KR930019109A - Synergistic herbicides and safeners - Google Patents

Synergistic herbicides and safeners Download PDF

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Publication number
KR930019109A
KR930019109A KR1019930004620A KR930004620A KR930019109A KR 930019109 A KR930019109 A KR 930019109A KR 1019930004620 A KR1019930004620 A KR 1019930004620A KR 930004620 A KR930004620 A KR 930004620A KR 930019109 A KR930019109 A KR 930019109A
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South Korea
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alkoxy
compound
alkyl
herbicide
halogen
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KR1019930004620A
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Korean (ko)
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KR100320834B1 (en
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슈베르트 한스-헤르베르트
다께히꼬 나까지마
바우어 클라우스
비링거 헤르만
해커 에르윈
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마이어, 마르쿠아르트
훽스트 아크티엔게젤샤프트
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

본 발명은 단자엽 식물 및 쌍자엽 식물 잡초에 대해 사용할 수 있는 작물 보호제에 관한 것이다. 상승 작용적으로 증가된 제초활성은 제초제 A 및 B의 혼합물을 사용하여 수득하며, 여기서 제초제 A는 제1항에서 정의된 하기 일반식(Ⅰ)의 치환된 N-페녹시설포닐-N′-(4,6-이치환된 피리미드-2-일)우레아를 나타내며;제초제 B는 퀸클로락, 몰리네이트, 티오벤카브, 부타클로르, 프레틸라 클로르, 디티오피르, 메페나셋, 페녹사프로프-에틸, 디메피페레이트, 피라졸리네이트(피라졸레이트), 피라족시펜, 벤조페나프, 나프로 아닐리드, 벤설푸른-메틸, 피라조설푸론-에틸, 시노설푸론, 벤푸레세이트, 브로모부티드, 다이무론, 디메타메트린, 에스프로카브, 피리부티카브, 부테나클로르, 피페로포스, 아닐로포스, 신메틸린, 프로파닐, 아마조설푸픈, NSK-850, HW-SZ, JC-940, CH-900 및/ 또는 ICIA-0051이다.The present invention relates to crop protection agents which can be used for monocotyledonous and dicotyledonous weeds. Synergistically increased herbicidal activity is obtained using a mixture of herbicides A and B, where herbicide A is substituted N-phenoxysulfonyl-N '-(of formula (I) 4,6-disubstituted pyrimid-2-yl) urea; herbicide B is quinclolac, molinate, thiobencarb, butachlor, pretilla chlor, dithiopyr, mefenacet, phenoxaprop Ethyl, dimepiperate, pyrazolinate (pyrazolate), pyrazoxifen, benzophenaf, naproanilide, bensulfur-methyl, pyrazosulfuron-ethyl, cynosulfuron, benfurate, bromobu Tied, dimuron, dimethamethrin, esprocarb, pyributycarb, butenaclor, piperophos, anilofos, citmethyllin, propanyl, amazosulfufne, NSK-850, HW-SZ, JC -940, CH-900 and / or ICIA-0051.

