KR940004092A - Manufacturing method of polyester maker - Google Patents

Manufacturing method of polyester maker Download PDF

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Publication number
KR940004092A
KR940004092A KR1019920015268A KR920015268A KR940004092A KR 940004092 A KR940004092 A KR 940004092A KR 1019920015268 A KR1019920015268 A KR 1019920015268A KR 920015268 A KR920015268 A KR 920015268A KR 940004092 A KR940004092 A KR 940004092A
Authority
KR
South Korea
Prior art keywords
polyester
reactive
alkyl group
lithium
manufacturing
Prior art date
Application number
KR1019920015268A
Other languages
Korean (ko)
Other versions
KR970010721B1 (en
Inventor
김우섭
김문찬
Original Assignee
구창남
동양나이론 주식회사
배도
동양폴리에스터 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 구창남, 동양나이론 주식회사, 배도, 동양폴리에스터 주식회사 filed Critical 구창남
Priority to KR1019920015268A priority Critical patent/KR970010721B1/en
Publication of KR940004092A publication Critical patent/KR940004092A/en
Application granted granted Critical
Publication of KR970010721B1 publication Critical patent/KR970010721B1/en

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/16—Physical properties antistatic; conductive

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

본 발명은 폴리에스터에 공중합성분을 첨가중합하여 제전성을 부여하는 것으로 공중합 성분으로 수평균 분자량이 2,000∼30,000인 일반식 (Ⅰ)의 폴리옥시알킬렌글리콜, 비반응성리튬 아미드 및 일반식 (Ⅱ)의 비반응성 알킬술폰산리튬염을 사용하는 것이며 섬유고유의 물성을 저해함이 없이 제전성능이 우수하여 의류용 및 기능복에 유용한 것이다.The present invention provides an antistatic property by adding a copolymerization component to a polyester to impart antistatic properties. The polyoxyalkylene glycol of general formula (I), non-reactive lithium amide and general formula (II) having a number average molecular weight of 2,000 to 30,000 as a copolymerization component It uses non-reactive alkyl sulfonate salt of) and it is useful for clothing and functional clothes because it has excellent antistatic performance without impairing the properties of fiber.

R1O(R2O)nH.........(Ⅰ)R 1 O (R 2 O) nH ......... (Ⅰ)

(상기에서, R1:C1∼C13인 알킬기 또는 H R2: C2∼C16인 알킬렌기 n:20∼150의 정수)(In the above, an integer of an alkyl group of R 1 : C 1 to C 13 or an alkylene group of HR 2 : C 2 to C 16 n: 20 to 150)

R3SO3Li.........(Ⅱ)R 3 SO 3 Li ......... (II)

(상기에서, R3:C3∼C25인 알킬기 또는 C7∼C30인 아릴기)(In the above, an alkyl group having R 3 : C 3 to C 25 or an aryl group having C 7 to C 30 )

Description

폴리에스터 제전사의 제조방법Manufacturing method of polyester maker

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (4)

폴리에스터에 공중합 성분을 첨가 중합하여 제전성을 부여함에 있어서, 공중합 성분으로 폴리옥시알킬렌글리콜 화합물 및 비반응성 알킬술폰산리튬염과 함께 비반응성 리튬아미드를 사용하는 것을 특징으로 하는 폴리에스터 제전사의 제조방법.In adding and copolymerizing a copolymerization component to polyester to impart antistaticity, a non-reactive lithium amide is used as a copolymerization component together with a polyoxyalkylene glycol compound and a non-reactive alkyl sulfonate lithium salt. Manufacturing method. 제1항에 있어서, 상기 비반응성 리튬아미드가 LiNH2, [(CH3)3Si2NLi, (C6H11)2NLi, [(CH3)2CH]2NLi 중에서 선택된 적어도 일종이고 함량이 폴리에스터 대비 0.001∼1중량%임을 특징으로 하는 폴리에스터의 제전사의 제조방법.The method of claim 1, wherein the non-reactive lithium amide is at least one selected from LiNH 2 , [(CH 3 ) 3 Si 2 NLi, (C 6 H 11 ) 2 NLi, [(CH 3 ) 2 CH] 2 NLi A method for producing a positive woven yarn of polyester, characterized in that 0.001 to 1% by weight relative to the polyester. 제1항에 있어서, 상기 폴리옥시알킬렌글리콜 화합물이 수평균분자량이 2,000 이상 30,000 이하인 하기 일반식(I)의 화합물이고 폴리에스터 전량 대비 0.01∼35중량%로 첨가하는 것을 특징으로 하는 폴리에스터제전사의 제조방법.The polyester agent according to claim 1, wherein the polyoxyalkylene glycol compound is a compound of formula (I) having a number average molecular weight of 2,000 or more and 30,000 or less and added at 0.01 to 35% by weight relative to the total amount of polyester. Method of Making a Transcription. (상기에서, Rl: C1∼C13인 알킬기 또는 H, R2: C2∼C16인 알킬렌기, n : 20∼150의 정수)(Wherein, R l: C 1 ~C 13 alkyl group or H, R 2: C 2 ~C 16 alkyl group, n: an integer of 20-150) 제1항에 있어서, 상기 비반응성 알킬술폰산리튬염이 하기 일반식(II)의 비반응성 폴리알킬술폰산리튬이고 폴리에스터 정량 대비 0.0l∼2중량%로 첨가함을 특징으로 하는 폴리에스터 제전사의 제조방법.The method of claim 1, wherein the non-reactive lithium lithium sulfonate salt is a non-reactive lithium polyalkyl sulfonate of the general formula (II) is added to the polyester quantitative agent of 0.01 to 2% by weight based on the amount of polyester Manufacturing method. (상기에서, R3: C3∼C25인 알킬기 또는 C7∼C30인 아릴기)(Wherein, R 3: C 3 ~C 25 alkyl group or C 7 ~C 30 aryl group) ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920015268A 1992-08-25 1992-08-25 Process for preparing antistatic electricity polyester fiber KR970010721B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019920015268A KR970010721B1 (en) 1992-08-25 1992-08-25 Process for preparing antistatic electricity polyester fiber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019920015268A KR970010721B1 (en) 1992-08-25 1992-08-25 Process for preparing antistatic electricity polyester fiber

Publications (2)

Publication Number Publication Date
KR940004092A true KR940004092A (en) 1994-03-14
KR970010721B1 KR970010721B1 (en) 1997-06-30

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ID=19338435

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920015268A KR970010721B1 (en) 1992-08-25 1992-08-25 Process for preparing antistatic electricity polyester fiber

Country Status (1)

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KR (1) KR970010721B1 (en)

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Publication number Publication date
KR970010721B1 (en) 1997-06-30

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