KR950002546B1 - Coke contact material for waste water treatment - Google Patents

Coke contact material for waste water treatment Download PDF

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Publication number
KR950002546B1
KR950002546B1 KR1019920004256A KR920004256A KR950002546B1 KR 950002546 B1 KR950002546 B1 KR 950002546B1 KR 1019920004256 A KR1019920004256 A KR 1019920004256A KR 920004256 A KR920004256 A KR 920004256A KR 950002546 B1 KR950002546 B1 KR 950002546B1
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contact material
sewage
present
cox
coke
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KR1019920004256A
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Korean (ko)
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KR930019567A (en
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김양묵
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김양묵
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

The filtering system using cokes consists of (1) grinding cokes to have surface as much as 300-400 m2/m3, (2) spreading ground cokes to have space as much as 30% of the filter bed on the screen, (3) stacking the screens and flowing upward waste water.

Description

오수처리용 콕스 접촉재Cox contact material for sewage treatment

제1도는 본 발명의 실시예시도임.1 is an exemplary view of the present invention.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

1 : 침전이상조 2 : 여상1: Sedimentation Abnormality tank 2: Filter phase

3 : 접촉재 4 : 오수유입관3: contact material 4: sewage inflow pipe

5 : 공기유입관 6 : 정화수5: air inlet pipe 6: purified water

7 : 배출구7: outlet

본 발명은 각종 오수정화 처리시에 유연탄의 연소후에 남는 잔사인 콕스를 오수정화에 유효한 미생물의 접촉재로 사용하는 것을 특징으로한 오수처리용 콕스 접촉재에 관한 것이다.The present invention relates to a coke contact material for sewage treatment, wherein coke, a residue remaining after combustion of bituminous coal in various sewage purification processes, is used as a contact material for microorganisms effective for sewage purification.

본 발명의 목적은 각종 방법으로 오수를 처리함에 있어서 종래 사용하던 자갈등의 접촉재 대신 본 발명의 콕스 접촉재를 제공하여 오수의 정화효율을 향상시킬 수 있게 하는데 있다.It is an object of the present invention to improve the purification efficiency of sewage by providing a cox contact material of the present invention instead of a contact material such as gravel which is conventionally used in treating sewage by various methods.

종래의 오수 접촉재로 자갈 쇄석, 하니캄튜브, 좁밥, 소석, 플라스틱 파이프, 모래, 안쓰라이트 목편, 활성탄, 랏셀편지(編也), 화학섬유의 끈을 엮어서 된 망상 또는 고리형 접촉재, 다공성 세라믹등을 사용하고 있다.Conventional sewage contact materials include gravel crushed stone, honey camp tube, millet, hydrated stone, plastic pipe, sand, anthrite wood chips, activated charcoal, ratsel letter, chemical fiber, reticulated or cyclic contact material, porous Ceramic is used.

종래의 미생물 접촉재중 자갈등은 세균의 부착성이 좋지 못하며 무게가 커서 여상(床)의 높이를 높히기 어려운 폐단이 있고 톱밥등의 식물성 접촉재는 부패성이 빨라 자주 교환해야 하는 문제점이 있으며 다공성세라믹은 비교적 균의 부착성이 좋아 오수의 처리효율이 높으나 값이 비싼 흠이 있다,Among conventional microbial contact materials, gravel is poor in adhesion of bacteria and has a large weight. 폐) There is a problem that it is difficult to raise the height, and vegetable contact materials such as sawdust have a problem of frequent decay because of fast decay. Porous ceramics have high degree of sewage treatment efficiency, but have a high cost,

하니캄튜브등은 중량이 가벼워서 여과상의 높이를 높게할 수는 있으나 표면적의 단순구조로 인하여 미생물의 부착성이 미흡하며 일본특허공보 소 63-30054호 및 동소 62-44798호에서 사용하는 화학섬유로 직조한 끈으로 엮어된 만상 접촉재는 수명이 한정될 뿐 아니라 우니의 부착이 증가할수록 그 중량으로 늘어지는 폐단이 있다.Honey Camp tube is light in weight and can increase the height of filtration, but due to the simple structure of surface area, it is insufficient to adhere to microorganisms. It is a chemical fiber used in Japanese Patent Publication No. 63-30054 and Japanese Patent Application No. 62-44798. The tangential contact material interwoven with the woven string has a limited lifetime, and there is a closed end that decreases as the weight of the uni- ness increases.