Description

상승 작용성 제초제 및 독성완화제Synergistic herbicides and safeners

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (19)

효과량의 하기 성분(A)를 (B1) 내지(B33)으로 이루어진 그룹중에서 선택된 하기 성분(B)와 함께 포함하는 제초제(단, 효과량의 성분(A)를 (B1) 내지 (B9), (B14) 내지 (B16) 및 (B28)을 포함하는 그룹중에서 선택된 단지 하나의 화합물(B)와 함께 함유하는 제초제는 제외된다). (A)하기 일반식(Ⅰ)의 화합물 또는 그의 염 :Herbicides comprising an effective amount of the following component (A) together with the following component (B) selected from the group consisting of (B1) to (B33), provided that the effective amount of component (A) is (B1) to (B9), Herbicides containing with only one compound (B) selected from the group comprising (B14) to (B16) and (B28) are excluded). (A) the compound of the following general formula (I) or a salt thereof: [상기식에서, (a)R1이 에록시, 프로폭시 또는 이소프로폭시이고, R2가 할로겐, NO2, CF3, CN, C1-C4-알킬, C1-C4-라콕시, C1-C4-알킬티오 또는 (C1-C4-알콜시)카보닐이고, n이 0, 1, 2 또는 3이거나; 또는 (a2)R1이 할로겐에 의해 치환된 임의의 불포화 C1-C6-알콕시, 임의의 불포화(C1-C6-알콕시, 일반식(C|1-C6-알킬)-S-(C1-C6-알킬)-SO-, (C1-C6-알킬)-SO2-, (C1-C6-알킬)-O-CO-의 라디칼, NO2, CN 또는 페닐; 또한 C2-C8-알케닐옥시 또는 -알키닐옥시이고, R2가 각각 할로겐, C1-C|4-알콕시 또는 C1-C4-알킬티오에 의해 치환될 수 있는 포화 또는 불포화 C1-C8-알킬, 페닐, 페녹시, C1-C4-알콕시, C1-C4-알킬티오, (C1-C4-알콕시)카보닐이거나, 또는 할로겐, NO2, C1-C4-알킬설포닐 또는 -알킬설피닐이고, n이 0, 1, 2 또는 3이거나; 또는 (a3)R1이 C1-C8-알콕시이고, R2가 각각 비치환되거나 할로겐, C1-C4-알콕시 또는 -알킬티오에 의해 치환된 C1-C4-알케닐 또는 -알키닐, 페닐 또는 페녹시이거나, 또는 C2-C|8-알킬설포닐 또는 -알킬 설피닐이고, n이 1,2 또는 3이거나; 또는 (a4)R1이, 각 경우에 페닐 라디칼상의 2-위치에서, 할로겐, 메톡시, 에틸 또는 프로필이고, R2가 페닐 라디칼상의 6-위치에서 (C1-C4-알콕시)카보닐이고, n이 1이며, 상기(a1) 내지 (a4)모두에서, R2은 수소, 포화 또는 불포화 C1-C8-알킬 또는 C1-C4-알콕시이고, R4및 R5는 서로 독립적으로 수소, 할로겐, C1-C4-알킬, C1-C4-알콕시 또는 C|1-C4-알킬티오(이들중 마지막 3개의 라디칼은 비치환되거나 할로겐, C1-C4-알콕시 또는 C1-C4-알킬티오에 의해 치환된다)이고, Y는 O 또는 S이고, E는 CH 또는 N이다]; (B)하기 (B1) 내지 (B33) 을 포함하는 그룹중에서 선택된 1개, 2개 또는 그 이상의 화합물 : B1)3,7-디클로로퀴놀린-8-카복실산 및 그의 염(퀸클로락)[Wherein (a) R 1 is ethoxy, propoxy or isopropoxy, and R 2 is halogen, NO 2 , CF 3 , CN, C 1 -C 4 -alkyl, C 1 -C 4 -lacockoxy , C 1 -C 4 -alkylthio or (C 1 -C 4 -alkoxy) carbonyl, n is 0, 1, 2 or 3; Or (a 2 ) any unsaturated C 1 -C 6 -alkoxy, R 1 is substituted by halogen, any unsaturated (C 1 -C 6 -alkoxy, general formula (C | 1 -C 6 -alkyl) -S - (C 1 -C 6 - alkyl) -SO-, (C 1 -C 6 - alkyl) -SO 2 -, (C 1 -C 6 - alkyl) -O-CO- of a radical, NO 2, CN or Phenyl; also C 2 -C 8 -alkenyloxy or -alkynyloxy, saturated or wherein R 2 can be substituted by halogen, C 1 -C | 4 -alkoxy or C 1 -C 4 -alkylthio, respectively Unsaturated C 1 -C 8 -alkyl, phenyl, phenoxy, C 1 -C 4 -alkoxy, C 1 -C 4 -alkylthio, (C 1 -C 4 -alkoxy) carbonyl, or halogen, NO 2 , C 1 -C 4 -alkylsulfonyl