KR950005800A - N-alloyl-C- (N-methyl anilino) imidoyl chloride derivatives and preparation method thereof - Google Patents

N-alloyl-C- (N-methyl anilino) imidoyl chloride derivatives and preparation method thereof Download PDF

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Publication number
KR950005800A
KR950005800A KR1019930015997A KR930015997A KR950005800A KR 950005800 A KR950005800 A KR 950005800A KR 1019930015997 A KR1019930015997 A KR 1019930015997A KR 930015997 A KR930015997 A KR 930015997A KR 950005800 A KR950005800 A KR 950005800A
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KR
South Korea
Prior art keywords
chlorine
hydrogen
nitro group
alloyl
preparation
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KR1019930015997A
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Korean (ko)
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KR0129789B1 (en
Inventor
김천석
김용태
양광규
권기성
성낙도
김기환
이용구
Original Assignee
박명규
재단법인 한국인삼연초연구소
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Priority to KR1019930015997A priority Critical patent/KR0129789B1/en
Publication of KR950005800A publication Critical patent/KR950005800A/en
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Publication of KR0129789B1 publication Critical patent/KR0129789B1/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/70—Compounds containing any of the groups, e.g. isoureas

Abstract

이 발명은 일반식(Ⅰ)로 표시되는 신규한 화합물에 관한 것임.This invention relates to the novel compound represented by general formula (I).

식중 X는 염소, 수소 또는 니트로기를 나타내고 Y는 X가 염소나 수소인 경우에는 수소가 아니라는 전제하에 수소, 염소, 알킬, 알콕시 또는 니트로기를 나타냄.Wherein X represents a chlorine, hydrogen or nitro group and Y represents hydrogen, chlorine, alkyl, alkoxy or nitro group provided that X is not hydrogen when X is chlorine or hydrogen.

이 화합물은 의약 및 농약 중간체로서 유용하게 이용됨. 본 발명은 전기한 일반식(Ⅰ)의 화합물을 제조하는 방법에도 관계됨.This compound is useful as a pharmaceutical and pesticide intermediate. The present invention also relates to a process for preparing the compound of general formula (I).

본 발명의 방법에 의하면 유사 물질인 X가 염소 도는 수소이고 Y가 수소인 공지화합물 제조 방법을 이용하는 경우보다 부반응이 적고 수율이 높은 효과가 있음.According to the method of the present invention, there is less side reaction and a higher yield than the case of using a known compound preparation method in which X is chlorine or hydrogen and Y is hydrogen.

Description

N-알로일-C-(N-메틸 아닐리노) 이미도일 클로라이드유도체 및 그 제조방법N-alloyl-C- (N-methyl anilino) imidoyl chloride derivatives and preparation method thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (3)

일반식(Ⅰ)으로 표시되는 N-알로일-C-(N-메틸아닐리노) 이미도일 클로라이드유N-alloyl-C- (N-methylanilino) imidoyl chloride oil represented by general formula (I) 식중 X는 염소인 경우, Y는 수소원자가 아니라는 전제하에, X는 염소, 수소 또는 니트로기이고, Y는 수소, 염소, 알콕시 또는 니트로기를 나타낸다.Wherein X is chlorine, X is chlorine, hydrogen or nitro group, and Y is hydrogen, chlorine, alkoxy or nitro group, provided that Y is not a hydrogen atom. N-알로일-C-카르보이미도일 디클로라이드를 트리에틸아민 및 N-메틸아닐린과 반응시켜 일반식(Ⅰ)의 N-아로일-C-(N-메틸 아닐리노)이미도일디클로라이드 유도체를 제조하는 방법에서, N-메틸 아닐린과 트리에틸아민을 미리 벤젠에 용해시킨 다음 벤젠에 용해시킨 N-알로일-C-카르보이미도일클로라이드용액에 가하여 반응시키고 생성물을 진공 증류하고 유기 용매에서 재결정화 시킴을 특징으로 하는 방법.N-aroyl-C-carboimidoyl dichloride is reacted with triethylamine and N-methylaniline to form N-aroyl-C- (N-methyl alinino) imidoyldichloride derivatives of general formula (I). In the preparation method, N-methyl aniline and triethylamine were previously dissolved in benzene and then added to an N-alloyl-C-carbodiimidoyl chloride solution dissolved in benzene to react and the product was vacuum distilled and recrystallized in an organic solvent. Method characterized by anger. 식중 X는 염소, 수소원자 또는 니트로기를 나타내고 Y는 수소, 염소, 알킬, 알콕시 또는 니트로기를 나타낸다.Wherein X represents a chlorine, hydrogen atom or nitro group and Y represents hydrogen, chlorine, alkyl, alkoxy or nitro group. 정제공정이 클로로포름/펜탄 또는 헥산, 벤젠, 디옥산등의 유기용매를 이용한 재결정 방법에 의하여 이루어짐을 특징으로 하는 방법.Purification process is characterized in that the recrystallization method using an organic solvent such as chloroform / pentane or hexane, benzene, dioxane. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930015997A 1993-08-18 1993-08-18 N-alloy-c-(n-methylanilino)imidoyl chloride derivatives and the process of production thereof KR0129789B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019930015997A KR0129789B1 (en) 1993-08-18 1993-08-18 N-alloy-c-(n-methylanilino)imidoyl chloride derivatives and the process of production thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019930015997A KR0129789B1 (en) 1993-08-18 1993-08-18 N-alloy-c-(n-methylanilino)imidoyl chloride derivatives and the process of production thereof

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KR950005800A true KR950005800A (en) 1995-03-20
KR0129789B1 KR0129789B1 (en) 1998-04-07

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