KR950000564A - Antimicrobial zeolite having excellent adsorption property containing hydrogen ions and antimicrobial resin composition containing the zeolite - Google Patents

Antimicrobial zeolite having excellent adsorption property containing hydrogen ions and antimicrobial resin composition containing the zeolite Download PDF

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Publication number
KR950000564A
KR950000564A KR1019930010812A KR930010812A KR950000564A KR 950000564 A KR950000564 A KR 950000564A KR 1019930010812 A KR1019930010812 A KR 1019930010812A KR 930010812 A KR930010812 A KR 930010812A KR 950000564 A KR950000564 A KR 950000564A
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South Korea
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zeolite
antimicrobial
resin composition
weight
content
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KR1019930010812A
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Korean (ko)
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KR970000303B1 (en
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권태현
류창석
천만석
김준
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최근선
주식회사 럭키
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Priority to KR1019930010812A priority Critical patent/KR970000303B1/en
Publication of KR950000564A publication Critical patent/KR950000564A/en
Priority to KR1019960040513A priority patent/KR0154964B1/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds

Abstract

본 발명은 수소 이온을 함유하는 항균성 제올라이트 및 이러한 제올라이트를 포함하는 항균성 수지 조성물에 관한 것이다.The present invention relates to an antimicrobial zeolite containing hydrogen ions and an antimicrobial resin composition comprising such a zeolite.

본 발명의 항균성 제올라이트는 수소 이온이 존재함으로 염기성 물질을 강하게 흡착한다. 이러한 작용은 암모니아와 아민과 같은 유독하고 자극적인 물질을 제거하는데 효과적으로 사용될 수 있다.The antimicrobial zeolite of the present invention strongly adsorbs a basic substance due to the presence of hydrogen ions. This action can be effectively used to remove toxic and irritating substances such as ammonia and amines.

또한 본 발명의 항균성 제올라이트는 아세틸렌, 에틸렌, 프로필렌 등과 같은 불포화 탄화수소 또는 가스, 물, 탄산가스, 황화합물 등과 같은 극성 물질등도 강하게 흡착하며, 특히 식품의 부패를 촉진시키는 에틸렌가스를 흡착하므로써 신선도 유지 용도에도 사용될 수 있다.In addition, the antimicrobial zeolite of the present invention strongly adsorbs polar hydrocarbons such as unsaturated hydrocarbons such as acetylene, ethylene, propylene, or gas, water, carbon dioxide, sulfur compounds, etc. Can also be used.

또한, 본 발명에 따른 제올라이트는 박테리아 또는 곰팡이를 억제할 수 있는 각종 분야에 적용될 수 있다.In addition, the zeolite according to the present invention can be applied to various fields capable of inhibiting bacteria or fungi.

Description

수소 이온을 함유한 흡착성이 우수한 항균성 제올라이트 및 그 제올라이트를 포함하는 항균성 수지조성물Antimicrobial zeolite having excellent adsorption property containing hydrogen ions and antimicrobial resin composition containing the zeolite

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제 1 도는 NH4 이온 교환후 열처리한 분말 X-선 회절스펙트럼이고, 제 2 도는 NH4 이온 교환후 열처리한 적외선 분광 스펙트럼이다.1 is a powder X-ray diffraction spectrum heat-treated after NH 4 ion exchange, and FIG. 2 is an infrared spectral spectrum heat-treated after NH 4 ion exchange.

