KR930019851A - Elastic metallized film and manufacturing method thereof - Google Patents

Elastic metallized film and manufacturing method thereof Download PDF

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KR930019851A
KR930019851A KR1019930003596A KR930003596A KR930019851A KR 930019851 A KR930019851 A KR 930019851A KR 1019930003596 A KR1019930003596 A KR 1019930003596A KR 930003596 A KR930003596 A KR 930003596A KR 930019851 A KR930019851 A KR 930019851A
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elastic
film
metallization
fibers
metallic coating
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KR1019930003596A
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Korean (ko)
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KR100275423B1 (en
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코헨 버나드
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마틴 에이취. 마이클
킴벌리-클라크코퍼레이션
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C23C14/20—Metallic material, boron or silicon on organic substrates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34—Sputtering
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

본 발명은 탄성 필름과, 이 필름의 적어도 한쪽 면의 적어도 일부분을 실질적으로 피복하는 금속성 코팅으로 이루어진 탄성 금속화 필름을 개시하고 있다. 탄성 필름은 열경화성 탄성 재료, 열가소성 탄성 재료 또는 천연폴리머 탄성 재료로 부터 형성될 수 있다. 필름은 또한 세공성이고(이거나)미세 천공될 수 있다. 탄성 금속화 필름은 두께가 약 1나노미터 내지 약 5미크론 범위이고, 필름이 약 25퍼센트 이상 신장할 때도 금속성 코팅은 필름상에 여전히 남아 있는다. 탄성 금속화 필름은 다른 재료와 접합시킴으로써 다층 재료를 형성할 수 있다. 또한, 본 발명은 탄성 금속화 필름의 제조 방법을 개시하고 있다.The present invention discloses an elastic metallized film consisting of an elastic film and a metallic coating substantially covering at least a portion of at least one side of the film. The elastic film may be formed from a thermosetting elastic material, a thermoplastic elastic material or a natural polymer elastic material. The film may also be porous and / or microperforated. Elastic metallized films range in thickness from about 1 nanometer to about 5 microns and the metallic coating still remains on the film even when the film is stretched by at least about 25 percent. The elastic metallized film can form a multilayer material by bonding with other materials. The present invention also discloses a method for producing an elastic metallized film.

Description

탄성 금속화 필름 및 그의 제조방법.Elastic metallized film and its manufacturing method.

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 탄성 금속화 필름을 제조하기 위한 예시적 공정의 설명도.1 is an explanatory diagram of an exemplary process for producing an elastic metallized film.

제2도는 비신장 상태에 있는 동안 코팅된 탄성 금속화 필름의 비신장된 예의 현미경 사진.2 is a micrograph of an unextended example of an elastic metallized film coated while in an unextended state.

제3도는 신장 상태에 있는, 제2도에 도시된 예시적인 탄성 금속화 필름 일부분의 현미경 사진.3 is a micrograph of a portion of the exemplary elastic metallization film shown in FIG. 2 in an extended state.

Claims (31)