본 발명은 이러한 종래의 오수처리에 있어서의 균의 접촉재의 4기능상의 미비점을 시정하기 위하여 여러가지로 연구한 결과 콕스 접촉재를 개발하였다.The present invention has developed a cox contact material as a result of various studies to correct the four-function incompleteness of the contact material of the bacteria in the conventional sewage treatment.

즉 콕스는 유연탄을 연소하고, 남는 잔사(殘渣)로서 비중이 대단히 가볍고 미세한 다공성 물질로서 비표면적(比表面積)이 대단히 커서 종래의 자갈모래에 비하여 오수정화에 유효한 미생물의 부착성이 양호하며 부패성이 없어 반복적으로 사용할 수 있으면서 오수의 정화 처리능력이 대단히 향상되는 특징이 있다.In other words, Cox burns bituminous coal and is a residue that is very light and has a very high specific gravity. It has a very large specific surface area and has good adhesion to microorganisms, which is effective for sewage purification, and decay. It can be used repeatedly, and the sewage purification ability is greatly improved.

본 발명을 상세히 설명하면 다음과 같다.The present invention is described in detail as follows.

오수를 산수여상법(散水床法)에 의하여 정화 처리함에 있어 종래의 미생물 접촉재로 자갈이나 쇠석을 사용하던 것을 본 발명에서는 유연탄을 연소하고 남은 잔사인 콕스를 균의 부착재로 사용한다. 종래 자갈이나 쇠석을 접촉재로 사용할 경우 지름이 30-70mm의 것을 사용하였을 때 비표면적이 100-200㎡/㎥에 불과하였으나 본 발명의 콕스 접촉재는 지름 10-30mm정도로 잘게 부수어 사용하였을 때 비표면적이 300-600㎡/㎥정도로 되어 종래의 자갈등에 비하여 비표면적이 훨씬 커서 동일조건에서 균의 부착성과 정화효율이 대단히 향상할 수 있다.Sewage Water Purification Method In the present invention, the use of gravel or scum as a conventional microbial contact material in purifying treatment according to the method of the present invention uses Cox, the residue remaining after burning bituminous coal, as a bacterium adhesion material. When using gravel or iron as a contact material, the specific surface area is only 100-200 m 2 / m 3 when the diameter of 30-70 mm is used, but the cox contact material of the present invention has a specific surface area when it is crushed to about 10-30 mm in diameter. It is about 300-600 m 2 / m 3, and the specific surface area is much larger than that of conventional gravel, so that the adhesion and purification efficiency of bacteria can be greatly improved under the same conditions.

또 종래의 쇠석이나 자갈등은 자체중량으로 인하여 여상의 높이를 높히기 어려우나 콕스 접촉재는 가벼워서 종래의 이상보다 높게 형성할 수 있고 따라서 산수여상법에 의한 오수처리 효과가 대단히 높다.In addition, the conventional iron or gravel is difficult to increase the height of the filter bed due to its own weight, but the Cox contact material is light and can be formed higher than the conventional one. Therefore, the sewage treatment effect by the arithmetic award method is very high.

또한 오수를 침적여상법(浸積床法)에 의하여 처리함에 있어서 종래 미생물 접촉재로서 자갈이나 쇠석등의 입상물, 하니캄튜브, 망상체, 다공질 세라믹등의 성형물을 사용하던 것을 본 발명의 콕스 접촉재를 사용한다.Also, sewage sedimentation method (浸 積 In the case of treating by the method of the present invention, the coke contact material of the present invention uses granular materials such as gravel or iron, molded articles such as honey camp tubes, reticulated bodies, and porous ceramics as conventional microbial contact materials.