Claims (16)

제올라이트내에 수소 이온을 함유함을 특징으로 하는 항균성 제올라이트.An antimicrobial zeolite comprising hydrogen ions in the zeolite. 제1항에 있어서, 이온 교환 가능한 양이온의 일부가 항균 금속인 아연, 구리, 은, 수은, 주석, 납, 비스무스, 카드뮴, 크롬, 탈륨으로 구성되는 군으로부터 선택된 적어도 한가지 금속 이온을 추가로 포함하는 것을 특징으로 하는 항균성 제올라이트.The method of claim 1, wherein some of the ion exchangeable cations further comprise at least one metal ion selected from the group consisting of zinc, copper, silver, mercury, tin, lead, bismuth, cadmium, chromium, thallium which are antibacterial metals. Antimicrobial zeolite, characterized in that. 제2항에 있어서, 아연, 구리, 은, 마그네슘, 칼슘으로 구성되는 군으로부터 선택된 적어도 한가지 금속이온을 추가로 함유하는 것을 특징으로 하는 항균성 제올라이트.The antimicrobial zeolite according to claim 2, further comprising at least one metal ion selected from the group consisting of zinc, copper, silver, magnesium and calcium. 제1항에 있어서, 제올라이트는 천연 혹은 합성 제올라이트인 것을 특징으로 하는 항균성 제올라이트.The antimicrobial zeolite of claim 1 wherein the zeolite is a natural or synthetic zeolite. 제4항에 있어서, 제올라이트는 A-형, X-형, Y-형, T-형, 캐버자이트, 모데나이트, 클리높틸로라이트, 에리오나이트로 구성되는 군으로부터 선택되는 것을 특징으로 하는 항균성 제올라이트.The method of claim 4, wherein the zeolite is selected from the group consisting of A-type, X-type, Y-type, T-type, caberzite, mordenite, clinotillolite, erionite Antimicrobial Zeolite. 제1항에 있어서, 수소 이온의 원이 유기 혹은 무기 브렌스테드 산임을 특징으로 하는 항균성 제올라이트.The antimicrobial zeolite of claim 1 wherein the source of hydrogen ions is an organic or inorganic Brenstead acid. 제1항에 있어서, 수소 이온의 함량이 0.05 내지 3중량%인 것을 특징으로 하는 항균성 제올라이트.The antimicrobial zeolite according to claim 1, wherein the content of hydrogen ions is 0.05 to 3% by weight. 제2항에 있어서, 은 이온의 함량이 0.01 내지 20중량% 범위이고, 아연 혹은 구리 함량이 0.5 내지 20중량%인 것을 특징으로 하는 항균성 제올라이트.The antimicrobial zeolite according to claim 2, wherein the content of silver ions is in the range of 0.01 to 20% by weight and the content of zinc or copper is 0.5 to 20% by weight. 제3항에 있어서, 은 이온의 함량이 0.01 내지 20중량%의 범위이고, 아연 혹은 구리 함량이 0.5 내지 20중량%이고, 칼슘 혹은 마그네슘의 함량이 0.5 내지 15중량%의 범위인 것을 특징으로 하는 항균성 제올라이트.The method of claim 3, wherein the content of silver ions is in the range of 0.01 to 20% by weight, the zinc or copper content is 0.5 to 20% by weight, and the calcium or magnesium content is in the range of 0.5 to 15% by weight. Antimicrobial Zeolite. 제올라이트내의 이온 교환가능한 양이온의 일부가 항균 금속인 아연, 구리, 은, 수은, 주석, 납, 비스무스, 카드뮴, 크롬, 탈륨으로 구성되는 군으로부터 선택된 적어도 한가지 금속 이온으로 치환되고 수소 이온을 함유한 항균성 제올라이트와 수지로 이루어지는 것을 특징으로 하는 항균성 수지 조성물.Antimicrobial properties containing hydrogen ions substituted with at least one metal ion selected from the group consisting of zinc, copper, silver, mercury, tin, lead, bismuth, cadmium, chromium and thallium, wherein some of the ion exchangeable cations in the zeolite are antibacterial metals An antimicrobial resin composition comprising a zeolite and a resin. 제11항에 있어서, 수지가 ABS 수지, 폴리스틸렌, 폴리에틸렌, 폴리프로필렌, 나일론, 폴리에스테르, 폴리아미드, 비닐리덴, 염화폴리비닐, 천연 고무 및 합성 고무로 구성된 군으로부터 선택된 것임을 특징으로 하는 항균성 수지 조성물.12. The antimicrobial resin composition according to claim 11, wherein the resin is selected from the group consisting of ABS resin, polystyrene, polyethylene, polypropylene, nylon, polyester, polyamide, vinylidene, polyvinyl chloride, natural rubber and synthetic rubber. . 제11항에 있어서, 수소 이온 항균성 제올라이트의 수지에 대한 함량이 0.05 내지 50중량%의 범위인 것을 특징으로 하는 항균성 수지 조성물.12. The antimicrobial resin composition according to claim 11, wherein the content of the hydrogen ion antimicrobial zeolite is in the range of 0.05 to 50% by weight. 제13항에 있어서, 수소 이온 항균성 제올라이트의 수지에 대한 함량이 0.1 내지 10중량%의 범위인 것을 특징으로 하는 항균성 수지 조성물.The antimicrobial resin composition according to claim 13, wherein the content of the hydrogen ion antimicrobial zeolite is in the range of 0.1 to 10% by weight. 제14항에 있어서, 수소 이온 항균성 제올라이트의 수지에 대한 함량이 0.1 내지 5중량%의 범위인 것을 특징으로 하는 항균성 수지 조성물.15. The antimicrobial resin composition according to claim 14, wherein the content of the hydrogen ion antimicrobial zeolite is in the range of 0.1 to 5% by weight. 제11항에 있어서, 구리, 아연, 수은, 주석, 납, 비스무스, 카드뮴, 크롬 및 탈륨으로 구성되는 군으로부터 선택된 적어도 한가지 금속이온을 추가로 포함하는 것을 특징으로 하는 항균성 수지 조성물.12. The antimicrobial resin composition according to claim 11, further comprising at least one metal ion selected from the group consisting of copper, zinc, mercury, tin, lead, bismuth, cadmium, chromium and thallium. 제16항에 있어서, 구리, 아연, 은, 칼슘, 마그네슘을 추가로 포함하는 것을 특징으로 하는 항균성 수지 조성물.The antimicrobial resin composition according to claim 16, further comprising copper, zinc, silver, calcium, and magnesium. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930010812A 1993-06-14 1993-06-14 Antimicrobial zeolite containing hydrogen ion KR970000303B1 (en)