or -alkylsulfinyl, n is 0, 1, 2 or 3; or (a 3 ) R 1 is C 1 -C 8 -alkoxy and R 2 is each unsubstituted Or C 1 -C 4 -alkenyl or -alkynyl, phenyl or phenoxy, or substituted by halogen, C 1 -C 4 -alkoxy or -alkylthio, or C 2 -C | 8 -alkylsulfonyl or- Alkyl sulfinyl And n is 1,2 or 3; or (a 4 ) R 1 is in each case 2-position on the phenyl radical, halogen, methoxy, ethyl or propyl, and R 2 is 6-position on the phenyl radical Is (C 1 -C 4 -alkoxy) carbonyl, n is 1 and in all of (a 1 ) to (a 4 ) above, R 2 is hydrogen, saturated or unsaturated C 1 -C 8 -alkyl or C 1 -C 4 -alkoxy, R 4 and R 5 are independently of each other hydrogen, halogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or C | 1 -C 4 -alkylthio (the last 3 of which are Radicals are unsubstituted or substituted by halogen, C 1 -C 4 -alkoxy or C 1 -C 4 -alkylthio), Y is O or S and E is CH or N]; One, two or more compounds selected from the group comprising (B1) to (B33): B1) 3,7-dichloroquinoline-8-carboxylic acid and salts thereof (quinchlorac) B2)N-(에틸티오카보닐)아제판(몰리네이트),B2) N- (ethylthiocarbonyl) azepan (molinate), B3)S-4-클로벤질 디에틸(티오카바메이트)(티오벤카브),B3) S-4-clobenzyl diethyl (thiocarbamate) (thiobencarb), B4)N-(부톡시메틸)-2-클로로-N-(2,6-디에틸-페닐)아세트아미드(부타클로로)B4) N- (butoxymethyl) -2-chloro-N- (2,6-diethyl-phenyl) acetamide (butachloro) B5)N-(2-프로폭시에틸)-2-클로로-N-(2,6-디에틸-페닐)아세트아미드(프레틸라클로르)B5) N- (2-propoxyethyl) -2-chloro-N- (2,6-diethyl-phenyl) acetamide (pretilachlor) B6)3,5-비스(메틸티오카보닐)-2-디플루오로메틸-4-(2-메틸프로필)-6-트리플루오로메틸피리딘, (MON-7200, 디티오피르)B6) 3,5-bis (methylthiocarbonyl) -2-difluoromethyl-4- (2-methylpropyl) -6-trifluoromethylpyridine, (MON-7200, dithiopyr) B7)2-(1,3-벤조티아졸-2-일옥시)-N-메틸-아세트아닐리드, (메페나셋)B7) 2- (1,3-benzothiazol-2-yloxy) -N-methyl-acetanilide, (mefenacet) B8)에틸 2-[4-(6-클로로벤즈옥사졸-2-일옥시)페녹시]프로피오네이트,(페녹사프로프-에틸)B8) ethyl 2- [4- (6-chlorobenzoxazol-2-yloxy) phenoxy] propionate, (phenoxaprop-ethyl) B9)N-(2-페닐프로프-2일티오카보닐)피페리딘 (MY-93, 디메피퍼레이트)B9) N- (2-phenylprop-2ylthiocarbonyl) piperidine (MY-93, dimeperperate) B10)4-(2,4-디클로로벤조일)-1,3-디메틸파라졸-5-일-툴루엔-4-설포네이트(피라졸리네이트, 피라졸레이트)B10) 4- (2,4-Dichlorobenzoyl) -1,3-dimethylparazol-5-yl-toluene-4-sulfonate (pyrazolinate, pyrazolate) B11)2-[4-(2,4-디클로로벤조일)-1,3-디메틸-피라졸-5-일옥시]아세토페논(피라족시펜)B11) 2- [4- (2,4-Dichlorobenzoyl) -1,3-dimethyl-pyrazol-5-yloxy] acetophenone (pyrazoxifen) B12)2-[4-(2,4-디클로로-m-톨루오일)-1,3-디메틸-파라졸-5-일옥시]-4′-메틸아세토페논(벤조페나프),B12) 2- [4- (2,4-Dichloro-m-toluoyl) -1,3-dimethyl-parazol-5-yloxy] -4'-methylacetophenone (benzophenaf), B13)2-(2-나프틸옥시)프로피온아닐리드(나프로아닐리드),B13) 2- (2-naphthyloxy) propionanilide (naproanilide), B14)메틸 