종래의 하니캄튜브는 비교적 중량이 가벼워 여상의 높이를 높힐 수는 있으나 구조물 표면이 단조로워서 비표면적이 넓지 못하여 오수의 처리능력이 별로 높지못한 미비점이 있고 다공실 세라믹 접촉재는 오수의 처리능력은 히니캄튜브에 비하여 높으나 값이 비싼 결점이 있다.Conventional honeycamp tube is relatively light in weight, which can increase the height of the filter, but the surface of the structure is monotonous, and the specific surface area is not wide, so that the sewage treatment capacity is not high. It has a higher but more expensive flaw than Nikcamp.

그러나 본 발명의 콕스 접촉재는 잘 알려진 바와 같이 천연의 고체연료인 유연탄을 연료로 사용한 후 남는 잔사이기 때문에 값이 저렴할뿐 아니라 어느 접촉재보다 다공성으로 가볍기 때문에 취급이 용이하고 간단한 가공으로 비표면적을 크게할 수 있어 처리능력을 보다 높힐 수 있다.However, the Cox contact material of the present invention is not only inexpensive because it is a residue remaining after the use of natural solid fuel bituminous coal as fuel, and is easy to handle because of its lighter porosity than any contact material. Can increase the processing power.

또 콕스 접촉재는 미세공이 균에 의하여 막힌 경우 여상에서 꺼내어 건조한 다음 희알칼리용액에 삶은다음 물로 세척하여 건조처리하면 본래의 다공성이 회복됨으로 재사용할 수 있다.In addition, Cox contact materials can be reused because micropores are blocked by bacteria, removed from the filter bed, dried, boiled in dilute alkaline solution, washed with water and dried to recover the original porosity.

또한 유동상법(流動床法)에 의한 오수처리에 있어서 종래 접촉재로 모래, 안쓰라이트, 발포 스티로폴등을 사용하던 것을 본 발명의 콕스 접촉재를 사용한다.In addition, in the sewage treatment by the fluidized bed method, the coke contact material of the present invention uses sand, anthrite, foamed styropole, etc. as a conventional contact material.

종래의 모래, 안쓰라이트, 발포 스티로폴등의 접촉재는 구조상 단조로워서 비표면적이 별로 크지 못하여 균의 접촉성이 미흡하나 본 발명의 콕스 접촉재는 2-5mm정도의 입자만 선별하여 사용하여도 다공성으로 인하여 종래의 상기 접촉재보다 오수의 처리능력이 높아 보다 효율적으로 다량의 오수를 처리할 수 있다.Conventional contact materials such as sand, anthrite, foamed styropol, etc. are monotonous in structure, so the specific surface area is not so large, so that the contactability of the bacteria is insufficient. It is possible to treat a large amount of sewage more efficiently than the conventional contact material because of the ability to treat sewage.

상술한 바와 같이 본 발명의 콕스는 고체연료의 부산물로서 다량 산출되는 저렴한 것으로 종래 콕스는 일부 연료, 특히 탄소강의 담금용도의 연료로 사용할 정도이고 별다른 산업적 용도가 없었으나 본 발명에서는 오수처리의 새로운 미생물 접촉재료 사용하기 때문에 콕스의 산업적 활용성이 넓게 되었을 뿐 아니라 특히 오수처리 기술분야에서 새로운 무기질 접촉재로서 다공성으로 비표면적이 넒어 미생물의 접촉이 양호하고 중량이 가벼워 취급이 용이하여 경제적으로 다량의 오수를 보다 능률적으로 처리할 수 있는 효과가 있다.As described above, the Cox of the present invention is inexpensive as a by-product of solid fuel, and the conventional Cox is used as a fuel for immersion of some fuels, especially carbon steel, and there is no industrial use. Cox has not only expanded the industrial utility of Cox, but also has a large specific surface area due to its porosity as a new inorganic contact material, especially in the field of sewage treatment technology. There is an effect that can be processed more efficiently.