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KR1019930010812A KR970000303B1 (en) 1993-06-14 1993-06-14 Antimicrobial zeolite containing hydrogen ion
KR1019960040513A KR0154964B1 (en) 1993-06-14 1996-09-18 Antibacterial resin composition comprising proton-containing antibacterial zeolite having high absorbing power

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100482298B1 (en) * 1997-12-30 2005-07-18 대림산업 주식회사 Antimicrobial Zeolite Composition and Antibacterial Resin Containing it
KR100479684B1 (en) * 1997-02-19 2005-07-28 한화종합화학 주식회사 Antibacterial and deodorant heat-curable resin composition and products containing the same and method for manufacturing same
KR100622437B1 (en) * 2005-08-12 2006-09-12 박영자 Antibiotic floor for stall
US8557564B2 (en) 2006-08-21 2013-10-15 Samsung Electronics Co., Ltd. Method of separating microorganism using nonplanar solid substrate and device for separating microorganism using the same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101306879B1 (en) * 2010-12-03 2013-09-10 금건수 Gas Absorbing Resin Composition For Food Package

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100479684B1 (en) * 1997-02-19 2005-07-28 한화종합화학 주식회사 Antibacterial and deodorant heat-curable resin composition and products containing the same and method for manufacturing same
KR100482298B1 (en) * 1997-12-30 2005-07-18 대림산업 주식회사 Antimicrobial Zeolite Composition and Antibacterial Resin Containing it
KR100622437B1 (en) * 2005-08-12 2006-09-12 박영자 Antibiotic floor for stall
US8557564B2 (en) 2006-08-21 2013-10-15 Samsung Electronics Co., Ltd. Method of separating microorganism using nonplanar solid substrate and device for separating microorganism using the same

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