α-(4,6-디메톡시피리미딘-2-일-카바모일설파모일)-0-톨루레이트(벤설푸른-메틸)B14) methyl α- (4,6-dimethoxypyrimidin-2-yl-carbamoylsulfamoyl) -0-tolurate (bensulfur-methyl) B15)메틸-5-(4,6-디메톡시피리미딘-2-일-카바모일설파모일)-1-메틸피라졸-4-카복실레이트(피라조설푸론-에틸)B15) methyl-5- (4,6-dimethoxypyrimidin-2-yl-carbamoylsulfamoyl) -1-methylpyrazole-4-carboxylate (pyrazosulfuron-ethyl) B16)1-(4,6-디메톡시-1,3,5-트리아진-2-일)-3-[2-(2-메톡시에톡시)페닐설포닐]우레아(시노설푸론),B16) 1- (4,6-dimethoxy-1,3,5-triazin-2-yl) -3- [2- (2-methoxyethoxy) phenylsulfonyl] urea (cynosulfuron), B17)2,3-디하이드로-3,3-디메틸벤조푸란-5-일에 탄설포네이트(벤프레세이트),B17) 2,3-dihydro-3,3-dimethylbenzofuran-5-yl tansulfonate (benpresate), B18)2-브로모-3,3-디메틸-N-(1-메틸-1-페닐-에틸)부티르아미드(브로모부티드),B18) 2-bromo-3,3-dimethyl-N- (1-methyl-1-phenyl-ethyl) butyramide (bromobutide), B19)1-(1-메틸-1-페닐에틸)-3-p-톨릴우레아(디므론, 다이무론)B19) 1- (1-methyl-1-phenylethyl) -3-p-tolylurea (dimron, dimuron) B20)N-(1,2-디메틸프로필)-N4-에틸-6-메틸티오-1,3,5-트리아진-2,4-디아민(디메타메트린),B20) N- (1,2-dimethylpropyl) -N 4 -ethyl-6-methylthio-1,3,5-triazine-2,4-diamine (dimethatrin), B21)S-벤질 1,2-디메틸프로필(에틸)티오카바메이트(에스프로카브),B21) S-benzyl 1,2-dimethylpropyl (ethyl) thiocarbamate (esprocarb), B22)O-3-3급-부틸페닐-6-메톡시-2-피리딜(메틸)티오카바메이트(피리부티카브, TSH-888)B22) O-3-tert-butylphenyl-6-methoxy-2-pyridyl (methyl) thiocarbamate (pyributycarb, TSH-888) B23)(Z)-N-부트-2-에닐옥시메틸-2-클로로-2′,6′-디에틸 아세트아닐리드(부테나클로르, KH-218),B23) (Z) -N-but-2-enyloxymethyl-2-chloro-2 ', 6'-diethyl acetanilide (butenachlor, KH-218), B24)S-2-메틸피레리디카보닐메틸 O,O-디프로필포스포로디티오에이트(피페로포스)B24) S-2-methylpyrididicarbonylmethyl O, O-dipropylphosphorodithioate (piperophosph) B25)S-4-클로로-N-이소프로필카바닐로일메틸 O,O-디메틸 포스포로디티오에이트(아닐로포스),B25) S-4-chloro-N-isopropylcarbanyloylmethyl O, O-dimethyl phosphorodithioate (anilofoss), B26) (1RS,2SR,4SR)-1,4-에폭시-p-멘트-2-일 2-메틸-벤질 에테르(신메틸린),B26) (1RS, 2SR, 4SR) -1,4-epoxy-p-ment-2-yl 2-methyl-benzyl ether (cinmethylline), B27)N-(3,4-디클로로페닐)프로판아미드(프로파닐),B27) N- (3,4-dichlorophenyl) propanamide (propanyl), B28)이마조설푸론(TH-913),B28) imazosulfuron (TH-913), B29)α-클로로-N-(3-메톡시-2-티에닐)메틸-2′,6′-디메틸아세트아닐리드(NSK-850), B30)4-에톡시벤즈-2′,3′-디하이드록로로아닐리드(HW-52), B31)1-디에틸카바모일-3-(2,6-트리메틸페닐-설포닐)-1,2,4-트리아졸(CH-(900)B29) α-chloro-N- (3-methoxy-2-thienyl) methyl-2 ', 6'-dimethylacetanilide (NSK-850), B30) 4-ethoxybenz-2', 3'- Dihydroloanilide (HW-52), B31) 1 -diethylcarbamoyl-3- (2,6-trimethylphenyl-sulfonyl) -1,2,4-triazole (CH- (900) B32)3-(2-클로로페닐메틸)-1-(1-메틸-1-페닐-에틸)우레아(JC-940) 및B32) 3- (2-Chlorophenylmethyl) -1- (1-methyl-1-phenyl-ethyl) urea (JC-940) and B33)2-(2-클로로-4-메실벤조일)사이클로헥산-1,3-디온(ICIA-0051)B33) 2- (2-Chloro-4-mesylbenzoyl) cyclohexane-1,3-dione (ICIA-0051) 제1항에 있어서, (a1)R1이 