탄성 필름 및 이 탄성 필름의 적어도 한쪽 면의 적어도 일부분을 실질적으로 피복하는 금속성 코팅으로 이루어지는 탄성 금속화 필름.An elastic metallized film comprising an elastic film and a metallic coating substantially covering at least a portion of at least one side of the elastic film. 제1항에 있어서, 탄성 필름이 열경화성 탄성 필름인 탄성 금속화 필름.The elastic metallized film of claim 1, wherein the elastic film is a thermosetting elastic film. 제1항에 있어서, 탄성 필름이 열가소성 탄성 필름인 탄성 금속화 필름.The elastic metallization film of claim 1, wherein the elastic film is a thermoplastic elastic film. 제1항에 있어서, 탄성 필름이 세공성 탄성 필름인 탄성 금속화 필름.The elastic metallized film according to claim 1, wherein the elastic film is a pore elastic film. 제1항에 있어서, 탄성 필름이 미세 천공된 탄성 필름인 탄성 금속화 필름.The elastic metallized film according to claim 1, wherein the elastic film is a microperforated elastic film. 제1항에 있어서, 탄성 필름이 탄성 폴리에스테르, 탄성 폴리우레탄, 탄성 폴리아미드, 에틸렌과 1종 이상의 비닐 모노머와의 탄성 코폴리머 및 탄성 A-B-A′블록 코폴리머(A및 A′는 서로 동일 또는 상이한 열가소성 폴리머이고, B는 탄성 폴리머 블록임)로 이루어진 군으로부터 선택된 탄성 폴리머로 이루어지는 탄성 금속화 필름.The elastic film, elastic polyurethane, elastic polyamide, elastic copolymer of ethylene and at least one vinyl monomer, and elastic ABA 'block copolymer (A and A') are the same or different from each other. Thermoplastic polymer, and B is an elastomeric polymer block. 제6항에 있어서, 탄성 폴리머가 가공 제조와 함께 블렌드 되는 탄성금속화 필름.The elastomeric metallization film of claim 6, wherein the elastic polymer is blended with the fabrication preparation. 제6항에 있어서, 탄성 폴리머가 점착성 부여 수지와 함게 블렌드되는 탄성 금속화 필름.The elastic metallization film of claim 6, wherein the elastic polymer is blended with the tackifying resin. 제8항에 있어서, 블렌드가 가공 제조를 추가로 함유하는 탄성 금속화 필름.The elastic metallization film of claim 8, wherein the blend further contains a processed preparation. 제1항에 있어서, 탄성 필름이 추가로 필름의 적어도 일면에 봉입된 1종 이상의 다른 분말상 재료를 함유하는 탄성 금속화 필름.The elastic metallization film of claim 1, wherein the elastic film further comprises at least one other powdered material encapsulated on at least one side of the film. 제10항에 있어서, 분말상 재료가 목재 펄프, 비탄성 섬유, 입상물 및 이들의 혼합물로 이루어지는 군으로부터 선택되는 탄성 금속화 필름.The elastic metallization film of claim 10 wherein the powdery material is selected from the group consisting of wood pulp, inelastic fibers, granular materials, and mixtures thereof. 제11항에 있어서, 비탄성 섬유가 폴리에스테르 섬유, 폴리아미드 섬유, 유리섬유, 폴리올레핀 섬유, 셀룰로오스 유도 섬유, 다성분 섬유, 천연 섬유, 흡수성 섬유, 전기 전도성 섬유 또는 이들 비탄성 섬유의 2종 이상의 블렌드로 이루어지는 군으로부터 선택되는 탄성 금속화 필름.The method of claim 11, wherein the inelastic fibers are polyester fibers, polyamide fibers, glass fibers, polyolefin fibers, cellulose derived fibers, multicomponent fibers, natural fibers, absorbent fibers, electrically conductive fibers, or blends of two or more of these inelastic fibers. An elastic metallized film selected from the group consisting of. 제11항에 있어서, 입상 물질이 활성탄, 점토, 전분, 금속 산화물 및 초흡수성 물질로 이루어지는 군으로부터 선택되는 탄성 금속화 필름.12. The elastic metallized film of claim 11 wherein the particulate material is selected from the group consisting of activated carbon, clay, starch, metal oxides and superabsorbent materials. 제1항에 있어서, 필름이 약 0.00064 내지 약 0.076㎝(약 0.25 내지 약 30mil)범위의 평균 두께를 갖는 탄성 금속화 필름.The elastic metallization film of claim 1, wherein the film has an average thickness in the range of about 0.00064 to about 0.076 cm (about 0.25 to about 30 mil). 제11항에 있어서, 필름이 약 0.0020 내지 약 0.025㎝(약 0.8 내지 약 10mil)의 범위의 평균 두께를 갖는 탄성 금속화 필름.The elastic metallized film of claim 11 wherein the film has an average thickness in the range of about 0.0020 to about 0.025 cm (about 0.8 to about 10 mil). 제12항에 있어서, 필름이 약 0.0025 내지 0.0051㎝(약 1 내지 약 2mil)의 범위의 평균 두께를 갖는 탄성 금속화 필름.The elastic metallization film of claim 12, wherein the film has an average thickness in the range of about 0.0025 to 0.0051 cm (about 1 to about 2 mil). 제1항에 있어서, 금속성 코팅이 알루미늄, 구리, 주석, 아연, 납, 니켈, 철, 금, 은, 구리 기재 합금, 알루미늄 기재 합금, 티타늄 기재 합금 및 철 기재 합금으로 이루어지는 군으로부터 선택되는 탄성 금속화 필름.The elastic metal of claim 1, wherein the metallic coating is selected from the group consisting of aluminum, copper, tin, zinc, lead, nickel, iron, gold, silver, copper base alloys, aluminum base alloys, titanium base alloys, and iron base alloys. Sum film. 제17항에 있어서, 금속성 코팅이 다중 층으로 이루어지는 탄성 금속화 필름.18. The elastic metallization film of claim 17, wherein the metallic coating consists of multiple layers. 제1항에 있어서, 금속성 코팅의 두께가 약 1나노미터 내지 약 5미크론 범위인 탄성 금속화 필름.The elastic metallization film of claim 1, wherein the metallic coating has a thickness in the range of about 1 nanometer to about 5 microns. 제19항에 있어서, 금속성 코팅의 두께가 약 5나노미터 내지 약 1미크론 범위인 탄성 금속화 필름.20. The elastic metallization film of claim 19, wherein the metallic coating has a thickness in the range of about 5 nanometers to about 1 micron. 제20항에 있어서, 금속성 코팅의 두께가 약 10나노미터 내지 약 500나노미터 범위인 탄성 금속화 필름.21. The elastic metallization film of claim 20, wherein the metallic coating has a thickness in the range of about 10 nanometers to about 500 nanometers. 제1항에 있어서, 필름이 약 25퍼센트 이상 신장되었을 때, 그의 금속성 코팅을 실질적으로 전부 보유하도록 제작된 것인 탄성 금속화 필름.The elastic metallization film of claim 1, wherein the elastic metallization film is constructed to retain substantially all of its metallic coating when the film is stretched at least about 25 percent. 제22항에 있어서, 필름이 약 30퍼센트 내지 약 100퍼센트 신장되었을 때, 그의 금속성 코팅을 실질적으로 전부 보유하도록 제작된 것인 탄성 금속화 필름.23. The elastic metallized film of claim 22 wherein the film is made to retain substantially all of its metallic coating when the film is stretched from about 30 percent to about 100 percent. 적어도 1개층이 제1항의 탄성 금속화 필름으로 이루어지는 다층 재료.A multilayer material comprising at least one layer of the elastic metallization film of claim 1. 탄성 필름을 제공하는 단계 및 이 탄성 필름의 적어도 한쪽면의 적어도 일부분을 금속화시켜서 그 부분을 금속성 코팅으로 실질적으로 피복하는 단계로 이루어지는 탄성 금속화 필름이 제조방법A method for producing an elastic metallized film, comprising providing an elastic film and metallizing at least a portion of at least one side of the elastic film to substantially cover the portion with a metallic coating. 제25항에 있어서, 탄성 필름의 금속화가 금속 증착 또는 금속 스퍼터링에 의해 달성되는 방법.The method of claim 25, wherein metallization of the elastic film is achieved by metal deposition or metal sputtering. 제25항에 있어서, 탄성 필름이 금속화 단계 동안 냉각되는 방법.The method of claim 25, wherein the elastic film is cooled during the metallization step. 제25항에 있어서, 탄성 필름을 금속화시키기 전에 탄성 필름의 표면을 전처리하는 단계를 추가로 포함하는 방법.The method of claim 25, further comprising pretreating the surface of the elastic film before metallizing the elastic film. 제25항에 있어서, 탄성 필름을 연신시키고 그것을 금속화 단계 동안 연신된 상태로 유지시키는 단계를 추가로 포함하는 방법.27. The method of claim 25, further comprising stretching the elastic film and keeping it stretched during the metallization step. 제29항에 있어서, 탄성 필름이 약 10퍼센트 이상 연신되는 방법.The method of claim 29, wherein the elastic film is stretched at least about 10 percent. 제30항에 있어서, 탄성 필름이 약 15퍼센트 내지 약 500퍼센트 연신되는 방법.The method of claim 30, wherein the elastic film is stretched from about 15 percent to about 500 percent. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930003596A 1992-03-12 1993-03-11 Elastic metallized film and process for making same KR100275423B1 (en)

