KR940021601A - 내수성과 접착력이 향상된 카페트용 라텍스의 제조 방법 - Google Patents

내수성과 접착력이 향상된 카페트용 라텍스의 제조 방법 Download PDF

Info

Publication number
KR940021601A
KR940021601A KR1019930003238A KR930003238A KR940021601A KR 940021601 A KR940021601 A KR 940021601A KR 1019930003238 A KR1019930003238 A KR 1019930003238A KR 930003238 A KR930003238 A KR 930003238A KR 940021601 A KR940021601 A KR 940021601A
Authority
KR
South Korea
Prior art keywords
weight
parts
styrene
carboxylic acid
butadiene
Prior art date
Application number
KR1019930003238A
Other languages
English (en)
Other versions
KR960005063B1 (ko
Inventor
김흥곤
박상욱
배재호
Original Assignee
김흥기
금호석유화학 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 김흥기, 금호석유화학 주식회사 filed Critical 김흥기
Priority to KR1019930003238A priority Critical patent/KR960005063B1/ko
Publication of KR940021601A publication Critical patent/KR940021601A/ko
Application granted granted Critical
Publication of KR960005063B1 publication Critical patent/KR960005063B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 초기 중합단계와 완성 중합단계를 거치는 카르복시산모노머-스티렌-부타디엔 라텍스를 제조하는 방법에 있어서, 씨앗 라텍스를 합성하고는 초기 중합단계 또는 입자를 키워나가는 완성 중합단계에서 하이드록시기를 갖는 가교제를 투입하는 카르복시산모노머-스티렌-부타디엔 라텍스의 제조방법으로서 섬유와의 접착력 및 내수강도를 증가시킨 것이다.

Description

내수성과 접착력이 향상된 카페트용 라텍스의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 초기 중합단계(Pre-Polymerization)와 완성 중합단계(finish-polymerization)를 거치는 카르복시산 모노머-스티렌-부타디엔 라텍스를 제조하는 방법에 있어서, 씨앗(seed) 라텍스를 합성하고는 초기 중합단계 또는 입자를 키워 나가는 완성 중합단계에서 하이드록시기를 갖는 가교제를 투입하는 카르복시산모노머-스티렌-부타디엔 백본(backbone) 라텍스의 제조방법.
  2. 제 1 항에 있어서, 초기 중합단계에서 1~5중량부의 가교제, 0.5~2.0중량부의 카르복시산, 0.5~1.0중량부의 아크릴산, 2~8중량부의 스티렌, 10~20중량부의 부타디엔, 2.0~6.0중량부의 메틸메타크릴레이트, 0.1~1.0중량부의 티 도데실 메캅탄 및 적정의 첨가제를 투입하여 중합시키고 완성 중합단계에서 25~45중량부의 부타디엔, 20~40중량부의 스티렌, 5~15중량부의 메틸메타크릴레이트, 0.5~1.0중량부의 아크릴산, 0.1~1.0중량부의 티 도데실 메캅탄을 투입하여 합성하는 카르복시산모노머-스티렌-부타디엔 라텍스의 제조방법.
  3. 제 2 항에 있어서, 가교제가 엔 메칠올 아크릴아마이드인 카르복시산모노머-스티렌-부타디엔 라텍스의 제조방법.
  4. 제 1 항에 있어서, 초기 중합단계에서 0.5~2.0중량부의 카르복시산, 0.5~1.0중량부의 아크릴산, 4~10중량부의 스티렌, 10~20중량부의 부타디엔, 2.0~4.0중량부의 메틸메타크릴레이트, 0.1~1.0중량부의 티 도데실 메캅탄 및 적정의 첨가제를 투입하여 중합시키고 완성 중합단계에서 1~5중량부의 가교제, 25~45중량부의 부타디엔, 20~40중량부의 스티렌, 5~15중량부의 메틸메타크릴레이트, 0.5~1.0중량부의 아크릴산, 0.1~1.0중량부의 티 도데실 메캅탄을 투입하여 합성하는 카르복시산모노머-스티렌-부타디엔 라텍스의 제조방법.
  5. 제 4 항에 있어서, 가교제가 2-하이드록시에틸메타크릴레이트인 카르복시산모노머-스티렌-부타디엔 라텍스의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930003238A 1993-03-04 1993-03-04 내수강도가 우수한 카페트용 라텍스의 제조방법 KR960005063B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019930003238A KR960005063B1 (ko) 1993-03-04 1993-03-04 내수강도가 우수한 카페트용 라텍스의 제조방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019930003238A KR960005063B1 (ko) 1993-03-04 1993-03-04 내수강도가 우수한 카페트용 라텍스의 제조방법