에톡시, 프로폭시 또는 이소프로폭시이고, R2가 6-위치에서 배향되고 상기 언급된 의미를 가지며, n이 0 또는 1이거나; 또는 (a2)R1이 할로겐에 의해 치환된 임의의 불포화 C1-C4-알콕시, C1-C4-알콕시, C1-C4-알킬티오 또는 -설피닐 또는 -설포닐, (C1-C4-알콕시)카보닐, NO2, CN 또는 페닐; 또한 C2-C5-알케닐옥시 또는 C2-C4-알키닐옥시이고, R2가 각각 상기 언급된 바와같이 치환될 수 있는 C1-C4-알킬, C2-C8-알케닐, (C1-C4-알콕시)카보닐, C1-C4-알콕시 또는 C1-C4-알킬티오이거나, 또는 할로겐이고, n이 0 또는 1이거나; 또는 (a3)R1이 메톡시, 에틸 또는 프로필이고, R2가 6-메톡시카보닐 또는 6-에톡시카보닐이고, n이 1이며, 상기 (a1) 내지 (a3) 모두에서, R3이 수소 또는 C1-C4-알킬이고, R4및 R5가 서로 독립적으로 할로겐, C1-C4-알킬, C1-C4-알콕시 또는 C1-C4-알킬티오(마지막 3개의 라디칼은 비치환되거나 할로겐, C1-C4-알콕시 또는 C1-C4-알킬티오에 의해 치환된다)이고, Y가 O 또는 S이고, E가 CH 또는 N인 일반식(Ⅰ)의 화합물 또는 그의 염을 포함하는 제초제.The compound of claim 1, wherein (a 1 ) R 1 is ethoxy, propoxy or isopropoxy, R 2 is oriented in the 6-position and has the meanings mentioned above and n is 0 or 1; Or (a 2 ) any unsaturated C 1 -C 4 -alkoxy, C 1 -C 4 -alkoxy, C 1 -C 4 -alkylthio or -sulfinyl or -sulfonyl, wherein R 1 is substituted by halogen; C 1 -C 4 -alkoxy) carbonyl, NO 2 , CN or phenyl; Also C 2 -C 5 -alkenyloxy or C 2 -C 4 -alkynyloxy, and R 2 may each be substituted as mentioned above with C 1 -C 4 -alkyl, C 2 -C 8 -al Is kenyl, (C 1 -C 4 -alkoxy) carbonyl, C 1 -C 4 -alkoxy or C 1 -C 4 -alkylthio, or halogen, n is 0 or 1; Or (a 3 ) R 1 is methoxy, ethyl or propyl, R 2 is 6-methoxycarbonyl or 6-ethoxycarbonyl, n is 1 and both of (a 1 ) to (a 3 ) are all R 3 is hydrogen or C 1 -C 4 -alkyl, and R 4 and R 5 are independently of each other halogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or C 1 -C 4 -alkyl Thio (the last three radicals are unsubstituted or substituted by halogen, C 1 -C 4 -alkoxy or C 1 -C 4 -alkylthio), Y is O or S, and E is CH or N A herbicide comprising the compound of (I) or a salt thereof. 제1항 또는 제2항에 있어서, 하기 일반식(A1), (A2) 및 (A3)의 화합물 또는 이들의 염중 하나 이상을 포함하는 제조체.The preparation according to claim 1 or 2, comprising at least one of the compounds of the following general formulas (A1), (A2) and (A3) or salts thereof. 제1항 내지 제3항중 어느 한 항에 있어서, 0.1 내지 99중량%의 활성물질 A 및 B를 통상의 제형화 보조제와 함께 포함하는 제초제.The herbicide according to any one of claims 1 to 3, comprising from 0.1 to 99% by weight of active substances A and B together with conventional formulation aids. 제1항 내지 제4항중 어느 한 항에 있어서, 활성물질들을 2-성분 혼합물의 경우에는 2:1 내지 1:200, 바람직하게는 1:1:1 내지 1:100의 중량비로, 3-성분 혼합물의 경우에는 2:1:1 내지 1:200:200, 바람직하게는 1:1:1 내지 1:100:100의 중량비로 포함하는 제초제.The three-component according to any one of claims 1 to 4, wherein the active substances are weighted in a weight ratio of 2: 1 to 1: 200, preferably 1: 1: 1 to 1: 100 in the case of a two-component mixture. In the case of a mixture, the herbicide comprises in a weight ratio of 2: 1: 1 to 1: 200: 200, preferably 1: 1: 1 to 1: 100: 100. 