실시예Example

본 발명의 실시예를 첨부도면에 의하여 상세히 실명하면 다음과 같다.Embodiments of the present invention with reference to the accompanying drawings in detail as follows.

제1도는 본 발명의 실시예시도로서, 침전여상조(1)에 일정한 간격의 다단으로 형성된 망상의 여상(2)위에 본 발명의 콕스 접촉재(3)을 공간률 30%가 유지되게 일정한 두께로 충진한다. 침전조(1)의 하방에 설치된 오수유입관(4)을 통하여 BOD 40mg/ℓ SS 50mg/ℓ함유의 15℃의 오수를 유량 1.0-10ℓ/min(체류시간으로 환산하여 5-0.5시간)의 범위에서 공급유입시킨다.1 is an exemplary embodiment of the present invention, the coke contact material 3 of the present invention on a mesh bed (2) formed in a multi-stage at regular intervals in the precipitation filter tank (1) to a constant thickness to maintain a space ratio of 30% Fill. Through the sewage inlet pipe 4 installed below the sedimentation tank 1, the wastewater at 15 ° C. containing BOD 40 mg / L SS 50 mg / L was flowed at a range of 1.0-10 L / min (5-0.5 hours in terms of residence time). Feed in.

한편 오수유입관(4)과 나란히 설치된 공기유입관(5)을 통하여 압축공기를 15-25ℓ/min의 비율로 공급하여 정화수(6)을 침전여상조(1)의 상부에 형성된 배출구(7)로 배출되게 하면서 오수를 정화처리한다.Meanwhile, the compressed air is supplied at a rate of 15-25 l / min through the air inlet pipe 5 installed in parallel with the sewage inlet pipe 4 to discharge the purified water 6 to the outlet 7 formed in the upper part of the precipitation filter tank 1. To clean up the sewage.

본 발명의 콕스 접촉재(3)에는 미리 기존의 폐수처리장의 폭기조의 오수를 3일간 통과시키어 오수에 함유된 미생물을 본 발명의 콕스(3)에 접촉 부착시킨 다음 상기와 같이 오수를 정화처리 하였다.The coke contact material 3 of the present invention was previously passed through the wastewater of the aeration tank of the existing wastewater treatment plant for 3 days, and microorganisms contained in the sewage were contacted and attached to the coke 3 of the present invention, and the wastewater was purified as described above. .

상기 실시예의 시험에 의한 결과는 오수의 체류시간 2.4-3시간으로 하였을 때 BOD 제거율이 95%였으며 이는 종래 자갈매체를 사용하였을 때의 58%, 쇠석을 사용하였을 때의 62%에 비하여 약 1.5배로 제거율이 향상된 것이다. 또 SS의 제거율은 거의 100%로서 자갈을 사용하였을 때의 70% 쇠석을 사용하였을 때의 78%이던 것에 비하여 1.5배 정도 향상된 것이다 .According to the test results of the above example, when the retention time of the sewage was 2.4-3 hours, the removal rate of BOD was 95%, which is about 1.5 times compared to 58% when using a gravel medium and 62% when using iron. The removal rate is improved. The removal rate of SS is almost 100%, which is 1.5 times better than that of 70% when using gravel and 78% when using gravel.

Claims (1)

산수여상법, 침적여상법, 접촉산화법, 유동상법, 혐기성법등의 공지한 오수처리에 있어서, 오수처리의 미생물 접촉재로 유연탄의 연소잔사인 콕스를 사용하는 것을 특징으로 한 오수처리용 콕스 접촉재.In well-known sewage treatment such as arithmetic filtration, immersion filtration, catalytic oxidation, fluidized bed, anaerobic, etc., Cox contact material for sewage treatment is characterized in that coke, a combustion residue of bituminous coal, is used as a microbial contact material for sewage treatment. .
KR1019920004256A 1992-03-16 1992-03-16 Coke contact material for waste water treatment KR950002546B1 (en)

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KR1019920004256A KR950002546B1 (en) 1992-03-16 1992-03-16 Coke contact material for waste water treatment

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KR950002546B1 true KR950002546B1 (en) 1995-03-21

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