-07-11 | 2005-05-31 | Goodyear Tire & Rubber | Mangueira para refrigerante |
GB201122436D0 (en) * | 2011-12-29 | 2012-02-08 | Wellstream Int Ltd | Flexible pipe body and method of manufacture |
CN102585733B (zh) * | 2012-02-14 | 2013-09-25 | 贵州轮胎股份有限公司 | 一种轮胎硫化胶囊的修补胶及其制备方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3062795A (en) * | 1958-04-01 | 1962-11-06 | Exxon Research Engineering Co | Process for preparing halogenated copolymers |
US3931090A (en) * | 1974-04-26 | 1976-01-06 | Xerox Corporation | Rubber composition for flexible belts |
DE2536674C3 (de) * | 1975-08-18 | 1979-09-27 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Vernetzbare Mischungen auf Basis von Kautschuk, Organosilanen und silikatischen Füllstoffen |
US4087343A (en) * | 1977-02-23 | 1978-05-02 | The Goodyear Tire & Rubber Company | Flexible cover of a platy-filled composition for an electrolytic cell |
US4569382A (en) * | 1981-05-11 | 1986-02-11 | The Goodyear Tire & Rubber Company | Composite of rubber and metal reinforcement therefor |
US4633912A (en) * | 1985-05-31 | 1987-01-06 | The Goodyear Tire & Rubber Company | Hose construction |
JPH064267B2 (ja) * | 1985-06-27 | 1994-01-19 | 横浜ゴム株式会社 | ポリアミド樹脂製薄肉内管を備えたホ−スの製造方法 |
US4721756A (en) * | 1986-09-25 | 1988-01-26 | The West Company | Molded rubber products |
JPH0615914B2 (ja) * | 1988-10-18 | 1994-03-02 | 東海ゴム工業株式会社 | 冷媒輸送用ホース |
JPH0733878B2 (ja) * | 1989-05-29 | 1995-04-12 | 東海ゴム工業株式会社 | 冷媒輸送用ホース |
US5200469A (en) * | 1990-04-18 | 1993-04-06 | Exxon Chemical Patents Inc. | Crosslinked elastomeric polymers and process for producing the same |
US5246778A (en) * | 1990-05-14 | 1993-09-21 | Exxon Chemical Patents Inc. | Hose composition |
-
1993
- 1993-09-09 US US08/118,344 patent/US5462091A/en not_active Expired - Lifetime
- 1993-12-30 CA CA 2112623 patent/CA2112623C/en not_active Expired - Fee Related
-
1994
- 1994-08-29 ES ES94113485T patent/ES2128474T3/es not_active Expired - Lifetime
- 1994-08-29 DE DE1994616063 patent/DE69416063T2/de not_active Expired - Fee Related
- 1994-08-29 EP EP19940113485 patent/EP0643095B1/en not_active Expired - Lifetime
- 1994-09-07 JP JP21377594A patent/JP3547490B2/ja not_active Expired - Fee Related
- 1994-09-08 KR KR1019940022581A patent/KR100307697B1/ko not_active IP Right Cessation
- 1994-09-08 CN CN94116203A patent/CN1063464C/zh not_active Expired - Fee Related
- 1994-09-08 BR BR9403470A patent/BR9403470A/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE69416063T2 (de) | 1999-07-15 |
KR100307697B1 (ko) | 2001-12-01 |
CA2112623A1 (en) | 1995-03-10 |
US5462091A (en) | 1995-10-31 |
CA2112623C (en) | 2004-03-30 |
EP0643095A1 (en) | 1995-03-15 |
CN1107865A (zh) | 1995-09-06 |
EP0643095B1 (en) | 1999-01-20 |
JP3547490B2 (ja) | 2004-07-28 |
ES2128474T3 (es) | 1999-05-16 |
CN1063464C (zh) | 2001-03-21 |
DE69416063D1 (de) | 1999-03-04 |
JPH07173349A (ja) | 1995-07-11 |
BR9403470A (pt) | 1995-05-16 |
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Legal Events
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A201 | Request for examination | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20070710 Year of fee payment: 7 |
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LAPS | Lapse due to unpaid annual fee |