하나 이상의 화합물A와 하나 이상의 화합물B를, 습윤성 분말, 유화성 농축물, 수성 용액, 유화액, 분무용액, 오일 또는 물을 기재로 하는 분산액, 서스포유화액, 현탁성 농축물, 오일-혼화성 용액, 캡슐 현탁액, 미세과립 형태의 과립, 분무 과립, 피복 과립 및 흡착 과립, 분제, 종자-드레싱제, 토양 적용 또는 살포용 과립, 수-분산성 과립, ULV제형, 미세캡슐 및 왁스를 포함하는 그룹중에서 선택된 통상의 작물보호 생성물 제형과 유사하게 제형화함을 포함하는, 제1항 내지 제5항중 어느 한 항에 따른 제초제의 제조방법.At least one compound A and at least one compound B may be prepared from a wettable powder, an emulsifiable concentrate, an aqueous solution, an emulsion, a spray solution, a dispersion based on oil or water, a suspo emulsion, a suspension concentrate, an oil-miscible solution , Groups comprising capsule suspensions, granules in the form of microgranules, spray granules, coated granules and adsorbent granules, powders, seed-dressing agents, soil application or spraying granules, water-dispersible granules, ULV formulations, microcapsules and waxes A method for preparing the herbicide according to any one of claims 1 to 5, comprising formulating similarly to a conventional crop protection product formulation selected from. 제초 효과량의 제1 내지 제5항중 어느 한 항에 따른 제초제를 원치않는 식물 또는 이들의 서식지에 적용함을 포함하는, 원치않는 식물의 방제방법.A method of controlling unwanted plants, comprising applying the herbicides according to any one of claims 1 to 5 to unwanted plants or their habitats. 제7항에 있어서, 유용 작물에서의 잡초를 방제하는 방법.8. The method of claim 7, wherein the weeds in the useful crop are controlled. 제8항에 있어서, 상기 유용 작물이 밀, 보리, 호밀, 벼 및 옥수수를 포함하는 그룹중에서 선택되는 방법.The method of claim 8, wherein said useful crop is selected from the group comprising wheat, barley, rye, rice and corn. 유용 작물에서의 잡초를 방제하기 위한, 제1항 내지 제5항중 어느 한 항에 따른 제초제의 용도.Use of the herbicide according to any one of claims 1 to 5 for controlling weeds in useful crops. 농작물을 제초제의 식물독성 부작용에 대해 보호하기 의한 제1항에 정의된 유형 B 화합물의 용도.Use of a type B compound as defined in claim 1 for protecting crops against phytotoxic side effects of herbicides. 농작물을 제1항에 정의된 유형 A 제초제의 식물독성 부작용에 대해 보호하기 위한 제1항에 정의된 유형 B 화합물의 용도.Use of a type B compound as defined in claim 1 to protect the crop against phytotoxic side effects of the type A herbicide as defined in claim 1. 농작물을 제초제의 식물독성 부작용에 대해 보호하기 위한 제1항에 따른 일반식(B19) 또는 (B32)의 화합물의 용도.Use of a compound of formula (B19) or (B32) according to claim 1 for protecting crops against phytotoxic side effects of herbicides. 농작물을 제1항에 정의된 일반식(Ⅰ)화합물 유형의 제초제의 식물독성 부작용에 대해 보호하기 위한 제1항에 정의된 일반식 (B19) 또는 (B32)의 화합물의 용도.Use of a compound of formula (B19) or (B32) as defined in claim 1 for protecting crops against phytotoxic side effects of herbicides of the formula (I) compound type as defined in claim 1. 