KR930021682A - Manufacturing method of polyester for film molding - Google Patents

Manufacturing method of polyester for film molding Download PDF

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Publication number
KR930021682A
KR930021682A KR1019920006392A KR920006392A KR930021682A KR 930021682 A KR930021682 A KR 930021682A KR 1019920006392 A KR1019920006392 A KR 1019920006392A KR 920006392 A KR920006392 A KR 920006392A KR 930021682 A KR930021682 A KR 930021682A
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KR
South Korea
Prior art keywords
polyester
producing
added
aluminosilicate
film molding
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Application number
KR1019920006392A
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Korean (ko)
Inventor
최우
박남규
최복돌
Original Assignee
하기주
주식회사 코오롱
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Publication date
Application filed by 하기주, 주식회사 코오롱 filed Critical 하기주
Publication of KR930021682A publication Critical patent/KR930021682A/en

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Abstract

테레프탈산을 주된 산성분으로 하고 에틸렌 글리콜을 주된 알콜 성분으로 하여 에스테르 교환 반응후 축중합 반응을 행하는 폴리에스테르 제조 방법에 있어서, 에스테르 교환 반응 종료후 축중합 반응 개시전 임의의 단계에 금속 화합물과 인화합물을 첨가하여 이어서 알루미노실리케이트를 에스테르 교환반응 생성물에 대하여 0.01∼0.1중량% 첨가하므로써 투명도와 이활성이 우수한 필름 성형용 폴리에스테르 제조방법.In a polyester production method wherein a polycondensation reaction is carried out after a transesterification reaction using terephthalic acid as a main acid component and ethylene glycol as a main alcohol component, a metal compound and a phosphorus compound are added at any stage before the start of the condensation polymerization reaction after the end of the transesterification reaction. A method for producing a polyester for film molding, which is excellent in transparency and activity by adding 0.01 to 0.1% by weight of aluminosilicate to the transesterification product.

Description

필름 성형용 폴리에스테르의 제조방법Manufacturing method of polyester for film molding

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (7)

에스테르 교환 반응 후, 축중합 반응으로 얻어지는 에틸렌 테레프탈레이트를 주된 반복 구조로 하는 필름 성형용 폴리에스테르의 제조방법에 있어서, 상기 에스테르화 반응 종료후 축중합 반응 개시전 임의의 단계에서 금속 화합물과 인 화합물을 첨가하고 이어서 알루미노실리케이트를 첨가하는 것을 특징으로 하는 필름 성형용 폴리에스테르의 제조방법.In the method for producing a polyester for film molding having an ethylene terephthalate obtained by a polycondensation reaction as a main repeating structure after a transesterification reaction, a metal compound and a phosphorus compound are added at any stage before the start of the polycondensation reaction after the completion of the esterification reaction. A method for producing a polyester for film molding, which is added followed by addition of aluminosilicate. 제1항에 있어서, 상기 알루미노실리케이트의 첨가량이 에스테르 교환반응 생성물에 대하여 0.01∼0.1중량%인 것을 특징으로 하는 필름 성형용 폴리에스테르의 제조방법.The method for producing a polyester for film molding according to claim 1, wherein the amount of the aluminosilicate added is 0.01 to 0.1% by weight based on the transesterification product. 제1항에 있어서, 상기 금속화합물은 마그네슘 화합물, 망간화합물 중에서 선택되어지는 적어도 1종 이상의 금속화합물인 것을 특징으로 하는 필름 성형용 폴리에스테르의 제조방법.The method of claim 1, wherein the metal compound is at least one metal compound selected from magnesium compounds and manganese compounds. 제1항 내지 제3항중 어느 하나의 항에 있어서, 상기 금속 산화물의 첨가량은 금속 원소를 기준으로 하여 에스테르 교환반응 생성물에 대하여 50∼200ppm인 것을 특징으로 하는 필름 성형용 폴리에스테르의 제조방법.The method for producing a polyester for film forming according to any one of claims 1 to 3, wherein the amount of the metal oxide added is 50 to 200 ppm with respect to the transesterification product based on the metal element. 제1항에 있어서, 상기 인화합물은 트리알킬포스페이트로써, 상기 금속 화합물에 대하여 당량비로 0.7∼1.3되도록 첨가되는 것을 특징으로 하는 필름 성형용 폴리에스테르의 제조방법.The method of claim 1, wherein the phosphorus compound is a trialkyl phosphate, and is added in an equivalence ratio of 0.7 to 1.3 with respect to the metal compound. 제1항에 있어서, 상기 알루미노실리케이트는 그 화합구조가 SiO2·Na2O·Al2O3이며, 이들의 구성비는 SiO240∼50중량%, Na2O 5∼10중량% 및 Al2O330∼40중량%인 것을 특징으로 하는 필름 성형용 폴리에스테르의 제조방법.According to claim 1, wherein the aluminosilicate is a compound structure of SiO 2 · Na 2 O · Al 2 O 3 , the composition ratio of these 40 to 50% by weight of SiO 2 , 5 to 10% by weight of Na 2 O and Al 2 O 3 30~40 process for producing a polyester film for forming which is characterized in that the percent by weight. 제1항에 있어서, 상기한 알루미노실리케이트는 평균 입경 0.8∼2.5㎛, 굴절률 1.49∼1.72인 것을 특징으로 하는 필름 성형용 폴리에스테르의 제조방법.The method for producing a polyester for film molding according to claim 1, wherein the aluminosilicate has an average particle diameter of 0.8 to 2.5 µm and a refractive index of 1.49 to 1.72. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920006392A 1992-04-16 Manufacturing method of polyester for film molding KR930021682A (en)

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KR930021682A true KR930021682A (en) 1993-11-22

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