KR940001038B1 - Method of manufacturing bulletproof cloth - Google Patents

Method of manufacturing bulletproof cloth Download PDF

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Publication number
KR940001038B1
KR940001038B1 KR1019910024422A KR910024422A KR940001038B1 KR 940001038 B1 KR940001038 B1 KR 940001038B1 KR 1019910024422 A KR1019910024422 A KR 1019910024422A KR 910024422 A KR910024422 A KR 910024422A KR 940001038 B1 KR940001038 B1 KR 940001038B1
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South Korea
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cloth
inch
denier
bulletproof
weaving
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KR1019910024422A
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Korean (ko)
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KR930013671A (en
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최상렬
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주식회사 코오롱
하기주
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H1/00Personal protection gear
    • F41H1/02Armoured or projectile- or missile-resistant garments; Composite protection fabrics

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Woven Fabrics (AREA)

Abstract

A belletproof cloth is manufactured by twining Poly-P-Phenylene terephthalamide filament yarn of 0.7-1.5-denier single yarn, 1,000-2,200 number of filaments, and more than 20 g/d strength to 8-10 T/cm, spinning it into a weft thread of 30-35 lines/inch, and performing water-repellent treatment thereupon to weave a cloth having more than 1,500 feet/sec. bulletproof and 80 % water-repellency, thereby providing flexible bulletproof cloth having excellent bulletproof property by simple process while reducing weight thereof.

Description

방탄복용 포지(布地)의 제조방법Manufacturing method of bulletproof cloth

본 발명은 전방향족 폴리아미드섬유(Poly-P-Phenylene terephthalamide)(이하 아라미드섬유라 칭함)를 고밀도로 제직한 후, 발수처리를 함으로써 얻어지는 방탄복용 포지의 제조방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a method for producing anti-ballistic garments obtained by carrying out water repellent treatment after weaving poly-P-Phenylene terephthalamide (hereinafter referred to as aramid fibers) at high density.

종래에는, 나일론 직물을 수 내지 수십겹 적층하거나 아라미드 섬유와 교대로 적층하기도 하고, 여기에 열경화성 수지를 함침 또는 라미네이트 형태의 방법으로 방탄복용 포지를 제조하는 방법들이 제시되었다.Conventionally, several to tens of layers of nylon fabrics are laminated or alternately laminated with aramid fibers, and methods for manufacturing bulletproof cloth for impregnation with a thermosetting resin or in the form of a laminate have been proposed.

이러한 제조방법은 나일론 단독 또는 아라미드 섬유를 부분적으로 상호 적층하여 사용하기 때문에 중량이 높아지는 반면에 방탄성을 저하되고, 이를 개선하기 위해 열경화성 수지(페놀, 에폭시, 폴리비닐부틸렌 등)를 함침 내지는 라미네이팅 함으로써 방탄성은 개선되었으나, 열경화성 수지의 처리에 의해 직물의 유연성이 없어져 버리는 결점이 있었다.Such a manufacturing method increases the weight due to the use of nylon alone or partially laminated with aramid fibers, while lowering the ballistic resistance, and impregnating or laminating thermosetting resins (phenol, epoxy, polyvinyl butylene, etc.) to improve this. This improved the ballistic resistance, but there was a drawback that the flexibility of the fabric was lost by the treatment of the thermosetting resin.

이에, 본 발명에서는 이러한 문제점들을 개선하기 위해 열경화성 수지등을 처리하지 않고, 전방향족 폴리아미드선유 단독으로만으로 고밀도로 제직 및 발수처리를 하는 간단한 공정으로 중량을 감소시키고 유연성을 가지는, 방탄성이 우수한 방탄복용 포지를 제조하는 방법이다.Therefore, in the present invention, in order to improve these problems, the weight reduction and flexibility in the simple process of weaving and water-repellent treatment at high density with only the aromatic polyamide wire oil alone without treating the thermosetting resin, etc., have excellent ballistic resistance. It is a method of manufacturing a body armor forge.

본 발명을 상세히 설명하면, 전방향족 폴리아미드(Poly-P-Phenyleneterephthalamide)의 필라멘트섬유(모노피라멘트가 1.5 데니어 이하인)를 8-10 T/10cm로 연사(撚絲)하여 경사와 위사를 각 30-35본/인치로 고밀도 제직한 후, 불소(F)계 또는 실리콘계 발수제를 처리함으로써, 제조공정을 2단축시키고, 중량을 감소시키면서 우수한 방탄성과 발수성을 가지며, 수지 2리를 하지 않음으로써 직물에 유연성을 부여시키는, 방탄복용 포지를 제조할 수 있었다.When explaining the present invention in detail, the filament fibers (mono-pyramid is 1.5 denier or less) of the wholly aromatic polyamide (Poly-P-Phenylene terephthalamide) is twisted to 8-10 T / 10cm to each warp and weft 30 After high-density weaving at -35 sheets / inch, treatment with fluorine (F) or silicone-based water repellent agent can shorten the manufacturing process, reduce weight, have excellent ballistic resistance and water repellency, and do not use resin 2 The body armor for body armor can be manufactured which gives flexibility.