제1항에 따른 유형 B화합물과 혼합된 제초제를 식물, 식물의 종자 또는 그들의 서식지에 적용함을 포함하는, 제초제의 식물 독성 부작용에 대해 유용한 식물을 보호하는 방법.A method of protecting a plant useful against phytotoxic side effects of herbicides comprising applying a herbicide mixed with a type B compound according to claim 1 to the plant, the seed of the plant or their habitat. 제15항에 있어서, 제1항에 정의된 유형 A 제초제를 제1항에 정의된 유형 B의 화합물과 혼합하는 방법.The method of claim 15, wherein the type A herbicide as defined in claim 1 is mixed with a compound of type B as defined in claim 1. 제15항에 있어서, 제1항에 따른 일반식 (B19) 또는 (B32)의 화합물과 혼합된 제초제를 사용하는 방법.16. The process according to claim 15, wherein a herbicide mixed with a compound of formula (B19) or (B32) according to claim 1 is used. 제16항에 있어서, 제1항에 정의된 유형 A유형의 제초제를 제1항에 정의된 일반식 (B19) 또는 (B32)의 화합물과 함께 사용하는 방법.The method of claim 16, wherein a herbicide of type A as defined in claim 1 is used in combination with a compound of formula (B19) or (B32) as defined in claim 1. 제1항 내지 제4항중 어느 한 항에 있어서, 유형 A의 화합물과 디므론과의 환합물중에서, 중량비가 1:0.1 내지 1:50, 바람직하게는 1:1 내지 1:30, 특히 1:10 내지 1:30인 제초제.The compound according to any one of claims 1 to 4, wherein the weight ratio of the compound of type A and dimron is from 1: 0.1 to 1:50, preferably from 1: 1 to 1:30, in particular 1: Herbicide of 10 to 1:30. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930004620A 1992-03-24 1993-03-24 Synergistic herbicides and safeners KR100320834B1 (en)

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DE19518837A1 (en) * 1994-06-03 1995-12-07 Basf Ag Herbicide compsns.
KR970073338A (en) * 1996-05-23 1997-12-10 에들러 마크 에스. Herbicidal compositions showing synergistic action and weed control method using the same
DE19832017A1 (en) * 1998-07-16 2000-01-27 Hoechst Schering Agrevo Gmbh Synergistic selective herbicidal composition, especially for use in rice, containing phenylsulfonylurea derivative and e.g. benthiocarb, pendimethalin or ethoxysulfuron
WO2000003592A2 (en) * 1998-07-16 2000-01-27 Aventis Cropscience Gnbh Herbicidal agents with substituted phenoxysulfonylureas
ECSP024321A (en) 2001-10-05 2003-05-26 Syngenta Participations Ag HERBICIDE COMPOSITION
SA05260065B1 (en) * 2004-03-26 2009-12-29 سينجنتا بارتيسيبيشنزا ايه جى A Herbicidal Combination
ITMI20062368A1 (en) 2006-12-11 2008-06-12 Isagro Spa HERBICIDE COMPOSITIONS

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KR100540357B1 (en) * 1998-04-03 2006-01-12 바이엘 크롭사이언스 케이. 케이. Agrochemical Granules

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