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US84985392A 1992-03-12 1992-03-12
US07/849,853 1992-03-12
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JP3655616B2 (en) 2003-03-19 2005-06-02 ファナック株式会社 Injection molding machine
JP4602654B2 (en) * 2003-08-29 2010-12-22 株式会社フルヤ金属 Thin film layer forming elastomer molding
US7666494B2 (en) * 2005-05-04 2010-02-23 3M Innovative Properties Company Microporous article having metallic nanoparticle coating
KR100952172B1 (en) 2008-03-28 2010-04-09 안우영 Patten sputtering apparatus for direct patten forming and method for circuit forming of flexible printed circuit board
US20100209672A1 (en) * 2009-02-17 2010-08-19 Yahya Hodjat Metallic Layer Membrane
JP5954583B2 (en) * 2012-11-20 2016-07-20 東レフィルム加工株式会社 Method for producing metallized porous sheet, and laminate comprising metallized porous sheet
JP6413116B2 (en) * 2014-10-31 2018-10-31 北川工業株式会社 Sliding resistant conductive cloth
KR102045927B1 (en) * 2018-01-17 2019-11-18 울산과학기술원 Stretchable electrode with controlled transmittance, manufacturing method thereof, and device comprising the same
CN114134464A (en) * 2021-10-26 2022-03-04 惠州市华阳光学技术有限公司 Structural color pigment and preparation method thereof

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DE68925580T2 (en) * 1989-04-14 1996-09-19 Katayama Tokushu Kogyo Kk Process for the production of a porous metallic foil
CA2073783A1 (en) * 1992-03-12 1993-09-13 Kimberly-Clark Corporation Elastomeric metallized fabric and process to make the same

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JPH0639960A (en) 1994-02-15
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