Publications (2)

Publication Number Publication Date
KR940021601A true KR940021601A (ko) 1994-10-19
KR960005063B1 KR960005063B1 (ko) 1996-04-20

Family

ID=19351642

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930003238A KR960005063B1 (ko) 1993-03-04 1993-03-04 내수강도가 우수한 카페트용 라텍스의 제조방법

Country Status (1)

Country Link
KR (1) KR960005063B1 (ko)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107987204A (zh) * 2017-12-12 2018-05-04 杭州龙驹合成材料有限公司 一种低成膜温度的丁苯胶乳的制备方法

Also Published As

Publication number Publication date
KR960005063B1 (ko) 1996-04-20

Similar Documents

Publication Publication Date Title
KR960010700A (ko) 고성능 보호 테이프를 위한 라텍스
ATE278714T1 (de) Verfahren zur herstellung eines polymeren umsetzungsprodukts
MX9707436A (es) Adhesivo sensible a la presion.
ATE195328T1 (de) Geschützte funktionelle initiatoren zur herstellung von am kettenende funktionalisierte polymeren
ATE353673T1 (de) Superabsorbierender schaum, verfahren zu seiner herstellung und seine verwendung
ATE394434T1 (de) Verfahren zur herstellung von wetterbeständigem thermoplastischen harz
DE58902136D1 (de) Hydroxylgruppenhaltige copolymerisate auf der basis von vinylester-, vinylaromat- und hydroxylalkylester-monomeren, verfahren zu ihrer herstellung sowie ihre verwendung in beschichtungsmitteln.
DE3884050D1 (de) Verfahren zur Herstellung eines Emulsionspolymers.
DE50307516D1 (de) Hagelbeständiges verbund-acrylglas und verfahren zu seiner herstellung
EP0753566A3 (en) Fabric washing composition and method for inhibiting deposition of dye
DE3766751D1 (de) Dispersionspolymere, verfahren zu ihrer herstellung und ihre verwendung.
KR940021601A (ko) 내수성과 접착력이 향상된 카페트용 라텍스의 제조 방법
ATE394426T1 (de) Verfahren zur herstellung von sbr-kautschuken mit verbesserter verarbeitbarkeit und niedrigem rollwiderstand
EP0790261A3 (en) Process for preparing beads of polymers having an acrylic basis
DE69112902D1 (de) Verfahren zur Herstellung von Acrylpolymere in Suspension.
DE50004139D1 (de) Kohlenhydratlatices, Verfahren zu ihrer Herstellung und ihre Verwendung
ATE438674T1 (de) Verfahren zur herstellung von oxycarbonylpolymeren, funktionalisierung, hergestellte polymere und funktionalisierungsagens
KR970707187A (ko) 열분해로 유리기를 형성하는 기의 고무 내 혼입에 의한 고무 개질 성형 재료의 제조 방법(Process for Producing Modified Rubber Moulding Masses by lncorporating Groups Into the Rubber That form Radicals by Thermal Decomposition)
ATE259838T1 (de) Verfahren zum herstellen einer lösung von dienpolymerisaten in vinylaromatischen verbindungen sowie zum herstellen von schlagzähen vinylaromatischen polymeren durch polymerisation dieser lösung
ATE247137T1 (de) Verfahren zur herstellung von ethylen/(meth)acrylatcopolymerisaten mit geringem restcomonomergehalt
ATE261996T1 (de) Verfahren zur herstellung eines polymeren umsetzungsprodukts
DE50104224D1 (de) Verfahren zur herstellung eines katalysatorsystems für die polymerisation von olefinen
DE59008132D1 (de) Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten.
DE69816803D1 (de) Verfahren zur herstellung einer beschichtungsstoffzusammensetzung
JPS5521424A (en) Preparation of modified vinyl chloride resin

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20020308

Year of fee payment: 7

LAPS Lapse due to unpaid annual fee