여기서, 전방향족 폴리아미드의 필라멘트섬유는 1,500데니어로 필라멘트수가 1,000-2,200개이고, 모노필라멘트 섬도가 1.5데이너, 바람직하게는 0.7-1.5데니어의 하이멀티 필라멘트(Hi-Multi Filament)사를 사용함으로써 방탄성을 증가시킬 수 있는데, 이는 동일 데니어에서 필라멘트가 가늘고 많아질수록 충격에 대한 흡수력이 증가될 수 있기 때문이다.Here, the filament fiber of the wholly aromatic polyamide is 1,500 denier, the number of filament is 1,000-2,200, the monofilament fineness is ballistic by using a high-density filament yarn of 1.5 denier, preferably 0.7-1.5 denier This can be increased because the thinner and more filaments in the same denier may increase the absorbency against impact.

아라미드 섬유는 필라멘트의 수가 많기 때문에 제직 특히, 고밀도 제직시에 제직성을 증가시켜 주고 원사의 강도를 일정 수준까지 상승시켜 주기 위해서 8-10T/10cm 정도의 연(撚)을 부여하는데, ST/10cm이하일 경우, 요구 수준으로의 강도 증가 목적을 달성할 수 없고, 또한 제직시 경사핌, 모우발생 등에 기인하여 절사의 원인이 될 수 있으므로 제직성이 저하된다.Since aramid fibers have a large number of filaments, in order to increase the weaving properties during weaving, especially high density weaving, and to increase the strength of the yarn to a certain level, aramid fibers are given about 8-10T / 10cm. In the case of the following, we cannot achieve the purpose of increasing the strength to the required level, and weaving is degraded because it may cause cutting due to warping, weeping and the like during weaving.

10T/10cm 이상일 경우, 과또한 연(撚)을 부여함으로써, 오히려 강도가 저하되고, 스날(snarl) 발생에 의해 역시 제직성이 불량해 지게 된다.In the case of 10T / 10cm or more, by providing excessive lead, the strength is lowered, and the weaving is also poor due to the generation of snarl.

방탄복은 파편에 의하는 제2차 충격에 대한 방어가 주목적이기 때문에 제직시 직물의 커버밀도가 각 30-35분/인치로 설계되어야 하며, 조직은 매트(Matt)직이어야 한다.Since body armor is primarily intended to protect against secondary impacts from debris, fabric weaves should be designed with a cover density of 30-35 minutes / inch and the tissue should be matte.

이와 같은 제직된 직물을 0.5-0.3%(ows)의 공지의 불소(F)계 또는 실리콘계 발수제로 함침, 처리한 후, 120-150℃에서 30-60초로 열처리함으로써, 직물의 표면에 발수 기능을 부여핼 줄 수 있다.This woven fabric is impregnated and treated with 0.5-0.3% (ows) of known fluorine (F) -based or silicone-based water repellent, and then heat-treated at 120-150 ° C. for 30-60 seconds to provide a water repellent function on the surface of the fabric. I can grant it.

이하 본 발명을 실시예 및 비교예에 의해 더욱 상세히 설명한다.Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples.

단, 본 발명이 실시예로 한정되는 것은 아니다.However, the present invention is not limited to the examples.

[실시예 1]Example 1

전방향족 폴리아미드(Poly-P-Phenylene-terphthalamide)의 필라멘트 섬유 1,500D/1,000F(단사데이너 1.5d, 강도 : 20g/d)를 8T/10cm의 연(撚)을 부여한 연사물을 경,위사로 하여 34×34본/인치의 밀도를 가지는 매트(Matt)조직으로 고밀도 제직한 후 1.5%(ows)의 불소(F)계 발수제로 150℃에서 30초간 열처리하였다.Filament fiber of poly-P-Phenylene-terphthalamide (Filament fiber 1,500D / 1,000F (Single yarn daily 1.5d, Strength: 20g / d)) After weaving a high-density into a matt (Matt) structure having a density of 34 × 34 pattern / inch, and heat-treated at 150 ℃ 30 seconds with 1.5% (ows) fluorine (F) -based water-repellent agent.

