KR930012905A - 폴리카보실란의 제조방법 - Google Patents

폴리카보실란의 제조방법 Download PDF

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Publication number
KR930012905A
KR930012905A KR1019910022586A KR910022586A KR930012905A KR 930012905 A KR930012905 A KR 930012905A KR 1019910022586 A KR1019910022586 A KR 1019910022586A KR 910022586 A KR910022586 A KR 910022586A KR 930012905 A KR930012905 A KR 930012905A
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KR
South Korea
Prior art keywords
polysilamethylrenosilane
polysilamethylenenosilane
mol
raw material
methyl
Prior art date
Application number
KR1019910022586A
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English (en)
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KR950006726B1 (ko
Inventor
정일남
이규환
석미연
Original Assignee
박원희
한국과학기술연구원
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Application filed by 박원희, 한국과학기술연구원 filed Critical 박원희
Priority to KR1019910022586A priority Critical patent/KR950006726B1/ko
Publication of KR930012905A publication Critical patent/KR930012905A/ko
Application granted granted Critical
Publication of KR950006726B1 publication Critical patent/KR950006726B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/60—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/02—Polysilicates

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Silicon Polymers (AREA)

Abstract

내용 없음

Description

폴리카보실란의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 다음 일반식(II)의 폴리실라메틸레노실란을 1-30기압하, 350-600℃의 온도에서 열적재배열반응시키는 것으로 됨을 특징으로 하는 일반식(I)의 폴리카보실란의 제조방법.
    상기 식중, 일반식(II)에 있어서 R2는 메틸기 또는 페닐기, R3는 메틸이거나 규소와 규소의 결합이고, x, y, z, n 및 m은 상수이며, a부분은 2, 4, 6-트리실라헵탄, b부분은 디메틸디클로로실란, c부분은 트리클로로실란을 탈염소화시켜서 얻은 것이다.
  2. 제1항에 있어서, 2, 4, 6-트리실라헵탄이 25몰%이상 포함된 폴리실라메틸레노실란을 원료로 사용하는 방법.
  3. 제1항에 있어서, 디메틸디클로로실란이 75몰%이하로 포함된 폴리실라메틸레노실란을 원료로 사용하는 방법.
  4. 제1항에 있어서, 메틸 또는 페닐기가 포함된 트리클로로실란이 10몰%이하로 포함된 폴리실라메틸레노실란을 원료로 사용하는 방법.
  5. 제1항에 있어서, 폴리실라메틸레노실란의 열적재배열반응을 1-20기압의 압력범위에서 수행하는 것이 특징인 방법.
  6. 제1항에 있어서, 폴리실라메틸레노실란의 열적재배열반응을 400-500℃의 온도범위에서 수행하는 것이 특징인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910022586A 1991-12-10 1991-12-10 폴리카보실란의 제조방법 KR950006726B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019910022586A KR950006726B1 (ko) 1991-12-10 1991-12-10 폴리카보실란의 제조방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019910022586A KR950006726B1 (ko) 1991-12-10 1991-12-10 폴리카보실란의 제조방법

Publications (2)

Publication Number Publication Date
KR930012905A true KR930012905A (ko) 1993-07-21
KR950006726B1 KR950006726B1 (ko) 1995-06-21

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ID=19324498

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Application Number Title Priority Date Filing Date
KR1019910022586A KR950006726B1 (ko) 1991-12-10 1991-12-10 폴리카보실란의 제조방법

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004042531A1 (de) * 2004-05-03 2005-12-15 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Polysilan-Polycarbosilan-Copolymer-Lösungen und daraus hergestellte sauerstoffarme keramische Formkörper mit Zusammensetzungen nahe SiC

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Publication number Publication date
KR950006726B1 (ko) 1995-06-21

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