이를 임의의 크기로 집단, 8겹(ply)으로 하여 총 중량이 920g이 되게 하여 방탄성을 측정한다.The ballistic resistance was measured by setting the total weight to 920 g as a collective, 8 ply of any size.

[실시예 2]Example 2

전방향족 폴리아미드(Poly-P-Phenylene-terephthalamide)의 필라멘트 섬유 1,500D/2,140F(단사데니어 0.7d, 강도 : 20g/d)를 실시예1과 동일하게 방탄성을 측정한다.Filament fibers 1,500D / 2,140F (single denier 0.7d, strength: 20 g / d) of wholly aromatic polyamide (Poly-P-Phenylene-terephthalamide) were measured in the same manner as in Example 1.

[비교예 1]Comparative Example 1

나일론 6의 필라멘트 섬유 840 데니어를 36×36 본/인치의 밀도를 가지는 매트(Matt) 조직의 직물로 제직하여, 임의의 크기로 절단, 16겹(ply)으로 하여 총 중량이 968g이 되게 하여 방탄성을 측정한다.The filament fiber 840 denier of nylon 6 is woven into a matt tissue fabric having a density of 36 × 36 bones / inch, cut into arbitrary sizes, and made into 16 plies so that the total weight is 968 g. Measure the elasticity.

[비교예 2]Comparative Example 2

나일론 6의 필라멘트 섬유 840 데니어를 36×36 본/인치의 밀도를 가지는 매트(Matt)조직의 직물로 제직하고, 1,500데니어의 아라미드 필라멘트 섬유를 17×17 본/인치의 밀도를 가지는 매트(Matt)상 직물로 제직하여, 유기 용매를 함유하는 에폭시 수지용액에 침지하여, 직포의 수지 함량이 20-25wt%되게 한 뒤 열처리후, 나일론 직물을 12겹(ply)으로, 아라미드 직물을 4겹(ply)으로 상호 적층하여 고온에서 가열,가압하였다.Weaving nylon 6 filament fiber 840 denier into a fabric of Matt tissue having a density of 36 × 36 bones / inch, and 1,500 denier aramid filament fibers having a density of 17 × 17 bones / inch Weaving into a woven fabric, immersed in an epoxy resin solution containing an organic solvent to make the resin content of the woven fabric 20-25wt%, and after heat treatment, ply the nylon fabric into 12 ply and ply the aramid fabric into 4 ply ) Were laminated to each other and heated and pressed at high temperature.

이를 임의의 크기로 절단하여 총 중량이 1,210g이 되게 하여 방탄성을 측정한다.Cut it to any size so that the total weight is 1,210 g to measure the ballistic resistance.

[표 1]TABLE 1

Claims (1)

단사데니어 0.7-1.5, 필라멘트수 1,000-2,200, 강도 20g/d 이상인 전방향족 폴리아미드 필라멘트사를 8-10T/cm로 연사하여 이를 경위사로 30-35 본/인치로 제직한 후, 발수처리하여 제조된 포지가 방탄성 1,500 피이트/초 이상, 발수도 80%를 가짐을 특징으로 하는 유연성이 우수한 방탄복용 포지의 제조방법.Single yarn denier 0.7-1.5, filament number 1,000-2,200, totally aromatic polyamide filament yarn having a strength of 20g / d or more is twisted to 8-10T / cm, weaved it to 30-35 bone / inch with a light warp yarn, and then produced by water repellent treatment A method for producing flexible body armor having excellent flexibility, characterized in that the forge has a ballistic resistance more than 1,500 feet / second, water repellency 80%.
KR1019910024422A 1991-12-26 1991-12-26 Method of manufacturing bulletproof cloth KR940001038B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1396698A1 (en) * 2002-09-06 2004-03-10 Teijin Twaron GmbH Penetration-restistant material and articles made of the same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101223129B1 (en) * 2008-01-08 2013-01-17 코오롱인더스트리 주식회사 Woven fabric for bulletproof cloth and bulletproof cloth manufactured by the same

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1396698A1 (en) * 2002-09-06 2004-03-10 Teijin Twaron GmbH Penetration-restistant material and articles made of the same
WO2004023060A1 (en) * 2002-09-06 2004-03-18 Teijin Twaron Gmbh Penetration-resistant material and articles made of the same
US7153790B2 (en) 2002-09-06 2006-12-26 Teijin Twaron Gmbh Penetration-resistant material and articles made of the same
HRP20050274B1 (en) * 2002-09-06 2008-11-30 Teijin Aramid Gmbh Penetration-resistant material and articles made of the same

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